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This paper focuses on analysis of charging of polymeric surfaces by means of impulse corona discharges in air. Internal (space charge densities and electric fields) as well as external (circuit current) characteristics of corona in a point-plane electrode configuration are investigated by means of computer simulations. Two types of onset positive corona modes, namely positive glow corona and burst pulse corona are identified. The developed and verified computer model is further used to study corona charging of a 2 mm thick polymeric material sample. Both the mechanism of charge deposition and distribution of deposited charges on the surface are dependent on the mode of the corona discharge used. In the case of glow corona, charge generation is limited to the anode region and the generated charges move towards the sample surface under applied electric field. Thereafter the deposited charge cloud expands radially along a portion of the surface with fairly constant concentration. In the case of burst pulse corona, series of positive charge clouds start from the anode and move towards the sample surface in a wave-like manner. Each burst contributes to the deposited charge, which spreads over the surface less extensively than that observed during glow corona charging. Index Terms--Impulse corona, glow, burst pulse, conduction current, surface charging, positive ions.

High‐voltage direct‐current power cables are vital for the efficient transport of electricity derived from renewable sources of energy. The most widely used material for high‐voltage power cable insulation – low‐density polyethylene (LDPE) – is usually crosslinked with peroxides, a process that releases unwanted by‐products. Hence, by‐product‐free crosslinking concepts that mitigate the associated increase in electrical conductivity are in high demand. Click chemistry‐type crosslinking of polyethylene copolymer mixtures that contain glycidyl methacrylate and acrylic acid co‐monomers is a promising alternative, provided that the curing reaction can be controlled. Here, we demonstrate that the rate of the curing reaction can be adjusted by tuning the number of epoxy and carboxyl groups. Both dilution of copolymer mixtures with neat LDPE and the selection of copolymers with a lower co‐monomer content have an equivalent effect on the curing speed. Ternary blends that contain 50 wt% of neat LDPE feature an extended extrusion window of up to 170 °C. Instead, at 200 °C rapid curing is possible, leading to thermosets with a low direct‐current electrical conductivity of about 10−16 S cm−1 at an electric field of 20 kV mm−1 and 70 °C. The conductivity of the blends explored here is comparable to or even lower than values measured for both ultraclean LDPE and a peroxide‐cured commercial crosslinked polyethylene grade. Hence, click chemistry curing represents a promising alternative to radical crosslinking with peroxides. © 2019 Society of Chemical Industry [ABSTRACT FROM AUTHOR]

It seems generally accepted that HVDC technology is to become increasingly relevant in power systems. With this expected future advance of HVDC, the use of gas insulated switchgear or lines for dc application are getting increasingly interesting. As in the case of dc the electric fields are determined resistively in contrast to the capacitive fields in the case of ac, gas insulated technology has to be revisited. In many previous works surface charging of model spacers was investigated. However, the ion flow problem to properly account for the electric conduction in the gas has not yet been solved. Further, no combination with inhomogeneous electric conductivity determined for example by temperature profiles from ohmic heating in nominal condition has been performed so far. In this paper, the gas conductivity arising from ions produced by natural radiation is computed by solving the ion flow field problem, and its role is compared to spacer bulk conductivities. Further, the impact of temperature profiles on spacer charging is investigated. The results indicate that for actual disc spacers, the spacer bulk conductivity is more important than that from the gas ionized by natural radiation. Especially in the case of polarity reversal, thermally enhanced spacer charging can result in considerable increase of tangential field strengths. [ABSTRACT FROM PUBLISHER]

Effect of surface charges on dc flashover characteristics of a composite polymeric insulator is studied by means of experiments and theoretical calculations. The considered insulator consisted of a glass fiber reinforced epoxy core covered with a layer of silicone rubber and terminated by metallic electrodes with rounded smooth edges. In the experiments, the insulator surface was charged by external corona while keeping the electrodes grounded and different charging levels were realized by varying its intensity. A series of disruptive discharge tests were carried out on the charged insulator under negative dc voltages. It was revealed that negative deposited surface charges led to an enhancement of the flashover performance whereas positive ones reduced the flashover voltage level. A theoretical model has been developed and utilized for analyzing the experimental results. In the model, surface charge density profiles deduced from measured surface potential distributions were used as boundary conditions for calculations of electric fields. The measured and calculated flashover voltages were found to be in agreement indicating that the observed variations in the flashover characteristics could be attributed to the modifications of the electric field produced by the surface charges. [ABSTRACT FROM PUBLISHER]

Distributions of charges are investigated on surfaces of polymeric cylindrical insulators that emerge due to dc corona discharges in surrounding air and by stressing with dc voltage. The studied model insulator consisted of a glass fiber reinforced epoxy core covered with a sheath of silicone rubber, terminated by metallic electrodes with rounded smooth edges. Surface potential distributions were measured 1 min after completing the charging process by means of a Kelvin electrostatic probe connected to an electrostatic voltmeter. The measured surface potential profiles were utilized to calculate corresponding charge density distributions. The obtained results demonstrated significant differences in the surface charge patterns for different charging conditions, which in turn may affect flashover withstand of the insulator. [ABSTRACT FROM PUBLISHER]