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11 results on '"Jin, Huaimin"'

7. Monometallic Endohedral Azafullerene

Author

Xiang, Wenhao, primary, Jiang, Xiaole, additional, Yao, Yang-Rong, additional, Xin, Jinpeng, additional, Jin, Huaimin, additional, Guan, Runnan, additional, Zhang, Qianyan, additional, Chen, Muqing, additional, Xie, Su-Yuan, additional, Popov, Alexey A., additional, and Yang, Shangfeng, additional

Published
2022
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8. TmCN@C 82 : Monometallic Clusterfullerene Encapsulating a Tm 3+ Ion.

Author

Zhang, Huichao, Xin, Jinpeng, Jin, Huaimin, Xiang, Wenhao, Chen, Muqing, Yao, Yang-Rong, and Yang, Shangfeng

Subjects
METAL cyanides, FULLERENES, MOLECULAR structure, X-ray crystallography, IONS, OXIDATION states
Abstract

Metal cyanide clusterfullerenes (CYCFs) are formed via the encapsulation of a single metal atom and a cyanide unit inside fullerene cages, endowing them with excellent properties in various applications. In this work, we report the synthesis, isolation, and characterizations of the first cases of thulium (Tm)-based CYCFs with the popular C82 carbon cages. The structural elucidation of the two TmCN@C82 isomers was achieved via diverse analytical techniques, including mass spectrometry, Vis-NIR spectroscopy, single-crystal X-ray crystallography, and cyclic voltammetry. The crystallographic analyses unambiguously confirmed the molecular structures of the two TmCN@C82 isomers as TmCN@Cs(6)-C82 and TmCN@C2v(9)-C82. Both TmCN clusters adopt a well-established triangular configuration, with the Tm ion located on the symmetrical plane of the carbon cages. The electronic structures of both TmCN@C82 isomers adopt a Tm3+(CN)−@(C82)2− configuration, exhibiting characteristic spectral and electrochemical properties reminiscent of divalent endohedral metallofullerenes (EMFs). Intriguingly, unlike the divalent Tm2+ ion observed in the mono-metallofullerenes Tm@C2n, a higher oxidation state of Tm3+ is identified in the monometallic TmCN cluster due to bonding with the cyanide anion. This result provides valuable insight into the essential role of the non-metallic endo-units in governing the oxidation state of the metal ion and the electronic behaviors of EMFs. [ABSTRACT FROM AUTHOR]

Published
2023
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11. All‐Sprayed‐Processable, Large‐Area, and Flexible Perovskite/MXene‐Based Photodetector Arrays for Photocommunication

Author

Deng, Wen, primary, Huang, Haichao, additional, Jin, Huaimin, additional, Li, Wen, additional, Chu, Xiang, additional, Xiong, Da, additional, Yan, Wei, additional, Chun, Fengjun, additional, Xie, Meilin, additional, Luo, Chao, additional, Jin, Long, additional, Liu, Chuanqi, additional, Zhang, Haitao, additional, Deng, Weili, additional, and Yang, Weiqing, additional

Published
2019
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