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Additives for tin halide perovskites are investigated and several mechanisms, including halide exchange, coordination with Sn halides, and sacrificial antioxidant behavior are observed to decrease Sn4+ content in the perovskites.

Two-dimensional metal halide perovskite nanocrystals are attractive for their blue-shifted absorption relative to their 3D counterparts, narrow emission line widths, high absorption cross sections,...

Surface ligand treatment provides a promising approach for passivating defect states, improving material and device stability, manipulating interfacial energetics, and improving the performance of ...

Interfacial chemistry and energetics significantly impact the performance of photovoltaic devices. In the case of Pb-containing organic metal halide perovskites, photoelectron spectroscopy has been...

Surface passivation is an effective way to boost the efficiency and stability of perovskite solar cells (PSCs). However, a key challenge faced by most of the passivation strategies is reducing the interface charge recombination without imposing energy barriers to charge extraction. Here, a novel multifunctional semiconducting organic ammonium cationic interface modifier inserted between the light-harvesting perovskite film and the hole-transporting layer is reported. It is shown that the conjugated cations can directly extract holes from perovskite efficiently, and simultaneously reduce interface non-radiative recombination. Together with improved energy level alignment and the stabilized interface in the device, a triple-cation mixed-halide medium-bandgap PSC with an excellent power conversion efficiency of 22.06% (improved from 19.94%) and suppressed ion migration and halide phase segregation, which lead to a long-term operational stability, is demonstrated. This strategy provides a new practical method of interface engineering in PSCs toward improved efficiency and stability.

All-perovskite tandem solar cells hold the promise of surpassing the efficiency limits of single-junction solar cells

Metal halide perovskite nanocrystals (NCs) are attractive materials for optoelectronics. However, further improvements in stability, reproducibility, and photoluminescence quantum yield (ΦPL) are e...

Fabrication of perovskite solar cells (PSCs) is highly humidity-sensitive. In this paper, humidity-insensitive fabrication (HIF) of efficient CH3NH3PbI3 (MAPbI3) PSCs using an antisolvent method is demonstrated. Characterizations including scanning electron microscope (SEM), X-ray diffraction (XRD), UV–vis absorption and steady-state photoluminescence (PL) of the MAPbI3 films prepared in a glovebox(∼0% RH) and 50% RH ambient air using the antisolvent method are carried out. The quality of the MAPbI3 films shows no obvious difference in these two cases. By analyzing the crystallization processes, the greatly suppressed influence of humidity is ascribed to the rapid crystallization process due to the antisolvent method. The photovoltaic performances and storage stability of MAPbI3 PSCs prepared at a series of relative humidity (RH) levels below 60% are found similar. Their average power conversion efficiency (PCE) is over 15% with the best PCE of 16.9%. In addition, the influence of absorbed water in the hydrophilic precursor to MAPbI3 films and associated solar cells is investigated. The influence of equal molar absorbance of H2O is found ignorable. It is concluded that antisolvent method is an ideal HIF route for fabrication of efficient PSCs in ambient air and may pave the way for massive and low-cost manufacturing of solar panels.

Blending two or more π-conjugated polymers together provides a means of manipulating charge transport properties and potentially improving the performance of organic thermoelectrics. Previous results have shown that π-conjugated polymer blends can display higher Seebeck coefficients than either of the individual polymers; however, significantly increased power factors and improved thermoelectric performance in polymer blends as compared to the individual polymers has not yet been demonstrated. The purpose of this work is to theoretically and experimentally probe how the electronic properties of the individual polymers influence the Seebeck coefficient, electrical conductivity, and power factor in polymer blends. Specifically, the influence of energetic disorder, energy offsets between the transport states in the two polymers, and charge-carrier localization lengths are investigated based on a theoretical model introduced by Arkhipov and Bassler. These calculations show that gains in the power factor should be attainable when the two polymers have a small (e.g., 0.1–0.2 eV) offset in their density of states (DOS) distributions and the polymer with the higher energy DOS has a wider DOS distribution and a larger localization length. Experimentally, power factors in an appropriate polymer blend are demonstrated to exceed the power factors of the individual polymers by nearly two-fold. Through the applied theoretical and experimental approach, this work provides guidance in regards to the energetics, density of states, and charge-carrier mobilities for designing higher performing organic thermoelectrics with π-conjugated polymer blends.

Herein, we describe the design and synthesis of a suite of molecules based on a benzodithiophene “universal crystal engineering core”. After computationally screening derivatives, a trialkylsilylethyne-based crystal engineering strategy was employed to tailor the crystal packing for use as the active material in an organic field-effect transistor. Electronic structure calculations were undertaken to reveal derivatives that exhibit exceptional potential for high-efficiency hole transport. The promising theoretical properties are reflected in the preliminary device results, with the computationally optimized material showing simple solution processing, enhanced stability, and a maximum hole mobility of 1.6 cm2 V−1 s−1.

Interfacial chemistry and energetics significantly impact the performance of photovoltaic devices. In the case of Pb-containing organic metal halide perovskites, photoelectron spectroscopy has been used to determine the energetic alignment of frontier electronic energy levels at various interfaces present in the photovoltaic device. For the Sn-containing analogues, which are less toxic, no such measurements have been made. Through a combination of ultraviolet, inverse, and X-ray photoelectron spectroscopy (UPS, IPES, and XPS, respectively) measurements taken at varying thickness increments during stepwise deposition of C

It is commonly assumed that charge-carrier transport in doped π-conjugated polymers is dominated by one type of charge carrier, either holes or electrons, as determined by the chemistry of the dopant. Here, through Seebeck coefficient and Hall effect measurements, we show that mobile electrons contribute substantially to charge-carrier transport in π-conjugated polymers that are heavily p-doped with strong electron acceptors. Specifically, the Seebeck coefficient of several p-doped polymers changes sign from positive to negative as the concentration of the oxidizing agents FeCl3 or NOBF4 increase, and Hall effect measurements for the same p-doped polymers reveal that electrons become the dominant delocalized charge carriers. Ultraviolet and inverse photoelectron spectroscopy measurements show that doping with oxidizing agents results in elimination of the transport gap at high doping concentrations. This approach of heavy p-type doping is demonstrated to provide a promising route to high-performance n-type organic thermoelectric materials. A broad range of characterization techniques is used to understand the dominant electron conduction in various p-type doped π-conjugated polymers, which show p-type and n-type thermoelectric power factors depending on the dopant concentration.

Fully fluorinated perfluorocarbon ligands are shown to modify the energetics and dielectric environment of quantum dots (QDs), resulting in a large hypsochromic shift in the optical gap. The original oleic acid (OA) ligands on PbS QDs can be completely replaced with thiolate and carboxylate-based perfluorocarbons, e.g., -SCF3 and CF3(CF2)14COOH (pFA), respectively. Ultraviolet photoelectron spectroscopy indicates that the work function varies by >1.3 eV depending on the electronegativity of the surface ligand, while cyclic voltammetry shows that an OA:pFA ratio of ∼2:1 increases the oxidation potential by 0.18 eV in solution. The diminished reduction potential of the conduction band is confirmed by photoinduced electron transfer experiments. The short thiolate ligands, -SCF3 and -SCH3, enhance the electron-donating ability of PbS QDs up to 7-fold because of an increase in the permeability of the ligand shell. This work shows that electron-withdrawing halogens like fluorine and chlorine can control the ban...

Halogenation, particularly fluorination, is commonly used to manipulate the energetics, stability, and morphology of organic semiconductors. In the case of organic photovoltaics (OPVs), fluorination of electron donor molecules or polymers at appropriate positions can lead to improved performance. In this contribution, we use ultraviolet photoelectron spectroscopy, external quantum efficiency measurements of charge-transfer (CT) states, and density functional theory calculations to systematically investigate the effects of halogenation on the bulk solid-state energetics of model anthradithiophene (ADT) materials, their interfacial energetics with C60, and the energetics of various ADT:C60 blend compositions. In agreement with previous work, nonhalogenated ADT molecules show higher energy CT states in blends with C60 and lower energy CT states in the ADT/C60 bilayers. However, this trend is reversed in the halogenated ADT/C60 systems, wherein the CT state energies of ADT:C60 blends are lower than those in t...

The concept of complementary semiconducting polymer blends (c-SPBs) has been recently proposed to achieve enhanced solution processability and/or melt-processing capability for organic electronics. In the previous study, we demonstrated the impact of conjugation-break spacers of matrix polymers. In the current work, we explore the influence of the side chains of the matrix polymer on the physical properties of the pure polymers and their corresponding c-SPBs, including electrical properties and phase transition behaviors. Six diketopyrrolopyrrole (DPP)-based polymers with pentamethylene conjugation-break spacers (CBSs) and various side chains, including branched-alkyl, triethylene glycol (TEG), and siloxane-terminated side chains, were synthesized and characterized. The UV–vis spectra show that the side chains have a noticeable impact on the intermolecular interactions in the solid states. In addition, side chains also have a significant influence on the thermal behaviors of the polymers. Polymers with as...

Accurate measurements of the valence electronic structures of organic semiconductors are important for the development and understanding of organic electronic devices, materials, and interfaces. Ultraviolet photoelectron spectroscopy (UPS) is a well-established technique for probing valence electronic structures; however, many organic semiconductors undergo rapid sample degradation upon exposure to traditional laboratory-based vacuum ultraviolet (VUV) photon sources. Here, we report on a novel VUV photon source for UPS measurements that utilizes H Lyman-α emission with a narrow linewidth and a widely tunable intensity, and apply it to a number of organic materials of interest to show its ability to overcome this hurdle of sample degradation. Furthermore, the H Lyman-α source displays no measureable higher energy emission lines, which significantly reduces the background over typical He I discharge sources and allows for the onset of the density of states to be clearly observed over several orders of magnitude.

Significant enhancements in the performance of organic–inorganic nanocomposite thermoelectrics may be obtained through appropriately adjusting energetics at the organic–inorganic interfaces. Through altering these interfacial energetics, the energy dependence of the electrical conductivity, and therefore the Seebeck coefficient, can in principle be readily manipulated through energy filtering. In this work, we controllably vary the energetic barrier between transport states in the conjugated polymer poly(3-hexylthiophene) and tellurium nanowires. The energetic barrier is adjusted from 0.08 to 0.88 eV by altering the concentration of the p-type dopant (FeCl3) present in the polymer phase. We show that the maximum power factors in these composites are increased beyond that of either the pure polymer or pure nanowires for barriers of both 0.08 and 0.88 eV. With both doping concentrations the Seebeck coefficient increases with the concentration of tellurium nanowires. Through comparison of the experimentally measured Seebeck coefficients with models for parallel and series connected composites, we determine that the enhanced Seebeck coefficients and power factors do not likely arise from energy filtering. Furthermore, we find that the electrical conductivity of the 5% FeCl3 doped blend can exceed that of either of the pure components by nearly an order of magnitude.

Zero-mode waveguides (ZMWs) are capable of modifying fluorescence emission through interactions with surface plasmon modes leading to either plasmon-enhanced fluorescence or quenching. Enhancement requires spectral overlap of the plasmon modes with the absorption or emission of the fluorophore. Thus, enhancement is limited to fluorophores in resonance with metals (e.g. Al, Au, Ag) used for ZMWs. The ability to tune interactions to match a wider range of fluorophores across the visible spectra would significantly extend the utility of ZMWs. We fabricated ZMWs composed of aluminum and gold individually and also in mixtures of three different ratios, (Al : Au; 75 : 25, 50 : 50, 25 : 75). We characterized the effect of mixed-metal ZMWs on single-molecule emission for a range fluorophores across the visible spectrum. Mixed metal ZMWs exhibited a shift in the spectral range where they exhibited the maximum fluorescence enhancement allowing us to match the emission of fluorophores that were nonresonant with single metal ZMWs. We also compared the effect of mixed-metal ZMWs on the photophysical properties of fluorescent molecules due to metal–molecule interactions. We quantified changes in fluorescence lifetimes and photostability that were dependent on the ratio of Au and Al. Tuning the enhancement properties of ZMWs by changing the ratio of Au and Al allowed us to match the fluorescence of fluorophores that emit in different regions of the visible spectrum.

Photon upconversion employing semiconductor nanocrystals (NCs) makes use of their large and tunable absorption to harvest light in the near-infrared (NIR) wavelengths as well as their small gap between singlet and triplet excited states to reduce energy losses. Here, we report the highest QY (11.8%) thus far for the conversion of NIR to yellow photons by improving the quality of the PbS NC. This high QY was achieved by using highly purified lead and thiourea precursors. This QY is 2.6 times higher than from NCs prepared with commercially available lead and sulfide precursors. Transient absorption spectroscopy reveals two reasons for the enhanced QY: longer intrinsic exciton lifetimes of PbS NCs and the ability to support a longer triplet lifetime for the surface-bound transmitter molecule. Overall, this results in a higher efficiency of triplet exciton transfer from the PbS NC light absorber to the emitter and thus a higher photon upconversion QY.

Precise doping of organic semiconductors allows control over the conductivity of these materials, an essential parameter in electronic applications. Although Lewis acids have recently shown promise as dopants for solution-processed polymers, their doping mechanism is not yet fully understood. In this study, we found that B(C6F5)3 is a superior dopant to the other Lewis acids investigated (BF3, BBr3 and AlCl3). Experiments indicate that Lewis acid-base adduct formation with polymers inhibits the doping process. Electron-nuclear double-resonance and nuclear magnetic resonance experiments, together with density functional theory, show that p-type doping occurs by generation of a water-Lewis acid complex with substantial Bronsted acidity, followed by protonation of the polymer backbone and electron transfer from a neutral chain segment to a positively charged, protonated one. This study provides insight into a potential path for protonic acid doping and shows how trace levels of water can transform Lewis acids into powerful Bronsted acids.

The concept of complementary semiconducting polymer blends (c-SPBs) for efficient charge transport was recently proposed and established by our group. In this study, we aim to reveal the influence of the length of conjugation-break spacers (CBSs) on charge transport properties of the matrix polymers and their corresponding complementary polymer blends. A series of 11 DPP-based semiconducting polymers DPP-Cm (m = 2–12) that incorporate CBSs of 2–12 methylene units along the polymer backbones were prepared and characterized. The UV–vis spectra and the ultraviolet photoelectron spectroscopy (UPS) measurements show that the CBS length has marginal influence on the polymer absorption spectra, energy levels, and band gaps. It also has little impact on polymer decomposition temperatures. However, the CBS length has a profound influence on polymer phase transition and the heat of fusion. As for the melt transitions, an odd–even effect is observed from DPP-C2 to DPP-C7, in which polymers with even-numbered CBSs sh...

Correction to “Surface Ligands for Methylammonium Lead Iodide Films: Surface Coverage, Energetics, and Photovoltaic Performance”

Metal halide perovskite nanocrystals have recently emerged as promising materials for light emitting displays and lasing applications due to their narrow emission wavelengths, high photoluminescence quantum yields, and readily adjustable emission wavelengths. For these metal halide perovskite nanocrystals to be useful in commercial applications, their stability must be increased and the photoluminescence quantum yields of the iodide (red emitting) and chloride (blue emitting) containing derivatives must also be increased. The photoluminescence quantum yields of blue emitting CsPbCl3 nanoparticles lag behind those of green emitting CsPbBr3 nanoparticles, with maximum photoluminescence quantum yields of 1–10% previously reported for CsPbCl3 as compared to 80–100% for CsPbBr3. Herein, we show that alkyltrichlorosilanes (R-SiCl3) can be used as Cl-sources for rapid anion exchange with host CsPbBr3 nanocrystals. This anion exchange reaction is advantageous in that it can be performed at room temperature and results in highly dispersible nanoparticles coated with siloxane shells. CsPbCl3 nanoparticles produced through Cl-exchange with R-SiCl3 show significantly improved long-term stability and high photoluminescence quantum yields of up to 12%. These siloxane coated nanocrystals are even stable in the presence of water, whereas CsPbCl3 nanoparticles synthesized through other routes rapidly degrade in the presence of water.

Organometal halide perovskite photovoltaics typically contain both electron and hole transport layers, both of which influence charge extraction and recombination. The ionization energy (IE) of the hole transport layer (HTL) is one important material property that will influence the open-circuit voltage, fill factor, and short-circuit current. Herein, we introduce a new series of triarylaminoethynylsilanes with adjustable IEs as efficient HTL materials for methylammonium lead iodide (MAPbI3) perovskite based photovoltaics. The three triarylaminoethynylsilanes investigated can all be used as HTLs to yield PV performance on par with the commonly used HTLs PEDOT:PSS and Spiro-OMeTAD in inverted architectures (i.e., HTL deposited prior to the perovskite layer). We further investigate the influence of the HTL IE on the photovoltaic performance of MAPbI3 based inverted devices using two different MAPbI3 processing methods with a series of 11 different HTL materials, with IEs ranging from 4.74 to 5.84 eV. The re...

A critically important question that must be answered to understand how organic solar cells operate and should be improved is how the orientation of the donor and acceptor molecules at the interface influences exciton diffusion, exciton dissociation by electron transfer, and recombination. It is exceedingly difficult to probe the orientation in bulk heterojunctions because there are many interfaces and they are arranged with varying angles with respect to the substrate. One of the best ways to study the interface is to make bilayer solar cells with just one donor–acceptor interface. Zinc phthalocyanine is particularly interesting to study because its orientation can be adjusted by using a 2 nm-thick copper iodide seed layer before it is deposited. Previous studies have claimed that solar cells in which fullerene acceptor molecules touch the face of zinc phthalocyanine have more current than ones in which the fullerenes touch the edge of zinc phthalocyanine because of suppressed recombination. We have more...

Hypothesis In situ crosslinking is expected to increase the solvent stability of coatings formed by surface-initiated ring opening metathesis polymerization (SI ROMP). Solvent-associated degradation limits the utility of SI ROMP coatings. SI ROMP coatings have a unique capacity for post-functionalization through reaction of the unsaturated site on the polymer backbone. Any post-reaction scheme which requires a liquid solvent has the potential to degrade the coating and lower the thickness of the resulting film. Experiments We designed a macromolecular crosslinking group based on PEG dinorbornene. The PEG length is tailored to the expected mean chain to chain distance during surface-initiated polymerization. This crosslinking macromer is randomly copolymerized with norbornene through SI ROMP on a gold coated substrate. The solvent stability of polynorbornene coatings with and without PEG dinorbornene is quantitatively determined, and the mechanism of degradation is further supported through XPS and AFM analyses. Findings The addition of the 0.25 mol% PEG dinorbornene significantly increases the solvent stability of the SI ROMP coatings. The crosslinker presence in the more stable films is supported with observable PEG absorbances by FTIR and an increase in contact angle hysteresis when compared to non-crosslinked coatings. The oxidation of the SI ROMP coatings is supported by the observation of carbonyl oxygen in the polynorbornene coatings. The rapid loss of the non-crosslinked SI ROMP coating corresponds to nanoscale pitting across the surface and micron-scale regions of widespread film loss. The crosslinked coatings have uniform nanoscale pitting, but the crosslinked films show no evidence of micron-scale film damage. In all, the incorporation of minimal crosslinking content is a simple strategy for improving the solvent stability of SI ROMP coatings.

In most research, fabrication of high performance perovskite solar cells (PSCs) has been carried out in a well-controlled environment (glove boxes), which may result in high cost for eventual manufacturing. Therefore, fabrication of efficient perovskite solar cell in ambient air is of great interest. We fabricated CH3NH3PbI3(MAPbI3) solar cells in ambient air without control of relative humidity (~20-50%RH) using the antisolvent method. The effect of both the antisolvent and the annealing process on the solar cell performance has been investigated. Solar cells with power conversion efficiency of over 15% and negligible hysteresis were obtained, which are close to the performance of solar cells fabricated at nitrogen environment in a glove box. It may pave the way for fabrication of highperformance PSCs in ambient air.

Isoindigo (iI) has proven successful as an electron-accepting building block for the preparation of electroactive materials for organic electronics. Its high yielding and scalable synthesis has enabled the rapid development of a large number of molecular and polymeric iI-based materials with remarkable physical properties. This perspective provides an overview of the fundamental properties of isoindigo and summarizes the progress in the development of new materials for varied electronic applications during the last 3 years, focusing in particular on organic photovoltaics (OPVs) and organic field effect transistors (OFETs). The fundamental electronic properties of isoindigo are discussed in the context of the substitution pattern effect (5,5′ vs 6,6′) on the frontier orbitals energies and optical properties. The development of molecular systems in the 6,6′-iI configuration for OPVs is examined with an emphasis on molecular design for improved electronic properties thanks to fine-tuning of the active layer ...

The effects of sterics and molecular orientation on the open-circuit voltage and absorbance properties of charge-transfer states are explored in model bilayer organic photovoltaics. It is shown that the open-circuit voltage correlates linearly with the charge-transfer state energy and is not significantly influenced by electronic coupling.

Tailor-made additives, which are molecules that share the same molecular structure as a parent molecule with only slight structural variations, have previously been demonstrated as a useful means to control crystallization dynamics in solution. For example, tailor-made additives can be added to solutions of a crystallizing parent molecule to alter the crystal growth rate, size, and shape. We apply this strategy as a means to predictably control morphology in molecular bulk-heterojunction (BHJ) photovoltaic cells. Through the use of an asymmetric oligomer substituted with a bulky triisobutylsilyl end group, the morphology of BHJ blends can be controlled resulting in a near doubling (from 1.3 to 2.2%) in power conversion efficiency. The use of tailor-made additives provides promising opportunities for controlling crystallization dynamics, and thereby film morphologies, for many organic electronic devices such as photovoltaics and field-effect transistors.

Most optimized donor-acceptor (D-A) polymer bulk heterojunction (BHJ) solar cells have active layers too thin to absorb greater than ∼80% of incident photons with energies above the polymer's band gap. If the thickness of these devices could be increased without sacrificing internal quantum efficiency, the device power conversion efficiency (PCE) could be significantly enhanced. We examine the device characteristics of BHJ solar cells based on poly(di(2-ethylhexyloxy)benzo[1,2-b:4,5-b′]dithiophene-co-octylthieno[3,4-c]pyrrole-4,6-dione) (PBDTTPD) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) with 7.3% PCE and find that bimolecular recombination limits the active layer thickness of these devices. Thermal annealing does not mitigate these bimolecular recombination losses and drastically decreases the PCE of PBDTTPD BHJ solar cells. We characterize the morphology of these BHJs before and after thermal annealing and determine that thermal annealing drastically reduces the concentration of PCBM in the mixed regions, which consist of PCBM dispersed in the amorphous portions of PBDTTPD. Decreasing the concentration of PCBM may reduce the number of percolating electron transport pathways within these mixed regions and create morphological electron traps that enhance charge-carrier recombination and limit device quantum efficiency. These findings suggest that (i) the concentration of PCBM in the mixed regions of polymer BHJs must be above the PCBM percolation threshold in order to attain high solar cell internal quantum efficiency, and (ii) novel processing techniques, which improve polymer hole mobility while maintaining PCBM percolation within the mixed regions, should be developed in order to limit bimolecular recombination losses in optically thick devices and maximize the PCE of polymer BHJ solar cells.

Polymer:fullerene solar cells are demonstrated with power conversion efficiencies over 7% with blends of PBDTTPD and PC61BM. These devices achieve open-circuit voltages (Voc) of 0.945 V and internal quantum efficiencies of 88%, making them an ideal candidate for the large bandgap junction in tandem solar cells. Voc’s above 1.0 V are obtained when the polymer is blended with multiadduct fullerenes; however, the photocurrent and fill factor are greatly reduced. In PBDTTPD blends with multiadduct fullerene ICBA, fullerene emission is observed in the photoluminescence and electroluminescence spectra, indicating that excitons are recombining on ICBA. Voltage-dependent, steady state and time-resolved photoluminescence measurements indicate that energy transfer occurs from PBDTTPD to ICBA and that back hole transfer from ICBA to PBDTTPD is inefficient. By analyzing the absorption and emission spectra from fullerene and charge transfer excitons, we estimate a driving free energy of –0.14 ± 0.06 eV is required for efficient hole transfer. These results suggest that the driving force for hole transfer may be too small for efficient current generation in polymer:fullerene solar cells with Voc values above 1.0 V and that non-fullerene acceptor materials with large optical gaps (>1.7 eV) may be required to achieve both near unity internal quantum efficiencies and values of Voc exceeding 1.0 V.

Solvent additives provide an effective means to alter the morphology and thereby improve the performance of organic bulk-heterojunction photovoltaics, although guidelines for selecting an appropriate solvent additive remain relatively unclear. Here, a family of solvent additives spanning a wide range of Hansen solubility parameters is applied to a molecular bulk-heterojunction system consisting of an isoindigo and thiophene containing oligomer as the electron donor and [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) as the electron acceptor. Hansen solubility parameters are calculated using the group contribution method and compared with the measured solubilities for use as a screening method in solvent additive selection. The additives are shown to alter the morphologies in a semipredictable manner, with the poorer solvents generally resulting in decreased domain sizes, increased hole mobilities, and improved photovoltaic performance. The additives with larger hydrogen bonding parameters, namely triethylene glycol (TEG) and N-methyl-2-pyrrolidone (NMP), are demonstrated to increase the open circuit voltage by ~0.2 V. Combining a solvent additive observed to increase short circuit current, poly(dimethylsiloxane), with TEG results in an increase in power conversion efficiency from 1.4 to 3.3%.

A set of six perfectly regioregular pendant 2,7-bis(phenyl-m-toluylamino)fluorene (TPF) functionalized polyolefins for use as charge transporting materials in polymer light emitting diodes (PLEDs) were prepared and characterized. Synthesis of these materials is straightforward, requiring only three or four steps, depending on the polymer, and final isolated yields over all steps combined were greater than 40% in all but one case. Most notably, these materials exhibit charge-carrier mobilities that can be controlled over 3 orders of magnitude by variation of the number of intermediary carbons (spacer length) between the pendant TPF groups. The range of hole mobilities encompasses the electron mobilities of common electron transport materials/emitters such as Alq3 and PBD, thus, affording the opportunity to fabricate electroactive polyolefin based PLEDs with well matched charge-carrier mobilities and improved performance. We believe this approach to charge-carrier mobility control in electroactive materials...

Acyclic diene metathesis polymerization (ADMET) was used to synthesize a series of perfectly regioregular polyolefins, in which the number of backbone atoms between pendant terfluorene groups was precisely controlled at 8, 14, or 20 carbons. Analogous random copolymers containing identical chromophore densities were also synthesized to study the impact of regioregularity on the performance of this class of materials in polymer light emitting diodes (PLEDs). Additionally, the backbone alkene remnants of ADMET were saturated to generate materials with somewhat different ordering. These saturated derivatives led to improvements in PLED external quantum efficiencies (EQEs) over their unsaturated analogues in most cases, with a large improvement in one material. Charge mobility, as manifested in current density during PLED characterization, and relative solid-state fluorescence quantum yield (ΦF) also exhibit reasonable dependencies, with longer distances between electroactive groups yielding lower PLED curren...