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The Small Magellanic Cloud (SMC) shows a large variation in ultraviolet (UV) dust extinction curves, ranging from Milky Way (MW) like to significantly steeper curves with no detectable 2175 Å bump. This result is based on a sample of only nine sight lines. From Hubble Space Telescope Space Telescope Imaging Spectrograph and IUE spectra of OB stars, we have measured UV extinction curves along 32 SMC sight lines where eight of these curves were published previously. We find 16 sight lines with steep extinction with no detectable 2175 Å bump, four sight lines with MW-like extinction with a detectable 2175 Å bump, two sight lines with fairly flat UV extinction and weak/absent 2175 Å bumps, and 10 sight lines with unreliable curves due to low SMC dust columns. Our expanded sample shows that the sight lines with and without the 2175 Å bump are located throughout the SMC and not limited to specific regions. The average extinction curve of the 16 bump-less sight lines is very similar to the previous average based on four sight lines. We find no correlation between dust column and the strength of the 2175 Å bump. We test the hypothesis that the 2175 Å bump is due to the same dust grains that are responsible for the mid-infrared carbonaceous (polycyclic aromatic hydrocarbon) emission features and find they are correlated, confirming recent work in the MW. Overall, the slope of the UV extinction increases as the amplitudes of the 2175 Å bump and far-ultraviolet curvature decrease. Finally, the UV slope is correlated with N (H i )/ A ( V ) and the 2175 Å bump and nonlinear far-ultraviolet rise amplitudes are anticorrelated with N (H i )/ A ( V ).

Dust extinction is one of the fundamental measurements of dust grain sizes, compositions, and shapes. Most of the wavelength-dependent variations seen in Milky Way extinction are strongly correlated with the single parameter R ( V ) = A ( V )/ E ( B − V ). Existing R ( V )-dependent extinction relationships use a mixture of spectroscopic and photometry observations, and hence do not fully capture all the important dust features or continuum variations. Using four existing samples of spectroscopically measured dust extinction curves, we consistently measure the R ( V )-dependent extinction relationship spectroscopically from the far-ultraviolet (FUV) to mid-infrared for the first time. Linear fits of A ( λ )/ A ( V ) dependent on R ( V ) are done using a method that fully accounts for their significant and correlated uncertainties. These linear parameters are fit with analytic wavelength-dependent functions to determine the smooth R ( V ) (2.3–5.6) and wavelength (912 Å–32 μ m) dependent extinction relationship. This relationship shows that the FUV rise, 2175 Å bump, and the three broad optical features are dependent on R ( V ), but the 10 and 20 μ m features are not. Existing literature relationships show significant deviations compared to this relationship especially in the FUV and infrared (IR). Extinction curves that clearly deviate from this relationship illustrate that this relationship only describes the average behavior versus R ( V ). We find tentative evidence that the relationship may not be linear with R ( V ) ^−1 especially in the ultraviolet (UV). For the first time, this relationship provides measurements of dust extinction that spectroscopically resolve the continuum and features in the UV, optical, and IR as a function of R ( V ), enabling detailed studies of dust grain properties and full spectroscopic accounting for the effects of dust extinction on astrophysical objects.

Interstellar dust extinction curves provide valuable information about dust properties, including the composition and size of the dust grains, and are essential to correct observations for the effects of interstellar dust. In this work, we measure a representative sample of near-infrared (NIR; 0.8–5.5 μ m) spectroscopic extinction curves for the first time, enabling us to investigate the extinction at wavelengths where it is usually only measured in broad photometric bands. We use IRTF/SpeX spectra of a sample of reddened and comparison stars to measure 15 extinction curves with the pair method. Our sample spans A ( V ) values from 0.78 to 5.65 and R ( V ) values from 2.43 to 5.33. We confirm that the NIR extinction curves are well fit by a power law, with indices and amplitudes differing from sight line to sight line. Our average diffuse NIR extinction curve can be represented by a single power law with index α = 1.7, but because of the sight line-to-sight line variations, the shape of any average curve will depend on the parental sample. We find that most of the variation in our sample can be linked to the ratio of total-to-selective extinction R ( V ), a rough measurement of the average dust grain size. Two sight lines in our sample clearly show the ice extinction feature at 3 μ m, which can be fitted by a modified Drude profile. We find tentative ice detections with slightly over 3 σ significance in two other sight lines. In our average diffuse extinction curve, we measure a 3 σ upper limit of A (ice)/ A ( V ) = 0.0021 for this ice feature.

An eruptive nova-like event took place in 1994 in the stellar-merger candidate V4332 Sgr. Following the eruption, dust consisting of refractory silicate-rich dust grains containing a significant component of AlO bonding was formed sometime between 1998 and 2003. Observations using Spitzer between 2005 and 2009 show significant changes in the 10 μm silicate stretch feature. There is a deepening of the 10 μm silicate stretch as well as the development of a feature between about 13 and 20 μm consistent with a blend of the MgO and FeO stretching features and the O–Si–O bending mode of increasingly ordered silicate dust. Near-infrared observations show the presence of AlO and water vapor in the outflow in 2003, 2004, and 2005: the AlO has significantly decreased in spectra obtained in 2014 while the water vapor remains largely unchanged. An attempt is made to correlate these observations and understand the significance of these changes using DUSTY modeling. The observations appear consistent with the kinetically controlled condensation of highly underoxidized SiO/AlO/Fe/Mg dust grains in the outflow followed by the continuous evolution of the initial condensate due to thermal annealing and oxidation of the dust via reaction with ambient O, OH, and H2O in the expanding, cooling shell. Periodic monitoring of this dust shell over the mid-infrared spectral range could yield useful information on the evolution of underoxidized silicate condensates exposed to hot water vapor in more conventional circumstellar environments. [ABSTRACT FROM AUTHOR]