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Stirring-promoted piezo-photocatalysis based on a three-dimensional foam architecture has great potential applications in wastewater treatment and water splitting. However, the detailed mechanism of stirring-promoted piezo-photocatalysis has not been quantitatively studied, and the utilization of visible light needs to be further improved. In this work, the high solar-driven piezo-photocatalytic ability of graphite carbon nitride (g-C

Photoassociation (PA) spectroscopy of Na spin-1 Bose–Einstein Condensate (BEC) was obtained and analyzed.

The Wigner function of the compass state (a superposition of four coherent states) develops phase-space structures of dimension much less than the Planck scale, which are crucial in determining the sensitivity of these states to phase-space displacements. In the present work, we introduce compass-like states that may have connection to the contemporary experiments, which are obtained by either adding photons to or subtracting photons from the superposition of two squeezed-vacuum states. We show that, when a significant quantity of photons is added (or subtracted), the Wigner function of these states are shown to have phase-space structures of an area that is substantially smaller than the Planck scale. In addition, these states exhibit sensitivity to displacements that is much higher than the standard quantum limit. Finally, we show that both the size of the sub-Planck structures and the sensitivity of our states are strongly influenced by the average photon number, with the photon addition case having a higher average photon number leading to the smaller sub-Planck structures and, consequently, being more sensitive to displacement than the photon subtraction case. Our states offer unprecedented resolution to the external perturbations, making them suitable for quantum sensing applications., Comment: PHYSICAL REVIEW A 107, 052614 (2023), 15 Figures, 20 pages

We have already reported the modification on the piperazine and phenyl rings of JNJ4796, a small-molecule fuse inhibitor targeting hemagglutinin (HA). In this study, we described the structure-activity relationship of the benzoxazole and tetrazole rings of JNJ4796. Many derivatives demonstrated good in vitro activity against IAV H1N1and Oseltamivir-resistant IAV H1N1 stains. Although compounds (R)-1e and (R)-1h exhibited excellent in vitro activity, high drug exposure level and low hERG inhibition, they displayed low oral efficacy. Excitedly, (R)-1a, a representative identified in our previous study, was found to show potent in vivo anti-IAV activity with the survival rates of 100%, 100% and 70% at 15, 5 and 1.67 mg/kg, respectively, comparable to JNJ4796. Currently, we are exploring different ways to ease its gastrointestinal response.

Revealing the charge transfer path is very important for studying the photocatalytic mechanism and improving photocatalytic performance. In this work, the charge transfer path turned by the piezoelectricity in Ag-BaTiO3 nanofibers is discussed through degrading methyl orange. The piezo-photocatalytic degradation rate of Ag-BaTiO3 is much higher than the photocatalysis of Ag-BaTiO3 and piezo-photocatalysis of BaTiO3, implying the coupling effect between Ag nanoparticle-induced localized surface plasmon resonance (LSPR), photoexcited electron-hole pairs, and deformation-induced piezoelectric field. With the distribution density of Ag nanoparticles doubling, the LSPR field increases by one order of magnitude. Combined with charge separation driven by the piezoelectric field, more electrons in BaTiO3 nanofibers are excited by plasmon-induced resonance energy transfer to improve the photocatalytic property.

Topological insulators host topology-linked boundary states, whose spin and charge degrees of freedom could be exploited to design topological devices with enhanced functionality. We experimentally observe that dissipationless chiral edge states in a spin-orbit coupled anomalous Floquet topological phase exhibit topological spin texture on boundaries, realized via a two-dimensional quantum walk. Our experiment shows that, for a walker traveling around a closed loop along the boundary in real space, its spin evolves and winds through a great circle on the Bloch sphere, which implies that edge-spin texture has nontrivial winding. This winding is linked to the bulk Dirac Hamiltonian around the energy-gap opening point. Our experiment confirms that two-dimensional anomalous Floquet topological systems exhibit topological spin texture on the boundary, which could inspire novel topology-based spintronic phenomena and devices., Comment: 6 pages, 4 figures

We study the effects of magnetic Feshbach resonance on the shifts in photoassociation (PA) spectra of ultracold Cs atoms. A series of atom loss spectra show a linear variation of the frequency shift with the PA laser intensity at different magnetic fields near the d-wave Feshbach resonance of optically trapped Cs atoms. The magnetic field-dependence of the slope of the shift on the PA laser intensity exhibits a dispersive change near the Feshbach resonance. The theoretical formula derived from a model based on Fano resonance fits well with the experimental data. Using a model rectangular potential with tunable well depth and applying the Franck-Condon principle, we obtain numerical results, which are found to be largely in disagreement with the experimental findings.

Metal-semiconductor piezo-photocatalysts are generally investigated due to their high photocatalytic performances by the coupling effect of piezotronics and localized surface plasmon resonance (LSPR). However, the mechanism is still indistinct, even the charge migration route is disputable. Here, the electron migration from Ag to BaTiO3 has been confirmed by electron spin resonance (ESR) and radical trapping experiments. Furthermore, this work first proposes that piezoelectric field can promote the photocatalytic properties through electrical modulation of plasmon-exciton interaction. To exactly reveal the mechanism, the piezo-photocatalysis process is fully simulated by numerical analysis and finite element method (FEM). The unabridged mechanism of piezotronics boosted photocatalysis of LSPR-BaTiO3 shows that piezoelectric field can modulate LSPR to generate more hot electrons, suppress Schottky barrier for improved hot electron injection from Ag to BaTiO3 and restrain the recombination of electron–hole pairs by spatial separation of opposite charges.

A multiphoton collective phase is a multiphoton-scattering feature that cannot be reduced to a sequence of two-photon scattering events, and the three-photon "triad phas" is the smallest nontrivial example. Observing a higher-order collective phase is experimentally challenging, and only triad and four-photon tetrad collective phases have been observed. We introduce a scheme to make higher-order multiphoton collective-phase observations feasible by designing a sparse interferometer, which significantly reduces complexity compared with the current best scheme for observing a multiphoton collective phase. Specifically, our scheme reduces the optical depth from logarithmic to constant and reduces the number of beam splitters from $O(n\log n)$ to linear scaling with respect to the collective-phase order $n$. As constant depth reduces loss and dispersion to a fixed rate regardless of collective-phase order, a major obstacle to observing large-scale collective phases is removed., 15 pages, 4 figures

A mobility edge, a critical energy separating localized and extended excitations, is a key concept for understanding quantum localization. The Aubry-André (AA) model, a paradigm for exploring quantum localization, does not naturally allow mobility edges due to self-duality. Using the momentum-state lattice of quantum gas of Cs atoms to synthesize a nonlinear AA model, we provide experimental evidence for a mobility edge induced by interactions. By identifying the extended-to-localized transition of different energy eigenstates, we construct a mobility-edge phase diagram. The location of a mobility edge in the low- or high-energy region is tunable via repulsive or attractive interactions. Our observation is in good agreement with the theory and supports an interpretation of such interaction-induced mobility edge via a generalized AA model. Our Letter also offers new possibilities to engineer quantum transport and phase transitions in disordered systems.

Organic compounds of actinyls and their bonding features have attracted extensive attention in nuclear waste separation due to their characteristics of separating fission products. Herein, detailed studies on the binding sites of [AnO2(COOH) n (H2O) m ]2-n (An = U, Np, Pu, and Am; n = 1-3; m = 0, 2, 4; 2n + m = 6) complexes toward Cs are predicted by calculation, and their electronic excitation characteristics were illustrated, providing theoretical supports for the design of Cs adsorbents. The quantum theory of atom in molecules and electron localization function have been implemented to analyze the chemical bonding characterization. The covalent character of An-OC bonds become weaker with increasing COOH- ligands, and the covalent interaction in An-OC bonds is more obvious than that in An-OH bonds. Total and partial population density of state suggest that the 2p orbits of O have more significant contribution in the low-energy region atoms and the 6d/5f orbits of An have more significant contribution in the high-energy region. The Cs+ best adsorption site on [UO2(COOH)2(H2O)2] and [UO2(COOH)3]- is the adjacent oxalates, and the [UO2(COOH)3]- complexes have better adsorption capacity. Besides, the electronic excitation characteristics of Cs+ adsorption on the UO2(COOH)2(H2O)2 complex were analyzed by the UV-vis spectrum and hole-electron distribution.

We report new observations of the hyperfine structure in three ro-vibrational levels of the b3Π2 state of NaCs near the dissociation limit 3S1/2 + 6P3/2. The experiment was done via photoassociation of ultracold atoms in a dual-species dark-spot magneto-optical trap, and the spectra were measured as atomic trap losses. The simulation of the hyperfine structure showed that the greater part of the observed structure belongs to almost isolated levels of the b3Π2 state, but there are other parts of mixed character where the contribution from the 1Σ symmetry dominates.

Herein, we report on the experimental observations and a quantitative determination of the laser-induced frequency shift (LIFS) in the photoassociation (PA) spectra of spinor Bose-Einstein condensate of sodium. Our investigations revealed a nonlinear dependence of the LIFS on the intensity of PA laser. By developing a model within the quadratic Stark effect, we simulate the experimental results via a theoretical model that confirms the former. The experimental observations and the theoretical analysis can further improve the accuracy of investigations on important molecular properties and on preparation of specific molecular states, with possible applications in various key fields.

We perform ab initio simulations of beryllium (Be) and magnesium oxide (MgO) at megabar pressures and compare their structural and thermodynamic properties. We make a detailed comparison of our two recently derived phase diagrams of Be (Wu et al 2021 Phys. Rev. B 104 014103) and MgO (Soubiran and Militzer 2020 Phys. Rev. Lett. 125 175701) using the thermodynamic integration technique, as they exhibit striking similarities regarding their shape. We explore whether the Lindemann criterion can explain the melting temperatures of these materials through the calculation of the Debye temperature at high pressure. From our free energy calculations, we find that the melting line of both materials is well represented by the Simon–Glazel fit T m(P) = T 0(1 + P/a)1/c , where T 0 = 1564 K, a = 15.8037 GPa and c = 2.4154 for Be, while T 0 = 3010 K, a = 10.5797 GPa and c = 2.8683 for the MgO in the B1. For the B2 phase, we use the values a = 26.1163 GPa and c = 2.2426. Both materials exhibit negative Clapeyron slopes on the boundaries between the two solid phases that are strongly affected by anharmonic effects, which also influence the location of the solid–solid–liquid triple point. We find that the quasi-harmonic approximation underestimates the stability range of the low-pressure phases, namely hcp for Be and B1 for MgO. We also compute the phonon dispersion relations at low and high pressure for each of the phases of these materials, and also explore how the phonon density of states is modified by temperature. Finally, we derive secondary shock Hugoniot curves in addition to the principal Hugoniot curve for both materials, and study their offsets in pressure between solid and liquid branches.

External-cavity diode laser (ECDL) has important applications in many fundamental and applied researches. Here we report a method to fast and widely tune the frequency of a stabilized ECDL. The beat frequency between the ECDL and a frequency-locked reference laser is identified by the voltage-controlled oscillator contained in a phase detector, whose output voltage is subtracted from the flexibly controlled PC signal to generate an error signal for stabilizing the ECDL. The output frequency of the stabilized ECDL can be shifted at a short characteristic time of ∼ 150 μs within a range of ∼ 620 MHz. The wide and fast-frequency tuning achieved by our method is compared with other previous works. We demonstrated the performance of our method by the efficient sub-Doppler cooling of Cs atoms with the temperature as low as 6 μK.

Background: Mycobacterium tuberculosis complex (MTBC) is the causative agent of tuberculosis (TB), which comprises several phylogenetically distinct lineages associated with different geographical regions. The Global Health Security Index (GHSI) has been developed to measure a country's capacity to cope with a public health emergency, but it lacks sufficient evidence corresponding association between GHSI and drug-resistant TB (DR-TB). The objectives of this study were to map the global distribution of MTBC lineage and to explore the correlation between GHSI and the prevalence of DR-TB globally. Methods: The GHSI, whole-genome sequencing (WGS), and verified data of TB were extracted from the online database, including the GHSI website, TBProfiler website, and Global Tuberculosis Report, respectively. We mapped the global geographic distribution of MTBC lineages. The hierarchical structure was visualized in different continents and sublineages, while the DR-TB was visualized by an error bar plot. We also performed two-dimensional twisted surface and interaction plots to explore the interaction between GHSI and gross domestic product (GDP) per capita on the prevalence of DR-TB. Findings: Lineage 4 was widely distributed globally and followed by East Asian lineage 2. Lineage 2 had the highest risk of developing DR-TB. We observed an interaction between ln(GHSI) and ln(GDP per capita) on the prevalence of multidrug-resistant TB (MDR-TB). We revealed a negative association between ln(GHSI) and DR-TB in countries whose ln(GDP per capita) were greater than 2.35. Interpretation: Lineage 4 is the most widely distributed, and lineage 2 is the most prevalent lineage with DR-TB. There was a negative association between GHSI and DR-TB but not in the countries with low income. More funding is needed to “End TB targets”, especially in low-income countries. Funding Statement: This study was funded by the National Key R&D Program of China (2017YFC0907000), Key Project of Philosophy and Social Science Research in Colleges and Universities in Jiangsu Province (2020SJZDA096), National Natural Science Foundation of China (81973103), and Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD). Declaration of Interests: The authors report no conflicts of interest in this work. Ethics Approval Statement: This study was approved by the ethics committee of Nanjing Medical University.

We develop a research of spin currents in a 23Na spinor Bose–Einstein condensate (BEC) by applying a magnetic field gradient. The spin current is successfully induced by the spin-dependent force arising from the magnetic field gradient. The dynamics of the spin components under the magnetic force is investigated. The study is promising to be extended to produce a longer spin-coherence and to enhance the sensitivity of the spin-mixing interferometry in a spinor BEC.

The study aims to describe the clustering characteristics of Mycobacterium tuberculosis (M.tb) strains circulating in eastern China and determine the ratio of relapse and reinfection in recurrent patients. We recruited sputum smear-positive pulmonary tuberculosis cases from five cities of Jiangsu Province, China, during August 2013 and December 2015. Patients were followed for the treatment outcomes and recurrence based on a cohort design. M.tb strains were isolated and genotyped using the 12-locus MIRU-VNTR. The Beijing family was identified by the extended Region of Difference (RD) analysis. The Hunter-Gaston Discriminatory Index (HGDI) was used to judge the resolution ability of MIRU-VNTR. The odds ratio (OR) together with 95% confidence interval (CI) were used to estimate the strength of association. We performed a cluster analysis on 2098 M.tb isolates and classified them into 545 genotypes and five categories (I, 0.19%; II, 0.43%; III, 3.34%; IV, 77.46%; V, 18.59%). After adjusting for potential confounders, the Beijing family genotype (OR = 118.63, 95% CI: 79.61–176.79, P = 0.001) was significantly related to the dominant strain infections. Patients infected with non-dominant strains had a higher risk of the pulmonary cavity (OR = 1.39, 95% CI: 1.01–1.91, P = 0.046). Among 37 paired recurrent cases, 22 (59.46%) were determined as endogenous reactivation, and 15 (40.54%) were exogenous reinfection. The type of M.tb strains prevalent in Jiangsu Province is relatively single. Beijing family strains infection is dominant in local tuberculosis cases. Endogenous reactivation appears to be a major cause of recurrent tuberculosis in Eastern China. This finding emphasizes the importance of case follow-up and monitoring after the completion of antituberculosis treatment.