36 results on '"K.C. Bhamu"'
Search Results
2. Dehydrogenation of a liquid organic hydrogen carrier compound 1-(3-cyclohexylpropyl)-3-ethylcyclohexane: A density functional theory study
- Author
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K.C. Bhamu, Jin Suk Chung, and Sung Gu Kang
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Fuel Technology ,Renewable Energy, Sustainability and the Environment ,Energy Engineering and Power Technology ,Condensed Matter Physics - Published
- 2022
3. Unveiling the dehydrogenation mechanism of 1,1,6,6-tetracyclohexylhexane: A first-principles study
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K.C. Bhamu, Jin Suk Chung, and Sung Gu Kang
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Fuel Technology ,Renewable Energy, Sustainability and the Environment ,Energy Engineering and Power Technology ,Condensed Matter Physics - Published
- 2022
4. Rational synthesis of alkaline earth metal vanadates: Structural origin of MgVO3 honeycomb lattice system and its electrochemical analysis for the detection of sulfadiazine
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Tata Sanjay Kanna Sharma, Jayasmita Jana, K.C. Bhamu, Jinu Song, Subramani Sivaselvam, Tran Van Tam, Sung Gu Kang, Jin Suk Chung, Seung Hyun Hur, and Won Mook Choi
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General Chemical Engineering ,Environmental Chemistry ,General Chemistry ,Industrial and Manufacturing Engineering - Published
- 2023
5. Carbide-directed enhancement of electrochemical hydrogen evolution reaction on tungsten carbide–oxide heterostructure
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Yen-Linh Thi Ngo, K.C. Bhamu, Anastasiia Voronova, Jayasmita Jana, Sung Gu Kang, Jin Suk Chung, Won Mook Choi, Jong Hyun Jang, Seung Hyun Hur, and Bora Seo
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General Chemical Engineering ,Environmental Chemistry ,General Chemistry ,Industrial and Manufacturing Engineering - Published
- 2022
6. Density functional theory-based study of the magnetic and optical properties of PbMO3 (M = Cr, Fe) using the modified BeckeJohnson mBJ functional
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S.M. Ramay, Asif Mahmood, K.C. Bhamu, Qasim Mahmood, Muhammad Yaseen, and Mirza Hassan
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Materials science ,Magnetic moment ,Condensed matter physics ,Spin polarization ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Polarization (waves) ,01 natural sciences ,0104 chemical sciences ,WIEN2k ,Condensed Matter::Materials Science ,Tetragonal crystal system ,Ferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,General Materials Science ,Density functional theory ,0210 nano-technology ,Plasmon - Abstract
In this study, we employed the density functional theory (DFT) approach using WIEN2k code to study the magnetic and optical behaviors of PbCrO 3 and PbFeO 3 perovskites in both cubic and tetragonal phases. We determined the stability of the ferromagnetic state in terms of the enthalpy of formation, the half-metallic behavior, and spin polarization. The origin and nature of the ferromagnetic state were attributed to John–Teller distortion and a super-exchange mechanism. Comparisons of the calculated crystal field, John–Teller distortion, and exchange energies indicated the stability of the ferromagnetic nature. Due to strong hybridization, the magnetic moment was reduced at the Cr/Fe sites but generated at the nonmagnetic sites. The optical characteristics were explained by in-depth analyses of the polarization, plasmonic resonance, transparency, and other features in terms of the computed parameters.
- Published
- 2019
7. Study of electronic, magnetic and thermoelectric properties of AV2O4 (A = Zn, Cd, Hg) by using DFT approach
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Shakeel Ahmad, Asif Mahmood, Mirza Hassan, Qasim Mahmood, Shahid M. Ramay, and K.C. Bhamu
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Magnetic moment ,Condensed matter physics ,Chemistry ,Analytical chemistry ,02 engineering and technology ,General Chemistry ,Electronic structure ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Crystal ,Thermal conductivity ,Ferromagnetism ,Electrical resistivity and conductivity ,Seebeck coefficient ,0103 physical sciences ,Thermoelectric effect ,General Materials Science ,010306 general physics ,0210 nano-technology - Abstract
We have investigated the electronic structure, magnetic and thermoelectric behavior of AV2O4 (A = Zn, Cd, Hg) by using first principle calculations. Various properties are extracted from the computed band structures (BS) and the densities of states (DOS). The studied compounds reveal half-metallic ferromagnetic (HMF) nature. The origin and nature of the observed ferromagnetism is described in terms of the calculated crystal field (ΔCF), John-Teller (ΔJT), direct ΔEX (d) and indirect exchange ΔEX (pd) energies. The strong hybridization of V-3d states with the O-2p state under the influence of octahedral environment reduces magnetic moment of V-atom and generates a fraction of the magnetic moments at Zn/Cd/Hg and O sites. The thermoelectric response is evaluated by calculating electrical conductivity (σ/τ), thermal conductivity (κ/τ), seebeck coefficient (S), power factor (P) and thermal efficiency by using BoltzTraP code.
- Published
- 2019
8. Ab-initio investigations for structural, mechanical, optoelectronic, and thermoelectric properties of Ba2SbXO6 (X Nb, Ta) compounds
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Subrahmanyam Sappati, K.C. Bhamu, Jagrati Sahariya, Amit Soni, Sung Gu Kang, Hansraj Karwasara, A.K. Kushwaha, and D. P. Rai
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Bulk modulus ,Materials science ,Condensed matter physics ,Mechanical Engineering ,Metals and Alloys ,Optical conductivity ,Shear modulus ,Condensed Matter::Materials Science ,Mechanics of Materials ,Seebeck coefficient ,Thermoelectric effect ,Materials Chemistry ,Condensed Matter::Strongly Correlated Electrons ,Direct and indirect band gaps ,Density functional theory ,Electronic band structure - Abstract
We report the structural, mechanical, electronic, optical, thermoelectric properties and spectroscopic limited maximum efficiency (SLME) of oxide double perovskite structure Ba2SbNbO6 and Ba2SbTaO6 compounds. All the investigations were performed through the first-principles density functional theory (DFT). The results obtained for the elastic constants affirms the mechanical stability of the studied double perovskite compounds. The calculated data of bulk modulus (B), shear modulus (G), and Young's modulus (E) for Ba2SbTaO6 are found to be greater than those of Ba2SbNbO6. The obtained ratio of Bulk to shear modulus (B/G) shows that Ba2SbNbO6 and Ba2SbTaO6 are ductile in nature and are suitable for the device fabrications. The electronic properties of studied compounds are explained in terms of their energy bands, total and partial density of states. The computed electronic band structure reveals the direct band gap semiconducting nature of both compounds. The energy dependent optical properties such as, dielectric tensor, optical conductivity, absorption, reflectivity, refraction and energy loss for both the studied compounds are investigated and are explained in order to highlight the potential of studied compounds for the photovoltaic applications. In addition to electronic and optical properties, we have also studied the electron relaxation time-dependent thermoelectric properties, such as Seebeck coefficient, electronic thermal conductivity, electrical conductivity, thermoelectric power factor, and the thermoelectric figure of merit as a function of chemical potential at various temperatures for p-type and n-type charge carriers. The high absorption spectra and good thermoelectric figure of merit reveal that both the studied compounds, Ba2SbXO6 (X = Nb, Ta) are promising materials for photovoltaic and thermoelectric applications. The calculated SLME of 26.8% reveals that Ba2SbNbO6 is an appealing candidate for single-junction solar cells.
- Published
- 2022
9. Spatial-temporal spectroscopy characterizations and electronic structure of methylammonium perovskites
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F. Fungara, Zhiyan Liu, Men Long, K.C. Bhamu, Rana Biswas, Di Cheng, Joong Mok Park, Jigang Wang, Joseph Shinar, Javier Vela, Satvik Shah, Liang Luo, and Ruth Shinar
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Photoluminescence ,Materials science ,Exciton ,Binding energy ,Physics::Optics ,02 engineering and technology ,Electronic structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Molecular physics ,0104 chemical sciences ,Condensed Matter::Materials Science ,symbols.namesake ,Rydberg formula ,symbols ,General Materials Science ,Direct and indirect band gaps ,0210 nano-technology ,Spectroscopy ,Perovskite (structure) - Abstract
Using time-resolved laser-scanning confocal microscopy and ultrafast optical pump/THz probe spectroscopy, we measure photoluminescence (PL) and THz-conductivity in perovskite micro-crystals and films. PL quenching and lifetime variations occur from local heterogeneity. Ultrafast THz-spectra measure sharp quantum transitions from excitonic Rydberg states, providing weakly bound excitons with a binding energy of ~13.5 meV at low temperatures. Ab-initio electronic structure calculations give a direct band gap of 1.64 eV, a dielectric constant of ~18, heavy electrons, and light holes, resulting in weakly bound excitons, consistent with the binding energies from the experiment. The complementary spectroscopy and simulations reveal fundamental insights into perovskite light-matter interactions.
- Published
- 2018
10. Revealing optoelectronic and transport properties of potential perovskites Cs2PdX6 (X = Cl, Br): A probe from density functional theory (DFT)
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Amit Soni, K.C. Bhamu, and Jagrati Sahariya
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Materials science ,Renewable Energy, Sustainability and the Environment ,business.industry ,Band gap ,chemistry.chemical_element ,02 engineering and technology ,Atmospheric temperature range ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,0104 chemical sciences ,symbols.namesake ,chemistry ,Boltzmann constant ,Thermoelectric effect ,symbols ,Optoelectronics ,General Materials Science ,Density functional theory ,Direct and indirect band gaps ,0210 nano-technology ,business ,Palladium - Abstract
Metal-halide perovskites are rapidly emerging crystalline materials that are reasonably preferred as leading aspirant for applications in optoelectronic and thermoelectric devices. In this paper, we have thoroughly reviewed and performed calculations to reveal optoelectronic and transport properties for a potential newcomer, Cs2PdX6 (X = Cl, Br) termed as Cesium Palladium Halides (CPH). Outcome of present computations are compared with available results and a reasonable agreement is recorded. Energy band gap computations performed reveal indirect band gap of 2.29 eV for Cs2PdCl6, which substantially reduces to 1.22 eV when ‘Cl’ is replaced by ‘Br’. Optical absorption spectra investigations performed here, in the energy range from 3 to 5 eV confirms effective utilization of these compounds in solar cells and other optoelectronic applications. In addition, the transport properties computations performed using semi-classical Boltzmann theory, shows constant pattern of thermo power near ambient temperature range (200–500 K), which admits possible utilization of these compounds as low temperature thermoelectric materials. Performed ZT calculations demonstrates reasonably good thermoelectric performance for both materials, as there exist minor variation (0.1) in the values over wide temperature ranges i.e. from 100 to 800 K. Further, detailed analysis of transport properties predicts p-type semiconducting nature of the present series of materials.
- Published
- 2018
11. Corrigendum to Density functional theory-based study of the magnetic and optical properties of PbMO3 (M = Cr, Fe) using the modified BeckeJohnson mBJ functional [J. Phys. Chem. Solids Vol 128, May 2019, Pages 275–282]
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S.M. Ramay, Qasim Mahmood, Mirza Hassan, Asif Mahmood, Muhammad Yaseen, and K.C. Bhamu
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Physics ,Thermodynamics ,General Materials Science ,Density functional theory ,General Chemistry ,Condensed Matter Physics - Published
- 2021
12. Designing a bimetallic transition metal oxide/hydroxide composite for effective electrocatalytic oxygen evolution reaction
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Yen-Linh Thi Ngo, Seung Hyun Hur, K.C. Bhamu, Jin Suk Chung, Sung Gu Kang, and Jayasmita Jana
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Tafel equation ,Materials science ,Oxygen evolution ,Oxide ,General Physics and Astronomy ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,Catalysis ,chemistry.chemical_compound ,chemistry ,Transition metal ,Chemical engineering ,Hydroxide ,Water splitting ,0210 nano-technology ,Bimetallic strip - Abstract
The oxygen evolution reaction (OER), owing to its sluggish nature, demands efficient and stable catalysts with low production cost, during the electrocatalytic water splitting. In this respect, a series of bimetallic ZnO-Ni(OH)2 composite materials were prepared as electrode materials for OER. The synthetic procedure followed the polyvinylpyrrolidone (PVP) and dopamine (DA) assisted hydrothermal process. The growth modification ability of PVP and adhesive property of polydopamine (from DA) were utilized to attain the 3D interconnected structures. The precursor concentrations were varied to obtain most efficient catalyst, ZNDP-1. In alkaline medium, ZNDP-1 showed a low over potential of 170 mV (@10 mAcm−2 current density) and a Tafel slope of 61 mV dec−1 with significant stability. The surface defects, porosity and synergism within metal centers might cause efficient electrocatalytic activity. Furthermore, DFT studies were performed to understand the mechanistic pathway.
- Published
- 2021
13. Thermoelectric properties of 2H-CuGaO2 for device applications: A first principle TB-mBJ potential study
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C. S. Praveen and K.C. Bhamu
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Materials science ,Condensed matter physics ,02 engineering and technology ,Electronic structure ,engineering.material ,Photon energy ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Thermoelectric materials ,01 natural sciences ,Electronic, Optical and Magnetic Materials ,Inorganic Chemistry ,Delafossite ,0103 physical sciences ,Thermoelectric effect ,Materials Chemistry ,Ceramics and Composites ,engineering ,Density of states ,Figure of merit ,Direct and indirect band gaps ,Physical and Theoretical Chemistry ,010306 general physics ,0210 nano-technology - Abstract
Here we report the structural, electronic, optical, and thermoelectric properties of delafossite type 2 H-CuGaO 2 using first principles calculations. The present calculation predict an indirect band gap of 1.20 eV and a direct band gap of 3.48 eV. A detailed analysis of the electronic structure is provided based on atom and orbital projected density of states. Frequency dependent dielectric functions, refractive index, and absorption coefficient as a function of photon energy are discussed. The thermoelectric properties with power factor, and the figure of merit are reported as a function of chemical potential in the region ± 0.195 ( μ − E F ) eV at constant temperature of 300 and 800 K. The thermoelectric properties shows that 2 H-CuGaO 2 could be potential candidate for engineering devises operating at high temperature for the chemical potential in the range of ± 0.055 ( μ − E F ) eV and beyond this range the thermoelectric performance of 2 H-CuGaO 2 get reduced.
- Published
- 2017
14. Thermoelectric properties of tetragonal half-Heusler compounds, TiXSb (X = Ge, Si): A probe from Density Functional Theory (DFT)
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K.C. Bhamu, D. P. Rai, H. Joshi, K.D. Verma, and Raj Kumar Thapa
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Materials science ,Condensed matter physics ,Mechanical Engineering ,Metals and Alloys ,02 engineering and technology ,Electronic structure ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,Condensed Matter::Materials Science ,Tetragonal crystal system ,Thermal conductivity ,Mechanics of Materials ,Seebeck coefficient ,0103 physical sciences ,Thermoelectric effect ,Materials Chemistry ,Density functional theory ,010306 general physics ,0210 nano-technology ,Electronic band structure - Abstract
We have presented the electronic and thermoelectric properties of d2/do type Heusler compounds TiXSb (X = Ge, Si) using Full Potential Linearized Augmented Plane Wave method (FP-LAPW), based on Density Functional Theory (DFT). For electron exchange, we have considered the most common Generalized Gradient Approximation (GGA), exchange potential. The electronic structure of both TiGeSb and TiSiSb showed overlapping between the valance and the conduction band, indicating their metallic nature. The transport coefficients were calculated by a post DFT treatment which involves the semi-classical Boltzmann Theory as implemented in the code BoltzTraP. The thermoelectric parameters are calculated along perpendicular and parallel directions with respect to chemical potential ( μ ) and temperature. Furthermore, we have also considered the phononic contribution to thermal conductivity ( κ p ) for better understanding of the materials thermodynamics and efficiency (ZT). The calculated ZT values showed TiSiSb as potential thermoelectric candidate at room temperature and under normal conditions, whereas TiGeSb had poor thermoelectric properties.
- Published
- 2017
15. First principles investigations of electronics, magnetic, and thermoelectric properties of rare earth based PrYO 3 (Y=Cr, V) perovskites
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K.C. Bhamu, Ghulam Murtaza, Riaz Ahmad, Qasim Mahmood, and B. Sabir
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Spintronics ,Condensed matter physics ,Magnetic moment ,Chemistry ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,Condensed Matter::Materials Science ,Thermal conductivity ,Ferromagnetism ,Seebeck coefficient ,0103 physical sciences ,Thermoelectric effect ,Density of states ,Condensed Matter::Strongly Correlated Electrons ,General Materials Science ,010306 general physics ,0210 nano-technology - Abstract
The structural, electronic, magnetic, optical and thermoelectric properties of PrYO 3 (Y=Cr, V) have been studied by using density functional based FP-LAPW+ lo method as implemented into WIEN2k code. The analysis of band structures and density of states confirm the half metallic ferromagnetism in studied compounds. The nature and origin of ferromagnetism has been depicted in terms of crystal field energies, exchange energies involved and exchange constants. Moreover, the reduction of magnetic moment from V/Cr, Pr sites and generation of small magnetic moments on oxygen and interstitials sites leads to negative value of indirect exchange energy Δ x ( pd ) and strong hybridization. Finally, the thermoelectric behavior has been explained by discussing the electrical conductivity, thermal conductivity, Seebeck coefficient, power factor and thermal efficiency. Moreover, evaluation of PrYO 3 on the basis of its magnetic and thermoelectric properties conform that the compounds are much suitable for spintronic and thermoelectric applications.
- Published
- 2017
16. Optoelectronic Analysis of CdGa2X4 (X= S, Se): A Promising Material for Solar Cells
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Jagrati Sahariya, K.C. Bhamu, Pancham Kumar, and Amit Soni
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Materials science ,business.industry ,020502 materials ,Mechanical Engineering ,02 engineering and technology ,Electronic structure ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0205 materials engineering ,Mechanics of Materials ,Optoelectronics ,General Materials Science ,0210 nano-technology ,business - Abstract
In this paper, the optoelectronic nature of the CdGa2X4 (X = S, Se) solar cell materials are examined using full potential linear augmented plane wave (FP-LAPW) method as embodied in WIEN2K code. In present computation, we have used most suitable modified Backe-Johnson (mBJ) potential under the framework of density functional theory (DFT). The calculated electronic properties like energy band structure and density of states spectra show that these materials exhibit a direct band gap (Γ–Γ) result of 3.22 eV and 2.36 eV for CdGa2S4 and CdGa2Se4 compounds, respectively. Absorption spectra for CdGa2X4 (X = S, Se) compounds have been studied and it has been found that above the band gap, absorption are taking place and it covers wide visible spectrum energy range. On the basis of calculated band gap, density of states and absorption coefficient spectra, it is found that these compounds can be suitably applicable in optoelectronic devices such as solar cell. The evaluated properties pose well agreement with available experimental data.
- Published
- 2017
17. Optoelectronic behavioral study of defect-chalcopyrite semiconductors XGa 2 Te 4 (X = Zn, Cd)
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K.C. Bhamu, Jagrati Sahariya, Amit Soni, and Pancham Kumar
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010302 applied physics ,Valence (chemistry) ,Materials science ,Absorption spectroscopy ,Band gap ,business.industry ,Mechanical Engineering ,Plane wave ,02 engineering and technology ,Electronic structure ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Mechanics of Materials ,0103 physical sciences ,Density of states ,Optoelectronics ,General Materials Science ,Dielectric loss ,Density functional theory ,0210 nano-technology ,business - Abstract
In this work, electronic structure and optical properties investigations for defect-chalcopyrite semiconductors ZnGa2Te4 and CdGa2Te4 are presented using full potential linearized augmented plane wave method. Energy bands and density of states (DOS) computations are performed using different flavors of exchange and correlations. The calculations are performed using Wu-Cohen generalized gradient approximation (WC-GGA), Perdew et al. (PBE-sol) and the most accurate modified Becke and Johnson (mBJ) potentials. Our investigations show that energy bands and DOS computed using mBJ potential are in better agreement with the available experimental data. Optical properties such as, dielectric tensor components, absorption spectra, reflectivity, refractivity, dielectric loss, are investigated using mBJ potential. Imaginary peaks of di-electric tensor e 2 ( ω ) , are interpreted by means of inter-band transitions from valence to conduction band. High intensity absorption curves from 3 to 5 eV, energy band gap depicted for ZnGa2Te4 (1.61 eV) and CdGa2Te4 (1.78 eV) materials indicates their applicability for solar photovoltaic and other optoelectronic applications.
- Published
- 2017
18. An Enhanced Thermoelectric Property of 1-D Silicon Atomic Wire: An Ab-Initio Study
- Author
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K.C. Bhamu, D. P. Rai, H. Joshi, P. K. Patra, and Raj Kumar Thapa
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Materials science ,Silicon ,chemistry ,Condensed matter physics ,Band gap ,Thermoelectric effect ,chemistry.chemical_element ,Direct and indirect band gaps ,Fermi energy ,Electronic band structure ,Semimetal ,Quasi Fermi level - Abstract
The band structure calculation was performed using the Full Potential Linearized Augmented Plane Wave Method (FP-LAPW) within a frame work of Density Functional Theory (DFT). We have observed a band gap in cubic bulk Silicon where as a Silicon atomic chain shows a Dirac cone like features along the ∆-symmetry, ~3.0 eV above Fermi energy (EF). An indirect band gap of about 1.16 eV is observed in case of bulk Si crystal. The narrow band gap has been shifted in case of Si-atomic wire to the conduction region. The shifted band gap in Si-nano structure indicates the semi-metal type behaviour, thereby increasing its electrical conductivity. The Boltzmann semi-classical transport theory is used to calculate the thermoelectric properties. The ZT value of Si atomic chain is ~1.55 at 120 K, which is higher than the experimental value, 1.2.
- Published
- 2016
19. Opto-electronic Analysis of Cs2PdCl2Br4 Perovskites Compounds for Photovoltaic Applications
- Author
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K.C. Bhamu, Ushma Ahuja, Jagrati Sahariya, and Amit Soni
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Materials science ,Absorption spectroscopy ,Band gap ,Plane wave ,02 engineering and technology ,Dielectric ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Molecular physics ,0104 chemical sciences ,Wave vector ,Density functional theory ,0210 nano-technology ,Electronic band structure ,Absorption (electromagnetic radiation) - Abstract
In this paper, electronic and optical properties of Cs2PdCl2Br4 perovskite compound are presented using full potential linearized augmented plane wave (FP-LAPW) method. All computations are performed using most accurate modified Becke Johnson (mBJ) potential within density functional theory. Energy band computations are performed over here to elaborate relationship between energy and wave vector (k). Pattern of occurrence observed for energy bands are analyzed in terms of plotted total and partial density of states. For investigating optical behavior of Cs2PdCl2Br4, we have computed dielectric tensor, absorption spectra, reflectivity and refraction spectra using mBJ potential. Different peaks recorded in the imaginary components of dielectric tensor are interpreted in terms of interband transitions for better understanding. Significant absorption intensity available in desired energy range and suitable band gap indicates effective utilization of this compound in photovoltaic applications.
- Published
- 2018
20. Investigating effect of strain on electronic and optical properties of lead free double perovskite Cs2AgInCl6 solar cell compound: A first principle calculation
- Author
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K.C. Bhamu, Amit Soni, and Jagrati Sahariya
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Materials science ,Band gap ,Mechanical Engineering ,Computation ,Photovoltaic system ,Metals and Alloys ,Plane wave ,02 engineering and technology ,Spin–orbit interaction ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,law.invention ,Computational physics ,Mechanics of Materials ,law ,Solar cell ,Materials Chemistry ,First principle ,0210 nano-technology ,Perovskite (structure) - Abstract
Despite serious problems associated with toxicity of lead, lead halide perovskite based solar cells have resulted with remarkable efficiency and hence gained much interest. To overcome this aspect, numerous solutions are attempted by researchers which include the development of new environmental friendly lead free double perovskite (DP) photovoltaic materials. Enlightening on the same line, we report first principle calculations on electronic and optical properties of Cs2AgInCl6 solar photovoltaic materials. Present opto-electronic computations for lead free DP compound, have been performed using the full potential linearized augmented plane wave method. In present investigations, we have adopted exchange and correlation potentials prescribed by Perdew et al. and the most accurate Tran-Blaha modified Becke-Johnson. Both exchange and correlation potential computations are performed with and without spin orbit coupling. Results obtained for electronic and optical properties are validated by systematic comparison with available experimental data. Reasonable reconciliation between investigated results and the available experimental data, endorse accuracy of present computations. To identify the effect of strain on energy gap and hence on the optical properties of Cs2AgInCl6 compound, computations of electronic and optical properties have also been performed under the different values of strain application.
- Published
- 2020
21. Half-metallic ferromagnetism in Fe, Co and Ni doped BaS: First principles calculations
- Author
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Savita Maurya, K.C. Bhamu, and Ramesh Sharma
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Materials science ,Ferromagnetism ,Magnetic moment ,Condensed matter physics ,Doping ,First principle ,Density functional theory ,Dielectric ,Electronic structure ,Spin (physics) - Abstract
The first principle investigation of structural, electronic, magnetic and optical properties of Ba1-xTMxS (x = 0.25) have been done using FPLAW method within the density functional theory (DFT) using generalized gradient approximation (GGA) for exchange correlation potential using two different functionals which are the PBE-sol and the modified Becke and Johnson local (spin) density approximation (mBJLDA). It was found that mBJLDA functional offer better account for the electronic structure of the Fe, Co and Ni-doped BaS. It was also observed that Fe/Co/Ni d, S p and Ba d states play a major role in determining the electronic properties of this alloy system. Investigation results shows that Ba0.75(Fe/Co/Ni)0.25S is ferromagnetic with magnetic moment of 3.72 µB, 2.73908 µB and 1.74324 µB at Fe, Co and Ni sites respectively. Complex dielectric constant e(ω) and normal incidence reflectivity R(ω) are also been investigate for broad range of photon energies. These results are compared with the some reported existing experimental values.The first principle investigation of structural, electronic, magnetic and optical properties of Ba1-xTMxS (x = 0.25) have been done using FPLAW method within the density functional theory (DFT) using generalized gradient approximation (GGA) for exchange correlation potential using two different functionals which are the PBE-sol and the modified Becke and Johnson local (spin) density approximation (mBJLDA). It was found that mBJLDA functional offer better account for the electronic structure of the Fe, Co and Ni-doped BaS. It was also observed that Fe/Co/Ni d, S p and Ba d states play a major role in determining the electronic properties of this alloy system. Investigation results shows that Ba0.75(Fe/Co/Ni)0.25S is ferromagnetic with magnetic moment of 3.72 µB, 2.73908 µB and 1.74324 µB at Fe, Co and Ni sites respectively. Complex dielectric constant e(ω) and normal incidence reflectivity R(ω) are also been investigate for broad range of photon energies. These results are compared with the some reported e...
- Published
- 2018
22. Electronic structure of Gd based transition metal antimonides GdTSb (T = Ni, Pt)
- Author
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Jagrati Sahariya, Amit Soni, Pancham Kumar, and K.C. Bhamu
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Metal ,Crystallography ,Materials science ,Magnetic moment ,Transition metal ,Band gap ,visual_art ,Atom ,visual_art.visual_art_medium ,Density of states ,Electronic structure ,Ternary operation - Abstract
We report the electronic and magnetic properties of ternary GdNiSb and GdPtSb compounds with cubic MgAgAs type structure. The energy bands, density of states and atom specific magnetic moments of compounds have been computed using GGA+U approach. The calculations predict that GdNiSb is a small band gap semiconductor whereas GdPtSb is metallic in nature.
- Published
- 2018
23. Opto-electronic analysis of promising photovoltaic Cs2PdCl4Br2: An upcoming perovskite material
- Author
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Amit Soni, K.C. Bhamu, and Jagrati Sahariya
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WIEN2k ,Materials science ,Absorption spectroscopy ,Plane wave ,Direct and indirect band gaps ,Density functional theory ,Electronic structure ,Atomic physics ,Energy (signal processing) ,Perovskite (structure) - Abstract
The metal halide perovskites are attracting much attention due to their potential applications in optoelectronic devices. Herein, we review and calculate a new avenue for Cs$_{\mathbf {2}}$PdCl$_{\mathbf {4}} \mathbf {Br} _{\mathbf {2}}$ perovskites by computing its electronic and optical properties to show its candidature in optoelectronics. For the computation of electronic and optical properties, we have used modified Becke Johnson approximation available in Wien2k code, based on full potential lineariesd augmented plane wave method. Investigated electronic and optical properties show that $\mathbf {Cs} _{\mathbf {2}}$PdCl$_{\mathbf {4}} \mathbf {Br} _{\mathbf {2}}$ has the indirect band gap of 1.70 eV. The significant intense peaks in absorption spectra between energy range 2–3 eV reveals the utility of this compound in solar cells and other optoelectronic devices.
- Published
- 2017
24. Density functional study of $$\hbox {AgScO}_2$$ AgScO 2 : Electronic and optical properties
- Author
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Jagrati Sahariya, Rishi Vyas, K.C. Bhamu, and K. R. Priolkar
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Physics ,Condensed matter physics ,business.industry ,Band gap ,Plane wave ,General Physics and Astronomy ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Optics ,Attenuation coefficient ,Density of states ,Density functional theory ,Local-density approximation ,0210 nano-technology ,business ,Refractive index ,Energy (signal processing) - Abstract
This paper focusses on the electronic and optical properties of scandium-based silver delafossite ( $$\hbox {AgScO}_2$$ ) semiconductor. The density functional theory (DFT) in the framework of full potential linearized augmented plane wave (FP-LAPW) scheme has been used for the present calculations with local density approximation (LDA) and generalized gradient approximation (GGA). Electronic properties deal with energy bands and density of states (DOSs), while optical properties describe refractive index and absorption coefficient. The energy bands are interpreted in terms of DOSs. The computed value of band gap is in agreement with that reported in the literature. Our results predict $$\hbox {AgScO}_2$$ as indirect band-gap semiconductor. Our calculated value of the refractive index in zero frequency limits is 2.42. The absorption coefficient predicts the applicability of $$\hbox {AgScO}_2$$ in solar cells and flat panel liquid crystal display as a transparent top window layer.
- Published
- 2017
25. Half-Metalicity in Fe doped HfO2
- Author
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Ramesh Sharma, K.C. Bhamu, and Chandra Kumar Dixit
- Subjects
Materials science ,Magnetic moment ,Absorption spectroscopy ,Condensed matter physics ,Band gap ,business.industry ,Fermi level ,Condensed Matter::Materials Science ,symbols.namesake ,Lattice constant ,Semiconductor ,Atom ,symbols ,Condensed Matter::Strongly Correlated Electrons ,business ,Metallic bonding - Abstract
This paper presents structural, electronic, optical and magnetic properties of pure and Fe doped cubic Hafnia (HfO2). We used mBJ potential within FP-LAPW approximation to compute these properties. The calculated values of band gap from relaxed atomic positions and lattice parameter is in good agreement with experimental band gap. The calculation indicates that the Fe doped compound is direct transition semiconductors with half-metallic property. With the increase of Fe-doping concentration, the Fermi level shifts towards valence band. The impurity may change the property of the bond formation to some extent, and make it to have metallic bond characteristic. The total magnetic moment is mainly due to 3d states of Fe atoms and small induced magnetic moment exists due to other nonmagnetic atom, with a magnetic moment of about 4.0 µB per Fe-dopant. We have also computed and interpreted the absorption spectrum corresponding to the imaginary part of dielectric function in the range 0-40 eV. The peaks are relat...
- Published
- 2017
26. Compton Profiles and Nature of Bonding in Tantalum Chalcogenides
- Author
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K.C. Bhamu, A. R. Jani, B. L. Ahuja, and Arvind Sharma
- Subjects
education.field_of_study ,Materials science ,Spectrometer ,Astrophysics::High Energy Astrophysical Phenomena ,Gaussian ,Population ,Compton scattering ,Tantalum ,chemistry.chemical_element ,Condensed Matter Physics ,Atomic and Molecular Physics, and Optics ,Condensed Matter::Materials Science ,symbols.namesake ,chemistry ,Atomic orbital ,symbols ,General Materials Science ,Atomic physics ,education ,Linear combination ,Line (formation) - Abstract
We report the Compton profiles of tantalum chalcogenides (TaS2 and TaSSe) using Hartree–Fock and hybridization of Hartree–Fock and density functional theories within linear combination of atomic (Gaussian) orbitals. To interpret the theoretical data on Compton line shapes, we have measured the Compton profiles using our in-house 100 mCi 241Am γ-ray Compton spectrometer. To understand the relative nature of bonding, we have obtained the equal-valence-electron-density (EVED) profiles. The EVED profiles shows that charge in TaSSe is more localized than TaS2 in the bonding direction which confirms that TaSSe is more covalent than TaS2, which is in agreement with the Mulliken’s population analysis.
- Published
- 2013
27. Electronic structure of ceramic CrSi2 and WSi2: Compton spectroscopy and ab-initio calculations
- Author
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K.C. Bhamu, Jagrati Sahariya, and B. L. Ahuja
- Subjects
education.field_of_study ,Materials science ,Band gap ,Population ,General Chemistry ,Condensed Matter Physics ,Molecular physics ,Brillouin zone ,Condensed Matter::Materials Science ,Tetragonal crystal system ,Ab initio quantum chemistry methods ,Linear combination of atomic orbitals ,Density of states ,Condensed Matter::Strongly Correlated Electrons ,General Materials Science ,Density functional theory ,Atomic physics ,education - Abstract
We report electron momentum densities of stable phases of transition metal disilicides CrSi2 (C40 hexagonal) and WSi2 (C11b body centered tetragonal) using a high energy 137Cs Compton spectrometer. To support the experimental investigations, we have computed theoretical Compton profiles, energy bands and density of states of both the isoelectronic compounds using density functional theory within linear combination of atomic orbitals. Theoretical calculations for the energy bands and density of states are performed for both the hexagonal and tetragonal phases of these silicides. In the tetragonal phase, both the silicides show metallic behavior. The hexagonal CrSi2 shows an energy gap (0.28 eV) between the valence band maximum at the L point and the conduction band minimum at the M point of the Brillouin zone, whereas the hexagonal WSi2 shows a semimetallic character. We have also scaled the experimental and theoretical profiles of the stable phases (hexagonal for CrSi2 and tetragonal for WSi2) on equal-valence-electron-density, which show more covalent character of WSi2 than that of CrSi2. The nature of bonding is in accordance with a present Mulliken's population analysis.
- Published
- 2013
28. Electronic structure of CaCO3: A Compton scattering study
- Author
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K.C. Bhamu, S.F. Mohammed, F.M. Mohammad, B. L. Ahuja, H. S. Mund, and Jagrati Sahariya
- Subjects
Momentum ,Physics ,Radiation ,Linear combination of atomic orbitals ,Density of states ,Compton scattering ,Density functional theory ,Electron ,Electronic structure ,Atomic physics ,Local-density approximation - Abstract
In the present work, we have studied electron momentum density of CaCO3 using a Compton scattering technique. The experiment has been performed using a 100 mCi 241Am (59.54 keV) Compton spectrometer. The experimental data have been interpreted in terms of theoretical Compton profiles. To compute the theoretical momentum densities, energy bands and density of states, we have used linear combination of atomic orbitals method as embodied in CRYSTAL09 code. We have used local density approximation, generalized gradient approximation (GGA) and second order GGA (SOGGA) within the frame work of density functional theory. It is seen that the GGA gives a better agreement with the experimental data than other approximations. We have also discussed the energy bands and density of states of CaCO3.
- Published
- 2013
29. Thermoelectric properties of doped BaHfO3
- Author
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Chandra Kr. Dixit, Ramesh Sharma, and K.C. Bhamu
- Subjects
Condensed Matter::Materials Science ,Materials science ,Condensed matter physics ,Electrical resistivity and conductivity ,Band gap ,Condensed Matter::Superconductivity ,Seebeck coefficient ,Thermoelectric effect ,Doping ,Ionic bonding ,Charge density ,Thermoelectric materials - Abstract
We have studied the structural stability, electronic structure, optical properties and thermoelectric properties of doped BaHfO3 by full potential linearized augmented plane wave (FP-LAPW) method. The electronic structure of BaHfO3 doped with Sr shows enhances the indirect band gaps of 3.53 eV, 3.58 eV. The charge density plots show strong ionic bonding in Ba-Hf, and ionic and covalent bonding between Hf and O. Calculations of the optical spectra, viz., the dielectric function, refractive index and extinction coefficient are performed for the energy range are calculated and analyzed. Thermoelectric properties of semi conducting are also reported first time. The doped BaHfO3 is approximately wide band gap semiconductor with the large p-type Seebeck coefficient. The power factor of BaHfO3 is increased with Sr doping, decreases because of low electrical resistivity and thermal conductivity.
- Published
- 2016
30. Nature of bonding in CaTiO3 and SrTiO3: A Compton scattering study
- Author
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Alpa Dashora, Gunjan Arora, K.C. Bhamu, and B. L. Ahuja
- Subjects
education.field_of_study ,Radiation ,Atomic orbital ,Chemistry ,Population ,Density of states ,Compton scattering ,Density functional theory ,Electron ,Compton wavelength ,Atomic physics ,Local-density approximation ,education - Abstract
Compton profile measurements for CaTiO 3 and SrTiO 3 perovskite compounds have been undertaken using 20 Ci 137 Cs Compton spectrometer. To understand the nature of bonding in both the compounds, we have analyzed the Compton line shape in terms of equal-valence-electron-density profiles. Electron momentum densities, energy bands and density of states computed using linear combination of the atomic orbitals method (within the framework of density functional theory) are analyzed using the experimental Compton line shapes. It is seen that the recently developed second order generalized gradient approximation gives a better description of momentum densities than the local density approximation. Moreover, bonding in both the ceramic compounds has also been discussed in terms of Mulliken's population analysis.
- Published
- 2012
31. Compton profiles of MoP and WP: Validation of second order generalized gradient approximation
- Author
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Jagrati Sahariya, B. L. Ahuja, H. S. Mund, K.C. Bhamu, Shailja Tiwari, and Ritu Joshi
- Subjects
education.field_of_study ,General Computer Science ,Condensed matter physics ,Chemistry ,Population ,Compton scattering ,General Physics and Astronomy ,General Chemistry ,Computational physics ,Momentum ,Computational Mathematics ,Lattice constant ,Mechanics of Materials ,Density of states ,Molecule ,Order (group theory) ,General Materials Science ,Density functional theory ,education - Abstract
Recently, Zhao and Truhlar (J. Chem. Phys. 128, 184109, 2008) have constructed second order generalized gradient approximation (SOGGA) within the density functional theory. The authors have successfully tested the performance of SOGGA by computing lattice constants, cohesive energies, bond distances and few energetic quantities of different solids and molecules. In this paper, to establish the usefulness of SOGGA in deducing the momentum densities, we have compared our experimental Compton profiles of MoP and WP with those computed using GGA and SOGGA within density functional theory. It is seen that SOGGAPBE based Compton profiles of both the samples are in better agreement with the corresponding experimental data than those derived from BPBE-GGA. In addition, energy bands, density of states and relative nature of bonding in both the phosphides is explained in terms of equal-valence-electron-density profiles and Mulliken’s population analysis.
- Published
- 2012
32. Magnetism, optical, and thermoelectric response of CdFe 2 O 4 by using DFT scheme
- Author
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Asif Mahmood, Yasir Javed, Muhammad Yaseen, Qasim Mahmood, K.C. Bhamu, and Shahid M. Ramay
- Subjects
Materials science ,Condensed matter physics ,Magnetism ,Scheme (mathematics) ,0103 physical sciences ,Thermoelectric effect ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,010306 general physics ,0210 nano-technology ,01 natural sciences - Published
- 2018
33. Electronic and Optical Properties of ZnAl2 Se4 and Its Use in Solar Cell
- Author
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Pancham Kumar, Jagrati Sahariya, K.C. Bhamu, and Amit Soni
- Subjects
010302 applied physics ,Materials science ,Polymers and Plastics ,business.industry ,Organic Chemistry ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,law.invention ,law ,0103 physical sciences ,Solar cell ,Materials Chemistry ,Optoelectronics ,Density functional theory ,0210 nano-technology ,business ,Refractive index - Published
- 2017
34. Compton profile study and electronic properties of tantalum diboride
- Author
-
Veera Raykar, B. L. Ahuja, and K.C. Bhamu
- Subjects
Boron Compounds ,Radiation ,Chemistry ,Fermi level ,Plane wave ,Ionic bonding ,Fermi surface ,Tantalum ,Electron Transport ,symbols.namesake ,Atomic orbital ,Models, Chemical ,Linear combination of atomic orbitals ,Condensed Matter::Superconductivity ,Materials Testing ,symbols ,Density of states ,Scattering, Radiation ,Density functional theory ,Computer Simulation ,Atomic physics ,Radiometry - Abstract
We have reported the first-ever experimental Compton profile (CP) of TaB2 using 20 Ci(137)Cs Compton spectrometer. To compare the experimental data, we have also computed the theoretical CPs using density functional theory (DFT) and hybridization of DFT and Hartree-Fock (HF) within linear combination of the atomic orbitals (LCAO) method. In addition, we have reported energy bands and density of states of TaB2 using LCAO and full potential-linearized augmented plane wave (FP-LAPW) methods. A real space analysis of CP of TaB2 confirms its metallic character which is in tune with the cross-overs of Fermi level by energy bands and Fermi surface topology. A comparison of equal-valence-electron-density (EVED) experimental profiles of isoelectronic TaB2 and NbB2 show more covalent (or less ionic) character of TaB2 than that of NbB2 which is in agreement with available ionicity data.
- Published
- 2013
35. A Compton scattering study of refractory niobium diborides
- Author
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B. L. Ahuja and K.C. Bhamu
- Subjects
Boron Compounds ,Niobium ,chemistry.chemical_element ,Space (mathematics) ,Momentum ,Condensed Matter::Materials Science ,Materials Testing ,Physics::Atomic and Molecular Clusters ,Scattering, Radiation ,Computer Simulation ,Physics::Chemical Physics ,Radiometry ,Physics ,Radiation ,Spectrometer ,Condensed matter physics ,Spectrum Analysis ,X-Rays ,Isotropy ,Compton scattering ,Computational physics ,Refractometry ,chemistry ,Models, Chemical ,Gamma Rays ,Density of states ,Density functional theory - Abstract
Isotropic Compton profile of NbB2 using 20 Ci 137Cs Compton spectrometer is compared with our theoretical profiles obtained from the density functional theory (DFT) within the first and the second order generalized gradient approximation (GGA) and the hybridization of Hartree–Fock and DFT. A good agreement between GGA based profiles and the experiment validates the applicability of second order GGA in momentum densities. Energy bands, density of states and real space analysis of the experimental profile show metallic character of NbB2.
- Published
- 2011
36. High energy Compton scattering study of TiC and TiN
- Author
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B. L. Ahuja, Alpa Dashora, Ritu Joshi, and K.C. Bhamu
- Subjects
Physics ,Radiation ,Astrophysics::High Energy Astrophysical Phenomena ,Compton scattering ,chemistry.chemical_element ,Fermi surface ,Momentum ,chemistry ,Linear combination of atomic orbitals ,Density of states ,Density functional theory ,Atomic physics ,Tin ,Fermi Gamma-ray Space Telescope - Abstract
We present the experimental Compton profiles of TiC and TiN using 661.65 keV γ-ray from 20 Ci 137 Cs source. To explain our experimental data on momentum densities, we have computed the theoretical profiles, energy bands and density of states using linear combination of atomic orbitals scheme within the framework of density functional theory. In addition the energy bands, density of states and Fermi surfaces using full potential linearised augmented plane wave method have also been computed. Energy bands and density of states obtained from both the theoretical models show metallic character of TiC and TiN. The anisotropies in Compton line shapes and the Fermi surface topology are discussed in term of energy bands.
- Published
- 2010
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