Search

This work aims to explore the gas permeation performance of two newly-designed ionic liquids, [C2mim][CF3BF3] and [C2mim][CF3SO2C(CN)2], in supported ionic liquid membranes (SILM) configuration, as another effort to provide an overall insight on the gas permeation performance of functionalized-ionic liquids with the [C2mim]+ cation. [C2mim][CF3BF3] and [C2mim][CF3SO2C(CN)2] single gas separation performance towards CO2, N2, and CH4 at T = 293 K and T = 308 K were measured using the time-lag method. Assessing the CO2 permeation results, [C2mim][CF3BF3] showed an undermined value of 710 Barrer at 293.15 K and 1 bar of feed pressure when compared to [C2mim][BF4], whereas for the [C2mim][CF3SO2C(CN)2] IL an unexpected CO2 permeability of 1095 Barrer was attained at the same experimental conditions, overcoming the results for the remaining ILs used for comparison. The prepared membranes exhibited diverse permselectivities, varying from 16.9 to 22.2 for CO2/CH4 and 37.0 to 44.4 for CO2/N2 gas pairs. The thermophysical properties of the [C2mim][CF3BF3] and [C2mim][CF3SO2C(CN)2] ILs were also determined in the range of T = 293.15 K up to T = 353.15 K at atmospheric pressure and compared with those for other ILs with the same cation and anion’s with similar chemical moieties.

This paper presents an experimental and analytical study about the mechanical response at elevated temperature of glass fibre reinforced polymer (GFRP) pultruded profiles. The paper first describes results of DMA and DSC tests that were used to evaluate the glass transition and decomposition processes of the GFRP pultruded material. The paper then describes an extensive study about the tensile, shear and compressive responses of the GFRP material at temperatures varying from 20 °C to 250 °C. In these tests the mechanical responses of the GFRP material as a function of temperature were assessed, namely the load–deflection curves, the stiffness, the failure modes and the ultimate strength. Results obtained in these experiments confirmed that the mechanical performance of GFRP is severely deteriorated at moderately high temperatures, particularly when loaded in shear and compression, owing to the glass transition of the resin. The final part of this paper assesses the accuracy of different empirical models and one phenomenological model to estimate the tensile, shear and compressive strengths of GFRP pultruded material as a function of temperature. All empirical models, including a function based on Gompertz statistical distribution suggested in the present paper, provided accurate estimates of tensile, shear and compressive strengths as a function of temperature. The phenomenological model was less accurate and in general provided non conservative estimates of material strength.