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1. Infrared spectroscopic evidence for carbon monoxide dissociation and radical pathways in the photochemical reactions on (η-cyclopentadienyl)(methyl)tricarbonyl-molydenum

Author

Richard H. Hooker, Anthony J. Rest, Ramli B. Hitam, Ramaier Narayanaswamy, and Khalil M. Mahmoud

Subjects
chemistry.chemical_classification, Infrared, Organic Chemistry, Infrared spectroscopy, Polymer, Photochemistry, Biochemistry, Dissociation (chemistry), Inorganic Chemistry, chemistry.chemical_compound, chemistry, Cyclopentadienyl complex, Materials Chemistry, Physical and Theoretical Chemistry, Carbon monoxide
Abstract

Infrared spectroscopy of organometallic complexes in polymers films at 12–293 K has been used to investigate reactive species; in the photoreactions of (η5-C5H5)Mo(CO)3(CH3) both CO dissociation and MoCH3 bond homolysisreactions were observed.

Published
1981
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