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Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $\mu$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $\mu$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere., Comment: 35 pages, 13 figures, 3 tables, Nature, accepted

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 \mu$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator., Comment: 48 pages, 12 figures, 2 tables. Under review at Nature

We present additional HARPS radial velocity observations of the highly eccentric ($e \sim 0.6$) binary system DMPP-3AB, which comprises a K0V primary and a low-mass companion at the hydrogen burning limit. The binary has a $507$ d orbital period and a $1.2$ au semi-major axis. The primary component harbours a known $2.2$ M$_{\oplus}$ planet, DMPP-3A b, with a $6.67$ day orbit. New HARPS measurements constrain periastron passage for the binary orbit and add further integrity to previously derived solutions for both companion and planet orbits. Gaia astrometry independently confirms the binary orbit, and establishes the inclination of the binary is $63.89 \pm 0.78 ^{\circ}$. We performed dynamical simulations which establish that the previously identified $\sim800$ d RV signal cannot be attributed to an orbiting body. The additional observations, a deviation from strict periodicity, and our new analyses of activity indicators suggest the $\sim800$ d signal is caused by stellar activity. We conclude that there may be long period planet 'detections' in other systems which are similar misinterpreted stellar activity artefacts. Without the unusual eccentric binary companion to the planet-hosting star we could have accepted the $\sim800$ d signal as a probable planet. Further monitoring of DMPP-3 will reveal which signatures can be used to most efficiently identify these imposters. We also report a threshold detection (0.2 per cent FAP) of a $\sim2.26$ d periodicity in the RVs, potentially attributed to an Earth-mass S-type planet interior to DMPP-3A b., Comment: 20 pages, 15 figures. Accepted for publication in MNRAS

Study Analysis Group 21 (SAG21) of NASA's Exoplanet Exploration Program Analysis Group (ExoPAG) was organized to study the effect of stellar contamination on space-based transmission spectroscopy, a method for studying exoplanetary atmospheres by measuring the wavelength-dependent radius of a planet as it transits its star. Transmission spectroscopy relies on a precise understanding of the spectrum of the star being occulted. However, stars are not homogeneous, constant light sources but have temporally evolving photospheres and chromospheres with inhomogeneities like spots, faculae, plages, granules, and flares. This SAG brought together an interdisciplinary team of more than 100 scientists, with observers and theorists from the heliophysics, stellar astrophysics, planetary science, and exoplanetary atmosphere research communities, to study the current research needs that can be addressed in this context to make the most of transit studies from current NASA facilities like HST and JWST. The analysis produced 14 findings, which fall into three Science Themes encompassing (1) how the Sun is used as our best laboratory to calibrate our understanding of stellar heterogeneities ("The Sun as the Stellar Benchmark"), (2) how stars other than the Sun extend our knowledge of heterogeneities ("Surface Heterogeneities of Other Stars") and (3) how to incorporate information gathered for the Sun and other stars into transit studies ("Mapping Stellar Knowledge to Transit Studies"). In this invited review, we largely reproduce the final report of SAG21 as a contribution to the peer-reviewed literature., Invited review in press at RASTI. Based on the ExoPAG SAG21 report (arXiv:2201.09905v1) and refined via feedback from three reviewers. 75 pages, 30 figures, 5 tables

The temperature profile of a planetary atmosphere is a key diagnostic of radiative and dynamical processes governing the absorption, redistribution, and emission of energy. Observations have revealed dayside stratospheres that either cool or warm with altitude for a small number of gas giant exoplanets, while other dayside stratospheres are consistent with constant temperatures. Here we report spectroscopic phase curve measurements for the gas giant WASP-121b, which constrain stratospheric temperatures throughout the diurnal cycle. Variations measured for a water vapour spectral feature reveal a temperature profile that transitions from warming with altitude on the dayside hemisphere to cooling with altitude on the nightside hemisphere. The data are well explained by models assuming chemical equilibrium, with water molecules thermally dissociating at low pressures on the dayside and recombining on the nightside. Nightside temperatures are low enough for perovskite (CaTiO3) to condense, which could deplete titanium from the gas phase and explain recent non-detections at the day-night terminator. Nightside temperatures are also consistent with the condensation of refractory species such as magnesium, iron, and vanadium. Detections of these metals at the day-night terminator suggest, however, that if they do form nightside clouds, cold trapping does not efficiently remove them from the upper atmosphere. Horizontal winds and vertical mixing could keep these refractory condensates aloft in the upper atmosphere of the nightside hemisphere until they are recirculated to the hotter dayside hemisphere and vaporised., Comment: Published in Nature Astronomy (publisher version is Open Access)

The temperature profile of a planetary atmosphere is a key diagnostic of radiative and dynamical processes governing the absorption, redistribution, and emission of energy. Observations have revealed dayside stratospheres that either cool [1,2] or warm [3,4] with altitude for a small number of gas giant exoplanets, while others are consistent with constant temperatures [5,6,7,8]. Here we report spectroscopic phase curve measurements for the gas giant WASP-121b,[9] which constrain stratospheric temperatures throughout the diurnal cycle. Variations measured for a water vapor spectral feature reveal a temperature profile that transitions from warming with altitude on the dayside hemisphere to cooling with altitude on the nightside hemisphere. The data are well explained by models assuming chemical equilibrium, with water molecules thermally dissociating at low pressures on the dayside and recombining on the nightside [10,11]. Nightside temperatures are low enough for perovskite (CaTiO3) to condense, which could deplete titanium from the gas phase [12,13] and explain recent non-detections at the day-night terminator [14,15,16,17]. Nightside temperatures are also low enough for refractory species, such as magnesium, iron, and vanadium, to condense. Detections [16,17,18,19] of these metals at the day-night terminator suggest, however, that if they do form nightside clouds, cold trapping is not as effective at removing them from the upper atmosphere. Note: Numbered references have been entered into the "Manuscript Comment" box.

One of the most exciting scientific challenges is to detect Earth-like planets in the habitable zones of other stars in the galaxy and search for evidence of life. The ability to observe and characterise dozens of potentially Earth-like planets now lies within the realm of possibility due to rapid advances in key space and imaging technologies. The associated challenge of directly imaging very faint planets in orbit around nearby very bright stars is now well understood, with the key instrumentation also being perfected and developed. Such advances will allow us to develop large transformative telescopes, covering a broad UV-optical-IR spectral range, which can carry out the detailed research programmes designed to answer the questions we wish to answer: Carry out high contrast imaging surveys of nearby stars to search for planets within their habitable zones. Characterise the planets detected to determine masses and radii from photometric measurements. Through spectroscopic studies of their atmospheres and surfaces, search for habitability indicators and for signs of an environment that has been modified by the presence of life. Active studies of potential missions have been underway for a number of years. The latest of these is the Large UV Optical IR space telescope (LUVOIR), one of four flagship mission studies commissioned by NASA in support of the 2020 US Decadal Survey. LUVOIR, if selected, will be of interest to a wide scientific community and will be the only telescope capable of searching for and characterizing a sufficient number of exoEarths to provide a meaningful answer to the question - Are we alone?. This paper is a submission to the European Space Agency Voyage 2050 call for white papers outlining the case for an ESA contribution to a Large UVOIR telescope., Submission to the European Space Agency Voyage 2050 call for white papers

A cloud opacity contrast feature that has been called a “long-lived sharp disruption” has been seen in the atmosphere of Venus in the near-infrared using Akatsuki’s IR2 camera, most clearly at equatorial latitudes. This feature was found to have a consistent planet-circling period of 4.9 days, and subsequent searches of past imagery revealed that it has probably existed for at least 30 years, the duration of near-infrared investigation of the deep atmosphere of Venus. Guided by the remarkably consistent morphological appearance of this feature, we have identified at least one previous instance of it in the Venus Express Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) data. We take advantage of the spectroscopic capabilities of VIRTIS to retrieve atmospheric parameters in the vicinity of this feature that cannot be retrieved using the limited filter selection on board Akatsuki. We find that the changes in measurable quantities, such as cloud particle acid mass fraction, water vapor, carbon monoxide, cloud base altitude, and particle size, suggest that the changes that take place in the vicinity of this feature are restricted to the lower clouds of Venus (below 50 km). We hypothesize that further evolution of this feature (over timescales of days to weeks) results in measurable variations in these parameters at altitudes in the middle clouds of Venus (50–57 km), lending credence to its identification as a baroclinic trough or Kelvin front.

A publicly available database of opacities for molecules of astrophysical interest, ExoMolOP, has been compiled for over 80 species, based on the latest line list data from the ExoMol, HITEMP and MoLLIST databases. These data are generally suitable for characterising high temperature exoplanet or cool stellar/substellar atmospheres, and have been computed at a variety of pressures and temperatures, with a few molecules included at room-temperature only from the HITRAN database. The data are formatted in different ways for four different exoplanet atmosphere retrieval codes; ARCiS, TauREx, NEMESIS and petitRADTRANS, and include both cross-sections (at R~=~$\frac{\lambda}{\Delta \lambda}$~=~15,000) and k-tables (at R~=~$\frac{\lambda}{\Delta \lambda}$~=~1000) for the 0.3~-~50$\mu$m wavelength region. Opacity files can be downloaded and used directly for these codes. Atomic data for alkali metals Na and K are also included, using data from the NIST database and the latest line shapes for the resonance lines. Broadening parameters have been taken from the literature where available, or from those for a known molecule with similar molecular properties where no broadening data are available. The data are available from www.exomol.com., Comment: 25 pages, 9 figures. Accepted for publication in A&A

We present a new optical transmission spectrum of the hot Jupiter WASP-79b. We observed three transits with the STIS instrument mounted on HST, spanning 0.3 - 1.0 um. Combining these transits with previous observations, we construct a complete 0.3 - 5.0 um transmission spectrum of WASP-79b. Both HST and ground-based observations show decreasing transit depths towards blue wavelengths, contrary to expectations from Rayleigh scattering or hazes. We infer atmospheric and stellar properties from the full near-UV to infrared transmission spectrum of WASP-79b using three independent retrieval codes, all of which yield consistent results. Our retrievals confirm previous detections of H$_{2}$O (at 4.0$\sigma$ confidence), while providing moderate evidence of H$^{-}$ bound-free opacity (3.3$\sigma$) and strong evidence of stellar contamination from unocculted faculae (4.7$\sigma$). The retrieved H$_{2}$O abundance ($\sim$ 1$\%$) suggests a super-stellar atmospheric metallicity, though stellar or sub-stellar abundances remain consistent with present observations (O/H = 0.3 - 34$\times$ stellar). All three retrieval codes obtain a precise H$^{-}$ abundance constraint: log(X$_{\rm{H^{-}}}$) $\approx$ -8.0 $\pm$ 0.7. The potential presence of H$^{-}$ suggests that JWST observations may be sensitive to ionic chemistry in the atmosphere of WASP-79b. The inferred faculae are $\sim$ 500 K hotter than the stellar photosphere, covering $\sim$ 15$\%$ of the stellar surface. Our analysis underscores the importance of observing UV - optical transmission spectra in order to disentangle the influence of unocculted stellar heterogeneities from planetary transmission spectra., Comment: 27 pages, 10 figures. Resubmitted to AJ after referee report

The chemical abundances of exoplanet atmospheres may provide valuable information about the bulk compositions, formation pathways, and evolutionary histories of planets. Exoplanets with large, relatively cloud-free atmospheres, and which orbit bright stars provide the best opportunities for accurate abundance measurements. For this reason, we measured the transmission spectrum of the bright (V ∼ 10.2), large (1.37 RJ), sub-Saturn mass (0.19 MJ) exoplanet WASP-127b across the near-UV to near-infrared wavelength range (0.3–5 μm), using the Hubble and Spitzer Space Telescopes. Our results show a feature-rich transmission spectrum, with absorption from Na, H2O, and CO2, and wavelength-dependent scattering from small-particle condensates. We ran two types of atmospheric retrieval models: one enforcing chemical equilibrium, and the other which fit the abundances freely. Our retrieved abundances at chemical equilibrium for Na, O, and C are all supersolar, with abundances relative to solar values of 9$^{+15}_{-6}$, 16$^{+7}_{-5}$, and 26$^{+12}_{-9}$, respectively. Despite giving conflicting C/O ratios, both retrievals gave supersolar CO2 volume mixing ratios, which adds to the likelihood that WASP-127b’s bulk metallicity is supersolar, since CO2 abundance is highly sensitive to atmospheric metallicity. We detect water at a significance of 13.7σ. Our detection of Na is in agreement with previous ground-based detections, though we find a much lower abundance, and we also do not find evidence for Li or K despite increased sensitivity. In the future, spectroscopy with James Webb Space Telescope will be able to constrain WASP-127b’s C/O ratio, and may reveal the formation history of this metal-enriched, highly observable exoplanet.

Exoplanets with cloud-free, haze-free atmospheres at the pressures probed by transmission spectroscopy represent a valuable opportunity for detailed atmospheric characterization and precise chemical abundance constraints. We present the first optical to infrared (0.3-5 microns) transmission spectrum of the hot Jupiter WASP-62b, measured with Hubble/STIS and Spitzer/IRAC. The spectrum is characterized by a 5.1-sigma detection of Na I absorption at 0.59 microns, in which the pressure-broadened wings of the Na D-lines are observed from space for the first time. A spectral feature at 0.4 microns is tentatively attributed to SiH at 2.1-sigma confidence. Our retrieval analyses are consistent with a cloud-free atmosphere without significant contamination from stellar heterogeneities. We simulate James Webb Space Telescope (JWST) observations, for a combination of instrument modes, to assess the atmospheric characterization potential of WASP-62b. We demonstrate that JWST can conclusively detect Na, H2O, FeH, and SiH within the scope of its Early Release Science (ERS) program. As the only transiting giant planet currently known in the JWST Continuous Viewing Zone, WASP-62b could prove a benchmark giant exoplanet for detailed atmospheric characterization in the James Webb era., 14 pages, 5 figures, accepted for publication in ApJL

Spectral retrieval has long been a powerful tool for interpreting planetary remote sensing observations. Flexible, parameterised, agnostic models are coupled with inversion algorithms in order to infer atmospheric properties directly from observations, with minimal reliance on physical assumptions. This approach, originally developed for application to Earth satellite data and subsequently observations of other Solar System planets, has been recently and successfully applied to transit, eclipse and phase curve spectra of transiting exoplanets. In this review, we present the current state-of-the-art in terms of our ability to accurately retrieve information about atmospheric chemistry, temperature, clouds and spatial variability; we discuss the limitations of this, both in the available data and modelling strategies used; and we recommend approaches for future improvement., 30 pages, 6 figures. Accepted by Space Science Reviews

We report ground-based transmission spectroscopy of the highly irradiated and ultra-short period hot-Jupiter WASP-103b covering the wavelength range $\approx$ 400-600 nm using the FORS2 instrument on the Very Large Telescope. The light curves show significant time-correlated noise which is mainly invariant in wavelength and which we model using a Gaussian process. The precision of our transmission spectrum is improved by applying a common-mode correction derived from the white light curve, reaching typical uncertainties in transit depth of $\approx$ 2x10$^{-4}$ in wavelength bins of 15 nm. After correction for flux contamination from a blended companion star, our observations reveal a featureless spectrum across the full range of the FORS2 observations and we are unable to confirm the Na absorption previously inferred using Gemini/GMOS or the strong Rayleigh scattering observed using broad-band light curves. We performed a Bayesian atmospheric retrieval on the full optical-infrared transmission spectrum using the additional data from Gemini/GMOS, HST/WFC3 and Spitzer observations and recover evidence for H$_2$O absorption at the 4.0$\sigma$ level. However, our observations are not able to completely rule out the presence of Na, which is found at 2.0$\sigma$ in our retrievals. This may in part be explained by patchy/inhomogeneous clouds or hazes damping any absorption features in our FORS2 spectrum, but an inherently small scale height also makes this feature challenging to probe from the ground. Our results nonetheless demonstrate the continuing potential of ground-based observations for investigating exoplanet atmospheres and emphasise the need for the application of consistent and robust statistical techniques to low-resolution spectra in the presence of instrumental systematics., Comment: 17 pages, 8 Figures, Accepted for publication in MNRAS

We present new observations of the transmission spectrum of the hot Jupiter WASP-6b both from the ground with the Very Large Telescope (VLT) FOcal Reducer and Spectrograph (FORS2) from 0.45-0.83 $\mu$m, and space with the Transiting Exoplanet Survey Satellite (TESS) from 0.6-1.0 $\mu$m and the Hubble Space Telescope (HST) Wide Field Camera 3 from 1.12-1.65 $\mu$m. Archival data from the HST Space Telescope Imaging Spectrograph (STIS) and Spitzer is also reanalysed on a common Gaussian process framework, of which the STIS data show a good overall agreement with the overlapping FORS2 data. We also explore the effects of stellar heterogeneity on our observations and its resulting implications towards determining the atmospheric characteristics of WASP-6b. Independent of our assumptions for the level of stellar heterogeneity we detect Na I, K I and H$_2$O absorption features and constrain the elemental oxygen abundance to a value of [O/H] $\simeq -0.9\pm0.3$ relative to solar. In contrast, we find that the stellar heterogeneity correction can have significant effects on the retrieved distributions of the [Na/H] and [K/H] abundances, primarily through its degeneracy with the sloping optical opacity of scattering haze species within the atmosphere. Our results also show that despite this presence of haze, WASP-6b remains a favourable object for future atmospheric characterisation with upcoming missions such as the James Webb Space Telescope., Comment: Accepted to MNRAS

In recent years, it has become clear that a substantial fraction of transiting exoplanets have some form of aerosol present in their atmospheres. Transit spectroscopy - mostly of hot Jupiters, but also of some smaller planets - has provided evidence for this, in the form of steep downward slopes from blue to red in the optical part of the spectrum, and muted gas absorption features throughout. Retrieval studies seeking to constrain the composition of exoplanet atmospheres must therefore account for the presence of aerosols. However, clouds and hazes are complex physical phenomena, and the transit spectra that are currently available allow us to constrain only some of their properties. Therefore, representation of aerosols in retrieval models requires that they are described by only a few parameters, and this has been done in a variety of ways within the literature. Here, I investigate a range of parameterisations for exoplanet aerosol and their effects on retrievals from transmission spectra of hot Jupiters HD 189733b and HD 209458b. I find that results qualitatively agree for the cloud/haze itself regardless of the parameterisation used, and indeed using multiple approaches provides a more holistic picture; the retrieved abundance of H2O is also very robust to assumptions about aerosols. I also find strong evidence that aerosol on HD 209458b covers less than half of the terminator region, whilst the picture is less clear for HD 189733b., 15 pages, 10 figures. Accepted in MNRAS

Over the last several years, spectroscopic observations of transiting exoplanets have begun to uncover information about their atmospheres, including atmospheric composition and indications of the presence of clouds and hazes. Spectral retrieval is the leading technique for interpretation of transmission spectra and is employed by several teams using a variety of forward models and parameter estimation algorithms. However, different model suites have mostly been used in isolation and so it is unknown whether the results from each are comparable. As we approach the launch of the James Webb Space Telescope we anticipate advances in wavelength coverage, precision, and resolution of transit spectroscopic data, so it is important that the tools that will be used to interpret these information rich spectra are validated. To this end, we present an inter-model comparison of three retrieval suites: TauREx, NEMESIS and CHIMERA. We demonstrate that the forward model spectra are in good agreement (residual deviations on the order of 20 - 40 ppm), and discuss the results of cross retrievals between the three tools. Generally, the constraints from the cross retrievals are consistent with each other and with input values to within 1 sigma However, for high precision scenarios with error envelopes of order 30 ppm, subtle differences in the simulated spectra result in discrepancies between the different retrieval suites, and inaccuracies in retrieved values of several sigma. This can be considered analogous to substantial systematic/astrophysical noise in a real observation, or errors/omissions in a forward model such as molecular linelist incompleteness or missing absorbers., 25 pages, 21 figures. Accepted in MNRAS

For solar-system objects, ultraviolet spectroscopy has been critical in identifying sources for stratospheric heating and measuring the abundances of a variety of hydrocarbon and sulfur-bearing species, produced via photochemical mechanisms, as well as oxygen and ozone. To date, less than 20 exoplanets have been probed in this critical wavelength range (0.2-0.4 um). Here we use data from Hubble's newly implemented WFC3 UVIS G280 grism to probe the atmosphere of the hot Jupiter HAT-P-41b in the ultraviolet through optical in combination with observations at infrared wavelengths. We analyze and interpret HAT-P-41b's 0.2-5.0 um transmission spectrum using a broad range of methodologies including multiple treatments of data systematics as well as comparisons with atmospheric forward, cloud microphysical, and multiple atmospheric retrieval models. Although some analysis and interpretation methods favor the presence of clouds or potentially a combination of Na, VO, AlO, and CrH to explain the ultraviolet through optical portions of HAT-P-41b's transmission spectrum, we find that the presence of a significant H- opacity provides the most robust explanation. We obtain a constraint for the abundance of H-, log(H-) = -8.65 +/- 0.62 in HAT-P-41b's atmosphere, which is several orders of magnitude larger than predictions from equilibrium chemistry for a 1700 - 1950 K hot Jupiter. We show that a combination of photochemical and collisional processes on hot hydrogen-dominated exoplanets can readily supply the necessary amount of H- and suggest that such processes are at work in HAT-P-41b and many other hot Jupiter atmospheres., Comment: 17 pages, 7 figures. Published in ApJL (October 8th 2020)

We present a 0.3-5 μm transmission spectrum of the hot Jupiter HAT-P-32Ab observed with the Space Telescope Imaging Spectrograph and Wide Field Camera 3 instruments mounted on the Hubble Space Telescope, combined with Spitzer Infrared Array Camera photometry. The spectrum is composed of 51 spectrophotometric bins with widths ranging between 150 and 400 Å, measured to a median precision of 215 ppm. Comparisons of the observed transmission spectrum to a grid of 1D radiative-convective equilibrium models indicate the presence of clouds/hazes, consistent with previous transit observations and secondary eclipse measurements. To provide more robust constraints on the planet's atmospheric properties, we perform the first full optical to infrared retrieval analysis for this planet. The retrieved spectrum is consistent with a limb temperature of 1248+9292 K, a thick cloud deck, enhanced Rayleigh scattering, and ∼10× solar H2O abundance. We find log(Z/Z o˙) =2.41+0.06-0.07, and compare this measurement with the mass-metallicity relation derived for the solar system., With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)

We present the first comprehensive look at the $0.35-5$ $\mu$m transmission spectrum of the warm ($\sim 800$ K) Neptune HAT-P-11b derived from thirteen individual transits observed using the Hubble and Spitzer Space Telescopes. Along with the previously published molecular absorption feature in the $1.1-1.7$ $\mu$m bandpass, we detect a distinct absorption feature at 1.15 $\mu$m and a weak feature at 0.95 $\mu$m, indicating the presence of water and/or methane with a combined significance of 4.4 $\sigma$. We find that this planet's nearly flat optical transmission spectrum and attenuated near-infrared molecular absorption features are best-matched by models incorporating a high-altitude cloud layer. Atmospheric retrievals using the combined $0.35-1.7$ $\mu$m HST transmission spectrum yield strong constraints on atmospheric cloud-top pressure and metallicity, but we are unable to match the relatively shallow Spitzer transit depths without under-predicting the strength of the near-infrared molecular absorption bands. HAT-P-11b's HST transmission spectrum is well-matched by predictions from our microphysical cloud models. Both forward models and retrievals indicate that HAT-P-11b most likely has a relatively low atmospheric metallicity ($, Comment: Accepted for publication in AJ. 33 pages, 23 figures

The planned launch of the James Webb Space Telescope in 2018 will herald a new era of exoplanet spectroscopy. JWST will be the first telescope sensitive enough to potentially characterize terrestrial planets from their transmission spectra. In this work, we explore the possibility that terrestrial planets with Venus-type and Earth-type atmospheres could be distinguished from each other using spectra obtained by JWST. If we find a terrestrial planet close to the liquid water habitable zone of an M5 star within a distance of 10 parsecs, it would be possible to detect atmospheric ozone if present in large enough quantities, which would enable an oxygen-rich atmosphere to be identified. However, the cloudiness of a Venus-type atmosphere would inhibit our ability to draw firm conclusions about the atmospheric composition, making any result ambiguous. Observing small, temperate planets with JWST requires significant investment of resources, with single targets requiring of order 100 transits to achieve sufficient signal to noise. The possibility of detecting a crucial feature such as the ozone signature would need to be carefully weighed against the likelihood of clouds obscuring gas absorption in the spectrum., Comment: 12 pages, 9 figures. This is a pre-copyedited, author-produced PDF of an article accepted for publication in MNRAS following peer review

Broad absorption signatures from alkali metals, such as the sodium (Na I) and potassium (K I) resonance doublets, have long been predicted in the optical atmospheric spectra of cloud-free irradiated gas-giant exoplanets1,2,3. However, observations have only revealed the narrow cores of these features rather than the full pressure-broadened profiles4-6. Cloud and haze opacity at the day-night planetary terminator are considered responsible for obscuring the absorption-line wings, which hinders constraints on absolute atmospheric abundances7-9. Here we present an optical transmission spectrum for the 'hot-Saturn' WASP-96b obtained with the Very Large Telescope, which exhibits the complete pressure-broadened profile of the sodium absorption feature. The spectrum is in excellent agreement with cloud-free, solar-abundance models assuming chemical equilibrium. We are able to measure a precise, absolute sodium abundance of log\epsilon_Na=6.9+0.6-0.4, and use it as a proxy to the planet's atmospheric metallicity relative to the solar value (Z_p/Z_\star=2.3+8.9/--1.7). This result is consistent with the mass-metallicity trend observed for solar-system planets and exoplanets10-12., Comment: Published in Nature

A key legacy of the recently launched TESS mission will be to provide the astronomical community with many of the best transiting exoplanet targets for atmospheric characterization. However, time is of the essence to take full advantage of this opportunity. JWST, although delayed, will still complete its nominal five year mission on a timeline that motivates rapid identification, confirmation, and mass measurement of the top atmospheric characterization targets from TESS. Beyond JWST, future dedicated missions for atmospheric studies such as ARIEL require the discovery and confirmation of several hundred additional sub-Jovian size planets (R_p < 10 R_Earth) orbiting bright stars, beyond those known today, to ensure a successful statistical census of exoplanet atmospheres. Ground-based ELTs will also contribute to surveying the atmospheres of the transiting planets discovered by TESS. Here we present a set of two straightforward analytic metrics, quantifying the expected signal-to-noise in transmission and thermal emission spectroscopy for a given planet, that will allow the top atmospheric characterization targets to be readily identified among the TESS planet candidates. Targets that meet our proposed threshold values for these metrics would be encouraged for rapid follow-up and confirmation via radial velocity mass measurements. Based on the catalog of simulated TESS detections by Sullivan et al. (2015), we determine appropriate cutoff values of the metrics, such that the TESS mission will ultimately yield a sample of $\sim300$ high-quality atmospheric characterization targets across a range of planet size bins, extending down to Earth-size, potentially habitable worlds., accepted to PASP

We present an atmospheric transmission spectrum for the ultra-hot Jupiter WASP-121b, measured using the Space Telescope Imaging Spectrograph (STIS) onboard the Hubble Space Telescope (HST). Across the 0.47-1 micron wavelength range, the data imply an atmospheric opacity comparable to - and in some spectroscopic channels exceeding - that previously measured at near-infrared wavelengths (1.15-1.65 micron). Wavelength-dependent variations in the opacity rule out a gray cloud deck at a confidence level of 3.8-sigma and may instead be explained by VO spectral bands. We find a cloud-free model assuming chemical equilibrium for a temperature of 1500K and metal enrichment of 10-30x solar matches these data well. Using a free-chemistry retrieval analysis, we estimate a VO abundance of -6.6(-0.3,+0.2) dex. We find no evidence for TiO and place a 3-sigma upper limit of -7.9 dex on its abundance, suggesting TiO may have condensed from the gas phase at the day-night limb. The opacity rises steeply at the shortest wavelengths, increasing by approximately five pressure scale heights from 0.47 to 0.3 micron in wavelength. If this feature is caused by Rayleigh scattering due to uniformly-distributed aerosols, it would imply an unphysically high temperature of 6810+/-1530K. One alternative explanation for the short-wavelength rise is absorption due to SH (mercapto radical), which has been predicted as an important product of non-equilibrium chemistry in hot Jupiter atmospheres. Irrespective of the identity of the NUV absorber, it likely captures a significant amount of incident stellar radiation at low pressures, thus playing a significant role in the overall energy budget, thermal structure, and circulation of the atmosphere., Comment: Accepted for publication in The Astronomical Journal

The results for the design study of the Long Wave Infrared Module (LWIR), a goal spectroscopic channel for the EChO ESA medium class candidate mission, are presented. The requirements for the LWIR module were to provide coverage of the 11–16 μm spectral range at a moderate resolving power of at least R = 30, whilst minimising noise contributions above photon due to the thermal background of the EChO instrument and telescope, and astrophysical sources such as the zodiacal light. The study output module design is a KRS-6 prism spectrograph with aluminium mirror beam expander and coated germanium lenses for the final focusing elements. Thermal background considerations led to enclosing the beam in a baffle cooled to approximately 25–29 K. To minimise diffuse astrophysical background contributions due to the zodiacal light, anamorphic designs were considered in addition to the elliptical input beam provided by the EChO telescope. Given the requirement that measurements in this waveband place on the performance of the infrared detector array, an additional study on the likely scientific return with lower resolving power (R

The James Webb Space Telescope (JWST) is predicted to make great advances in the field of exoplanet atmospheres. Its 25 m2 mirror means that it can reach unprecedented levels of precision in observations of transit spectra, and can thus characterise the atmospheres of planets orbiting stars several hundred pc away. Its coverage of the infrared spectral region between 0.6 and 28 {\mu}m allows the abundances of key molecules to be probed during the transit of a planet in front of the host star, and when the same planet is eclipsed constraints can be placed on its temperature structure. In this work, we explore the possibility of using low-spectral-resolution observations by JWST/NIRSpec and JWST/MIRI-LRS together to optimise wavelength coverage and break degeneracies in the atmospheric retrieval problem for a range of exoplanets from hot Jupiters to super Earths. This approach involves stitching together non-simultaneous observations in different wavelength regions, rendering it necessary to consider the effect of time-varying instrumental and astrophysical systematics. We present the results of a series of retrieval feasibility tests examining the effects of instrument systematics and star spots on the recoverability of the true atmospheric state, and demonstrate that correcting for these systematics is key for successful exoplanet science with JWST.

In recent years, an increasing number of observations have been made of the transits of ‘Hot Jupiters’, such as HD 189733b, about their parent stars from the visible through to mid-infrared wavelengths, which have been modelled to derive the likely atmospheric structure and composition of these planets. As measurement techniques improve, the measured transit spectra of ‘Super-Earths’ such as GJ 1214b are becoming better constrained, allowing model atmospheric states to be fitted for this class of planet also. While it is not yet possible to constrain the atmospheric states of small planets such as the Earth or cold planets like Jupiter, it is hoped that this might become practical in the coming decades and if so, it is of interest to determine what we might infer from such measurements. In this work we have constructed atmospheric models of the Solar System planets from 0.4 to 15.5 μm that are consistent with ground-based and satellite observations and from these calculate the primary transit and secondary eclipse spectra (with respect to the Sun and typical M-dwarfs) that would be observed by a ‘remote observer’, many light years away. From these spectra we test what current retrieval models might infer about their atmospheric states and compare these with the ‘ground truths’ in order to assess: (a) the inherent uncertainties in transit spectra observations; (b) the relative merits of primary transit and secondary eclipse spectra; and (c) the advantages of acquiring directly imaged spectra of these planets. We find that observing secondary eclipses of the Solar System would not give sufficient information for determining atmospheric properties with 10 m-diameter telescopes from a distance of 10 light years, but that primary transits give much better information. We find that a single transit of Jupiter in front of the Sun could potentially be used to determine temperature and stratospheric composition, but for the Earth the mean atmospheric composition could only be determined if it were orbiting a much smaller M-dwarf. For both Jupiter and Earth we note that direct imaging with sufficient nulling of the light from the parent star theoretically provides the best method of determining the atmospheric properties of such planets.

We present an optical eclipse observation of the hot Jupiter WASP-12b using the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope. These spectra allow us to place an upper limit of $A_g < 0.064$ (97.5% confidence level) on the planet's white light geometric albedo across 290--570 nm. Using six wavelength bins across the same wavelength range also produces stringent limits on the geometric albedo for all bins. However, our uncertainties in eclipse depth are $\sim$40% greater than the Poisson limit and may be limited by the intrinsic variability of the Sun-like host star --- the solar luminosity is known to vary at the $10^{-4}$ level on a timescale of minutes. We use our eclipse depth limits to test two previously suggested atmospheric models for this planet: Mie scattering from an aluminum-oxide haze or cloud-free Rayleigh scattering. Our stringent nondetection rules out both models and is consistent with thermal emission plus weak Rayleigh scattering from atomic hydrogen and helium. Our results are in stark contrast with those for the much cooler HD 189733b, the only other hot Jupiter with spectrally resolved reflected light observations; those data showed an increase in albedo with decreasing wavelength. The fact that the first two exoplanets with optical albedo spectra exhibit significant differences demonstrates the importance of spectrally resolved reflected light observations and highlights the great diversity among hot Jupiters., 8 pages, 4 figures, 1 table, published in ApJL, in press

Infrared radiation emitted from a planet contains information about the chemical composition and vertical temperature profile of its atmosphere. If upper layers are cooler than lower layers, molecular gases will produce absorption features in the planetary thermal spectrum. Conversely, if there is a stratosphere - where temperature increases with altitude - these molecular features will be observed in emission. It has been suggested that stratospheres could form in highly irradiated exoplanets, but the extent to which this occurs is unresolved both theoretically and observationally. A previous claim for the presence of a stratosphere remains open to question, owing to the challenges posed by the highly variable host star and the low spectral resolution of the measurements. Here we report a near-infrared thermal spectrum for the ultrahot gas giant WASP-121b, which has an equilibrium temperature of approximately 2,500 kelvin. Water is resolved in emission, providing a detection of an exoplanet stratosphere at 5-sigma confidence. These observations imply that a substantial fraction of incident stellar radiation is retained at high altitudes in the atmosphere, possibly by absorbing chemical species such as gaseous vanadium oxide and titanium oxide., This is the authors' version of the manuscript. 23 pages, 9 figures, 4 tables

We present a thermal emission spectrum of the bloated hot Jupiter HAT-P-32Ab from a single eclipse observation made in spatial scan mode with the Wide Field Camera 3 (WFC3) aboard the Hubble Space Telescope (HST). The spectrum covers the wavelength regime from 1.123 to 1.644 microns which is binned into 14 eclipse depths measured to an averaged precision of 104 parts-per million. The spectrum is unaffected by a dilution from the close M-dwarf companion HAT-P-32B, which was fully resolved. We complemented our spectrum with literature results and performed a comparative forward and retrieval analysis with the 1D radiative-convective ATMO model. Assuming solar abundance of the planet atmosphere, we find that the measured spectrum can best be explained by the spectrum of a blackbody isothermal atmosphere with Tp = 1995 +/- 17K, but can equally-well be described by a spectrum with modest thermal inversion. The retrieved spectrum suggests emission from VO at the WFC3 wavelengths and no evidence of the 1.4 micron water feature. The emission models with temperature profiles decreasing with height are rejected at a high confidence. An isothermal or inverted spectrum can imply a clear atmosphere with an absorber, a dusty cloud deck or a combination of both. We find that the planet can have continuum of values for the albedo and recirculation, ranging from high albedo and poor recirculation to low albedo and efficient recirculation. Optical spectroscopy of the planet's day-side or thermal emission phase curves can potentially resolve the current albedo with recirculation degeneracy., 14 pages, 10 figures, 3 tables, accepted for publication in MNRAS

We present results from the first observations of the Hubble Space Telescope (HST) Panchromatic Comparative Exoplanet Treasury (PanCET) program for WASP-101b, a highly inflated hot Jupiter and one of the community targets proposed for the James Webb Space Telescope (JWST) Early Release Science (ERS) program. From a single HST Wide Field Camera 3 (WFC3) observation, we find that the near-infrared transmission spectrum of WASP-101b contains no significant H$_2$O absorption features and we rule out a clear atmosphere at 13{\sigma}. Therefore, WASP-101b is not an optimum target for a JWST ERS program aimed at observing strong molecular transmission features. We compare WASP-101b to the well studied and nearly identical hot Jupiter WASP-31b. These twin planets show similar temperature-pressure profiles and atmospheric features in the near-infrared. We suggest exoplanets in the same parameter space as WASP-101b and WASP-31b will also exhibit cloudy transmission spectral features. For future HST exoplanet studies, our analysis also suggests that a lower count limit needs to be exceeded per pixel on the detector in order to avoid unwanted instrumental systematics., Comment: 7 pages, 4 figures, 1 table, Accepted to ApJL

We present transmission spectroscopy of the hot-Jupiter WASP-31b using FORS2 on the VLT during two primary transits. The observations cover a wavelength range of $\approx$400-840nm. The light curves are corrupted by significant systematics, but these were to first order invariant with wavelength and could be removed using a common-mode correction derived from the white light curves. We reach a precision in the transit depth of $\approx$140 ppm in 15 nm bins, although the precision varies significantly over the wavelength range. Our FORS2 observations confirm the cloud-deck previously inferred using HST/STIS. We also re-analyse the HST/STIS data using a Gaussian process model, finding excellent agreement with earlier measurements. We reproduce the Rayleigh scattering signature at short wavelengths ($\lesssim$5300 $\AA$) and the cloud-deck at longer wavelengths. However, our FORS2 observations appear to rule out the large potassium feature previously detected using STIS, yet it is recovered from the HST/STIS data, although with reduced amplitude and significance ($\approx$2.5$\sigma$). The discrepancy between our results and the earlier STIS detection of potassium ($\approx$4.3$\sigma$) is either a result of telluric contamination of the ground-based observations, or an underestimate of the uncertainties for narrow-band features in HST/STIS when using linear basis models to account for the systematics. Our results further demonstrate the use of ground-based multi-object spectrographs for the study of exoplanet atmospheres, and highlight the need for caution in our interpretation of narrow-band features in low-resolution spectra of hot-Jupiters., Comment: 16 pages, 10 figures, 5 tables, accepted for publication in MNRAS

WASP-39b is a hot Saturn-mass exoplanet with a predicted clear atmosphere based on observations in the optical and infrared. Here we complete the transmission spectrum of the atmosphere with observations in the near-infrared (NIR) over three water absorption features with the Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3) G102 (0.8-1.1 microns) and G141 (1.1-1.7 microns) spectroscopic grisms. We measure the predicted high amplitude H2O feature centered at 1.4 microns, and the smaller amplitude features at 0.95 and 1.2 microns, with a maximum water absorption amplitude of 2.4 planetary scale heights. We incorporate these new NIR measurements into previously published observational measurements to complete the transmission spectrum from 0.3-5 microns. From these observed water features, combined with features in the optical and IR, we retrieve a well constrained temperature Teq = 1030(+30,-20) K, and atmospheric metallicity 151 (+48,-46)x solar which is relatively high with respect to the currently established mass-metallicity trends. This new measurement in the Saturn-mass range hints at further diversity in the planet formation process relative to our solar system giants., Comment: Accepted for publication in AJ. 15 pages, 14 figures, 4 tables, 6 equations

As an exoplanet orbits its host star it reflects and emits light, forming a distinctive phase curve. By observing this light, we can study the atmosphere and surface of distant planets. The planets in our Solar System show a wide range of atmospheric phenomena, with stable wind patterns, changing storms, and evolving anomalies. Brown dwarfs also exhibit atmospheric variability. Such temporal variability in the atmosphere of a giant exoplanet has not to date been observed. HAT-P-7 b is an exoplanet with a known offset in the peak of its phase curve. Here we present variations in the peak offset ranging between -0.086+0.033-0.033 to 0.143+0.040-0.037 in phase, implying that the peak brightness repeatedly shifts from one side of the planet's substellar point to the other. The variability occurs on a timescale of tens to hundreds of days. These shifts in brightness are indicative of variability in the planet's atmosphere, and result from a changing balance of thermal emission and reflected flux from the planet's dayside. We suggest that variation in wind speed in the planetary atmosphere, leading to variable cloud coverage on the dayside and a changing energy balance, is capable of explaining the observed variation., Published in Nature Astronomy. 24 pages, including Supplementary Information. This is the accepted, but not journal-edited, version

The recent discovery of three Earth-sized, potentially habitable planets around a nearby cool star, TRAPPIST-1, has provided three key targets for the upcoming James Webb Space Telescope (JWST). Depending on their atmospheric characteristics and precise orbit configurations, it is possible that any of the three planets may be in the liquid water habitable zone, meaning that they may be capable of supporting life. We find that present-day Earth levels of ozone, if present, would be detectable if JWST observes 60 transits for innermost planet 1b and 30 transits for 1c and 1d., 5 pages, 3 figures. Accepted as a letter in MNRAS. Typos corrected in this version

A peak in the infrared phase curve occurring after eclipse suggests a westward shift in the dayside hotspot of hot giant exoplanet CoRoT-2b, calling into question our understanding of atmospheric dynamics on hot gas giants.

We present transmission spectroscopy of the warm Saturn-mass exoplanet WASP-39b made with the Very Large Telescope (VLT) FOcal Reducer and Spectrograph (FORS2) across the wavelength range 411-810nm. The transit depth is measured with a typical precision of 240 parts per million (ppm) in wavelength bins of 10nm on a V = 12.1 magnitude star. We detect the sodium absorption feature (3.2-sigma) and find evidence for potassium. The ground-based transmission spectrum is consistent with Hubble Space Telescope (HST) optical spectroscopy, strengthening the interpretation of WASP-39b having a largely clear atmosphere. Our results demonstrate the great potential of the recently upgraded FORS2 spectrograph for optical transmission spectroscopy, obtaining HST-quality light curves from the ground., 11 pages, 5 figures, accepted for publication in ApJ

The high sensitivity and broad wavelength coverage of the James Webb Space Telescope will transform the field of exoplanet transit spectroscopy. Transit spectra are inferred from minute, wavelength-dependent variations in the depth of a transit or eclipse as the planet passes in front of or is obscured by its star, and the spectra contain information about the composition, structure and cloudiness of exoplanet atmospheres. Atmospheric retrieval is the preferred technique for extracting information from these spectra, but the process can be confused by astrophysical and instrumental systematic noise. We present results of retrieval tests based on synthetic, noisy JWST spectra, for clear and cloudy planets and active and inactive stars. We find that the ability to correct for stellar activity is likely to be a limiting factor for cloudy planets, as the effects of unocculted star spots may mimic the presence of a scattering slope due to clouds. We discuss the pros and cons of the available JWST instrument combinations for transit spectroscopy, and consider the effect of clouds and aerosols on the spectra. Aerosol high in a planet’s atmosphere obscures molecular absorption features in transmission, reducing the information content of spectra in wavelength regions where the cloud is optically thick. We discuss the usefulness of particular wavelength regions for identifying the presence of cloud, and suggest strategies for solving the highly-degenerate retrieval problem for these objects.

KMOS (K-Band Multi Object Spectrograph) is a novel integral field spectrograph installed in the VLT's ANTU unit. The instrument offers an ability to observe 24 2.8"$\times$2.8" sub-fields positionable within a 7.2' patrol field, each sub-field producing a spectrum with a 14$\times$14-pixel spatial resolution. The main science drivers for KMOS are the study of galaxies, star formation, and molecular clouds, but its ability to simultaneously measure spectra of multiple stars makes KMOS an interesting instrument for exoplanet atmosphere characterization via transmission spectroscopy. We set to test whether transmission spectroscopy is practical with KMOS, and what are the conditions required to achieve the photometric precision needed, based on observations of a partial transit of WASP-19b, and full transits of GJ 1214b and HD 209458b. Our analysis uses the simultaneously observed comparison stars to reduce the effects from instrumental and atmospheric sources, and Gaussian processes to model the residual systematics. We show that KMOS can, in theory, deliver the photometric precision required for transmission spectroscopy. However, this is shown to require a) pre-imaging to ensure accurate centering and b) a very stable night with optimal observing conditions (seeing $\sim$0.8"). Combining these two factors with the need to observe several transits, each with a sufficient out-of-transit baseline (and with the fact that similar or better precision can be reached with telescopes and instruments with smaller pressure,) we conclude that transmission spectroscopy is not the optimal science case to take advantage of the abilities offered by KMOS and VLT., Comment: 11 pages, accepted to MNRAS

We explore cloudy, extended H2-He atmosphere scenarios for the warm super-Earth GJ 1214b using an optimal estimation retrieval technique. This planet, orbiting an M4.5 star only 13 pc from the Earth, is of particular interest because it lies between the Earth and Neptune in size and may be a member of a new class of planet that is neither terrestrial nor gas giant. Its relatively flat transmission spectrum has so far made atmospheric characterisation difficult. The NEMESIS algorithm (Irwin et al. 2008) is used to explore the degenerate model parameter space for a cloudy, H2-He-dominated atmosphere scenario. Optimal estimation is a data-led approach that allows solutions beyond the range permitted by ab initio equilibrium model atmosphere calculations, and as such prevents restriction from prior expectations. We show that optimal estimation retrieval is a powerful tool for this kind of study, and present an exploration of the degenerate atmospheric scenarios for GJ 1214b. Whilst we find a family of solutions that provide a very good fit to the data, the quality and coverage of these data are insufficient for us to more precisely determine the abundances of cloud and trace gases given an H2-He atmosphere, and we also cannot rule out the possibility of a high molecular weight atmosphere. Future ground- and space-based observations will provide the opportunity to confirm or rule out an extended H2-He atmosphere, but more precise constraints will be limited by intrinsic degeneracies in the retrieval problem, such as variations in cloud top pressure and temperature., 15 pages, 13 figures, 10 tables. Accepted for publication in MNRAS

International audience; The Atmospheric Remote-Sensing Infrared Exoplanet Large-survey (ARIEL) is one of the three candidate missions selected by the European Space Agency (ESA) for its next medium-class science mission due for launch in 2026. The goal of the ARIEL mission is to investigate the atmospheres of several hundred planets orbiting distant stars in order to address the fundamental questions on how planetary systems form and evolve. During its four (with a potential extension to six) years mission ARIEL will observe 500+ exoplanets in the visible and the infrared with its meter-class telescope in L2. ARIEL targets will include gaseous and rocky planets down to the Earth-size around different types of stars. The main focus of the mission will be on hot and warm planets orbiting close to their star, as they represent a natural laboratory in which to study the chemistry and formation of exoplanets. The ARIEL mission concept has been developed by a consortium of more than 50 institutes from 12 countries, which include UK, France, Italy, Germany, the Netherlands, Poland, Spain, Belgium, Austria, Denmark, Ireland and Portugal. The analysis of the ARIEL spectra and photometric data in the 0.5-7.8 micron range will allow to extract the chemical fingerprints of gases and condensates in the planets' atmospheres, including the elemental composition for the most favorable targets. It will also enable the study of thermal and scattering properties of the atmosphere as the planet orbit around the star. ARIEL will have an open data policy, enabling rapid access by the general community to the high-quality exoplanet spectra that the core survey will deliver.

We have developed a new retrieval approach to modelling near-infrared spectra of Uranus that represents a significant improvement over previous modelling methods. We reanalysed IRTF/SpeX observations of Uranus observed in 2009 covering the wavelength range 0.8 to 1.8 microns and reported by Tice et al. (2013). By retrieving the imaginary refractive index spectra of cloud particles we are able to consistently define the real part of the refractive index spectra, through a Kramers-Kronig analysis, and thus determine self-consistent extinction cross-section, single-scattering and phase-function spectra for the clouds and hazes in Uranus' atmosphere. We tested two different cloud-modelling schemes used in conjunction with the temperature/methane profile of Baines et al. (1995), a reanalysis of the Voyager-2 radio-occultation observations performed by Sromovsky, Fry and Tomasko (2011), and a recent determination from Spitzer (Orton et al., 2014). We find that both cloud-modelling schemes represent the observed centre-of-disc spectrum of Uranus well, and both require similar cloud scattering properties of the main cloud residing at approximately 2 bars. However, a modified version of the Sromovsky, Fry and Tomasko (2011) model, with revised spectral properties of the lowest cloud layer, fits slightly better at shorter wavelengths and is more consistent with the expected vertical position of Uranus' methane cloud. We find that the bulk of the reflected radiance from Uranus arises from a thick cloud at approximately the 2 bar level, composed of particles that are significantly more absorbing at wavelengths > 1.0 micron than they are at wavelengths < 1.0 micron. This spectral information provides a possible constraint on the identity of the main particle type., 52 Pages, 14 Figures