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Human emissions of greenhouse gases have caused a predictable rise of 1.2 °C in global temperatures. Over the last 70 years, the rise has occurred at a geologically unprecedented speed and scale. To avoid a worsening situation, most developed nations are turning to renewable sources of power to meet their climate commitments, including the UK, Norway, Denmark and The Netherlands. The North Sea basin offers many advantages in the transition from fossil fuels by virtue of its natural resources, physical setting, offshore infrastructure and skilled workforce. Nonetheless, the magnitude of the up-front costs and the scale required to achieve net zero emissions are rarely acknowledged. In addition, some of the technologies being planned are commercially immature. In particular, the current cost of the capture, transport and disposal of carbon dioxide is problematic as a large-scale solution to industrial emissions. Repurposing the North Sea to meet a low-carbon future will require substantial collaboration between governments and industrial sectors. There are nonetheless significant opportunities for companies prepared to switch from the traditional oil and gas business to renewable energy production and other sustainable activities.

The Rukwa Rift Basin, Tanzania is regarded as a modern example of a cratonic rift zone despite complex polyphase extensional and episodic inversion structures. We interpret 2D seismic reflection data tied to wells to identify and describe structures controlling stratigraphic sequences (Late Carboniferous to Pleistocene) in two main segmented Rukwa Rift domains, A and B, which are controlled by the Chisi and Saza shear zones. Fault geometry and stratal patterns are illustrated in relation to their kinematic interaction with folds. Fold structures reflect both extensional and compressional deformation and were mapped with a particular interest for their helium potential. We illustrate fault bend folds, fault propagation folds and fault propagation monoclines that are related to extension events. Folds related to compression exhibit various structural styles reflecting at least two phases of episodic and widespread inversion. First, Early Jurassic inversion phase which involved multi-faulted anticlines in the Karoo strata. Second, a mild and widespread inversion structures during the Pleistocene which are characterised by both symmetrical and asymmetrical anticlines styles. Taken together, the extensional and compressional fold structures, stratal juxtapositions and unconformities define stratigraphic packages that are widely distributed in the Rukwa Rift Basin, and form potential subsurface traps for helium-nitrogen–rich gases, from which some seep to the surface, evidently documented in thermal springs across the region.

Clay-coated grains play an important role in preserving reservoir quality in high-pressure, high-temperature (HPHT) sandstone reservoirs. Previous studies have shown that the completeness of coverage of clay coats effectively inhibits quartz cementation. However, the main factors controlling the extent of coverage remain controversial. This research sheds light on the influence of different depositional processes and hydrodynamics on clay-coat coverage and reservoir quality evolution. Detailed petrographic analysis of core samples from the Triassic fluvial Skagerrak Formation, Central North Sea, identified that channel facies offer the best reservoir quality; however, this varies as a function of depositional energy, grain size and clay content. Due to their coarser grain size and lower clay content, high-energy channel sandstones have higher permeabilities (100–1150 mD) than low-energy channel sandstones ( Supplementary material: of data and technique used in this study are available at https://doi.org/10.6084/m9.figshare.c.6438450

Karstified and fractured Lower Carboniferous (Mississippian) limestones of the UK have been evaluated for their geothermal potential. This wholly undeveloped resource is calculated to be in excess of 26 million GWh (95 EJ) for the P90 case and as much as 35 million GWh (129 EJ) for the P50 case for six regions in England and Wales, ranging in scale from Kent at 0.04 million GWh (P50) to Northern England at 15 million GWh (P50). The evaluation used three sources of evidence to assess the distribution, current burial depth, likely temperatures and transmissivity of these limestones. Seismic and outcrop data, well logs and core from drilled wells and water chemistry data from thermal springs were used to demonstrate the presence of deep, water bearing, permeable limestones. Geothermometry calculations using spring-water composition data provided clues about temperatures at which the issuing water equilibrated with its original host rock indicating that water now reaching the surface had acquired its solutes at temperatures significantly in excess of 30 °C and depths much greater than 1km. The UK uses about 2.5 EJ per annum yielding a resource to use ratio of 40-50 years assuming no natural inflow or reinjection of cooled water for reheating.

The energy transition has started. While traditional petroleum exploration and production will become increasingly difficult, the offshore region around the UK, Norway, Denmark and the Netherlands offers many opportunities for companies prepared to embrace low-carbon energy and related activities. We present 19 ideas for new sustainable business. If climate commitments are to be met, the scale of the transformation will be immense. Assuming the economics of floating technologies improve, we envisage the majority of the North Sea (>100,000km2) to be repurposed for renewable power and related activities. In order to fully unlock the future value in wind, solar and ocean energies, as well as in subsurface storage, companies and governments will need to work together to create an integrated energy system.

The Forties Sandstone Member is an important deep-water reservoir in the Central North Sea. The role of depositional characteristics, grain-coating clays, and diagenesis in controlling the reservoir quality of the sandstones is poorly understood. The main aim of the study is to understand the role of depositional characteristics, grain-coating and pore-filling clays, and diagenesis in controlling the reservoir quality evolution of turbidite-channel sandstones. The study employed a multi-disciplinary technique involving thin section petrography and scanning electron microscopy (SEM) to investigate the impact of grain size, clay matrix content, mode of occurrence of grain-coating chlorite and illite, and their impact in arresting quartz cementation and overall reservoir quality in the sandstones. Results of our study reveal that porosity evolution in the sandstones has been influenced by both primary depositional characteristics and diagenesis. Sandstones with coarser grain size and lower pore-filling clay content have the best reservoir porosity (up to 28%) compared to those with finer grain size and higher pore-filling clay content. Quartz cement volume decreases with increasing clay-coating coverage. Clay coating coverage of >40% is effective in arresting quartz cementation. Total clay volume of as low as 10% could have a deleterious impact on reservoir quality. The Forties Sandstone Member could potentially be a suitable candidate for physical and mineralogical storage of CO2. However, because of its high proportion (>20%) of chemically unstable minerals (feldspar, carbonates, and clays), their dissolution due to CO2 injection and storage could potentially increase reservoir permeability by an order of magnitude, thereby affecting the geomechanical and tensile strength of the sandstones. Therefore, an experimental study investigating the amount of CO2 to be injected (and at what pressure) is required to maintain and preserve borehole integrity. The findings of our study can be applied in other reservoirs with similar depositional environments to improve their reservoir quality prediction.

Large scale storage of heat is critical for the successful decarbonisation of the UK’s energy mix and for grid-balancing. Heat generation currently accounts for 50% of all energy use in the UK and most of this is produced by burning fossil natural gas. Heat is regarded as a single-use commodity, discarded or dissipated when not required in summer yet a lifesaving necessity during the colder winter months. Here we estimate the theoretical potential capacities for the storage of heat in the subsurface using aquifers and flooded mines, with a consideration of seasonal storage of heat in particular. We set this against the theoretical potential volumes of waste heat and solar thermal energy that could be exploited. This contributes to the wider knowledge base of the capacity of different forms of energy storage available through other means and highlights the potential for the UK. Our calculations indicate that the theoretical potential for large-scale underground thermal-energy storage in the UK is substantial, much larger than which might ever be needed and the location of such storage is well matched to the places where people live and work and therefore where the demand for heat occurs.

Hydrocarbon reservoirs hosted in Permian strata were some of the first to have been discovered in Europe. With discoveries in the Zechstein carbonates of Norway in recent years, and with exploration of Zechstein prospects both onshore and offshore UK, as well as in Dutch, Danish and Norwegian offshore sectors, understanding the architecture of the Zechstein carbonates remains very relevant. Here we study outcrops of Roker Formation carbonates (Z2, Ca2) in NE England to better understand geological processes associated with deformation following evaporite dissolution, with implications for exploration and production. Collapse of Z2 Roker Formation strata in NE England, following the dissolution of c. 100 m or more of the Z1 Hartlepool Anhydrite, resulted in fundamental changes to the architecture of the succession. Complete dissolution of the anhydrite removed an effective regional seal and dramatically enhanced matrix and fracture permeability of the overlying Roker Formation. The collapsed Roker Formation can be vertically divided into three zones, based upon the degree of deformation. The lower zone and vertical collapse-breccia pipes that can extend across all zones have the highest permeabilities. The process of collapse was gradual, with local variations in the degree of brecciation. We derive a schematic sequence of collapse, recognizing the impact of mechanical barriers within the succession in retarding deformation up-section and it is this that ultimately leads to the vertical zonation. Timing of evaporite dissolution is poorly constrained: it could have occurred soon after deposition, at the end of the Permian or during Tertiary uplift. It is known that evaporite dissolution has occurred offshore, with the oil fields Auk and Argyll (UK Central North Sea) given as examples of dissolution collapse-brecciated reservoirs. Reservoir quality is typically improved, with both matrix and fracture porosity and permeability enhanced. Complete evaporite dissolution could in some cases lead to the potential breach of the seal.

The Alma Field (formerly Argyll and then Ardmore) is located within Blocks 30/24 and 30/25 on the western margin of the Central Graben. Hamilton drilled the first discovery well 30/24-1 in 1969 and the field, named ‘Argyll’, became the first UK offshore oilfield when production commenced in 1975. Oil was produced from the Devonian Buchan Formation, Permian Rotliegend and Zechstein groups, and Jurassic Fulmar Formation from 1976 until 1992, when the field was abandoned for economic reasons. In 2002, Tuscan Energy and Acorn Oil & Gas redeveloped the field and renamed it as ‘Ardmore’. A further 5 MMbbl were produced until 2005, when the field was again abandoned due to commercial considerations. In 2011, EnQuest was awarded the licence to redevelop the field and renamed it as ‘Alma’. The field came on stream in October 2015 and has produced oil at an average c. 6000 bopd since start-up. Total ultimate recovery was expected to be about 100 MMbbl. As of end 2005, the field had produced 72.6 MMbbl as Argyll and 5 MMbbl as Ardmore. A further 4.3 MMbbl has been produced from the Alma Field to September 2017 (which includes about 0.5 MMbbl from a long-reach well drilled into the Duncan/Galia Field immediately west of Alma). In January 2020 EnQuest announced that the Alma Field would cease production early. The total production from the three phases of field development will be about 85 MMbbl of oil.

The Breagh Field is in UK Blocks 42/12a, 42/13a and 42/8a. It is a gas field with multiple reservoir intervals within sandstones of the Early Carboniferous Yoredale Formation (equivalent to the Middle Limestone Formation within the Yoredale Group onshore). It was the first and is presently the only field developed within these sandstones, offshore UK. Breagh was discovered in 1997 by well 42/13-2 and proved by development well 42/13a-A1. Its crest is at 7110 ft TVDSS (true vertical depth subsea), marked by the unconformity between the base Zechstein and the subcropping Yoredale Formation. It has a free water level at 7690 ft TVDSS, a maximum column height of 510 ft and a field extent of 94 km2. Breagh was developed using ten wells from a 12 slot normally unattended platform; five of the wells have been stimulated by hydraulic fractures with proppant injection. The unprocessed gas flows through a 110 km 20-inch diameter pipeline to the Teesside Gas Processing Plant. Production started in 2013, reached a peak rate of 150 MMscfgd in 2014 and, by the end of 2018, had produced 140 bcf. The field is operated by INEOS Oil and Gas UK Ltd (70%) with partner ONE-Dyas B.V. (30%).

The Morag Field is a small oilfield underlying the Maureen Field in UK Block 16/29a. Black oil is trapped within Upper Permian, Morag Member, vuggy and fractured dolomite rafts between 9300 and 10 600 ft true vertical depth subsea. The dolomite reservoir occurs at the top of a Zechstein salt dome. Morag was discovered in 1979 by well 16/29a-A1, the first platform well drilled for the overlying Maureen Field with its Paleocene sandstone reservoir. Morag was produced via a single well (16/29a-A1) between 1991 and 1994. Three more platform wells were drilled into the Permian interval prior to Maureen Field start up but only one penetrated oil-bearing dolomite (16/29a-A2). An additional well (16/29a–A23Z) was drilled into the Morag Field in 1993. The well encountered Morag Member at virgin pressure and tested oil at high flow rate but then the well failed due to mechanical problems. Oil in place was calculated to be about 24 MMbbl in four independent fault blocks. Ultimately 16/29a-A1 delivered 2.6 MMbbl from a fault block calculated to have held 6.7 MMbbl stock tank oil initially in place.

Located 160 km NE of the Shetland Islands in the East Shetland Basin, the Dunlin Cluster comprises four produced fields, Dunlin, Dunlin SW, Osprey and Merlin, in addition to some near-field satellite discoveries, Skye and Block 6. Dunlin was discovered in July 1973 and production began in August 1978. The field was developed using a concrete gravity-base platform, Dunlin Alpha, which also served as the production facility for the rest of the Dunlin Cluster. Osprey was discovered in 1974 but not tied-in until January 1991. Dunlin SW was discovered in 1973 but not brought onto production until 1996. Merlin was discovered in February 1997 and tied-in later that same year. Fairfield Energy acquired the Dunlin Cluster in 2008, and a programme of investment and facilities improvements, primarily in fuel gas infrastructure and power generation, sought to boost water-injection rates and bolster production, thereby extending the life of the asset. Ultimately, the Dunlin Cluster ceased production on 15 June 2015 after having maximized economic hydrocarbon recovery. The total Dunlin Cluster production exceeded 500 MMbbl of oil (Dunlin and Dunlin SW, 395 MMbbl oil; Osprey, 92 MMbbl oil; and Merlin, 27 MMbbl oil).

The, as yet undeveloped, heavy-oil fields of the Western Platform contain about 500 MMbbl of oil in place. The fields are reservoired in highly porous and permeable, Middle Eocene, deep-water sandstones of the Tay Sandstone Member, deposited as turbidite flows from a shelf immediately to the west. Oil gravity varies from 19° API in the Harbour Field to 12° API in the northern end of the Pilot Field. The reservoirs are shallow: Pilot and Harbour are at about 2700 ft TVDSS, with the Narwhal, Elke, Blakeney and Feugh discoveries being deeper at about 3300 ft TVDSS. Overall, oil viscosity decreases and API oil gravity increases with depth. To date, the high oil viscosity has precluded development of these discoveries, and many previous operators have considered various development schemes, all based on water flood. The development of the Pilot Field is being planned using either a hot-water-flood, steam-flood or polymer-flood approach, which all have the potential of achieving a very high recovery factor of 35–55%. Steam has been evaluated in most detail and about 240 MMbbl could be recovered should all of these discoveries be steam flooded.

The Cavendish Field is located in UK Continental Shelf Block 43/19a on the northern margin of the Outer Silverpit Basin of the Southern North Sea, 87 miles (140 km) NE of the Lincolnshire coast in a water depth of 62 ft (18.9 m). The Cavendish Field is a gas field in the upper Carboniferous Namurian C (Millstone Grit Formation) and Westphalian A (Caister Coal Formation) strata. It was discovered in 1989 by Britoil-operated well 43/19-1. Production started in 2007 and ceased in 2018. Gas initially in place was 184 bcf and at end of field life 98 bcf had been produced. The field was developed by three wells drilled through the normally unmanned platform into fluvio-deltaic sandstone intervals that had sufficiently good reservoir quality to be effective reservoirs. The majority of the formation within closure comprises mudstones, siltstones and low permeability, non-reservoir-quality feldspathic sandstones. The quality of the reservoir is variable and is controlled by grain size, feldspar content and diagenesis. The field is a structural trap, sealed by a combination of intra-Carboniferous mudstones and a thick sequence of Permian mudstones and evaporites.

The Humbly Grove Field has, for the UK, a unique development history. It was discovered as an oilfield in May 1980 and produced as an oilfield until 2000 along with small satellite fields Herriard (developed) and Hester9s Copse (not developed). Peak production of 2219 bopd was achieved during July 1986 but, by October 1988, the rate had fallen to around 1000 bopd, a rate that was more or less maintained until October 1995 after which the production fell rapidly. At this point the decision was taken to reconfigure the field as a gas storage facility. Significant renewed pressure depletion occurred between 2000 and 2005, following which first cushion and then storage gas was injected into two reservoirs: the Middle Jurassic, Great Oolite Group and the uppermost Triassic, Rhaetian Westbury Formation. Gas storage operations commenced in 2005 and the reservoirs have undergone cyclical gas injection and gas withdrawal since that date. The cyclical injection of gas and re-pressuring of the Great Oolite reservoir causes mobile oil to be swept towards dedicated oil production wells. This operates effectively as an enhanced oil recovery scheme. The co-produced liquid hydrocarbons provide a valuable secondary income stream for the field.

This volume was conceived when one of us (JG) returned to the UK in mid-1996. Having not worked the UK offshore since the late 1980s it was clear that there had been many changes, not least in the number of fields on production. During that first year back in the UK, JG9s copy of Abbots (1991) UK Oil and Gas Fields, 25 Years Commemorative Volume became exceedingly well used. A casual comment to Wendy Cawthorne of the Geological Society library to this effect solicited the response that JG was not alone in finding Abbots (1991) useful. Memoir 14 was the Geological Society9s 9best seller9. However, although Abbots (1991) continues to sell well, it was by 1996 out of date insofar as it contains papers describing only about half of the fields then on production. A combination of egotistical zeal, wishing for a bestseller and altruism towards the UK industry led us to make an offer to the Geological Society to revise Memoir 14. The offer was accepted and by April 1998, editors had been appointed and letters of invitation to contribute to the memoir were sent to exploration managers in all the UK operating companies. The responses to those letters were for the most part positive. A request was made to authors for manuscripts to be sent to the editors by June 1999. The first to arrive was six months ahead of schedule (thanks A. Yaliz & N. McKim for their paper on the Douglas Field). However, neither the editors

Hutton (discovered in 1973) and NW Hutton (discovered in 1975), together with Q-West (discovered in 1994) and Darwin (discovered in 1983, undeveloped), are part of a single petroleum system. The main fields were defined as two separate legal entities. Although Q–West covered multiple blocks, it was wholly developed via the Hutton platform. Together, Hutton and NW Hutton produced 328 MMbbl of oil and a small quantity of associated gas from Middle Jurassic Brent Group sandstones. The trap is a complex series of tilted fault blocks sealed by Mid–Upper Jurassic Heather and Kimmeridge Clay Formation mudstones. Oil was sourced from the Kimmeridge Clay Formation, which is mature for oil generation in the hanging walls to the field-bounding faults and deep on the footwall flanks. NW Hutton underperformed relative to Hutton. In part this was due to the poorer reservoir quality encountered at depth compared with the shallower Hutton Field but a significant component of the underperformance was due to the way in which the field was developed and then operated. Both fields contain areas of unproduced and unswept oil, with the NW Hutton portion having the largest remaining oil in place.

Minewater heating is a form of shallow geothermal energy provision that exploits abandoned subsurface mines that have since flooded after mining activity ceased. Groundwater that occupies the void space left from material extraction is warmed to ambient temperatures by heat transfer exchanges with the surrounding rock.By using ground source heat pumps, the temperatures of these waters can be lifted to those suitable for domestic heat use, with efficient electrical input. An assessment to determine the feasibility of the implementation of a minewater heating system on the Durham University campus is currently in progress, with results due in March 2022. The system would use abandoned coal mines of the Durham Coalfield to heat several student accommodation buildings built above.Assuming abstraction and reinjection of the minewater, we investigated the available heat resource using a numerical modelling tool developed at Durham University. This tool modelled the minewater flow through the void space of the mines and thermal interaction with the surrounding rock.A new methodology was developed for the digitisation of historic mine plans provided by the UK’s Coal Authority, which have then been modelled to provide 3D visualisation of technical factors critical to the success of such a project. Various configurations have been tested, and results indicate over 11 million kWh of heat in place resource available, at temperatures of 14°C. This heat in place figure is likely an underestimation of the resource as records indicate deeper seams were also mined at the locality. We subsequently carried out an assessment of the economic feasibility. If a decentralised configuration were chosen for the design, it would be advisable to focus on three buildings with the most student rooms. Initial costs would be high, driven mainly by the associated costs of drilling injection and extraction wells. As the target seams are relatively shallow (145m for extraction and 70m for injection), smaller wells could be used, costing roughly £40,000 per well. If a centralised design were used, costs would be reduced by drilling fewer wells. However, retrofit work to replace the original centralised gas infrastructure connections could induce significant cost and disruption. However, running costs would be low, and emissions savings from not using gas boilers would be significant; peak daily CO₂ emissions from gas were 17,992 kg in 2019.Finally, to assess the internal policy structure of the university and the feasibility of permission to be granted for the project, a social acceptance study was undertaken with key members of the university’s Board of Directors. Considering the project through the concept of risk, obstacles to implementation were identified, and potential policy solutions were developed.This study provided insights into current institutional views on engaging with innovative energy technologies. Future work may benefit from understanding these to produce relevant solutions to mitigate them in their feasibility studies.

Organic-inorganic interactions between hydrocarbons and most minerals in deeply buried reservoirs remain unclear. In this study, gold capsules and fused silica capillary capsules (FSCCs) with different combinations of nC16H34, water (distilled water, CaCl2 water) and minerals (quartz, feldspar, calcite, kaolinite, smectite, and illite) were heated at 340 °C for 3–10 d, to investigate the evolution and reaction pathways of the organic–inorganic interactions in different hot systems. After heating, minerals exhibited little alteration in the anhydrous systems. Mineral alterations, however, occurred obviously in the hydrous systems. Different inorganic components affected nC16H34 degradation differently. Overall, water promoted the free-radical thermal-cracking reaction and step oxidation reaction but suppressed the free-radical cross-linking reaction. The impact of CaCl2 water on the nC16H34 degradation was weaker than the distilled water as high Ca2+ concentration suppressed the formation of free radicals. The presence of different waters also affects the impact of different minerals on nC16H34 degradation, via its impact on mineral alterations. In the anhydrous nC16H34-mineral systems, calcite and clays catalyzed generation of low-molecular-weight (LMW) alkanes, particularly the clays. Quartz, feldspar, and calcite catalyzed generation of high-molecular-weight (HMW) alkanes and PAHs, whereas clays catalyzed the generation of LMW alkanes and mono-bicyclic aromatic hydrocarbons (M-BAHs). In the hydrous nC16H34-distilled water–mineral systems, all minerals but quartz promoted nC16H34 degradation to generate more LMW alkanes, less HMW alkanes and PAHs. In the nC16H34-CaCl2 water–mineral systems, the promotion impact of minerals was weaker than that in the systems with distilled water. This study demonstrated the generation of different hydrocarbons with different fluorescence colors in the different nC16H34-water–mineral systems after heating for the same time, implying that fluorescence colors need to be interpreted carefully in investigation of hydrocarbon charging histories and oil origins in deeply buried reservoirs. Besides, the organic–inorganic interactions in different nC16H34-water–mineral systems proceeded in different pathways at different rates, which likely led to preservation of liquid hydrocarbons at different depth (temperature). Thus, quantitative investigations of the reaction kinetics in different hydrocarbon-water-rock systems are required to improve the prediction of hydrocarbon evolution in deeply buried hydrocarbon reservoirs. Graphical abstract

Meteorological-tsunami-like (or meteotsunami-like) periodic oscillation was muographically detected with the Tokyo-Bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) deployed in the underwater highway called the Trans-Tokyo Bay Expressway or Tokyo Bay Aqua-Line (TBAL). It was detected right after the arrival of the 2021 Typhoon-16 that passed through the region 400 km south of the bay. The measured oscillation period and decay time were respectively 3 hours and 10 hours. These measurements were found to be consistent with previous tide gauge measurements. Meteotsunamis are known to take place in bays and lakes, and the temporal and spatial characteristics of meteotsunamis are similar to seismic tsunamis. However, their generation and propagation mechanisms are not well understood. The current result indicates that a combination of muography and trans-bay or trans-lake underwater tunnels will offer an additional tool to measure meteotsunamis at locations where tide gauges are unavailable.

Previously CO2, as a heat-extraction fluid, has been proposed as a superior substitute for brine in geothermal energy extraction. Hence, the new concept of CO2-plume geothermal (CPG) is suggested to generate heat from geothermal aquifers using CO2 as the working fluid. In January 2015, a CPG-thermosiphon system commenced at the SECARB Cranfield Site, Mississippi. By utilising CO2, the demand for the pumping power is greatly reduced due to the thermosiphon effect at the production well. However, there are still parameters such as aquifer thermal depletion, required high injection rates, and CO2-plume establishment time, that hinder CPG from becoming viable. Moreover, the fluvial nature of sedimentary aquifers significantly affects the heat and mass transfer inside the aquifer, as well as the system performance. In the present study, a direct-CO2 thermosiphon system is considered that produces electricity from a 3D braided-fluvial sedimentary aquifer by providing an excess pressure at the surface that is used in the turbine. The system performance and net power output are analyzed in 15 3D fluvial heterogeneous - with channels’ widths of 50, 100, and 150 m - and three homogeneous aquifer realizations with different CO2 injection rates. It is observed that the presence of fluvial channels significantly increases the aquifer thermal depletion pace (22-120%) and therefore, reduces the system’s performance up to about 75%. Additionally, it is found that the CPG system with the CO2 injection rate of 50 kg/s and the I-P line parallel to the channels provides the maximum cycle operation time (44 years), as well as the optimum performance for the heterogeneous cases of the present study by providing about 0.06-0.12 TWh energy during the simulation time of 50 years. Also, to prevent rapid drops in excess pressure, a system with a yearly adjustable injection rate is implemented, which prevents the production well bottomhole temperature to fall below 80 ◦C.

Tidal measurements are of great significance since they may provide us with essential data to apply towards protection of coastal communities and sea traffic. Currently, tide gauge stations and laser altimetry are commonly used for these measurements. On the other hand, muography sensors can be located underneath the seafloor inside an undersea tunnel where electric and telecommunication infrastructures are more readily available. In this work, the world’s first under-seafloor particle detector array called the Tokyo-bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) was deployed underneath the Tokyo-Bay seafloor for conducting submarine muography. The resultant 80-day consecutive time-sequential muographic data were converted to the tidal levels based on the parameters determined from the first-day astronomical tide height (ATH) data. The standard deviation between ATH and muographic results for the rest of a 79-day measurement period was 12.85 cm. We anticipate that if the length of the TS-HKMSDD is extended from 100 m to a full-scale as large as 9.6 km to provide continuous tidal information along the tunnel, this muography application will become an established standard, demonstrating its effectiveness as practical tide monitor for this heavy traffic waterway in Tokyo and in other important sea traffic areas worldwide.

Coal‐formed gas generated from the Permo‐Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin, offshore eastern China. However, the proven gas reserves from this source rock are remain low to date, and the distribution characteristics and accumulation model for the coal‐formed gas are not clear. Here we review the coal‐formed gas deposits formed from the Permo‐Carboniferous coal measures in the Bohai Bay Basin. The accumulations are scattered, and dominated by middle‐small sized gas fields, of which the proven reserves ranging from 0.002 to 149.4×108m3 with an average of 44.30×108m3 and a mid‐point of 8.16×108m3. The commercially valuable gas fields are mainly found in the central and southern parts of the basin. Vertically, the coal‐formed gas is accumulated at multiple stratigraphic levels from Paleogene to Archaeozoic, among which the Paleogene and Permo‐Carboniferous are the main reservoir strata. According to the transporting pathway, filling mechanism and the relationship between source rocks and reservoir, the coal‐formed gas accumulation model can be defined into three types: “Upward migrated, fault transported gas” accumulation model, “Laterally migrated, sandbody transported gas” accumulation model, and “Downward migrated, sub‐source, fracture transported gas” accumulation model. Source rock distribution, thermal evolution and hydrocarbon generation capacity are the fundamental controlling factors for the macro distribution and enrichment of the coal‐formed gas. The fault activity and the configuration of fault and caprock control the vertical enrichment pattern.

SUMMARY Cosmic ray muons are highly penetrating, with some reaching several kilometres into solid rock. Consequently, muon detectors have been used to probe the interiors of large geological structures, by observing how the muon flux varies with direction of arrival. There is an increasing need to discriminate between materials differing only slightly in bulk density. A particularly demanding application is in monitoring underground reservoirs used for CO2 capture and storage, where bulk density changes of approximately 1 per cent are anticipated. Muon arrival is a random process, and it is the underlying expectation values, not the actual muon counts, which provide information on the physical parameters of the system. It is therefore necessary to distinguish between differences in muon counts due to real geological features, and those arising from random error. This is crucial in the low-contrast case, where the method can reach the information theoretic limit of what a data source can reveal, even in principle. To this end, methods to analyse information availability in low-contrast muon radiography have been developed, as have means to optimally interpret the available data, both for radiography and for tomography. This includes a method for calculating expectation values of muon flux for a given geological model directly, complementing existing Monte Carlo techniques. A case study, using a model of carbon capture is presented. It is shown that the new data analysis techniques have the potential to approximately double the effective sensitivity of the detectors.

The Permo-Carboniferous sandstones in the Gubei area, Bohai Bay Basin, are reservoirs for large accumulations of natural gas. The natural gas accumulations only occur in the sandstone beds thicker than 1.9 m. Moreover, the maximum porosity of every bed correlates positively with bed thickness up to 2.0 m and for thicker beds porosity is uniform. Porosity transitional zones developed at the top and bottom of each bed, with mean thicknesses of 1.25 m and 0.75 m, respectively. Porosity shows a positive correlation with the distance to the sandstone/mudstone contact in the zones. Interpretations based upon an extensive petrographic and geochemical database indicate that the sandstones experienced a mass fluid input from the adjacent mudstones during the early diagenesis. The infiltration resulted in extensive clay coats and pore-filling cements in sandstones, which were effective for inhibiting dissolution of grains during subsequent diagenesis process. The mass introduction only affected the marginal parts of the sandstones within 1.25 m of the top and 0.75 m of the bottom of every bed, causing thin sandstone beds with thickness of approximately 2 m to be tightly cemented totally. Thus the central parts of each (thicker) beds became preferential sites for the natural gas accumulation. The differential levels of cementation in thin and thick sandstone beds observed here has significant implications for exploration of similar interbedded sandstone and shale sequences elsewhere including shale gas targets.

Late Carboniferous-Permian was a longest-lived and most widespread ice age. The depositional environment, diagenesis and reservoir quality of carbonate rocks as response to the glacio-eustatic changes was analyzed in this study. The Upper Carboniferous Xiaohaizi Formation in the western Tarim Basin is an important oil reservoir. The dolostones from the Xiaohaizi Formation have very good physical properties, with maximum porosity and permeability of 16.6% and 214mD, respectively. The sedimentary facies of the Xiaohaizi Formation consist of carbonate shoals and lagoon on a mixed siliciclastic-carbonate platform. There was a strong heterogeneity of carbonate rocks deposited on shoals. Porous dolostones always alternate with tight sparry allochemical limestones. Based on the petrographic observation and stable isotope measurement, the controlling factors for the heterogeneity and reservoir quality were revealed. The palaeosol, vadose silt, karst breccia, detrital kaolinite, darkening of dolostones and enrichment of 18O indicate the short-lasting subaerial emergence during the glacial period. During the glacial sea level fall, the mixed siliciclastic and carbonate allochems deposited on bioclastic and intraclastic shoals, while dolomitization of calcic grains occurred under a relatively low-temperature. Through the correlation analysis of physical property, lithology, rock components, it's suggested that the reservoir quality of the Xiaohaizi Formation was controlled by mixed sedimentation and dolomitization associated with glacio-eustatic fluctuation. At the burial diagenesis, the effect of hydrothermal fluid on physical properties of dolostones with relative high primary porosity was positive, whereas resulted in the poikilotopic calcite cementation. The assembly of fluorite, dickite and authigenic pyrite were indicators for hydrothermal fluid accumulation. The control of glacio-eustatic fluctuations on sedimentation and diagenesis in carbonates could be used to forecast the reservoir quality.

The reservoir quality of tight sandstones is generally determined by the depositional environment, burial depth and diagenesis. However, the relationship between reservoir quality of tight sandstones and the controlling factors are very complicated. Deeply buried Middle-Upper Jurassic Shishugou Group sandstones are important tight oil sandstone reservoirs in the central Junggar Basin of NW china. The individual sandstones are thin (2–20 m, av.7.8 m), overlain by an unconformity and directly connected to the source rock by a well-developed fault system. The diagenetic system and reservoir quality of the Shishugou Group sandstones in the Central Junggar Basin was investigated using petrology, mineralogy, pore characteristics, sedimentary facies, burial and thermal history, knowledge of hydrocarbon charging, fault/fracture system, diagenetic reactions and sequence, controlling factors of reservoir quality, paleo-porosity reconstruction and formation mechanism of high-quality reservoir. The thin-section observation, scanning electron microscope (SEM and BSD), granularity analysis, Xray diffraction (XRD) and fluorescence microscope, 3D seismic and well logging analysis were used in this research. The top unconformity and faults system were the pathways for water and hydrocarbon migration. Organic acids and meteoric water with high concentrations of CO2 were the main fluids that caused dissolution of volcanic rock fragments, feldspar, analcime cement and early calcite cement. The paleo-porosity variation of Shishugou Group sandstones was analyzed quantitatively by the inversion and back stripping with the constrain of diagenetic evolution history and theoretical compaction models. The comprehensive researches including the origin of pore waters, origin of acidic fluids, fault/fracture system and hydrocarbon charging history, show that near-surface or meteoric diagenetic reactions of Shishugou Group sandstones closely beneath top unconformities were in open (geochemical) diagenetic systems, and that diagenetic (geochemical) systems were relatively open, especially in the faults-developed zone during burial process. The central sandstone body of the point bar, underwater distributary channel and distributary channel, which were cut through by the oil source fault, retained high-quality reservoir. The reservoir quality can be mostly predicted as a function of sedimentary environment (sedimentary facies and provenance), diagenetic reactions and burial history with the constrain of source rocks, diagenetic system and fault system.

Organic-inorganic interactions after oil charging are critical for determining the ongoing evolution of hydrocarbons and rock quality in water-wet siliciclastic reservoirs. It is the conceptual approach of this study to simulate and decipher these interactions by using quantitative analyses of the interrelated changes of minerals, water, hydrocarbons, gases, and organic acids in heated oil-water-rock systems. The experimental results show that organic-inorganic interactions occur between the organic oil and inorganic feldspar in the presence of water. Water promotes the oil degradation by an extra supply of H+ and OH- ions. In the oil-water-rock systems, mutual exchanges of H+ and OH- ions among minerals, water, and hydrocarbons probably result in the mutual interactions between oil degradation and mineral alteration, with water serving as a matrix for the ion exchange. In the oil-water-feldspar system, feldspar alteration does not cease in the oil zone in the presence of some water and, inversely, oil degradation can even accelerate the alterations of the aluminosilicate minerals. The mineral alterations from feldspar to boehmite, illite, and muscovite promote the oil degradation in the oil-deionized water-feldspar systems with the mutual ion exchange. Due to a possible competition between the Brønsted acid sites in the minerals and the halide anions or the direct replacement of K-feldspar by albite, the mineral alterations retard the oil degradation in the oil-NaCl water-feldspar systems. The experimental results also indicate that oil degradation via free radical cross-linking and free radical thermal cracking is extensive in anhydrous oil systems and may lead to blocking of pores and throats by the generated pyrobitumen in the oil zone of a reservoir. In contrast, in the oil-water transition zone of a reservoir, oil degradation via thermal cracking and oxidative decomposition may dominate the oil degradation and may lead to the generation of secondary pores with leaching of minerals by the generated CO2 and organic acids. This study clearly demonstrates that organic-inorganic interactions are very complex and proceed in diverse pathways in different hydrogeochemical systems. Thus, further quantitative investigations of the reaction pathways and reaction kinetics of coupled mineral alteration and oil degradation in oil-water-rock systems are merited. Meanwhile, the incorporation of such organic-inorganic reactions into geochemical models will improve the prediction of the evolution of organic and inorganic species in petroleum reservoirs.

Proximal to distal fan change in grain size, clay matrix content, and grain-coating clays have been identified as key contributing factors for eservoir quality evolution of submarine fan turbidite sandstones. This study evaluated the role played by grain-coating and pore-filling clays, depositional facies, and diagenesis in reservoir quality evolution of the Paleocene Forties submarine fan sandstones (Central North Sea) from proximal to distal fan settings. To help provide a comprehensive understanding of the role played by pore-filling and grain-coating clays in destroying and preserving reservoir quality, respectively, in turbidite sandstones, we have used a multi-disciplinary approach including petrography, burial history, scanning electron microscopy, and stable isotopes analysis. Results of the study showed that reservoir quality is influenced by both depositional facies and diagenesis. The proximal-fan, amalgamated sandstones facies have the best reservoir quality due to coarser grain size, lower pore-filling clays, and lower amount of ductile grains. In contrast, the distal-fan, mud-prone heterolithic facies have the poorest reservoir quality due to finer grain size, higher pore-filling clays, and higher amount of ductile grains. Pore-filling clays between 10 and 30% have a deleterious effect on reservoir quality, reducing porosities and permeabilities to generally

Tidal measurements are of great significance since they may provide us with essential data to apply towards protection of coastal communities and sea traffic. Currently, the tide gauge stations, satellite-based, pressure-based and ultrasonic-based techniques are commonly used. However, with these techniques, sensors have to be either floated on the sea surface or sunk onto the seafloor. The former option makes it difficult to conduct the tide measurements in high traffic maritime sea channels, and the latter option requires the construction of undersea electric and telecommunication infrastructures to support real time monitoring. On the other hand, with muography, sensors can be located underneath the seafloor inside, for example, an undersea tunnel where the electric and telecommunication infrastructures are more readily available. In this work, the world’s first under-seafloor particle detector array called the Tokyo-bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) was deployed underneath the Tokyo-Bay seafloor for conducting submarine muography. Time-sequential muographic data were converted to the tidal levels above the detector and compared with the data acquired from the nearby tide gauge station. The results were consistent, indicating that submarine muography could be an alternative tool for tide measurements. We anticipate that if the length of the TS-HKMSDD is extended from 100 m to a full-scale as large as 9.6 km to provide continuous tidal information along the tunnel, muography will become an established standard, demonstrating its effectiveness as practical tide monitor for this heavy traffic waterway in Tokyo and in other important sea traffic areas worldwide.

Catastrophic failure of a tailings dam at an iron ore mine complex in Brumadinho, Brazil, on 25th January 2019 released 11.7 million m3 of tailings downstream. Although reportedly monitored using an array of geotechnical techniques, the collapse occurred without any apparent warning. It claimed more than 200 lives and caused considerable environmental damage. Here we present the Intermittent Small Baseline Subset (ISBAS) technique on satellite-based interferometric synthetic aperture radar (InSAR) data to assess the course of events. We find that parts of the dam wall and tailings were experiencing deformation not consistent with consolidation settlement preceding the collapse. Furthermore, we show that the timing of the dam collapse would have been foreseeable based on this observed precursory deformation. We conclude that satellite-based monitoring techniques may help mitigate similar catastrophes in the future. Ground deformation and a sudden acceleration of movement in the final two months preceded the catastrophic collapse of the Brumadinho Tailings Dam in Brazil, according to advanced analyses of InSAR remote sensing data.

The Jurassic Shaximiao Formation on the eastern slope of western Sichuan depression in western Sichuan Basin of China develops a single or overlapping channel sandstones with strong internal heterogeneity. This study aims to reveal the origin of the differences of physical properties within the sandstone reservoirs under different assemblies of lithofacies. Based on analysis of sedimentary structure and grain size, the lithofacies are classified into nine types. Based on the classification of lithofacies formed under different energy of sedimentary environment and mechanical differentiation, the effect of early compaction on physical properties of sandstone reservoirs is confirmed. It is suggested that the physical properties of lithofacies can be influenced by differential diagenesis in different lithofacies assemblies. The rate of early compaction depends on the grain sorting and compositional maturity. The massive bedded lithofacies are prone to be of good grain sorting and high compositional maturity with relatively low compaction rate of 70.91%–72.75%. There are relatively high porosities and permeabilities of sandstones in the lithofacies assembly containing massive bedded lithofacies. Because of the export of diagenetic fluid along the bedding plane of parallel bedded sandstones, there would be relatively intensive dissolution of sandstones developed with parallel bedded lithofacies. Even if the development of parallel bedded sandstones could enhance the dissolution, yet they are subjected to relatively strong compaction, leading to the low proportion of intergranular pores. The permeability of sandstones within the lithofacies assembly containing parallel bedded lithofacies seems to be low. The porosity and permeability of sandstones within the lithofacies assembly containing horizontal bedded lithofacies are both poorer than other assemblies, caused by strong compaction, cementation and weak dissolution. The direction of bedding, argillaceous contents, and the capacity of resistance to compaction are the key factors controlling the physical property of high-quality sandstone reservoirs. The research conclusions can be used to interpret the genesis of different physical properties of sandstone reservoirs in other similar gas fields.