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We demonstrate here that lignin can be successfully combined with silica to create a multifunctional material with considerable sorption capabilities. Experiments were carried out in which a silica/lignin hybrid was used for the removal of lead(II) ions from water solutions. Adsorption kinetics were also determined and preliminary regeneration tests were performed. The effectiveness of the adsorption process depends on the following parameters: contact time of adsorbent and adsorbate (equilibrium times: 5 min for concentration 25 mg/L, 10 min for 50 and 75 mg/L, 60 min for 100 mg/L), pH (optimal pH = 5) and adsorbent mass. The kinetics of the adsorption of lead(II) ions on the SiO2/lignin biosorbent are best described by a pseudo-second-order model. Adsorption isotherms of lead(II) ions were also determined. The experimental data were found to be in agreement with the Langmuir model, and the maximal sorption capacity of the adsorbent with respect to lead(II) was 89.02 mg/g.

Herein, the potential of lignin activation with selected ionic liquids (ILs) was investigated to enhance the usefulness of lignin in materials science and electrochemical systems. The main objective was to increase the carbonyl content in lignin through selective oxidation, which would enable its use as a sustainable alternative, for example, in electrode materials and composite systems. Using ILs as activators, the modification process focused on maintaining the structural integrity of lignin while increasing its functional group profile. The research included the precise control of air supply as the oxidant and regulation of the process temperature to prevent lignin depolymerization. Advanced kinetic and thermodynamic analyses of thermal decomposition were performed using thermogravimetric analysis, differential thermogravimetric analysis, and differential thermal analysis, with kinetic modeling based on the Coats-Redfern method. These methodologies facilitated a detailed understanding of the thermal stability, degradation kinetics, and reactivity of the material. Results revealed that the activation of lignin with ILs significantly increases the carbonyl (quinone) group content, enhancing its potential as a reversible proton and electron acceptor in electrochemical applications. The study highlights the importance of balancing degradation kinetics and structural properties of lignin to optimize its reactivity and functional performance. Mechanisms such as F1 and D4 effectively describe the degradation process, with the activation energy (E a ) ranging from 66.691 to 309.389 kJ/mol. The enthalpy (ΔH) ranges from 62.488 to 302.950 kJ/mol, while the ΔS values, both positive and negative, reflect the heterogeneity of the reaction depending on the system and ionic liquid conditions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2025. Published by Elsevier B.V.)

This paper, for the first time, presents a potential application of titanium(IV) oxide and silicon(IV) oxide combined with lignin through a solvent-free mechanical process as admixtures for cement composites. The designed TiO 2 -SiO 2 (1:1 wt./wt.) hybrid materials mixed with lignin were extensively characterized using Fourier transform infrared spectroscopy (FTIR), electrokinetic potential analysis, thermal analysis (TGA/DTG), and porous structure properties. In addition, particle size distributions and scanning electron microscopy (SEM) were conducted to evaluate morphological and microstructural properties. In the next step, the effect of the TiO 2 -SiO 2 /lignin hybrid admixture on the workability, hydration process, microstructure, porosity, mechanical, and antimicrobial properties of the cement composites was evaluated. It was observed that appropriately designed hybrid systems based on lignin contributed to better workability, with an improvement of 25 mm, and reduced porosity of cement composites, decreasing from 14.4 % to 13.3 % in the most favorable sample. Additionally, a higher microstructure density was observed, and with increasing amounts of hybrid material admixture, the mechanical parameters also improved. In addition, the TiO 2 -SiO 2 /lignin hybrid systems had significant potential due to their high microbial purity, suggesting their effectiveness in minimizing microbial accumulation on surfaces. The final stage of analysis involved employing response surface methodology (RSM) to ascertain the optimum composition of cement composites. The results obtained indicate that the TiO 2 -SiO 2 /lignin admixtures are a promising approach for the valorization of lignin waste flows in the design of cement composites., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Recent studies have focused on the development of bio-based products from sustainable resources using green extraction approaches, especially nanocellulose, an emerging nanoparticle with impressive properties and multiple applications. Despite the various sources of cellulose nanofibers, the search for alternative resources that replace wood, such as Lygeum spartum , a fast-growing Mediterranean plant, is crucial. It has not been previously investigated as a potential source of nanocellulose. This study investigates the extraction of novel cellulose micro/nanofibers from Lygeum spartum using a two-step method, including both alkali and mechanical treatment as post-treatment with ultrasound, as well as homogenization using water and dilute alkali solution as a solvent. To determine the structural properties of CNFs, a series of characterization techniques was applied. A significant correlation was observed between the Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD) results. The FTIR results revealed the elimination of amorphous regions and an increase in the energy of the H-bonding modes, while the XRD results showed that the crystal structure of micro/nanofibers was preserved during the process. In addition, they indicated an increase in the crystallinity index obtained with both methods (deconvolution and Segal). Thermal analysis based on thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) confirmed improvement in the thermal properties of the isolated micro/nanofibers. The temperatures of maximum degradation were 335 °C and 347 °C. Morphological analysis using a scanning electron microscope (SEM) and atomic force microscope (AFM) showed the formation of fibers along the axis, with rough and porous surfaces. The findings indicate the potential of Lygeum spartum as a source for producing high-quality micro/nanofibers. A future direction of study is to use the cellulose micro/nanofibers as additives in recycled paper and to evaluate the mechanical properties of the paper sheets, as well as investigate their use in smart paper.

In this study, new, functional hydroxyapatite-lignin hybrid systems were designed and characterized. The efficacy of the mechanical method utilized to obtain these systems was confirmed by Fourier transform infrared spectroscopy. The hybrid materials were also noted for their good electrokinetic stability and thermal stability. The introduction of 2.5 to 10 wt% hydroxyapatite-lignin systems into an unplasticized PVC blend using a two-step kneading and pressing method resulted in composites with relatively homogeneous distribution, as confirmed by SEM observations. The processing properties of the filler-containing blends were investigated using plastographometric analysis and MFR tests. The introduction of a lignin-predominant hybrid system into the PVC matrix results in a significant improvement of thermal stability, softening temperature, and tensile strength, while maintaining sufficient impact strength for numerous applications. Hybrid materials containing higher amounts of added lignin are promising materials with bacteriostatic properties. This can be utilized to stabilize and prevent the deposition of microorganisms, as well as the formation of biofilms, on material surfaces, thereby limiting the spread of pathogens. New eco-composites based on PVC and a hybrid filler containing lignin show promise in producing components with surfaces resistant to bacterial colonization. Hence, these materials could be used in medical and hospital equipment., Competing Interests: Declaration of competing interest The authors declare that they do not have any known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The research presented in this article focuses on the use of inorganic-organic material, based on titanium dioxide and lignin, as a filler for polylactide (PLA) biocomposites. To date, no research has been conducted to understand the impact of hybrid fillers consisting of TiO 2 and lignin on the supermolecular structure and crystallization abilities of polylactide. Polymer composites containing 1, 3 or 5 wt.% of hybrid filler or TiO 2 were assessed in terms of their structure, morphology, and thermal properties. Mechanical properties, including tensile testing, bending, impact strength, and hardness, were discussed. The hybrid filler is characterized by a very good electrokinetic stability at pH greater than 3-4. The addition of all fillers led to a small decrease in the glass transition temperature but, most importantly, the addition of 1% of the hybrid filler to the PLA matrix increased the degree of crystallinity of the material by up to 20%. Microscopic studies revealed differences in the crystallization behavior and nucleation ability of fillers. The use of hybrid filler resulted in higher nucleation density and shorter induction time than in unfilled PLA or PLA with only TiO 2 . The introduction of small amounts of hybrid filler also affected the mechanical properties of the composites, causing an increase in bending strength and hardness. This information may be useful from a technological process standpoint and may also help to increase the range of applicability of biobased materials.

The main objective of this study was to discover new packaging materials that could integrate one of the most expected properties, such as UV protection, with a self-cleaning ability defined as photocatalytic performance. Accordingly, new hybrid additives were used to transform LDPE films into materials with complex performance properties. In this study, titanium dioxide-lignin (TL) hybrid systems with a weight ratio of inorganic to organic precursors of 5-1, 1-1, and 1-5 were prepared using a mechanical method. The obtained materials and pristine components were characterized using measurement techniques and research methods, such as Fourier-transform infrared spectroscopy (FTIR), thermal stability analysis (TGA/DTG), measurement of the electrokinetic potential as a function of pH, scanning electron microscopy (SEM), and particle size distribution measurement. It was found that hydrogen bonds were formed between the organic and inorganic components, based on which the obtained systems were classified as class I hybrid materials. In the next step, inorganic-organic hybrid systems and pristine components were used as fillers for a low-density polyethylene (LDPE) composite, 5 and 10% by weight, in order to determine their impact on parameters such as tensile elongation at break. Polymer composites containing titanium dioxide in their matrix were then subjected to a test of photocatalytic properties, based on which it was found that all materials with TiO 2 in their structure exhibit photocatalytic properties, whereby the best results were obtained for samples containing the TiO 2 -lignin hybrid system (1-1). The mechanical tests showed that the thin sheet films had a strong anisotropy due to chill-roll extrusion, ranging from 1.98 to 3.32. UV-Vis spectroscopy revealed four times higher light absorption for composites in which lignin was present than for pure LDPE, in the 250-450 nm range. On the other hand, the temperature at 5% and 30% weight loss revealed by TGA testing increased the highest performance for LDPE/TiO 2 materials (by 20.4 °C and 8.7 °C, respectively).

Recently, much attention has been focused on the application of the Ionic Liquids (ILs) with herbicidal activity in agriculture. It has been suggested that through the appropriate selection of cations and anions, one can adjust the properties of ILs, particularly the hydrophobicity, solubility, bioavailability, toxicity. In practical agricultural conditions, it will be beneficial to reduce the mobility of herbicidal anions, such as the commonly applied 2,4-dichlorophenoxyacetic acid [2,4-D] in the soil. Furthermore, microplastics are becoming increasingly prevalent in the soil, potentially stimulating herbicidal sorption. Therefore, we investigated whether cations in ILs influence the mobility of anions in OECD soil supplemented with polystyrene microplastic (PS). For this purpose, we used the 2,4-D based ILs consisting of: a hydrophilic choline cation [Chol][2,4-D] and a hydrophobic choline cation with a C 12 chain [C 12 Chol][2,4-D]. Characterization of selected micropolystyrene was carried out using the BET sorption-desorption isotherm, particle size distribution and changes in soil sorption parameters such as soil sorption capacity and cation exchange capacity. Based on the batch sorption experiment, the effect of microplastic on the sorption of individual cations and anions in soil contaminated with micropolystyrene was evaluated. The results obtained indicate that the introduction of a 1-10% (w/w) PS resulted in an 18-23% increase of the soil sorption capacity. However, the sorption of both ILs' cations increased only by 3-5%. No sorption of the [2,4-D] anion was noted. This suggests that cations and anions forming ILs, behave independently of each other in the environment. The results indicate the fact that ILs upon introduction into the environment are not a new type of emerging contaminant, but rather a typical mixture of ions. It is worth noting that when analyzing the behavior of ILs in the environment, it is necessary to follow the fate of both cations and anions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The requirements related to reducing the carbon footprint of cement production have directed the attention of researchers to the use of waste materials such as blast-furnace slag or fly ashes, either as a partial replacement for cement clinker or in the form of new alternative binders. This paper presents alkali-activated materials (AAMs) based on blast-furnace slag partially replaced with fly ash, metakaolin, or zeolite, activated with water glass or water glass with a small amount of water, and doped with zinc oxide. The mortars were tested for flow, hydration heat, mechanical strength, microstructure, and antimicrobial activity. The obtained test results indicate the benefits of adding water, affecting the fluidity and generating a less porous microstructure; however, the tested hydration heat, strength, and antibacterial properties are related to more favorable properties in AAMs produced on water glass alone.

In this study, new TiO 2 -lignin hybrid systems were synthesized and characterized by various methods, including non-invasive backscattering (NIBS), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), elemental analysis (EA) and zeta potential analysis (ZP). The weak hydrogen bonds between the components, as shown on FTIR spectra, proved the production of class I hybrid systems. TiO 2 -lignin systems were found to display good thermal stability and relatively good homogeneity. These newly designed hybrid materials were used to produce functional composites via rotational molding in a linear low-density polyethylene (LLDPE) matrix at 2.5 % and 5.0 % loading by weight of the fillers, namely, TiO 2 , TiO 2 -lignin (5:1 wt./wt.), TiO 2 -lignin (1:1 wt./wt.), TiO 2 -lignin (1:5 wt./wt.) and pristine lignin, creating rectangular specimens. The mechanical properties of the specimens were measured via compression testing and by low-energy impact damage testing (the drop test). The results showed that the system containing 5.0 % by weight of TiO 2 -lignin (1:1 wt./wt.) had the most positive effect on the container's compression strength, while the LLDPE filled with 5.0 % by weight of TiO 2 -lignin (5:1 wt./wt.) demonstrated the best impact resistance among all the tested composites., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

In this research, we aimed to design an eco-efficient composite based on alkali-activated materials (AAMs) with self-cleaning properties for sustainable construction. Significant emphasis was placed on determining the role of the type of precursor, the amount of sodium silicate, and the addition of titanium dioxide on the rheological and mechanical properties of AAMs. An important aspect of the research was the modification of AAM with titanium dioxide to obtain the self-cleaning properties. Titanium dioxide, thanks to its photocatalytic properties, enables the reduction of organic pollutants and nitrogen oxides in the urban atmosphere and promotes the cleaning of material surfaces. Blast furnace slag (BFS) was used as the source material, which was then substituted in subsequent formulations with metakaolinite at 50% and fly ash and zeolite at 30%. The best-activated AAMs, in which blast furnace slag and its mixture with metakaolinite were used as precursors, achieved compressive strengths of 50 MPa. BFS mixtures with pozzolans were more difficult to polymerize, although their final strengths were still relatively high, in the range of 33-37 MPa. Adding titanium dioxide (T) improved the final strengths and slightly lowered the heat of hydration and spreading of the AAM mortars. The best self-cleaning properties were achieved with composites that comprised a mixture of blast furnace slag, fly ash, and 2% titanium dioxide.

Nanoparticles are extremely promising components that are used in diagnostics and medical therapies. Among them, silica nanoparticles are ultrafine materials that, due to their unique physicochemical properties, have already been used in biomedicine, for instance, in cancer therapy. The aim of this study was to investigate the cytotoxicity of three types of nanoparticles (SiO2, SiO2-SH, and SiO2-COOH) in relation to red blood cells, as well as the impact of silicon dioxide nanoparticles on biological membranes and liposome models of membranes. The results obtained prove that hemolytic toxicity depends on the concentration of nanoparticles and the incubation period. Silica nanoparticles have a marginal impact on the changes in the osmotic resistance of erythrocytes, except for SiO2-COOH, which, similarly to SiO2 and SiO2-SH, changes the shape of erythrocytes from discocytes mainly towards echinocytes. What is more, nanosilica has an impact on the change in fluidity of biological and model membranes. The research gives a new view of the practical possibilities for the use of large-grain nanoparticles in biomedicine.

CuO nanoparticles (NPs) were added to cement matrices in quantities of 0.25, 0.50 and 1.00 wt% to inhibit the growth of Gram-positive (Bacillus cereus, Staphylococcus aureus) and Gram-negative (Pseudomonas aeruginosa, Escherichia coli) bacteria. It was shown that CuO NPs, in all tested concentrations, improved the antibacterial properties of the cement matrix. Nevertheless, the best mechanical, structural and durability properties were obtained for cement composites doped with CuO NPs at 0.25 wt%. Larger amounts of NPs caused a decrease in all parameters relative to the reference mortar, which may be the result of a slight change in the porosity of the composite microstructure. For 0.50 wt% CuO NPs, a slight increase in the volume of micropores in the cement matrix was observed, and an increased number of larger pores was confirmed by non-invasive computed tomography (CT). The reduction in the mechanical parameters of composites with 0.50 and 1.00 wt% CuO NPs may also be due to the slower hydration of the cement binder, as confirmed by changes in the heat of hydration for these configurations, or agglomeration of NPs, especially for the 1.00 wt% concentration, which was manifested in a decrease in the plasticity of the mortars., (© 2023. The Author(s).)

In this publication, the functional TiO 2 -lignin hybrid materials were designed and characterized. Based on elemental analysis and Fourier transform infrared spectroscopy, the efficiency of the mechanical method used to obtain systems was confirmed. Hybrid materials were also characterized by good electrokinetic stability, in particular in the inert and alkaline environments. The addition of TiO 2 improves thermal stability in the entire analyzed range of temperatures. Similarly, as the content of inorganic component increases, the homogeneity of the system and the occurrence of smaller nanometric particles increase. In addition, a novel synthesis method of cross-linked polymer composites based on a commercial epoxy resin and an amine cross-linker was described as a part of the article, where additionally newly designed hybrids were also used. Subsequently, the obtained composites were subjected to simulated tests of accelerated UV-aging, and then their properties were studied, including changes in wettability (using water, ethylene glycol, and diiodomethane as measurement liquids) and surface free energy by the Owens-Wendt-Eabel-Kealble method. Changes in the chemical structure of the composites were monitored by FTIR spectroscopy due to aging. Microscopic studies of surfaces were also carried out as well as measurements in the field of changes in color parameters in the CIE-Lab system., Competing Interests: Declaration of competing interest The authors declare that they do not have any known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

In this article, halloysite-lignin hybrid materials (HL) were designed and obtained. The weak hydrogen bonds found between the components were determined based on Fourier transform infrared spectroscopy (FTIR), proving the achievement of class I hybrid systems. The HL systems were characterized by very good thermal stability and relatively good homogeneity, which increased as the proportion of the inorganic part increased. This was confirmed by analyzing scanning electron microscope (SEM) images and assessing particle size distributions and polydispersity indexes. Processing rigid poly(vinyl chloride) (PVC) with HL systems with a content of up to 10 wt% in a Brabender torque rheometer allowed us to obtain composites with a relatively homogeneous structure confirmed by SEM observations; simultaneously, a reduction in the fusion time was noted. An improvement in PVC thermal stability of approximately 40 °C for composites with HL with a ratio of 1:5 wt/wt was noted. Regardless of the concentration of the HL system, PVC composites exhibited inconsiderably higher Young's modulus, but the incorporation of 2.5 wt% of fillers increased Charpy impact strength by 5-8 kJ/m 2 and doubled elongation at break. This study demonstrated that favorable mechanical properties of PVC composites can be achieved, especially with an HL system with a ratio of 5:1 wt/wt.

In this study, lignin-based spherical particles (Lig-IL) with the use of 1-(propoxymethyl)-1H-imidazolium hydrogen sulfate were prepared in different biopolymer and ionic liquid (IL) weight ratios. The application of IL during the preparation of spherical particles is an innovative method, which may be beneficial for further applications. The particles were obtained with the use of the soft-templating method and their chemical, structural and morphological characterization was performed. The spherical shape of products and their size (91-615 nm) was confirmed with the use of scanning electron microscopy (SEM) images and the particle size distribution results. The attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectra were analyzed to identify functional groups of all precursors and produced material and it was confirmed, that all materials exhibit characteristic hydroxyl and carboxylic groups, but the presence of carbonyl group was detected. Moreover, the zeta potential analysis was performed to evaluate the electrokinetic behavior of obtained materials. It was confirmed, that all materials are colloidally stable in pH above 4. Produced lignin-based spherical particles were used for evaluation of their antibacterial properties. Particles were tested against Staphylococcus aureus ( S. aureus ), a gram-positive bacterium, and Escherichia coli ( E. coli ), a gram-negative one. It was observed, that only the material with the highest addition of IL showed the antibacterial properties against both strains. A reduction of 50% in the number of microorganisms was observed for particles with the addition of hydrogen sulfate ionic liquid in a 1:1 ratio after 1 h. However, all prepared materials exhibited the antibacterial activity against a gram-positive bacterium., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2022 Stanisz, Klapiszewski, Dobrowolska, Piasecki, Czaczyk and Jesionowski.)

The influence of filler particle size on selected physicochemical and functional properties of polymer composites was analyzed. The following test was carried out for the system: the bisphenol A glycerolate (1 glycerol/phenol) di-methacrylate (BPA.DM) was subjected to UV-polymerization in bulk with N-vinyl-2-pyrrolidone (NVP) as a polymer matrix and talc with particle sizes ranging from ≤8 to 710 µm as a non-toxic and cheap mineral filler. An effective method of preparing cross-linked polymeric composites with talc was developed. The obtained samples were subjected to structural analysis and the thermal, mechanical and flammability properties were assessed. It has been empirically confirmed that the talc particles are incorporated into the composite structure. However, with increasing particle size, the composite heterogeneity increases. In the case of the developed method of sample production, homogeneous systems were obtained for particles in the ≤8-250 µm range. The surface roughness of the samples correlates directly with the size of talc particles. The value of Young's modulus during the axial stretching of samples decreases with the increasing size of talc particles. For the composites containing ≤15 and ≤35 µm talc particles, the highest values were obtained under bending conditions. There was no equivocal effect of particle size on the composites' swelling in water. The addition of talc reduces the flame height and intensity slightly. The biggest difference was obtained for the composites containing relatively large talc particles. It was proved that the selected properties of polymer composites can be controlled depending on the size of the talc particles.

This paper presents an analysis of research results for silica aerogel cement composites over the past twenty years. Recently, two trends in the development of these composites have been noted, towards structural applications and towards ultralight composites for coatings and renders. Ongoing research shows that important aspects of cementitious composites with good mechanical performance are the proper selection of aggregates and improved adhesion at the silica aerogel-cement binder interface, which will guarantee high compressive strength with the lowest possible thermal conductivity. The best physicomechanical performance of aerogel cement composites with low thermal conductivity below 0.03 W/(m·K) was obtained when cenospheres and aerogel were used in a weight percentage of 5%. In turn, the prerequisites for using aerogel cement composites as coatings for energy-efficient building façades are the use of large amounts of silica aerogel as a substitute for lightweight aggregates or the selection of an optimal composition of lightweight aggregates and aerogel, ensuring the lowest possible thermal conductivity coefficient. Other important standpoints are water transport and moisture protection of the silica aerogel-based coatings. Therefore, in recent years, more and more elements of the hygrothermal performance, porosity and durability of silica aerogel cement composites have been developed. The article also points out the weaknesses of the application of silica aerogel in the cement matrix, the most important of which are the lack of adhesion at the boundary of the aerogel-cement binder, the increased porosity of the composite, the high water absorption capacity and the significant decrease in compressive strength with large volumes of silica aerogel. Solving these issues will certainly contribute to the wider applicability of these materials in the construction industry.

In recent years, increasing attention has been paid to the durability of building materials, including those based on cementitious binders. Important aspects of durability include the increase of the strength of the cement matrix and enhancement of material resistance to external factors. The use of nanoadditives may be a way to meet these expectations. In the present study, zinc, titanium and copper oxides, used in single and binary systems (to better the effect of their performance), were applied as additives in cement mortars. In the first part of this work, an extensive physicochemical analysis of oxides was carried out, and in the second, their application ranges in cement mortars were determined. The subsequent analyses were employed in determining the physicochemical properties of pristine oxides: Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray fluorescence (EDXRF), scanning electron microscopy (SEM), measurement of the particle size distribution, as well as zeta potential measurement depending on the pH values. Influence on selected physicomechanical parameters of the cement matrix and resistance to the action of selected Gram-positive and Gram-negative bacteria and fungi were also examined. Our work indicated that all nanoadditives worsened the mechanical parameters of mortars during the first 3 days of hardening, while after 28 days, an improvement was achieved for zinc and titanium(IV) oxides. Binary systems and copper(II) oxide deteriorated in strength parameters throughout the test period. In contrast, copper(II) oxide showed the best antibacterial activity among all the tested oxide systems. Based on the inhibitory effect of the studied compounds, the following order of microbial susceptibility to inhibition of growth on cement mortars was established (from the most susceptible, to the most resistant): E. coli < S. aureus < C. albicans < B. cereus = P. aeruginosa < P. putida .

Water pollution by toxic substances, such as azo dyes, is a serious environmental problem that needs to be addressed. This study presents the synthesis and characterization of new polymeric sorbents, based on the epoxy resin Epidian ® 5 (Ep5), as a potential adsorbent for the removal of the toxic azo dye C.I. Acid Violet 1 (AV1). Triethylenetetramine (TETA) was applied as a cross-linking agent in the amounts of 1 g (6.67 wt %), 1.5 g (10 wt %), and 2 g (13.33 wt %). The use of a compound with amino groups allows for the simultaneous functionalization of the obtained material. The reaction was carried out in an environment of ethylene glycol, with the addition of a porophore solvent (toluene) and bis(2-ethylhexyl)sulfosuccinate sodium salt (S). The attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) revealed the existence of a strong band in the 828-826 cm -1 range corresponding to the second-order amine group, which indicates their incorporation into the epoxy structure. The glass transition and decomposition temperatures of the resins decreased with the increasing amounts of amine in the material. The thermogravimetry (TGA) analysis demonstrated that all products are thermally stable up to 340 °C. The surface morphology and microstructural properties of the obtained sorbents were determined using scanning electron microscopy (SEM) images and showed an irregular star shape, with dimensions ranging from 400 to 1000 µm. The adsorption capacities of Ep5-TETA1, Ep5-TETA1.5, Ep5-TETA2 and Ep5-TETA1.5 + S for AV1 evaluated during batch experiments were found to be 2.92, 3.76, 7.90 and 3.30 mg/g, respectively.

Within this study, the ZrO 2 /lignin and ZrO 2 -SiO 2 /lignin hybrid materials were obtained for the first time. The mechanical grinding method was used for this purpose. In order to determine the properties of obtained lignin-based hybrids and the components used to produce them, as well as to evaluate the efficiency of their preparation, the authors used such research techniques as scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), elemental analysis, porous structure analysis and thermal stability assessment (TGA/DTG). The next step involved using the components and produced hybrid materials as polymer fillers for poly(methyl methacrylate) (PMMA). The obtained lignin-based hybrid biocomposites have then been thoroughly characterized using gel permeation chromatography (GPC), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and hardness testing. All the conducted tests confirm the possibility of using the obtained bio-based products in practice, within the widely understood construction industry, for producing durable building facades or noise barriers, among others., (Copyright © 2021 The Authors. Published by Elsevier B.V. All rights reserved.)

The construction industry in the 21st century faces numerous global challenges associated with growing concerns for the environment. Therefore, this review focuses on the role of lignin and its derivatives in sustainable construction. Lignin's properties are defined in terms of their structure/property relationships and how structural differences arising from lignin extraction methods influence its application within the construction sector. Lignin and lignin composites allow the partial replacement of petroleum products, making the final materials and the entire construction sector more sustainable. The latest technological developments associated with cement composites, rigid polyurethane foams, paints and coatings, phenolic or epoxy resins, and bitumen replacements are discussed in terms of key engineering parameters. The application of life cycle assessment in construction, which is important from the point of view of estimating the environmental impact of various solutions and materials, is also discussed., (Copyright © 2021 Elsevier B.V. All rights reserved.)

A new type of functional lignin-based spherical particles (L-CTAB) prepared with the use of hexadecyltrimethylammonium bromide (CTAB) was applied as an effective biosorbent for removing vanadium(V) ions. The porous structure, characteristic functional groups, electrokinetic stability, morphology and size of the L-CTAB particles were examined. The conditions of removal were also investigated, including pH (2-12), sorbent mass (0.1-0.5 g), concentration (10-100 mg/dm3), phase contact time (1-240 min) and temperature (293-333 K). At pH 5.0 the maximum sorption percentage (%S) of V(V) was 45%, while at pH 2.0 it was 32%. The maximum sorption capacity of V(V) for L-CTAB was found to be 10.79 mg/g. The kinetic data indicate that the sorption followed the pseudo-second-order and film diffusion models. Sorption equilibrium for V(V) ions removal by L-CTAB was reached after 60 min at the initial concentrations 10 and 50 mg/dm 3 . It has been shown that the adsorption of V(V) ions on the surface of L-CTAB is a heterogeneous, endothermic and spontaneous reaction, as evidenced by the calculated values of thermodynamic parameters - free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) - for the tested systems at different temperatures. HCl solutions, used as an L-CTAB regeneration agent, quantitatively eluted V(V) ions., (Copyright © 2021 Elsevier B.V. All rights reserved.)

This study concerns the synthesis of biocomposites with kraft lignin, investigation of their physicochemical properties, and tests of their resistance to environmental factors such as UV irradiation and water. The biocomposites were synthesized using bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BPA.DA) as a main monomer, ethylene glycol dimethacrylate (EGDMA) as a reactive diluent, and kraft lignin (L) as an environmentally friendly filler, in a UV curing process. Morphological analysis of the resulting materials was carried out using scanning electron microscopy and confocal microscopy. Thermal properties were investigated using thermogravimetric analysis. Tensile and flexural tests were performed for all obtained materials. Additionally, the wettability and swelling of the obtained composite samples were analyzed. The changes observed in the structure and properties of the polymers as a result of aging were investigated by means of ATR-FTIR analysis, optical profilometry and hardness tests. The results obtained regarding the effect of lignin addition on the properties of composite materials, with particular emphasis on their resistance to environmental factors, may be of crucial importance for their further applications, inter alia as UV-curable coating materials., (Copyright © 2021 Elsevier B.V. All rights reserved.)

In this study, MgO-lignin (MgO-L) dual phase fillers with varying amounts of lignin as well as pristine lignin and magnesium oxide were used as effective bio-fillers to increase the ultraviolet light protection and enhance the barrier performance of low density polyethylene (LDPE) thin sheet films. Differential scanning calorimetry (DSC) was used to check the crystalline structure of the studied samples, and scanning electron microscopy (SEM) was applied to determine morphological characteristics. The results of optical spectrometry in the range of UV light indicated that LDPE/MgO-L (1:5 wt/wt) composition exhibited the best protection factor, whereas LDPE did not absorb ultraviolet waves. Moreover, the addition of hybrid filler decreased the oxygen permeability factor and water vapor transmission compared with neat LDPE and its composites with pristine additives, such as lignin and magnesium oxide. The strong influence of the microstructure on thin sheet films was observed in the DSC results, as double melting peaks were detected only for LDPE compounded with inorganic-organic bio-fillers: LDPE/MgO-L.

This study presents the preparation and the thermo-mechanical characteristics of polymeric blends based on di(meth)acrylates monomers. Bisphenol A glycerolate diacrylate (BPA.GDA) or ethylene glycol dimethacrylate (EGDMA) were used as crosslinking monomers. Methyl methacrylate (MMA) was used as an active solvent in both copolymerization approaches. Commercial polycarbonate (PC) was used as a modifying soluble additive. The preparation of blends and method of polymerization by using UV initiator (Irqacure ® 651) was proposed. Two parallel sets of MMA-based materials were obtained. The first included more harmless linear hydrocarbons (EGDMA + MMA), whereas the second included the usually used aromatic copolymers (BPA.GDA + MMA). The influence of different amounts of PC on the physicochemical properties was discussed in detail. Chemical structures of the copolymers were confirmed by attenuated total reflection-Fourier transform infrared (ATR/FT-IR) spectroscopy. Thermo-mechanical properties of the synthesized materials were investigated by means of differential scanning calorimetry (DSC), thermogravimetric (TG/DTG) analyses, and dynamic mechanical analysis (DMA). The hardness of the obtained materials was also tested. In order to evaluate the surface of the materials, their images were obtained with the use of atomic force microscopy (AFM).

The synthesis, thermal, and mechanical properties of epoxy resin composites incorporating waste fibers of hemp were studied. Five different systems with increasing quantity of the eco-filler were obtained. For the synthesis of polymeric materials, the commercial epoxy resins Epidian ® 5 and triethylenetetramine (TETA) were applied as crosslinking agents. The composites were obtained based on the polyaddition reaction of an amine group with an epoxide ring. ATR/FT-IR (Attenuated Total Reflection-Fourier Transform Infrared) analysis was used to confirm the chemical structure of the composites and the course of curing processes. Moreover, the influence of the eco-friendly components on the mechanical properties was determined, while thermal properties of the materials were investigated by thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC). Dynamic mechanical studies (DMA) and Shore hardness tests of the obtained polymers were also carried out. The DSC curves and DMA analysis revealed that all materials were characterized by a similar glass transition range. Furthermore, the DMA and hardness measurements of the composites demonstrated an increasing elasticity with the increase in the amount of eco-filler present in the compositions.

A functional PbO-lignin electrode hydrid material composite was designed and manufactured. Moreover, its connection efficiency was confirmed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). We noted that the superficial layers of PbO combined with layers of the biopolymer and that oxygen atoms present in both materials had influence on the chemical environment of the neighboring compound. Hence, it can be said that the addition of PbO significantly contributes to the improvement of thermal stability of the final inorganic-organic system. In the framework of the study, the dispersive, morphological and structural characteristics were determined using scanning electron microscopy (SEM) and laser diffraction method. Electrochemical studies indicated that the PbO-lignin material exhibits better electrochemical properties compared to PbO without the addition of kraft lignin (increased capacitance, lower charge transfer resistance), as the specific capacitance after 5000 charge/discharge cycles was still at 95% of the initial value. Such promising operating parameters show that this material can be successfully used as an electrode material for energy management systems., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Lignin-Al 2 O 3 hybrids were tested as effective additives for application in abrasive materials. The main focus was on the reduction of environmental pollution. The emission of volatile compounds, mainly phenol and formaldehyde, was investigated using detailed evolved gas analysis (EGA) performed by means of mass spectroscopy (QMS) in combined differential scanning calorimetry (DSC) and thermogravimetry (TG) analysis. It was established that the addition of lignin-Al 2 O 3 hybrid additives can reduce the emission of phenol and formaldehyde. Crucially, free phenol emission was not detected from the lignin-Al 2 O 3 additives or from lignin itself using the TG-MS method. Moreover, the addition of lignin-type fillers to phenolic composites can lower emissions of the two aforementioned compounds. No emission of other toxic compounds was detected. The mechanical properties of the lignin-alumina hybrids and resin systems were investigated using the three-point flexural test (also as an element of an ageing test), a compressive test, and testing of abrasibility. The results indicate that the lignin and alumina used as a hybrid additive for abrasive materials improve the adhesion between the binder and abrasive grain, and increase the flexibility of the composites, which has a positive impact on the performance of the final products., (Copyright © 2020. Published by Elsevier B.V.)

Biopolymer-based spherical particles exhibit unique properties including narrow sizes and many functional groups on their surfaces. Therefore, they show great potential for application in many scientific and industrial processes. The main aim of this study was to prepare lignin-based spherical particles with the use of a cationic surfactant, hexadecyl(trimethyl)ammonium bromide (CTAB). In the first step, different preparation procedures were tested with varying parameters, including biopolymer and surfactant ratios, lignin filtration, and experimental time. The morphological and dispersion characteristics of the materials were determined to select the best samples with the most promising properties, which could then be tested for their acute toxicity. It was observed that almost all materials were characterized by spherical shapes in micro- and nanosizes. The sample with the best physicochemical properties was used for further analysis and then tested for medical applications: the improvement of the stability of a drug molecule, cilazapril (CIL). The formulated material (CIL@LC-2a 1:1 wt./wt.) exhibited outstanding properties and significantly improved the stability of cilazapril as tested in conditions of increased temperature and humidity. Lignin spherical particles may be employed as a promising material for shielding other active compounds from decomposition.

A series of cresol-based benzoxazines were synthesized for potential application as a polymer matrix in abrasive composites. The chemical structures of the obtained benzoxazine resins were investigated in detail using Fourier transform infrared spectroscopy (FTIR) and hydrogen-1 as well as carbon-13 nuclear magnetic resonance spectroscopy ( 1 H NMR, 13 C NMR) with an additional analysis using two-dimensional NMR techniques (2D NMR 1 H- 1 H COSY, 1 H- 13 C gHSQC and gHMBC). Structural analysis confirmed the presence of vibrations of -O-C-N- at ~950 cm -1 wavenumber, characteristic for an oxazine ring. The thermal properties of benzoxazine monomers were examined using differential scanning calorimetry (DSC) analysis. The polymerization enthalpy varied from 143.2 J/g to 287.8 J/g. Thermal stability of cresol-based benzoxazines was determined using thermogravimetry (TGA) analysis with additional analysis of the amount of volatile organic compounds (VOC) emitted from the synthesized benzoxazines during their crosslinking by static headspace coupled with gas chromatography technique (HS-GC). The amount of residual mass significantly differed between all synthesized polybenzoxazines in the range from 8.4% to 21.2%. The total VOC emission for benzoxazines decreased by 46-77% in reference to a conventional phenolic binder. The efficiency of abrasive composites with the benzoxazine matrix was evaluated based on abrasion tests. Performed analyses confirmed successful synthesis and proper chemical structure of cresol-based benzoxazines. All the experiments indicated that benzoxazines based on different cresol isomers significantly differ from each other. Good thermal performance and stability of the abrasive composites with the polybenzoxazine matrix and significantly lower VOC emission allow us to state that benzoxazines can be a promising and valuable alternative to the phenolics and a new path for the development of modern, eco-friendly abrasives., Competing Interests: The authors declare no conflict of interest.

In the framework of this publication, silica-lignin hybrid materials were designed, obtained, characterized and then used as admixtures for cement composites. High-energy mechanical grinding of individual components was used to produce the systems that allowed ensuring adequate homogeneity of the final products. As a result of the analysis of Fourier transform infrared spectroscopy, it has been confirmed that weak physical interactions occur between the components. This allowed classifying the resulting systems as I class hybrid materials. In addition, the efficiency of obtaining final products was also inferred on the basis of obtained porous structure parameters and colorimetric data. The achieved bio-admixture with different weight ratios of silica and lignin was added to cement pastes in the amount ranging from 0.5 to 1 wt.%. The study showed that increasing the ratio of lignin in the admixture from 0.15 to 1 wt.% had a positive effect on the rheological properties of the pastes, while the mechanical properties of the composite were deteriorated. In turn, a higher amount of silica in the admixture acted in reverse. The most favorable results were obtained for a silica-lignin bio-admixture with a weight ratio of components equal to 5:1 wt./wt. A significant increase in compressive strength was gained at satisfactory plasticity of the paste., Competing Interests: The authors declare no conflict of interest.

The presented study describes the application of lignin-based dual component fillers into low-density polyethylene (LDPE) and an examination of their selected properties. The main experimental procedure was focused on the preparation of thin sheet films using polyethylene and its composites with 5% by wt. of fillers: MgO, MgO-lignin dual phase systems with varying amounts of lignin and pristine lignin. Analysis of morphology revealed that elongated voids appeared in the structure for hybrid filler with a higher content of lignin (min. 50% by wt. of lignin versus MgO) and also for pristine lignin. Moreover, the prepared sheets were subjected to the thermoforming process by using the positive forming method (male mold). The thermoforming ability of all composites was evaluated by means of a comparison of wall thickness distribution on thermoformed shapes. The most noticeable percentage of wall thinning occurred for films which consisted of LDPE/MgO-lignin (5:1 wt./wt.) composite. In contrast, the best material arrangement and the highest mean percentage wall thickness were observed in the case of the shape formed with LDPE/MgO-lignin (1:5 wt./wt.). In addition, as part of research studies, the measurements of the contact angle have been conducted. The analysed LDPE films, in particular LDPE/MgO-L, have been recognized as materials with high wettability.

Inorganic-organic hybrids are a group of materials that have recently become the subject of intense scientific research. They exhibit some of the specific properties of both highly durable inorganic materials (e.g., titanium dioxide, zinc) and organic products with divergent physicochemical traits (e.g., lignin, chitin). This combination results in improved physicochemical, thermal or mechanical properties. Hybrids with defined characteristics can be used as fillers for polymer composites. In this study, three types of filler with different MgO/lignin ratio were used as fillers for polypropylene (PP). The effectiveness of MgO-lignin binding was confirmed using Fourier transform infrared spectroscopy. The fillers were also tested in terms of thermal stability, dispersive-morphological properties as well as porous structure. Polymer composites containing 3 wt.% of each filler were subjected to wide angle X-ray diffraction tests, differential scanning calorimetry and microscopic studies to define their structure, morphology and thermal properties. Additionally, tensile tests of the composites were performed. It was established that the composition of the filler has a significant influence on the crystallization of polypropylene-either spherulites or transcrystalline layers were formed. The value of Young's modulus and tensile strength remained unaffected by filler type. However, composites with hybrid fillers exhibited lower elongation at break than unfilled polypropylene.

Functional magnesium oxide-lignin hybrid materials were obtained via mechanicalgrinding. Their particle shape and size as well as physicochemical properties were characterized.MgO-lignin materials with biocomponent content (between 20% and 80% amount of total weight offiller) were used as a partially bio-structured modifier of low density polyethylene. The compositeswith 5% by weight of dual fillers and polyethylene grafted with maleic anhydride werecompounded in a twin screw extruder working in co-rotating mode. The prepared blends were castextruded using a single screw extruder and laboratory cast line. The properties of the obtainedfilms were verified in case of their weldability. The seal strength as well as shear test and tearstrength of the welded sheets were examined. The results showed that the shortest equivalent timerequired to perform correct weld occurred in the system, where the highest amount of lignin wasused in hybrid filler MgO-L (1:5 w/w ). From mechanical tests of welds, a sharp increase in ultimateseal force was noticed for almost all compositions with lignin, especially where MgO was coupledwith a high lignin content. For those composition seal open force raised up to 37.0 N, from thevalue of 23.6 N, achieved for neat low density polyethylene (LDPE). Tear strength of weld sheetsconfirmed once more that LDPE composition with MgO-L (1:5 w/w ) achieved the highest ultimateforce with its value of 71.5 N, and it was ~20.0 N higher than in the case of neat LDPE., Competing Interests: The authors declare no conflict of interest.

Silica aerogel-based materials exhibit a great potential for application in many industrial applications due to their unique porous structure. In the framework of this study, carbon fiber and nickel coated carbon fiber-silica aerogel nanocomposites were proposed as effective electromagnetic shielding material. Herein, the initial oxidation of the surface of carbon fibers allowed the deposition of a durable Ni metallic nanolayer. The fibers prepared in this way were then introduced into a silica aerogel structure, which resulted in obtaining two nanocomposites that differed in terms of fiber volume content (10% and 15%). In addition, analogous systems containing fibers without a metallic nanolayer were studied. The conducted research indicated that carbon fibers with a Ni nanolayer present in the silica aerogel structure negatively affected the structural properties of the composite, but were characterized by two-times higher electrical conductivity of the composite. This was because the nickel nanolayer effectively blocked the binding of the fiber surface to the silica skeleton, which resulted in an increase of the density of the composite and a reduction in the specific surface area. The thermal stability of the material also deteriorated. Nevertheless, a very high electromagnetic radiation absorption capacity between 40 and 56 dB in the frequency range from 8 to 18 GHz was obtained., Competing Interests: The authors declare no conflict of interest.

In this study, a technology for obtaining functional inorganic-organic hybrid materials was designed using waste polymers of natural origin, i.e., kraft lignin and magnesium lignosulfonate, and alumina as an inorganic component. Al 2 O 3 -lignin and Al 2 O 3 -lignosulfonate systems were prepared by a mechanical method using a mortar grinder and a planetary ball mill, which made it possible to obtain products of adequate homogeneity in an efficient manner. This was confirmed by the use of Fourier transform infrared spectroscopy and thermogravimetric analysis. In the next step, the developed hybrid materials were used as functional admixtures in cement mixtures, thus contributing to the formation of a modern, sustainable building material. How the original components and hybrid materials affected the mechanical properties of the resulting mortars was investigated. The admixture of biopolymers, especially lignin, led to cement composites characterized by greater plasticity, while alumina improved their strength properties. It was confirmed that the system containing 0.5 wt.% of alumina-lignin material is the most suitable for application as a cement mortar admixture.

In this study, the kraft lignin/cubic boron nitride hybrid materials have been obtained and characterized for the first time. The effectiveness of the combination of lignin and boron nitride was evaluated on the basis of Fourier transform infrared spectroscopy. Furthermore, it was confirmed that the addition of cubic boron nitride (cBN) improved the thermal stability of the inorganic-organic material. Upswing in thermal properties allowed to apply the prepared materials in preparation of model abrasive composites. Beneficial influence of the lignin/cBN filler was also proven by a noticeable decrease in the amount of harmful phenol released from the compositions during headspace gas chromatography analysis. Mechanical properties of the lignin/boron nitride hybrids and resin systems were investigated by the three-point flexural test. The obtained results show that the used additives can be promising materials for abrasive tools combining the good properties of lignin as a plasticizer and of cubic boron nitride as a filler which improves the thermal and mechanical properties of finished products and, at the same time, limits the negative impact on human health and environment., (Copyright © 2018. Published by Elsevier B.V.)

In this paper, silica⁻lignin hybrid materials were used as fillers for a polylactide (PLA) matrix. In order to simulate biodegradation, PLA/hybrid filler composite films were kept in soil of neutral pH for six months. Differential scanning calorimetry (DSC) allowed analysis of nonisothermal crystallization behavior of composites, thermal analysis provided information about their thermal stability, and scanning electron microscopy (SEM) was applied to define morphology of films. The influence of biodegradation was also investigated in terms of changes in mechanical properties and color of samples. It was found that application of silica⁻lignin hybrids as fillers for PLA matrix may be interesting not only in terms of increasing thermal stability, but also controlled biodegradation. To the best knowledge of the authors, this is the first publication regarding biodegradation of PLA composites loaded with silica⁻lignin hybrid fillers.

In this research we use ionic liquids in combination with mild process conditions to provide a selective increase in the content of carbonyl groups in the kraft lignin structure. Such modification can improve the properties of the pristine biopolymer. In this study, aromatic substituted ionic liquids were synthesized using [C 4 C 1 Im][HSO 4 ] as a template structure. The substituents were intended to increase the affinity of the ionic liquid to the aromatic structure of kraft lignin, and to increase access to the oxidizing agent, which was atmospheric oxygen. [Benzyl(C 2 OC 1 )Im][HSO 4 ] and [benzylC 4 Im][HSO 4 ] activate the surface of the biopolymer more effectively than [C 4 C 1 Im][HSO 4 ]. This was confirmed based on X-ray photoelectron spectroscopy, which showed the content of CO groups to be almost doubled compared with unmodified lignin. The analysis also revealed targeting of the hydroxyl groups of lignin to the carboxyl groups during activation in [C 4 C 1 Im][HSO 4 ]., (Copyright © 2018 Elsevier B.V. All rights reserved.)

A novel, eco-friendly method for the activation of lignin by controlled oxidation was studied. The results obtained for six acidic imidazolium ionic liquids containing the hydrogen sulfate anion were compared. The key goal of this research was to increase the content of carbonyl groups in the lignin structure because these may play the main role in the transport of protons and electrons in active materials for electrochemical applications. By means of a variety of analytical techniques (FTIR, 13 C CP/MAS NMR, and X-ray photoelectron spectroscopy; selected reactions to determine the presence of carbonyl groups; SEM; zeta-potential analysis; thermogravimetric analysis/differential thermogravimetric analysis; and porous structure analysis), it was determined that the product obtained after treatment with 3-cyclohexyloxymethy-1-methylimidazolium hydrogen sulfate had favorable properties, in terms of the target application. Electrochemical tests proved that the obtained materials could be used as anodes in lithium batteries. The results show that the activation of lignin with ionic liquids can increase its capacity and maintain stability., (© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)

α-Amylase from Aspergillus oryzae was immobilized via covalent bonds and by physical interactions on a synthesized titania/lignin novel hybrid support. A temperature of 5°C, a pH of 7.0, an initial enzyme solution concentration of 3.0mg/mL and a 3h process duration were found to be optimal for the highest activity of the immobilized enzyme. Moreover, the effect of temperature, pH, storage time and repeated catalytic cycles on the activity of free and immobilized enzyme was examined. Bound α-amylase showed enhanced thermal and chemical stability, and its reusability was also improved. Immobilized α-amylase retained over 80% of its initial activity when stored for 30days at 4°C. Kinetic parameters of the free and immobilized biocatalyst were calculated and compared. The maximum reaction rate (V max ) and turnover number (k cat ) were slightly lower for the immobilized enzyme than for the free enzyme. It should be clearly stated that this work presents a useful protocol to produce stable and active immobilized α-amylase onto titania/lignin hybrid which may also be applied to immobilization of other enzymes., (Copyright © 2017 Elsevier B.V. All rights reserved.)

A chitin/lignin material with defined physicochemical and morphological properties was used as an effective adsorbent of environmentally toxic metals from model systems. Particularly significant is its use in the neutralization of real industrial wastes. The ions Ni 2+ , Cu 2+ , Zn 2+ and Pb 2+ were adsorbed on the functional sorbent, confirming the high sorption capacity of the newly obtained product, primarily due to the presence on its surface of numerous active functional groups from the component biopolymers. The kinetics of the process of ion adsorption from model solution were investigated, and the experimental data were found to fit significantly better to a type 1 pseudo-second-order kinetic model, as confirmed by the high correlation coefficient of 0.999 for adsorption of both nickel(II) copper(II) zinc(II) and lead(II) ions. The experimental data obtained on the basis of adsorption isotherms corresponded to the Langmuir model. The sorption capacity of the chitin/lignin material was measured at 70.41 mg(Ni 2+ )/g, 75.70 mg(Cu 2+ )/g, 82.41 mg(Zn 2+ )/g and 91.74 mg(Pb 2+ )/g. Analysis of thermodynamic parameters confirmed the endothermic nature of the process. It was also shown that nitric acid is a very effective desorbing (regenerating) agent, enabling the chitin/lignin material to be reused as an effective sorbent of metal ions. The sorption abilities of the chitin/lignin system with respect to particular metal ions can be ordered in the sequence Ni 2+ 2+ 2+ 2+ . Tests were also performed with the adsorption of ions of nickel(II), copper(II), zinc(II) and lead(II) from wastewater obtained from galvanization and battery production plants, confirming the ability of the chitin/lignin sorbent to adsorb harmful ions from real industrial wastes., (Copyright © 2017 Elsevier Ltd. All rights reserved.)