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Shallow marine thrombolites from a newly discovered Lower Cretaceous cold seep in the Outer Carpathians (Poland) were analysed in order to untangle the complex sedimentological and biogeochemical processes involved in their formation and their diagenetic modifications. The studied thrombolites are made of two components: (i) microcrystalline mesoclots; and (ii) spar‐filled framework cavities. These components are dominated by calcite and show a complex spatial relationship, resulting in a heterogeneous, clotted fabric. The mesoclots exhibit digitate structures, often concentrically‐laminated, and are chiefly composed of microcrystalline material with δ13C values from −34.8 to −19.4‰ PeeDee Belemnite. Biomarkers analyses show the presence of 2, 6, 10, 15, 19‐pentamethylicosane within the mesoclots. The mesoclots host <5 mm wide microtubes filled with isopachous calcite recording even lower δ13C values (from −39.0 to −20.5‰ PeeDee Belemnite). The morphology of the mesoclots relative to their internal lamination and their geochemistry indicates that their growth was linked to anaerobic oxidation of methane while the microtubes acted as conduits for hydrocarbon‐charged fluids. The framework cavities are internally lined with framboidal pyrite, and are cemented by calcite spar with relatively high δ13C (−15.1 to −7.3‰ PeeDee Belemnite) and low δ18O values (−9.3 to −4.4‰ PeeDee Belemnite). Carbonate precipitation within the framework cavities is interpreted to have been related to bacterial sulphate reduction. U‐shaped trace fossils attributed to the ichnogenus Balanoglossites cross‐cut both mesoclots and framework cavities. The mechanisms involved in the formation and diagenesis of thrombolites at cold seeps are yet to be fully understood, and this work provides new insights on these complex biogeochemical and sedimentological processes. [ABSTRACT FROM AUTHOR]

Abstract: The Caledonian foreland basin of Poland onlaps the SW slope of the East European Craton and is elongated in a NW–SW direction along the margin of the Baltica palaeocontinent. The base of the synorogenic clastic wedge rises in age from Llandovery to Ludlow between NW and SE Poland, respectively. As the initial influx of orogen‐derived detritus can be unequivocally identified, this diachronism documents a southeastward migration of the basin depocentre, parallel to the present‐day Caledonian Deformation Front. Our best‐fit plate model shows an oblique collision of Baltica and Avalonia, the latter initially indenting the Baltica margin in the NW. Afterwards, Baltica was progressively underthrust beneath Avalonia towards the SE in response to the oblique soft‐mode closure of the Tornquist Ocean. The final deformation event within the Caledonian foreland took place in the earliest Devonian as a far‐field effect of sinistral orogen‐parallel displacements along the Iapetus suture. [ABSTRACT FROM AUTHOR]