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Landslide deposits preserved in the geological record afford opportunities to better inform hillslope and seismic hazard and risk models, particularly in regions where observational records are short. In the Southern Alps of New Zealand, small coseismic landslides are frequent, but the geological record preserves several instances of more substantial (> 1 km3) but infrequent mass failures. With an estimated volume of 27 km3, the giant Green Lake Landslide represents one of the largest subaerial landslides on Earth. Previous work has suggested this deep-seated mass movement was most likely triggered by high-intensity seismic shaking, but that local structural weakness and/or glacial debuttressing may help to explain the anomalously large failure volume. Resolving the potential contribution of the latter is important given predictions concerning alpine deglaciation in the coming decades to centuries. Key to resolution are secure chronologies of landslide emplacement and past glacier change. Here we present in situ cosmogenic 10Be exposure ages from the Green Lake Landslide that suggest an emplacement age of 15.5 ± 0.7 ka. Recent work shows that glacial retreat in the region was underway by 19 ka, indicating that the Green Lake Landslide was emplaced 3–4 kyr after the onset of glacier retreat. Given the geometry of the former confining valley glacier, we expect that the deglaciation-landslide age gap is closer to the upper end of this estimate. If correct, this conclusion places greater weight on the roles of local geological structure and/or a great earthquake as factors contributing to the exceptionally large volume of this event.

This review focuses on the recognition of volcanic ash occurrences in marine sediment cores and on using their appearance and properties to deduce their origin. Widespread marine tephra layers are important marker horizons for both volcanological as well as general geological investigations. We describe ash detection by visual inspection and logging of sediment cores. Ash layer structure and texture, particle morphologies and lithological compositions of primary volcanic deposits are summarized and processes modifying them are discussed, both natural processes acting on and in the seafloor, i.e. erosion and bioturbation, and anthropogenic modifications during drilling/coring and core preparation. We discuss primary emplacement processes of marine fall and flow tephra deposits derived from either subaerial or submarine sources in order to identify distinguishing properties. We also elaborate on processes generating secondary, resedimented volcaniclastic layers such as submarine landslides and shelf erosion as well as fluvial input and ice-rafting, and how they can be distinguished from primary volcaniclastic deposits, which is essential in tephrostratigraphy. Finally, methods of tephra correlation between cores and on-land deposits/volcanoes are illustrated because they allow us to extend the 1D information from single cores to 3D distribution and facies changes of tephras and to bridge the land–sea gap.

Although analyses of tephra-derived glass shards have been undertaken in New Zealand for nearly four decades (pioneered by Paul Froggatt), our study is the first to systematically develop a formal, comprehensive, open-access reference dataset of glass-shard compositions for New Zealand tephras. These data will provide an important reference tool for future studies to identify and correlate tephra deposits and for associated petrological and magma-related studies within New Zealand and beyond. Here we present the foundation dataset for TephraNZ, an open-access reference dataset for selected tephra deposits in New Zealand. Prominent, rhyolitic, tephra deposits from the Quaternary were identified, with sample collection targeting original type sites or reference locations where the tephra's identification is unequivocally known based on independent dating and/or mineralogical techniques. Glass shards were extracted from the tephra deposits, and major- and trace-element geochemical compositions were determined. We discuss in detail the data reduction process used to obtain the results and propose that future studies follow a similar protocol in order to gain comparable data. The dataset contains analyses of glass shards from 23 proximal and 27 distal tephra samples characterising 45 eruptive episodes ranging from Kaharoa (636 ± 12 cal yr BP) to the Hikuroa Pumice member (2.0 ± 0.6 Ma) from six or more caldera sources, most from the central Taupō Volcanic Zone. We report 1385 major-element analyses obtained by electron microprobe (EMPA), and 590 trace-element analyses obtained by laser ablation (LA)-ICP-MS, on individual glass shards. Using principal component analysis (PCA), Euclidean similarity coefficients, and geochemical investigation, we show that chemical compositions of glass shards from individual eruptions are commonly distinguished by major elements, especially CaO, TiO2, K2O, and FeOtt (Na2O+K2O and SiO2/K2O), but not always. For those tephras with similar glass major-element signatures, some can be distinguished using trace elements (e.g. HFSEs: Zr, Hf, Nb; LILE: Ba, Rb; REE: Eu, Tm, Dy, Y, Tb, Gd, Er, Ho, Yb, Sm) and trace-element ratios (e.g. LILE/HFSE: Ba/Th, Ba/Zr, Rb/Zr; HFSE/HREE: Zr/Y, Zr/Yb, Hf/Y; LREE/HREE: La/Yb, Ce/Yb). Geochemistry alone cannot be used to distinguish between glass shards from the following tephra groups: Taupō (Unit Y in the post-Ōruanui eruption sequence of Taupō volcano) and Waimihia (Unit S); Poronui (Unit C) and Karapiti (Unit B); Rotorua and Rerewhakaaitu; and Kawakawa/Ōruanui, and Okaia. Other characteristics, including stratigraphic relationships and age, can be used to separate and distinguish all of these otherwise-similar tephra deposits except Poronui and Karapiti. Bimodality caused by K2O variability is newly identified in Poihipi and Tahuna tephras. Using glass-shard compositions, tephra sourced from Taupō Volcanic Centre (TVC) and Mangakino Volcanic Centre (MgVC) can be separated using bivariate plots of SiO2/K2O vs. Na2O+K2O. Glass shards from tephras derived from Kapenga Volcanic Centre, Rotorua Volcanic Centre, and Whakamaru Volcanic Centre have similar major- and trace-element chemical compositions to those from the MgVC, but they can overlap with glass analyses from tephras from Taupō and Okataina volcanic centres. Specific trace elements and trace-element ratios have lower variability than the heterogeneous major-element and bimodal signatures, making them easier to fingerprint geochemically.

Tephra deposits in Aotearoa New Zealand (ANZ) have been studied for >180 years. The now-global discipline of tephrochronology, which has some developmental roots in ANZ, forms the basis of a powerful chronostratigraphic correlational tool and age-equivalent dating method for geological, volcanological, palaeoenvironmental, and archaeological research in ANZ. Its utility is founded on the key principle that tephras or cryptotephras provide widespread isochrons in many different environments. In the first part of this article, we summarise the history of tephra studies in ANZ and then describe how tephras have been mapped, characterised, and correlated using field and laboratory-based methods. We document advances in geochemical fingerprinting of glass; tephra/cryptotephra detection and correlation by sediment-core scanning methods (e.g. X-radiography, CT imaging, XRF elemental analysis, magnetic susceptibility); statistical correlation methods; and dating of tephras/cryptotephras. We discuss the advent of ANZ cryptotephra studies (from mid-1970s) and their more-recent growth. The second part comprises examples of applications of tephrochronology in ANZ: climate-event stratigraphy (NZ-INTIMATE project); eruptive-event stratigraphy in the Auckland Volcanic Field; developments in the marine tephra record; advances in identifying, correlating, and dating old (pre-50 ka) tephras and weathered-tephra deposits; forming soils/paleosols on tephras; tephras and archaeology; Kopouatai bog tephrostratigraphy and palaeoenvironments; and volcanic-hazard assessments.

The accurate and precise reconstruction of Quaternary climate as well as the events that punctuate it is an important driver of the study of lake sediment archives. However, until recently lake sediment-based palaeoclimate reconstructions have largely concentrated on Northern Hemisphere lake sequences due to a scarcity of continuous and high-resolution lake sediment sequences from the Southern Hemisphere, especially from the southern mid-latitudes. In this context, the deep maar lakes of the Auckland Volcanic Field of northern New Zealand are significant as several contain continuous and well-laminated sediment sequences. Onepoto Basin potentially contains the longest temporal lake sediment record from the Auckland Volcanic Field (AVF), spanning from Marine Isotope Stage 6e (MIS 6e) to the early Holocene when lacustrine sedimentation was terminated by marine breach of the south-western crater tuff ring associated with post-glacial sea-level rise. The Onepoto record consists of two new, overlapping cores spanning ca. 73 m combined with archive material in a complete composite stratigraphy. Tephrochronology and 14C dating provide the fundamental chronological framework for the core, with magnetic relative palaeo-intensity variability downcore, and meteoric 10Be influx into the palaeolake to refine the chronology. The µ-XRF (micro X-ray fluorescence) downcore variability for the entirety of the lake sediment sequence has been established with measurement of a range of proxies for climate currently underway. This work will produce the first continuous record of the last 200 kyr of palaeoclimate from northern New Zealand to date.

Tephrochronology is of paramount importance in New Zealand where paleoclimate studies use ages of volcanic ash layers as chronological makers. Maar lakes in the Auckland Volcanic Field (AVF) are ch...

A 9.3-m-long lake sediment core from dune-impounded Lake Kai Iwi in Northland, New Zealand provides a nearly continuous record of environmental changes from multi-proxy organic, physical index, and µ-XRF elemental data sets. The chronology for the upper 3 m of the core was established by 210Pb, 14C and tephrochronology and includes Marine Isotope Stage (MIS) 1 (Holocene), MIS 2 and late MIS 3. From this well-dated section of the core stratigraphy we were able to infer the environmental proxies that respond to wind and/or precipitation during cool periods (MIS 2 and 4) and with the warm periods (MIS 1 and 5). Principal component analysis (PCA) and cluster analysis were performed on the µ-XRF elemental data set including elements common in lake sediments (P, S, Fe, Ti, K, Ca, and Si) and five ratios (Sr/Ca, Br/Cl, Mn/Fe, Ti/K, and Inc/coh) to identify patterns in the µ-XRF proxy data associated with environmental change manifesting as changes in precipitation and wind deposition. The PCA indicates that Component (PC)-1 represents detrital versus organic deposition, and PC-2 is associated with nutrient influx versus anoxic conditions in the lake. The cool periods of MIS 2 and 4 are apparent in the µ-XRF data as having increased detrital influx in the form of Sr/Ca from marine derived sediments from the exposed continental shelf during low sea level indicating cool and dry conditions. Warmer and wetter periods (MIS 1 and 5) are identified by increased Ti/K influx from precipitation runoff and increased organic productivity as shown by Inc/coh and total organic carbon. The Holocene warm equivalent conditions of MIS 5e are not represented in the lower part of the Lake Kai Iwi core stratigraphy consistent with an extrapolated basal age of 117 ± 8.5 ka BP.

Auckland Volcanic Field (AVF) is a basaltic intraplate volcanic field in North Island, New Zealand, upon which >1.6 million people live. Seismic velocity tomography and geochemistry suggest a prima...

Tephra deposits are used by many disciplines of the natural sciences, not only for gaining important insight into volcanism, but also for chronological purposes, especially the dating of sedimentary sequences throughout geological time. Use of these deposits as isochronous tie points relies on the ability to accurately correlate tephra from one site to another including more diffuse, distal sites, as well as to possibly identify the source eruption. However, the ability to uniquely identify tephra deposits, and thus correlate them with certainty, is not without its complications. Here we present a case study from North Island, New Zealand, to highlight the complications and intricacies of achieving robust tephra deposit correlations. We highlight three key issues including: 1) the large uncertainties associated with direct dating techniques for older (≥1 Ma) tephra horizons; 2) the lack of/or minimalist amount of published and accessible geochemical data; and 3) the lack of data pertaining to the source regions themselves. We report new age and geochemical data for tephra deposits from a region that has been the depositional site of many eruptions since at least 12 Ma. Of the tephra horizons sampled in this region, six contained sufficient zircons for fission-track dating. Ages of the horizons range from 1.4 to 5.7 Ma, in good agreement with previously assigned age constraints based on biostratigraphic and/or paleomagnetic markers. However, the precision of these ages (2σ uncertainties of ±0.4–1.6 Ma) is insufficient to correlate the tephra horizons to either their specific source (eruption event) or alternative tephra deposits using geochronology alone. Therefore, in addition to the new (and existing) age data, we present the results of major and trace element analysis of glass shards from 18 tephra horizons. For most horizons the geochemical signatures of the glass shards are internally homogeneous for both major and trace elements, suggesting a single source eruption. In a few cases, however, the tephra horizons exhibit heterogeneous geochemical signatures, which, when coupled with the deposit morphology, suggest evidence for reworking, post-depositional devitrification, and a more complex source history. We discuss correlation of the tephra horizons to onshore and offshore counterparts and also to source. Our results emphasise the importance of combining geochronological constraints with geochemical fingerprinting and additional parameters including stratigraphy to provide the most accurate correlations. As a result, we encourage the use of electronic storage files in publications to give access to full geochemical (including secondary standard data) and chronological datasets. This will not only allow complete characterisation of the tephra, but also facilitate rigorous statistical assessment to produce accurate correlation to other deposits in future studies.

Although analyses of tephra-derived glass shards have been undertaken in New Zealand for nearly four decades (pioneered by Paul Froggatt), our study is the first to systematically develop a formal, comprehensive, open access, reference dataset of glass-shard compositions for New Zealand tephras. These data will provide an important reference tool for future studies to identify and correlate tephra deposits and for associated petrological and magma-related studies within New Zealand and beyond. Here we present the foundation dataset for TephraNZ, an open access reference dataset for selected tephra deposits in New Zealand. Prominent, rhyolitic, tephra deposits from the Quaternary were identified, with sample collection targeting original type sites or reference locations where the tephra's identification is unequivocally known based on independent dating or mineralogical techniques. Glass shards were extracted from the tephra deposits and major and trace element geochemical compositions were determined. We discuss in detail the data reduction process used to obtain the results and propose that future studies follow a similar protocol in order to gain comparable data. The dataset contains analyses of twenty-three proximal and twenty-seven distal tephra samples characterising 45 eruptive episodes ranging from Kaharoa (636 ± 12 cal. yrs BP) to the Hikuroa Pumice member (2.0 ± 0.6 Ma) from six or more caldera sources, most from the central Taupō Volcanic Zone. We report 1385 major element analyses obtained by electron microprobe (EMPA), and 590 trace element analyses obtained by laser ablation (LA)-ICP-MS, on individual glass shards. Using PCA, Euclidean similarity coefficients, and geochemical investigation, we show that chemical compositions of glass shards from individual eruptions are commonly distinguished by major elements, especially CaO, TiO2, K2O, FeOt (Na2O+ K2O and SiO2/K2O), but not always. For those tephras with similar glass major-element signatures, some can be distinguished using trace elements (e.g. HFSEs: Zr, Hf, Nb; LILE: Ba, Rb; REE: Eu, Tm, Dy, Y, Tb, Gd, Er, Ho, Yb, Sm), and trace element ratios (e.g. LILE / HFSE: Ba / Th, Ba / Zr, Rb / Zr; HFSE / HREE: Zr / Y, Zr / Yb, Hf / Y; LREE / HREE: La / Yb, Ce / Yb). Geochemistry alone cannot be used to distinguish between glass shards from the following tephra groups: Taupō (Unit Y in the post-Ōruanui eruption sequence of Taupō volcano) and Waimihia (Unit S); Poronui (Unit C) and Karapiti (Unit B); Rotorua and Rerewhakaaitu; and Kawakawa/Ōruanui, Okaia, and Unit L (of the Mangaone subgroup eruption sequence). Other characteristics can be used to separate and distinguish all of these otherwise-similar eruptives except Poronui and Karapiti. Bimodality caused by K2O variability is newly identified in Poihipi and Tahuna tephras. Using glass shard compositions, tephra sourced from Taupō Volcanic Centre (TVC) and Mangakino Volcanic Centre (MgVC) can be separated using bivariate plots of SiO2/K2O vs. Na2O+K2O. Glass shards from tephras derived from Kapenga Volcanic Centre, Rotorua Volcanic Centre, and Whakamaru Volcanic Centre have similar major- and trace-element chemical compositions to those from the MgVC, but can overlap with glass analyses from tephras from Taupō and Okataina volcanic centres. Specific trace elements and trace element ratios have lower variability than the heterogeneous major element and bimodal signatures, making them easier to geochemically fingerprint.

Mid-latitude Southern Hemisphere proxy records of changing environment, especially those that demonstrate past variability of the South Westerly Winds (SWW), are poorly-constrained prior to the Last Glacial Interglacial Transition (LGIT; ca. 14–11.7 ka BP) and are typically located far enough south or north that they often do not reflect both tropical and SWW signals. With this deficiency in mind, we present a ca. 117 ± 8.5 ka BP lake sediment record from Lake Kai Iwi, Northland, New Zealand (~36°S), located at a latitude that demonstrates changes in precipitation associated with both the northward expansion of the SWW belt and from tropical El Nino Southern Oscillation (ENSO) variability. We converted Lake Kai Iwi μ-XRF proxy data to even time-steps in order to apply Morelet wavelet analysis for identification of millennial-scale periodicities in the data that were likely driven by orbital forcing. The results indicate that Lake Kai Iwi records a ~1 ka periodicity possibly associated with Northern Hemisphere ice sheet dynamics; a ~2–4 ka periodicity associated with ~2.4 ka Hallstatt solar cycles, and a ~9 ka periodicity linked to CO2 outgassing from upwelling in the Southern Ocean driven by changes in intensity and position of the SWW.

The Auckland Volcanic Field (AVF), which last erupted ca. 550 years ago, is a late Quaternary monogenetic basaltic volcanic field (ca. 500 km 2 ) in the northern North Island of New Zealand. Prior to this study only 12 out of the 53 identified eruptive centres of the AVF had been reliably dated. Careful sample preparation and 40 Ar/ 39 Ar analysis has increased the number of well-dated centres in the AVF to 35. The high precision of the results is attributed to selection of fresh, non-vesicular, non-glassy samples from lava flow interiors. Sample selection was coupled with separation techniques that targeted only the groundmass of samples with 10 μm wide, coupled with ten-increment furnace step-heating of large quantities (up to 200 mg) of material. The overall AVF age data indicate an onset at 193.2 ± 2.8 ka, an apparent six-eruption flare-up from 30 to 34 ka, and a ≤ 10 kyr hiatus between the latest and second-to-latest eruptions. Such non-uniformity shows that averaging the number of eruptions over the life-span of the AVF to yield a mean eruption rate is overly simplistic. Together with large variations in eruption volumes, and the large sizes and unusual chemistry within the latest eruptions (Rangitoto 1 and Rangitoto 2), our results illuminate a complex episodic eruption history. In particular, the rate of volcanism in AVF has increased since 60 ka, suggesting that the field is still in its infancy. Multiple centres with unusual paleomagnetic inclination and declination orientations are confirmed to fit into a number of geomagnetic excursions, with five identified in the Mono Lake, two within the Laschamp, one within the post-Blake or Blake, and two possibly within the Hilina Pali.

The Auckland Volcanic Field (AVF) represents the youngest and northernmost of three subjacent Quaternary intraplate basaltic volcanic fields in the North Island, New Zealand. Previous studies on AVF eruptive products suggested that their major- and trace-element, and Sr-, Nd- and Pb-isotopic signatures primarily reflect their derivation from the underlying asthenospheric and lithospheric mantle. All AVF lavas however ascend through a ca. 20–30 km thick continental crust, and some do carry crustal xenoliths, posing the question whether or not crustal contamination plays a role in their formation. Here we present new Os and Pb isotopic data, and Os and Re concentrations for 15 rock samples from 7 AVF volcanic centres to investigate mantle and crustal petrogenetic processes. The samples include the most primitive lavas from the field (Mg# 59–69) and span a range of eruption sizes, ages, locations, and geochemical signatures. The data show a large range in Os concentrations (6–579 ppt) and 187Os/188Os isotope ratios from mantle-like (0.123) to highly radiogenic (0.547). Highly radiogenic Os signatures together with relatively low Os contents in most samples suggest that ascending melts experienced contamination primarily from metasedimentary crustal rocks with high 187Os/188Os ratios (e.g., greywacke). We further demonstrate that < 1% metasedimentary crustal input into the ascending melt can produce the radiogenic Os isotope signatures observed in the AVF data. This low level of crustal contamination has no measurable effect on the corresponding trace element ratios and Sr-Nd-Pb isotopic compositions. In addition, high Os contents (195–578 ppt) at slightly elevated but mantle-like Os isotopic compositions (187Os/188Os = 0.1374–0.1377) in some samples suggest accumulation of xenocrystic olivine-hosted mantle sulphides from the Permian-Triassic ultramafic Dun Mountain Ophiolite Belt, which traverses the crust beneath the Auckland Volcanic Field. We therefore infer that the AVF Os isotopic compositions and Os contents reflect contamination from varying proportions of heterogeneous crustal components, composed of Waipapa and Murihiku terrane metasediments, and ultramafic rocks of the Dun Mountain Ophiolite Belt. This demonstrates, contrary to previous models that primitive lavas from the Auckland Volcanic Field do show evidence for variable interaction with the crust.

Highlights • Sedimentary characteristics and geochemistry of tephra deposits are reported across 21 cores. • Four types of tephra lithofacies are distinguished. • Geomorphic sub-environments play a key role in tephra preservation. • Isolated semi-confined basin settings generally preserve the highest number of tephra deposits. • For eruptions VEI≥6 volcaniclastic sediments may swamp the marine system for centuries. Tephra (volcanic ash) deposits are important isochronous markers for correlating marine sediments or events recorded in marine sediment cores. However, the active tectonics that are commonly associated with volcanic activity at plate tectonicboundaries also drive large-scale deformation, leading to steep and variable local and regional bathymetry (e.g., ridges, basins and canyons systems). This complex bathymetry influences gravity-flow behaviour and paths, which can rework and redeposit tephras, resulting in stratigraphic complexities. Such as, the mis-identification of primary versus reworked tephra deposits, and in turn lead to the development of inaccurate chronostratigraphies. Here we present 36 tephra deposits from 21 shallow marine sediment cores that traverse the length of the southern and central margin of eastern North Island, New Zealand. Using major and trace element geochemical compositions for glass shards from the tephras, we correlate these deposits to three major rhyolitic eruptions from the Taupō Volcanic Zone (TVZ) approximately 200 km west, including; Taupō (1718 cal yrs. BP), Kaharoa (636 cal yrs. BP), and Kawakawa/Oruanui (KOT; 25.4 ka). Based on their morphology, depositional character and inferred emplacement mechanisms, the tephra deposits are grouped into four lithofacies types; (1) primary deposits, (2) volcaniclastic-rich turbidites, (3) blebs/pods of volcaniclastic-rich material, and (4) complex deposits. Primary deposits form syn-eruptively through airfall onto the ocean surface, settling over hours to days through the water column under diffuse vertical gravity currents. Volcaniclastic-rich turbidites are formed through secondary redeposition and entrainment by post-eruptive turbidity currents, while blebs/pods of material are interpreted to have formed by erosion and/or bioturbation. Complex deposits form through the interaction of all these mechanisms producing an overthickened array of primary and redeposited units within a single facies. Herein, we argue that redeposited units of volcaniclastic-rich turbidites or small blebs/pods can be used as tentative chronological markers if the geochemical composition of the glass shards have a homogeneous signature, i.e. a single eruptive source. Where the glass shards in redeposited units have mixed geochemical compositions, and are not stratigraphically associated with a primary deposit source, they cannot be used as chronological marker horizons. This emphasises the need for accurate and rigorous data reduction without overlooking the importance of data points that are statistical outliers. We also show that the highest preservation of tephra deposits is found in semi-confined isolated basin settings, including a wide range of deposit types. Due to erosive sediment flows that bypass through submarine distributary systems, these major sediment dispersal pathways preserve few volcaniclastic deposits. Our findings have important implications not only for identifying primary or redeposited characteristics in marine tephras for building accurate chronostratigraphies, but also as a guide geomorphic sub-environments with the best preservation of tephras in marine sedimentary systems.