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The aim of the presented research was to determine the suitability of both non-modified and modified buckwheat husk (BH) as a filler for urea–formaldehyde adhesive in plywood production. The effect of two modification methods, acetylation and silanization, was investigated. Infrared spectroscopy outcomes confirmed that both acetylation and silanization of the filler had occurred. Based on the results, it was found that the introduction of BH had a significant effect on both the adhesive properties and the characteristics of the manufactured plywood. The application of non-modified husks led to a reduction in viscosity and an extension of the gelation time, and the produced plywood boards were characterized by reduced bonding quality and increased delamination. Modification of the husk surface by acetylation and silanization with 3-aminopropyltriethoxysilane contributed to the noticeable improvement in the resin properties. On the other hand, the improvement in plywood properties, consisting of the increase in bonding quality and reduced delamination, was observed only in the case of the silanized husk. Furthermore, the use of non-modified and acetylated husk did not significantly influence the formaldehyde emission. The reduction in the investigated emission of formaldehyde was observed only in the case of variants containing 15 and 20% of silanized buckwheat husk. [ABSTRACT FROM AUTHOR]

A significant amount of logging residue is produced during roundwood harvesting. Logs are often left in forest sites due to, for example, ecological or logistical aspects. Taking into account the fact that the number of studies focused on changes in the properties of the residue is very low, it was decided to conduct research on the effect of a three-year storage period in forest stands on the chemical properties and energy potential of the wood. The research design allowed for the determination of changes during up to three years of storage. The performed analysis showed a highly negative impact on the characteristics of the material. These adverse effects were probably caused by the activity of microorganisms such as fungi and bacteria, as evidenced by the increased concentrations of ergosterol and low-molecular-weight organic acids. Moreover, it was found that wood stored for three years was characterized by a lower cellulose content; an increased percentage of lignin; a reduced content of sterols (desmosterol, stigmasterol, lanosterol and β-sitosterol) and phenolic acids; and reduced antioxidant activity, as determined with the ABTS+ method. Storing logs also led to a reduction in the energy potential of the residues, as shown by a reduction in net and gross calorific value and an increased ash content. [ABSTRACT FROM AUTHOR]

Due to the fact that impregnation with fire retardant usually reduces the strength of the produced particleboards, this research was carried out to investigate whether it is possible to use phenol–formaldehyde (PF) resin modified using various amounts (0%, 5%, 10%, 15%, and 20%) of polymeric 4,4′-methylene diphenyl diisocyanate (pMDI) for this purpose. The need to optimize the addition of pMDI is particularly important due to health and environmental aspects and high price. Furthermore, the curing process of hybrid resins is still not fully explained, especially in the case of small loadings. Manufactured particleboards differed in the share of impregnated particles (50% and 100%). The mixture of potassium carbonate and urea was used as the impregnating solution. Based on the outcomes of hybrid resins properties, it was found that the addition of pMDI leads to the increase in solid content, pH, and viscosity of the mixtures, to the improvement in resin reactivity determined using differential scanning calorimetry and to the decrease in thermal stability in the cured state evaluated using thermogravimetric analysis. Moreover, particleboard property results have shown that using impregnated particles (both 50% and 100%) decreased the strength of manufactured boards bonded using neat PF resin. However, the introduction of pMDI allowed us to compensate for the negative impact of fire-retardant-treated wood and it was found that the optimal loading of pMDI for the board containing 50% of impregnated particles is 5% and for board made entirely of treated wood it is 10%. [ABSTRACT FROM AUTHOR]

Insulating materials made from straw are becoming increasingly popular in the construction industry. Straw can be used in the construction of buildings as uncompressed straw chips or in the form of compressed panels. This study aimed to determine the possibility of manufacturing boards from straw particles with densities in the range of 150–400 kg/m3, allowing favorable mechanical properties while simultaneously providing high thermal and acoustic insulation properties. The study also analyzed the influence of the degree of carpentry density on the quality of the manufactured boards. The study shows that insulation boards can be produced from straw particles with satisfactory properties already at densities in the range of 200–150 kg/m3. Boards with this density have a compressive strength of 150 kPa, thermal resistance of 0.033–0.046 W/(m·K), and a sound absorption coefficient above 0.31. [ABSTRACT FROM AUTHOR]

The production of plywood from impregnated veneers allows a wood-based product protected in the entire cross-section to be obtained. The conducted research was focused on the properties of veneers impregnated with a mixture of potassium carbonate and urea, such as pH, wettability, colour change and surface roughness. In addition, the properties of plywood produced with melamineurea-formaldehyde resin, such as the shear strength and formaldehyde emission, were the subject of research as well. It was found that the impregnated veneers were characterized by an increased pH, increased wettability, a completely different colour and unchanged surface roughness. Moreover, the impregnation of the veneers caused a decrease in the bonding quality of the plywood and a reduction in formaldehyde emissions from the finished product. It can be concluded that the melamine-urea-formaldehyde adhesive is more suitable for the production of fire-resistant plywood than the urea-formaldehyde adhesive. [ABSTRACT FROM AUTHOR]

The aim of the study was to investigate the effect of propylamine addition to urea-formaldehyde resin on the properties of resultant plywood. The research consisted in investigating the properties of both liquid and cured resins, as well as the produced plywood. Studies have shown that the incorporation of propylamine adversely affected reactivity of the adhesive mixtures by increasing their pH. The evaluation of adhesive chemical structure with FTIR spectroscopy showed some slight changes indicating the reaction of formaldehyde with introduced modifier. The addition of propylamine contributed to the considerable reduction of free formaldehyde contained in the cured adhesive. Furthermore, the propylamine was also found to work effectively as a formaldehyde scavenger by significantly reducing the hazardous emission from plywood. However, based on the results of bonding quality, delamination, bending strength and modulus of elasticity it was found that application of propylamine resulted in a noticeable deterioration of plywood properties. Therefore, the amount of introduced modifier should not exceed 1% of solid UF resin. [ABSTRACT FROM AUTHOR]

This work examines the possibility of applying non-modified nanocellulose and nanocellulose functionalized with 3-aminopropyltriethoxysilane (APTES) as a formaldehyde scavenger for commonly used urea-formaldehyde (UF) adhesive. The effect of silanization was determined with the use of Fourier transform infrared spectroscopy (FTIR), flame atomic absorption spectrometry (FAAS), and elemental analysis. Moreover, the ability of cellulosic nanoparticles to absorb the formaldehyde from an aqueous solution was investigated. After homogenization, cured UF adhesives were examined with the use of FTIR, energy-dispersive spectroscopy (SEM-EDS), and the perforator method to determine the content of formaldehyde. Manufactured boards made of rape straw particles and wood particles were tested in terms of their physico-mechanical properties and formaldehyde emission. Studies have shown that the applied method of silanization was effective. Furthermore, in the case of non-modified nanocellulose, no sign of formaldehyde scavenging ability was found. However, the functionalization of cellulosic nanoparticles with APTES containing an amino group led to the significant reduction of formaldehyde content in both the aqueous solution and the UF adhesive. The mechanical properties of both strawboards and particleboards were improved due to the nanocellulose reinforcement; however, no effect of silanization was found. Nevertheless, functionalization with APTES contributed to a decrease in formaldehyde emission from boards, which was not found in the case of the introduction of non-modified cellulosic nanoparticles. [ABSTRACT FROM AUTHOR]

The aim of the presented study was to apply various bark species (birch, beech, maple, pine and spruce) as fillers for urea-formaldehyde (UF) resin in three-layer plywood manufacturing. For this purpose, all types of bark were ground and added to the adhesive mixture. The resultant plywood was subjected to investigations of the following: tensile strength, modulus of elasticity (MOE), bending strength (MOR) and formaldehyde emission. The results indicate a reduction in the tensile strength. Moreover, the lack of significant improvement in strength parameters can be explained by too high a load of the filler (20 wt%). In the case of formaldehyde emissions, a reduction was observed for birch (B-1), beech (B-2), maple (B-3) and pine bark (B-4). In addition, an increase in the emission of formaldehyde was recorded only for spruce bark. [ABSTRACT FROM AUTHOR]

Engineered wood products, such as glulam beams, attract much attention from the building industry in recent years. Therefore, there is a constant necessity to seek new models of structural beams, which assume the use of outsized sawn wood pieces as an alternative for the standard construction timber. Three variants of glulam beams, composed of the main yield and side boards arranged in various structures, were proposed. Moreover, the usefulness of wedge-jointed, small-sized timber pieces was also investigated. The manufactured beams were tested, in terms of their mechanical properties, such as bending strength, elastic energy, modulus of elasticity, and resilience. The outcomes have shown that the beams manufactured using wedge-bonded timber of lower grade do not deviate considerably from beams produced from homogeneous lamellas. Furthermore, the results of modulus of elasticity, in the case of the three-layered beams composed of both small-sized non-homogenous main yield and side boards, exceeded the requirements from EN 14080. It allowed us to classify the obtained materials as GL 32c, which is the highest grade specified within the standard. [ABSTRACT FROM AUTHOR]

This study examined the effect of applying cellulose nanoparticles as a filling material for phenol-formaldehyde (PF) resin in the process of manufacturing water-resistant plywood. Based on investigations that concerned the rheological behavior of resin mixture containing various amounts of nanofiller, the modification of resin resulted in a major increase of viscosity. Although Fourier transform infrared spectroscopy did not fully explain the effect of modification on the chemical structure of the adhesive, there was a noticeable improvement in the morphology of cured nanocellulose-reinforced resin. Based on the bonding quality results, the optimum amount of nanocellulose was 3 PBW (parts by weight) per 100 PBW of resin and it allowed the achievement of a notable increase in shear strength values. Moreover, introduction of cellulosic nanoparticles had a positive effect on mechanical properties such as bending strength and modulus of elasticity. In summary, the research showed that it is possible to apply nanocellulose as a modifier for the adhesives in the process of manufacturing water-resistant plywood. [ABSTRACT FROM AUTHOR]

The possibility of replacing the rye flour commonly used as a filler for urea formaldehyde resins was investigated for plywood production with birch bark characterized by various particle dimensions. The effects on the curing and rheological properties of the adhesives were investigated. Moreover, the plywood was tested to evaluate the formaldehyde emissions, bonding quality, modulus of elasticity, and bending strength. The results showed that the size of the bark particles had a significant effect on the viscosity of the adhesives but did not affect other properties of the resin. Replacing the flour with the bark significantly decreased the formaldehyde release, but there was no clear correlation with the dimensional fraction of the bark powder. The particle size had notable effects on bonding quality and mechanical properties. The best results were obtained for a sieve with square holes whose inside lengths were 0.315; however, all plywood samples achieved shear strength values exceeding the requirements of EN 314-2 (1993). [ABSTRACT FROM AUTHOR]

Various flours were added as fillers for urea-formaldehyde (UF) resin, and effects on the rheological behavior and the curing properties of the resin were evaluated. The plywood properties such as bonding quality, bending strength, modulus of elasticity, and formaldehyde-release were tested. Five types of flours were used, i.e., rye flour, hemp flour, coconut flour, rice flour, and pumpkin flour. The type of flour had a major influence on the properties of resin mixture such as gel time, solid content, and viscosity. The use of rye and pumpkin flour resulted in a longer gelling time, and the adhesive mixture filled with rice flour did not attain the desired viscosity value needed for the production of plywood. The best mechanical properties and bonding quality were achieved by addition of pumpkin flour. However, the bonding quality of plywood glued with an adhesive filled with every other flour retained good values exceeding 1 N/mm² as required by the standard EN 314-2 (1993). The use of hemp flour as a filler for UF resin led to a substantial decrease of free formaldehyde content. [ABSTRACT FROM AUTHOR]

It was determined how the impregnation of birch veneers with a mixture of potassium carbonate and urea affected the fire protection properties, shear strength, modulus of elasticity and modulus of rigidity of plywood glued with PF and UF resin. Veneers were impregnated by soaking in aqueous fire retardant solutions with concentrations of 20% and 30%. Measurements of mass loss, burned area and time of ignition showed the fire protection provided to be very effective. Impregnation did not significantly affect the modulus of elasticity or modulus of rigidity of the plywood. Impregnation caused a decrease in bonding quality, especially in the case of plywood with UF resin soaked in water. For the samples with PF resin, both immersed and boiled in water, impregnation had less impact on the shear strength: its values exceeded 1 N/mm2, thus meeting the requirements of EN 314-2. [ABSTRACT FROM AUTHOR]

This research evaluated the possibility of using sawmill by-products from the roundwood-processing line in the production of wood-based panels. Due to its number of favorable properties, interesting chemical composition and large reserves resulting from the lack of industrial applications, the research focused particularly on the use of bark. Manufactured variants of boards differed in the proportions of wood chips to bark (70:30, 60:40, 50:50). Moreover, the boards containing only wood chips and a mixture of chips and sawdust were used as references. Urea-formaldehyde adhesive mixed with ammonium nitrate as a hardener was applied as a binding agent for the boards. Based on the mechanical properties (modulus of elasticity, modulus of rupture, internal bonding), physical properties (density, thickness swelling, water absorption) and content and emission of formaldehyde, it was found that it is possible to produce boards characterized by good properties from sawmill by-products without advanced processing. Moreover, the use of bark instead of sawdust in order to increase the homogeneity of the cross-section allows one to obtain panels with significantly lower formaldehyde emission and water uptake. [ABSTRACT FROM AUTHOR]

Pine timber of Polish origin intended for structural purposes is characterized by significant variability in the quality parameters. Technological suitability determined on the basis of relevant international classifications is based on the assessment of both selected mechanical and physical properties of wood. Moreover, the description of visual properties is also a valuable indicator regarding defect distribution. In the group of quality features playing a crucial role in the classification of sawn timber, there are knots, disruptions of grains, cracks, etc. Thus, the aim of the research was to determine the correlation between the presence of selected defects and the strength properties of individual timber pieces. This type of study is based on a nondestructive test method that allows for high optimization of sawn materials processing. In the case of sawn timber of Polish origin, the modulus of elasticity (MOE) determined using the sonic test is commonly used as a criterion. The research material was harvested from southern Poland. The results of the conducted studies confirmed a correlation between an increasing occurrence of particular types of defects and the results of MOE. Furthermore, as a result of the performed investigations, no significant effect of narrow surface cracks on strength properties was observed. [ABSTRACT FROM AUTHOR]

The aim of this study was to determine the mechanical properties of laminated beams containing selected wood species in the tension zone using a four-point bending test. Three beam types were manufactured with respect to the timber used in the tension zone, i.e., beams containing oak or beech timber of I and II quality class and pine timber with no defects (as defects had been removed). The manufactured beams were assessed with respect to bending strength and the modulus of elasticity. The obtained results were compared with the performance of BSH (Industrial beams GL made in Germany—Brettschichtholz) industrial beams. We concluded that beams made from pine timber are an appropriate alternative to spruce beams. The static bending strength of the beams made with hardwood faces was 70% higher than that of beams made with pine wood. All types of beams manufactured in the laboratory met the requirements of at least the GL24c class. [ABSTRACT FROM AUTHOR]

Engineered wood products (EWP) such as glulam beams are gaining more and more popularity due to several advantages resulting from the wood itself, as well as the constant search for structural materials of natural origin. However, building materials face some requirements regarding their strength. Thus, the study aimed to assess the static bending strength of structural beams produced with the use of pine wood, after the periodic loading of approximately 80 kN for a year. The manufactured beams differed in the type of facing layers, i.e., pine timber with a high modulus of elasticity and plywood. The produced beams, regardless of their structure, are characterized by a similar static bending strength. Moreover, it has been shown that the loading of beams in the range of about 45% of their immediate capacity does not significantly affect their static bending strength and linear modulus of elasticity. [ABSTRACT FROM AUTHOR]

In studies on Polish pine wood, the parameters determining its usefulness for processing are highly variable. In contrast, international studies on the optimum utilization of coniferous sawn wood describes its visual features as those indicating the distribution of defects and their impact on the selected mechanical and physical properties of sawn wood. Knottiness is one of the qualitative properties of sawn wood that is essential for wood grading. The objective of this study was to determine a correlation between variable knots and their soundness on the one hand and their selected strength parameters on the other. One of the basic issues of this work includes structural timber optimization. For Polish sawn wood, these indicators are still relatively new. The study material involved edged butt-end log lumber from a 120-year-old forest stand. The results confirmed a correlation between knots frequency and modulus of elasticity. The correlation was strong, indicating that sound knots play a major role in the process of the strength assessments. The study did not demonstrate a significant share of rotten knots and their effect on strength. [ABSTRACT FROM AUTHOR]

The aim of this study was to assess the static bending strength of pine glulam manufactured when obtaining the main yield, i.e., structural timber or timber to be used in the production of structural glulam. Analyses were conducted on pine timber harvested from three different locations in Poland. Two beam variants were manufactured, differing in the timber arrangement, horizontal vs. vertical. It was shown that the static bending strength of beams manufactured in the vertical timber arrangement variant is slightly higher than that of beams produced from horizontally arranged layers, with the latter beams characterised by a smaller confidence interval for this strength. Moreover, it was found that the difference in the value of the 5th percentile for both beam types is slight and both beam types are considered to exhibit a high bending strength of over 40 N/mm2. [ABSTRACT FROM AUTHOR]

The paper assessed the feasibility of manufacturing glued structural elements made of pine wood after grading it mechanically in a horizontal arrangement. It was assumed that the pine wood was not free of defects and that the outer lamellas would also be visually inspected. This would result in only rejecting items with large, rotten knots. Beams of the assumed grades GL32c, GL28c and GL24c were made of the examined pine wood. Our study indicated that the expected modulus of elasticity in bending was largely maintained by the designed beam models but that their strength was connected with the quality of the respective lamellas, rather than with their modulus of elasticity. On average, the bending strength of the beams was 44.6 MPa. The cause of their destruction was the individual technical quality of a given item of timber, which was loosely related to its modulus of elasticity, assessed in a bending test. Although the modulus of elasticity of the manufactured beam types differed quite significantly (11.45–14.08 kN/mm2), the bending strength for all types was similar. Significant differences occurred only during a more detailed analysis because lower classes were characterized by a greater variation of the bending strength. In this case, beams with a strength of 24 MPa to 50 MPa appeared. [ABSTRACT FROM AUTHOR]

The study assessed the quality of pine lumber by marking the modulus of elasticity in the horizontal system. The research material was a plank with the following dimensions: 137 mm wide × 39.50 mm thick × 3485 mm long. The pine wood was obtained by sawing timber in the form of logs with round cross sections and originating from the Forest Division Olesno (50°52′30″ N, 18°25′00″ E). Each long log was sawn to provide four logs of about 3.5 m, which were marked as butt-end logs (O), middle logs (S)—2 items, and top logs (W). The origin of the logs from the trunk (Pinus sylvestris L.) has a significant impact on the physical and mechanical properties of the wood from which they are made. Only butt-end logs (log type O) allows for the production of high-quality timber elements. The pine timber that was evaluated in this paper had a high density of about 570 kg/m3 and a high percentage of timber items were assigned to class C24 and higher (above 50%). The adopted horizontal model of evaluation of the modulus of elasticity gave similar results to those obtained in an evaluation according to the EN-408. [ABSTRACT FROM AUTHOR]