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Access to sustainable, clean, affordable, and reliable electricity is crucial for social and economic development, yet Sub-Saharan Africa (SSA) struggles significantly in this context. In CHAD, only 11.3% of the population is able to access electricity, making it one of the least electrified countries in SSA with the lowest clean energy access. In rural areas, electricity access falls to just 1.3%. This research applies and executes a Multi-Objective Particle Swarm Optimization (MOPSO) algorithm using MATLAB R2023b to assess the techno-economic, environmental, and social impacts of a hybrid system based on optimal PV/Wind/Battery/Fuel Cell (FC)/Diesel generator (DG) sizing for rural electrification in CHAD. The proposed system's self-sufficiency index (SSSI) and the Annualized System Cost (ASC) were chosen as objective functions to guarantee the economic feasibility of the system, higher self-sufficiency, and lower dependence on external energy sources (DG). The simulation results show that the optimal size of the proposed system supplies the load demand by 100% of the renewable energy sources (RES) fraction, and the optimal capacities of the main components to supply the load demand are: Solar Power (493 KW), Wind Turbine (166 KW), Battery Energy Charge/Discharge (229180 kWh /221300 kWh), Hydrogen tank storage energy (83 874 kWh), Electrolyzer size (202 KW), Fuel cell size (144 KW). The evelized cost of electricity (LCOE) of 0.2982 $/kWh, which is 51.12% lower than the national unit production costs of electricity in rural areas of CHAD (0.61 $/kWh). This LCOE is also the lowest compared to previous works done using HOMER Pro for the country of CHAD. The results also give a levelized cost of hydrogen (LCOH) of 3.8563 US $/kg, lower than for all studies found in the literature for the country of Chad. The proposed system's yearly avoided greenhouse gas (GHG) emission is 374 640 kg. The proposed system will create five (5) new jobs (JCO) and improve the Human Development Index (HDI) of the study area by 17.66% (the obtained HDI is 0.4683, and the CHAD HDI is 0.398) with an SSSI of 51.14%. This study provides a better practical energy design tool in decision-making for designers, companies, investors, policymakers, and the Chadian government when implementing this type of system in particular rural locations.

The most widely used material in electron transport layers (ETL) of inverted organic solar cells (iOSCs) is zinc oxide (ZnO). However, the brittleness, inorganic nature, surface defects, and photocatalytic activity of ZnO lead to poor stability in iOSCs. Herein, the light‐soaking and thermal stability of iOSCs are substantially improved by modifying ZnO surface with polyurethane diacrylate (SAR) or urethane acrylate (OCS)‐based ultraviolet (UV) resins. The UV resins significantly reduce the energy barrier, suppress surface defects, and improve interfacial contact between ZnO ETL and the organic photoactive layer. Notably, the SAR and OCS resins mitigate the photocatalytic activity of ZnO, electrical leakage, and interfacial resistance during photoaging of OSCs. As a result, iOSCs based on modified ZnOs retain over 80% of initial efficiency under 1 sun illumination for light soaking 1000 h. Furthermore, SAR and OCS resins on ZnO surfaces form a robust crosslinked network with excellent solvent resistant properties, which result in enhanced thermal stability. These results reveal that this simple and effective approach is a promising procedure to fabricate high‐performance iOSCs.

Influence of pore size on the optical and electrical properties of TiO2 thin films was studied. TiO2 thin films with different weight percentages (wt%) of carbon black were deposited by screen printing method on fluorine doped tin oxide (FTO) coated on glass substrate. Carbon black decomposed on annealing and artificial pores were created in the films. All the films were 3.2 µm thick as measured by a surface profiler. UV-VIS-NIR spectrophotometer was used to study transmittance and reflectance spectra of the films in the photon wavelength of 300–900 nm while absorbance was studied in the range of 350–900 nm. Band gaps and refractive index of the films were studied using the spectra. Reflectance, absorbance, and refractive index were found to increase with concentrations of carbon black. There was no significant variation in band gaps of films with change in carbon black concentrations. Transmittance reduced as the concentration of carbon black in TiO2 increased (i.e., increase in pore size). Currents and voltages (I-V) characteristics of the films were measured by a 4-point probe. Resistivity (ρ) and conductivity (σ) of the films were computed from the I-V values. It was observed that resistivity increased with carbon black concentrations while conductivity decreased as the pore size of the films increased.