122 results on '"Kunal Mondal"'
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2. Carbon nanomaterials‐based electrically conductive scaffolds for tissue engineering applications
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Genevieve Abd, Raquel S. Díaz, Anju Gupta, Tagbo H. R. Niepa, Kunal Mondal, Seeram Ramakrishna, Ashutosh Sharma, Andrés D. Lantada, and Monsur Islam
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carbon nanomaterials ,carbon nanotubes ,conductive scaffolds ,graphene ,tissue engineering ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Medical technology ,R855-855.5 - Abstract
Abstract In tissue engineering, the pivotal role of scaffolds is underscored, serving as key elements to emulate the native extracellular matrix. These scaffolds must provide structural integrity and support and supply electrical, mechanical, and chemical cues for cell and tissue growth. Notably, electrical conductivity plays a crucial role when dealing with tissues like bone, spinal, neural, and cardiac tissues. However, the typical materials used as tissue engineering scaffolds are predominantly polymers, which generally characteristically feature poor electrical conductivity. Therefore, it is often necessary to incorporate conductive materials into the polymeric matrix to yield electrically conductive scaffolds and further enable electrical stimulation. Among different conductive materials, carbon nanomaterials have attracted significant attention in developing conductive tissue engineering scaffolds, demonstrating excellent biocompatibility and bioactivity in both in vitro and in vivo settings. This article aims to comprehensively review the current landscape of carbon‐based conductive scaffolds, with a specific focus on their role in advancing tissue engineering for the regeneration and maturation of functional tissues, emphasizing the application of electrical stimulation. This review highlights the versatility of carbon‐based conductive scaffolds and addresses existing challenges and prospects, shedding light on the trajectory of innovative conductive scaffold development in tissue engineering.
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- 2024
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3. Advanced manufacturing technologies for enhancing security in nuclear and radiological materials transport
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Kunal Mondal, Ryan Karkkainen, Oscar Martinez, Isaac Sikkema, Mahim Mathur, Sam Hollifield, and Mingyan Li
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Advanced manufacturing ,Nuclear security ,Nuclear transport ,Radiological transport ,Additive manufacturing ,Advanced materials ,Nuclear engineering. Atomic power ,TK9001-9401 - Abstract
Advanced manufacturing technologies have transformed various industries, including nuclear security areas such as nuclear and radiological transport. This review manuscript describes the intersection of advanced manufacturing technologies and their applications to enhance the safety, efficiency, and reliability of nuclear and radiological transport. The manuscript discusses key technologies such as additive manufacturing, advanced materials, robotics, and data analytics, highlighting their aids to consolidate nuclear security in the background of nuclear and radiological transport. By providing a comprehensive perspective overview of these advancements, this review provides a deeper understanding of the potential benefits and challenges related to the integration of advanced manufacturing into this critical sector.
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- 2023
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4. Enhancing the Faradaic efficiency of solid oxide electrolysis cells: progress and perspective
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Prashik S. Gaikwad, Kunal Mondal, Yun Kyung Shin, Adri C. T. van Duin, and Gorakh Pawar
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Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Computer software ,QA76.75-76.765 - Abstract
Abstract To reduce global warming, many countries are shifting to sustainable energy production systems. Solid oxide electrolysis cells (SOECs) are being considered due to their high hydrogen generation efficiency. However, low faradaic efficiency in scaling SOEC technology affects costs and limits large-scale adoption of hydrogen as fuel. This review covers SOECs’ critical aspects: current state-of-the-art anode, cathode, and electrolyte materials, operational and materials parameters affecting faradaic efficiency, and computational modeling techniques to resolve bottlenecks affecting SOEC faradaic efficiency.
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- 2023
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5. Advanced manufacturing and digital twin technology for nuclear energy
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Kunal Mondal, Oscar Martinez, and Prashant Jain
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advanced manufacturing ,additive manufacturing ,automation ,robotics ,digital twin technology ,cost-effectiveness ,General Works - Abstract
Advanced manufacturing techniques and digital twin technology are rapidly transforming the nuclear industry, offering the potential to enhance productivity, safety, and cost-effectiveness. Customized parts are being produced using additive manufacturing, automation, and robotics, while digital twin technology enables the virtual modeling and optimization of complex systems. These advanced technologies can significantly improve operational efficiency, predict system behavior, and optimize maintenance schedules in the nuclear energy sector, leading to heightened safety and reduced downtime. However, the nuclear industry demands the highest levels of safety and security, as well as intricate manufacturing processes and operations. Thus, challenges such as data management and cybersecurity must be addressed to fully realize the potential of advanced manufacturing techniques and digital twin technology in the nuclear industry. This comprehensive review highlights the critical role of digital twin technology with advanced manufacturing toward nuclear energy to improve performance, minimize downtime, and heighten safety, ultimately contributing to the global energy mix by providing dependable and low-carbon electricity.
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- 2024
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6. Synthesis of high-surface-area mesoporous SnO2 nanomaterials using carbon template
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Monsur Islam, Kunal Mondal, Vinay Kishnani, Ankur Gupta, and Ashutosh Sharma
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Carbon ,SnO2 nanomaterials ,Resorcinol formaldehyde ,Mesoporous ,Template synthesis ,Technology - Abstract
Metal oxide porous nanomaterials are of great interest across scientific fields due to their intriguing properties, allowing their usage from lab-scale research to industrial applications. However, the production of high surface area metal oxide nanomaterials still poses significant challenges. This study introduces a novel method for synthesizing highly porous tin oxide (SnO2) nanostructures using carbon as the template material. The synthesis process includes the formation of a precursor composite containing resorcinol-formaldehyde gel and a tin oxide precursor, which is first carbonized to convert the resorcinol-formaldehyde into a porous three-dimensional carbon framework. This framework acts as a scaffold for the nucleation of SnO2 nanoparticles. Subsequent oxidation selectively removes the carbon template, yielding highly porous SnO2 nanomaterials. Electron microscopy analysis shows that the nanomaterials feature a particle size with average diameter of ∼30 nm, whereas Gas adsorption-desorption characterization indicates pronounced mesoporosity, with a pore size of 3 nm and a specific surface area of 476 m2/g. The enhanced surface area surpasses the previously reported studies on porous SnO2. This is significant considering the easy production process of the nanomaterials, which signifies its potential for large-scale production. Furthermore, this approach offers versatility, as different materials can replace the carbon component, allowing for tailored nanostructure design and enhanced properties. The resulting materials can offer exciting possibilities in the field of materials science and nanotechnology.
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- 2024
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7. Fundamentals of bio-electrochemical sensing
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Mahesh M. Shanbhag, G. Manasa, Ronald J. Mascarenhas, Kunal Mondal, and Nagaraj P. Shetti
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Electrochemistry ,Electrochemical transducer ,Biosensors ,Voltammetry ,Bio-receptors ,Chemical engineering ,TP155-156 - Abstract
The utilization of bio-functionalities such as biorecognition or catalysis derived them their name biosensors. Bio-electrochemical sensing is a new discipline that combines the advantages of biological detection and electrochemical transduction. Bio-electrochemical sensors are devices that use biological materials such as enzymes, antibodies, DNA, or cells as receptors to detect target analytes in a variety of samples. Electrodes convert biological interactions into electrical impulses, which can be studied using various electrochemical techniques. Bio-electrochemical sensors have demonstrated significant promise for use in clinical diagnostics, environmental monitoring, food safety, and biotechnology. Biosensors have received numerous applications in recent years because they are fast, simple, and inexpensive for practical applications. In this article, we cover the basic principles, design strategies, immobilization and regeneration techniques, along with the advantages and applications of bio-electrochemical sensors. Finally, this article discusses the rationale for developing electrochemical biosensors in the context of the various bio-receptors that can be applied.
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- 2023
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8. A prospective and retrospective study of the outcome of high tibial osteotomy in osteoarthritis of the knee with varus deformity
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Prashant Kumar, Swarnava Dattagupta, Kunal Mondal, Dipak Kumar Jha, and Prasanta Kumar Pujari
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high tibial osteotomy ,kss ,lysholm ,tomofix ,Orthopedic surgery ,RD701-811 - Abstract
Introduction: Knee osteoarthritis (OA) degenerative condition causes progressive wear in the articular cartilage and rises pressure over the medial compartment of the knee joint which will end up as a varus deformity. High tibial osteotomy (HOT) is one of the surgical managements in treatment of OA. The goal of the treatment is to relieve medial compartment knee pain and slowdown the arthritic progression. Materials and Methods: This prospective observational study was done on 20 patients of all ages and both genders having medial compartment OA with varus deformity of all grades over 24-month duration. Functional evaluation was done by the Knee Society Score, functional score, and the Lysholm score, whereas radiological evaluation was done by calculating various angles in orthoroentgenogram. Results: All the function scores hold high statistical significance. Changes in hip knee axis (HKA), medial proximal tibial angle, and tibial joint angle were statistically significant. All osteotomy sites consolidated in 6 months with not a single case of nonunion. Conclusion: HOT is an effective technique and has excellent functional and radiological outcomes with minimal complications in the management of OA. Appropriate patient selection, proper osteotomy type, and precise surgical techniques are essential for the success of HOT.
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- 2023
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9. ZnO/CuO nanostructures anchored over Ni/Cu tubular films via pulse electrodeposition for photocatalytic and antibacterial applications
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Hrudaya Jyoti Biswal, Pandu R. Vundavilli, Kunal Mondal, Nagaraj P. Shetti, and Ankur Gupta
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CuO/ZnO nanocomposite ,Pulse electrodeposition ,Photocatalytic degradation ,MB dye ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Energy conservation ,TJ163.26-163.5 - Abstract
In this work, we report the fabrication of Ni and Cu tubular substrates and the synthesis of ZnO/CuO nanocomposite on them through the process of pulse electrodeposition. The systematic variation in CuO incorporation in the ZnO matrix and the processing technique were noticed to affect the structural, optical, photocatalytic, and anti-bacterial properties, which are well in accordance with the Field Emission-Scanning Electron Microscope, X-ray Diffraction, Fourier transform Infrared Spectroscopy and UV-Differential reflectance spectroscopy results. The remediation capabilities of the photocatalytic substrates were assessed through the degradation of methylene blue (MB) dye under solar irradiation. Optimized CuO incorporation within the ZnO nanorods resulted in the degradation of a 20 ppm of MB dye solution within 40 min and a higher concentration of 50 ppm within 95 min. The Ni and Cu electroformed tubes as substrates provided not only a reusable supporting frame but also a large surface-area for the growth of ZnO/CuO nanocomposite. The current study also dealt with the anti-bacterial efficacy of the above-mentioned substrates against E.coli. Hence, the Ni and Cu tubular thin film substrates with nanorods of ZnO/CuO composite were explored for the removal of organic as well as biological contaminants from waste water.
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- 2023
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10. An evaluative study to find the correlation between semitendinosus graft dimension with respect to patient’s anthropometry
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Tanmay Datta, Dibyendu Biswas, Kunal Mondal, and Santu Sarkar
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anterior cruciate ligament ,anthropometry ,graft and semitendinosus ,Medicine - Abstract
Background: A prospective study of a cohort of anterior cruciate ligament (ACL) reconstructed patients 7 years after surgery revealed degenerative radiographic changes in 95% of patients, and only 47% were able to return to their previous activity level following ACL reconstruction. Aims and Objectives: The aims of this study were to find the correlation between Semitendinosus graft dimension with respect to patients anthropometry such as age, height, weight, body mass index (BMI), and true leg length (TLL). Materials and Methods: The proposed study was the patients coming to orthopedics-outpatient department and emergency with 30 complete thickness ACL tears which were screened and recruited based on fulfillment of inclusion and exclusion criteria from January 2020 to August 2021 (20 months duration). The sample size was sufficient to draw conclusive findings. Correlation was calculated by Pearson correlation analysis. The Pearson product-moment correlation coefficient was a measure of the linear dependence between two variables X and Y. P≤0.05 was considered for statistically significant. Results: The age has positive correlation with graft length (r=0.11) and relatively strong positive correlation with graft diameter (r=0.437). Height has relatively strong positive correlation with graft length (r=0.4258) and graft diameter (r=0.1375). Weights have strong positive correlation with graft length (r=0.604). TLL also had positive correlation with graft length (0.23) and graft diameter (r=0.1). Conclusion: In selective cases, graft may be reinforced with additional Hamstring tendon harvest like gracilis or any alternative graft such as Bone–patellar tendon–bone (BPB) and Peroneus longus tendon autograft that may be taken to prevent graft failure and future complications. This current data can be a reference for surgeons in preoperative planning and counseling to patients about alternative autograft selection.
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- 2022
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11. Porous potassium tantalate-reduced graphene oxide nano cube architecture for high performance hybrid supercapacitors
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Apurva Nandagudi, Sumedha H. Nagarajarao, Shivaraj B. Patil, V.G. Dileep Kumar, M.S. Santosh, Ankur Gupta, Kunal Mondal, and Basavanakote M. Basavaraja
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KTaO3 ,rGO ,Nano cubes ,Chronopotentiometry ,Hybrid supercapacitor ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 - Abstract
Energy storage has always been a major concern in the present-day situation. Advanced energy storage devices are batteries, supercapacitor and solar cells. However, advancements have been noteworthy in the field of high-performance hybrid supercapacitors. On this note, we have fabricated a hybrid supercapacitor electrode material Potassium tantalate nano cube (KT NCs) and its reduced graphene oxide composite (KT-rGO NCs) and tested its electrochemical performance. The materials showed high performances with specific capacitance of 565 F/g for KT NCs and 850 F/g for KT-rGO NCs respectively. Energy densities of both KT NCs & KT-rGO NCs are 28.24 Wh/Kg and 29.50 Wh/kg with good retention capacities. Further detailed study of both KT NCs and KT-rGO NCs are carried out with characterization techniques like XRD, FTIR, BET, Raman and HRTEM for structural analysis and electrochemical measurements to analyse various parameters pertaining to its charge storage capacity.
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- 2023
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12. Transformation of a ceramic precursor to a biomedical (metallic) alloy: Part I – sinterability of Ta2O5 and TiO2 mixed oxides
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Maureen P. Chorney, Bridger P. Hurley, Kunal Mondal, Amey R. Khanolkar, Jerome P. Downey, and Prabhat K. Tripathy
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Tantalum pentoxide ,Titanium dioxide ,Sintering ,Phase evolution ,Mixed oxides ,Oxide morphology ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Energy conservation ,TJ163.26-163.5 - Abstract
Mixed Ta2O5 – TiO2 binary system was studied by a combination of differential thermal analysis (DTA), scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), X-ray diffraction (XRD) and in situ high temperature X-ray diffraction (HT-XRD) techniques. Different compositions of the mixed oxide powders were fabricated by ball–milling the powdered compositions, pelletizing the homogenized composite powders, and heating the green pellets in air at different temperatures for fixed time intervals. The sintered pellets were evaluated and characterized with respect to porosity, morphology, and phase distribution. DTA runs of the un-sintered powders indicated the onset temperatures for both exothermic and endothermic changes in the binary system. Significant amount of sintering was observed to take place at temperatures higher than 900 °C. Both room and high temperature X-ray diffraction patterns exhibited consistency in phase formation. A ternary compound (TaTiO4) and a ternary solid solution (Ti0.33Ta0.67O2) were observed to form in both room and high temperatures in addition to the respective binary phases (Ta2O5 and TiO2). A sintering temperature in the range 900–1000 °C was observed to be adequate to achieve the requisite mechanical strength and optimum internal porosity (40–48%) for subsequent electrochemical polarization experiments.
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- 2022
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13. High Tibial Osteotomy versus Proximal Fibular Osteotomy in Medial Compartmental Osteoarthritis of Knee: A Longitudinal Study
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Tanmay Datta, Kunal Mondal, Avijit Basak, and Pinaki Das
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knee osteoarthritis ,kellgren lawrence score ,oxford knee score ,visual analouge scale score ,Medicine - Abstract
Introduction: Osteoarthritis (OA) is a chronic degenerative intra-articular disorder of cartilage and bone. Knee joint is most commonly involved due to its pivotal role in weight bearing as it is constantly exposed to wear and tear. Osteotomy procedures can achieve normal alignment of the weight bearing axis of the lower limbs. Aim: To evaluate and compare the functional outcome of High Tibial Osteotomy (HTO) and Proximal Fibular Osteotomy (PFO) in medial compartmental osteoarthritis of knee joint. Materials and Methods: This prospective longitudinal study was conducted in a tertiary healthcare centre, IPGMER and SSKMH, Kolkata, West Bengal, India from October 2019 to November 2021 for a duration of 26 months, in which 40 osteotomies were performed around the knee. Considering the inclusion and exclusion criteria 20 proximal fibular osteotomies and 20 high tibial osteotomies were operated avoiding the patients with advanced stage or tricompartmental OA. The scoring system considered for evaluation of the functional outcome was Oxford Knee Score (OKS) and Visual Analouge Scale (VAS) Score. The analysis was done through paired t-test with determining of p-value where value ≤0.05 was considered as statistically significant. Results: Majority of the patients in the present study were more than 45 years of age. The most frequent age group was 46-50 years followed by 51-55 years. The follow-up period was atleast 15 months where the OKS score was 39.35±3.51 and 41.20±4.50 with p-value of 0.1556 and VAS score was 5.50±1.10 and 3.80±1.10 with p-value of
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- 2022
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14. One-step manufacturing process for neodymium-iron (magnet-grade) master alloy
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Prabhat K. Tripathy, Kunal Mondal, and Amey R. Khanolkar
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Energy material ,Oxide precursor ,Sintering ,Polarization ,Magnet-grade master alloy ,One-step fabrication ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Energy conservation ,TJ163.26-163.5 - Abstract
Neodymium iron boron magnet has registered heightened demand due to its rapidly increasingly application in the clean energy sector. These magnets are manufactured by melting the mixture, consisting of neodymium, iron and boron followed by casting into ingots. The ingots are subsequently pulverized to powder, which, in turn, is sintered and magnetized to form the permanent magnet. An alternative approach is the controlled addition of boron to the neodymium iron master alloy to fabricate the magnet. The present process discusses an alternative and novel electrochemical approach to prepare the neodymium-iron master alloy, directly from the mixed oxides of neodymium and iron, in just one step. The mixed oxide pellet was cathodically polarized in a pool of molten calcium chloride in the temperature range 800–950°C, against an oxygen-evolving anode. The reduced alloy could not only retain its original structure but also exhibited magnetic behavior.
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- 2021
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15. Recent advances in the thermal barrier coatings for extreme environments
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Kunal Mondal, Luis Nuñez, III, Calvin M. Downey, and Isabella J. van Rooyen
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Thermal barrier coating ,Gradient coating ,High temperature application ,Harsh environments ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Energy conservation ,TJ163.26-163.5 - Abstract
Thermal barrier coatings (TBCs) are gaining tremendous research interest for protecting aircraft turbine blades, power plants, and other applications from high-temperature exposure. This opinion spotlights on those recent progresses that have directed to the use of TBCs for component life addition and, lately, as an essential part of advanced components design for high temperatures and related harsh environments, such as applications in the nuclear industries. Development of this coatings has been driven by results obtained from laboratory and industrial testing, corroborated by engine and gas-turbine testing and related high-temperature application experience. Factors that have led to the choice of current high-tech advanced coating fabrication methods–such as plasma spray deposition (PSP), electron-beam physical vapor deposition (EB-PVD), and electrophoretically fabricated thermal barrier coatings, have also been highlighted in current coating research and development. Here, we provide a short review on the present status of TBCs, their latest advances in fabrication and performance, drawbacks associated with them, as well as recommendations for their futuristic use in harsh high-temperature environments.
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- 2021
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16. Nanostructured ZnO-Based Electrochemical Sensor with Anionic Surfactant for the Electroanalysis of Trimethoprim
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Vinoda B. Patil, Davalasab Ilager, Suresh M. Tuwar, Kunal Mondal, and Nagaraj P. Shetti
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trimethoprim ,electrochemical sensor ,zinc oxide nanoparticles ,anionic surfactant ,biomedical applications ,Technology ,Biology (General) ,QH301-705.5 - Abstract
In this research, detection of trimethoprim (TMP) was carried out using a nanostructured zinc oxide nanoparticle-modified carbon paste electrode (ZnO/CPE) with an anionic surfactant and sodium dodecyl sulphate (SDS) with the help of voltametric techniques. The electrochemical nature of TMP was studied in 0.2 M pH 3.0 phosphate-buffer solution (PBS). The developed electrode displayed the highest peak current compared to nascent CPE. Effects of variation in different parameters, such as pH, immersion time, scan rate, and concentration, were investigated. The electrode process of TMP was irreversible and diffusion controlled with two electrons transferred. The effective concentration range (8.0 × 10−7 M–1.0 × 10−5 M) of TMP was obtained by varying the concentration with a lower limit of detection obtained to be 2.58 × 10−8 M. In addition, this approach was effectively employed in the detection of TMP in pharmaceutical dosages and samples of urine with the excellent recovery data, suggesting the potency of the developed electrode in clinical and pharmaceutical sample analysis.
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- 2022
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17. Direct and Sensitive Electrochemical Evaluation of Pramipexole Using Graphitic Carbon Nitride (gCN) Sensor
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Yogesh M. Shanbhag, Mahesh M. Shanbhag, Shweta J. Malode, S. Dhanalakshmi, Kunal Mondal, and Nagaraj P. Shetti
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graphitic carbon nitride ,Pramipexole ,voltammetric approach ,heterogenous rate constant ,diffusion coefficient ,Biotechnology ,TP248.13-248.65 - Abstract
Pramipexole (PMXL) belongs to the benzothiazole class of aromatic compounds and is used in treating Parkinson’s disease; however, overdosage leads to some abnormal effects that could trigger severe side effects. Therefore, it demands a sensitive analytical tool for trace level detection. In this work, we successfully developed an electrochemical sensor for the trace level detection of PMXL, using the voltammetric method. For the analysis, graphitic carbon nitride (gCN) was opted and synthesized by using a high-temperature thermal condensation method. The synthesized nanoparticles were employed for surface characterization, using transmission electron microscopy (TEM), X-ray diffraction (XRD), and atomic force microscopy (AFM) techniques. The electrochemical characterization of the material was evaluated by using the electrochemical impedance spectroscopy (EIS) technique to evaluate the solution–electrode interface property. The cyclic voltammetry (CV) behavior of PMXL displayed an anodic peak in the forward scan, indicating that PMXL underwent electrooxidation, and an enhanced detection peak with lower detection potential was achieved for gCN-modified carbon paste electrode (gCN·CPE). The influence of different parameters on the electrochemical behavior was analyzed, revealing the diffusion governing the electrode process with an equal number of hydronium ions and electron involvement. For the fabricated gCN·CPE, good linearity range was noticed from 0.05 to 500 µM, and a lower detection limit (LD) of 0.012 µM was achieved for the selected concentration range (0.5 to 30 µM). Selectivity of the electrode in PMXL detection was investigated by conducting an interference study, while the tablet sample analysis demonstrates the sensitive and real-time application of the electrode. The good recovery values for the analysis illustrate the efficiency of the electrode for PMXL analysis.
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- 2022
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18. An Electrochemical Electrode to Detect Theophylline Based on Copper Oxide Nanoparticles Composited with Graphene Oxide
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Vinoda B. Patil, Shweta J. Malode, Sumitra N. Mangasuli, Suresh M. Tuwar, Kunal Mondal, and Nagaraj P. Shetti
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theophylline ,graphene oxide ,CuO nanoparticles ,voltammetry techniques ,limit of detection ,Mechanical engineering and machinery ,TJ1-1570 - Abstract
The electrochemical analysis of theophylline (THP) was investigated by fabricating a carbon paste electrode (CPE) modified with graphene oxide (GO) along with copper oxide (CuO) nanoparticles (CuO-GO/CPE). The impact of electro-kinetic parameters such as the heterogeneous rate constant, the scan rate, the accumulation time, the pH, the transfer coefficient, and the number of electrons and protons transferred into the electro-oxidation mechanism of THP has been studied utilizing electrochemical methods such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The differential pulse voltammetry technique was employed to investigate THP in pharmaceutical and biological samples, confirming the limit of detection (LOD) and quantification (LOQ) of the THP. X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis were performed to characterize the CuO nanoparticles. The CuO-GO/CPE was more sensitive in THP detection because its electrocatalytic characteristics displayed an enhanced peak current in the 0.2 M supporting electrolyte of pH 6.0, proving the excellent sensing functioning of the modified electrode.
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- 2022
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19. A Review on Gel Polymer Electrolytes for Dye-Sensitized Solar Cells
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Prasad Raut, Vinay Kishnani, Kunal Mondal, Ankur Gupta, and Sadhan C. Jana
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DSSC ,liquid electrolytes ,solar cells ,Mechanical engineering and machinery ,TJ1-1570 - Abstract
Significant growth has been observed in the research domain of dye-sensitized solar cells (DSSCs) due to the simplicity in its manufacturing, low cost, and high-energy conversion efficiency. The electrolytes in DSSCs play an important role in determining the photovoltaic performance of the DSSCs, e.g., volatile liquid electrolytes suffer from poor thermal stability. Although low volatility liquid electrolytes and solid polymer electrolytes circumvent the stability issues, gel polymer electrolytes with high ionic conductivity and enduring stability are stimulating substitutes for liquid electrolytes in DSSC. In this review paper, the advantages of gel polymer electrolytes (GPEs) are discussed along with other types of electrolytes, e.g., solid polymer electrolytes and p-type semiconductor-based electrolytes. The benefits of incorporating ionic liquids into GPEs are highlighted in conjunction with the factors that affect the ionic conductivity of GPEs. The strategies on the improvement of the properties of DSSCs based on GPE are also presented.
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- 2022
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20. A Molten Salt Electrochemical Process for the Preparation of Cost-Effective p-Block (Coating) Materials
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Prabhat Kumar Tripathy and Kunal Mondal
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molten salt ,three-electrode set up ,galvanostatic deposition ,p-block elements ,coated component ,Crystallography ,QD901-999 - Abstract
Solar energy applications rely heavily on p-block elements and transition metals. Silicon is, by far, the most commonly used material in photovoltaic cells and accounts for about 85% of modules sold presently. Of late, thin film photovoltaic cells have gained momentum because of their higher efficiencies. Most of these thin film devices are made out of just five elements, namely, cadmium, tellurium, selenium, indium, gallium and copper. The present manuscript describes an elegant and inexpensive molten salt-based electrolytic process for fabricating a tellurium-coated metallic substrate. A three-electrode set up was employed to coat iridium with tellurium from a molten bath containing lithium chloride, lithium oxide and tellurium tetrachloride (LiCl-Li2O-TeCl4) at 650 °C for a duration ranging from 30 to 120 min under a galvanostatic mode. The tellurium coating was observed to be thick, uniform, smooth and homogeneous. Additionally, the deposited tellurium did not chemically react with the iridium substrate to form intermetallic compounds, which is a good feature from the standpoint of the device’s performance characteristics. The present process, being generic in nature, shows the potential for the manufacture of both the coated substates and high-purity elements not just for tellurium but also for other p-block elements.
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- 2022
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21. Fabrication of High Surface Area Microporous ZnO from ZnO/Carbon Sacrificial Composite Monolith Template
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Kunal Mondal, Monsur Islam, Srujan Singh, and Ashutosh Sharma
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ZnO ,porous metal oxides ,bet surface area ,sacrificial template ,Mechanical engineering and machinery ,TJ1-1570 - Abstract
Fabrication of porous materials from the standard sacrificial template method allows metal oxide nanostructures to be produced and have several applications in energy, filtration and constructing sensing devices. However, the low surface area of these nanostructures is a significant drawback for most applications. Here, we report the synthesis of ZnO/carbon composite monoliths in which carbon is used as a sacrificial template to produce zinc oxide (ZnO) porous nanostructures with a high specific surface area. The synthesized porous oxides of ZnO with a specific surface area of 78 m2/g are at least one order of magnitude higher than that of the ZnO nanotubes reported in the literature. The crucial point to achieving this remarkable result was the usage of a novel ZnO/carbon template where the carbon template was removed by simple heating in the air. As a high surface area porous nanostructured ZnO, these synthesized materials can be useful in various applications including catalysis, photocatalysis, separation, sensing, solar energy harvest and Zn-ion battery and as supercapacitors for energy storage.
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- 2022
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22. A Review on Advanced Manufacturing for Hydrogen Storage Applications
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Zach Free, Maya Hernandez, Mustafa Mashal, and Kunal Mondal
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bulk hydrogen storage ,advanced manufacturing ,3D printing ,carbon ,metal hydrides ,Technology - Abstract
Hydrogen is a notoriously difficult substance to store yet has endless energy applications. Thus, the study of long-term hydrogen storage, and high-pressure bulk hydrogen storage have been the subject of much research in the last several years. To create a research path forward, it is important to know what research has already been done, and what is already known about hydrogen storage. In this review, several approaches to hydrogen storage are addressed, including high-pressure storage, cryogenic liquid hydrogen storage, and metal hydride absorption. Challenges and advantages are offered based on reported research findings. Since the project looks closely at advanced manufacturing, techniques for the same are outlined as well. There are seven main categories into which most rapid prototyping styles fall. Each is briefly explained and illustrated as well as some generally accepted advantages and drawbacks to each style. An overview of hydrogen adsorption on metal hydrides, carbon fibers, and carbon nanotubes are presented. The hydrogen storage capacities of these materials are discussed as well as the differing conditions in which the adsorption was performed under. Concepts regarding storage shape and materials accompanied by smaller-scale advanced manufacturing options for hydrogen storage are also presented.
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- 2021
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23. Palladium-Functionalized Graphene for Hydrogen Sensing Performance: Theoretical Studies
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Vinay Kishnani, Anshul Yadav, Kunal Mondal, and Ankur Gupta
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density functional theory ,hydrogen sensing ,palladium ,Technology - Abstract
The adsorption characteristics of H2 molecules on the surface of Pd-doped and Pd-decorated graphene (G) have been investigated using density functional theory (DFT) calculations to explore the sensing capabilities of Pd-doped/decorated graphene. In this analysis, electrostatic potential, atomic charge distribution, 2D and 3D electron density contouring, and electron localization function projection, were investigated. Studies have demonstrated the sensing potential of both Pd-doped and Pd-decorated graphene to H2 molecules and have found that the gap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO), i.e., the HOMO-LUMO gap (HLG), decreases to 0.488 eV and 0.477eV for Pd-doped and Pd-decorated graphene, respectively. When H2 is adsorbed on these structures, electrical conductivity increases for both conditions. Furthermore, chemical activity and electrical conductivity are higher for Pd-decorated G than Pd-doped G, whereas the charge transfer of Pd-doped graphene is far better than that of Pd-decorated graphene. Also, studies have shown that the adsorption energy of Pd-doped graphene (−4.3 eV) is lower than that of Pd-decorated graphene (−0.44 eV); a finding attributable to the fact that the recovery time for Pd-decorated graphene is lower compared to Pd-doped graphene. Therefore, the present analysis confirms that Pd-decorated graphene has a better H2 gas sensing platform than Pd-doped graphene and, as such, may assist the development of nanosensors in the future.
- Published
- 2021
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24. Carbon Nanostructures for Energy and Sensing Applications
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Kunal Mondal, Bhuvaneshwari Balasubramaniam, Ankur Gupta, Abdellatif Ait Lahcen, and Mirosław Kwiatkowski
- Subjects
Technology (General) ,T1-995 - Published
- 2019
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25. Improving the quality of tiger shrimp Penaeus monodon through dietary incorporation of algae as a source of natural pigment
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Kunal Mondal, Subhra Bikash Bhattacharyya, and Abhijit Mitra
- Subjects
shrimp ,aquaculture, feed, algae, pigment. ,Aquaculture. Fisheries. Angling ,SH1-691 ,Agriculture (General) ,S1-972 - Abstract
Tiger shrimp is one of the major candidate species for export oriented aquaculture which dominates the seafood market in regions of European Union, Japan and USA. Carotenoid content in seafood has now become one of the important criteria in determining the quality of edible product. Recent trends in supplementing fish diets with natural pigment source are an alternative to the utilization of expensive synthetic pigments. In this context, green algae Enteromorpha intestinalis was selected as a source of natural pigment for inclusion in the diet of tiger shrimp Penaeus monodon. Astaxanthin being an important category of carotenoid pigment was monitored in shrimp muscle tissue during the feeding trial. Significant variation (p
- Published
- 2015
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26. Recent Advances in Soft E-Textiles
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Kunal Mondal
- Subjects
textiles ,smart fabrics ,smart sensing ,fibers ,electronic textiles ,Engineering machinery, tools, and implements ,TA213-215 ,Technological innovations. Automation ,HD45-45.2 - Abstract
E-textiles (electronic textiles) are fabrics that possesses electronic counterparts and electrical interconnects knitted into them, offering flexibility, stretchability, and a characteristic length scale that cannot be accomplished using other electronic manufacturing methods currently available. However, knitting is only one of the technologies in e-Textile integration. Other technologies, such as sewing, embroidery, and even single fiber-based manufacture technology, are widely employed in next-generation e-textiles. Components and interconnections are barely visible since they are connected intrinsically to soft fabrics that have attracted the attention of those in the fashion and textile industries. These textiles can effortlessly acclimatize themselves to the fast-changing wearable electronic markets with digital, computational, energy storage, and sensing requirements of any specific application. This mini-review focuses on recent advances in the field of e-textiles and focuses particularly on the materials and their functionalities.
- Published
- 2018
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27. Hydration Phenomena of Functionalized Carbon Nanotubes (CNT)/Cement Composites
- Author
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Bhuvaneshwari Balasubramaniam, Kunal Mondal, Karunya Ramasamy, Gadyam S. Palani, and Nagesh R. Iyer
- Subjects
carbon nanotubes (CNT) ,cement ,cement composites ,hydration products ,surface functionalization ,Micro Structural Characterization ,compressive and tensile strengths ,Chemicals: Manufacture, use, etc. ,TP200-248 ,Textile bleaching, dyeing, printing, etc. ,TP890-933 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 - Abstract
The exciting features of carbon nanotubes (CNTs), such as high elastic modulus, high thermal and electrical conductivities, robustness, and nanoscopic surface properties make them attractive candidates for the cement industry. They have the potential to significantly enhanceengineering properties. CNTs play an important and critical role as nano-anchors in concrete, which enhance the strength by bridging pores in the composite matrix, thereby ensuring robust mechanical strength. The diameter, dispersion, aspect ratio, and interfacial surface interaction of CNTs affect the physical and mechanical properties of concrete, if due care is not taken. In this paper, the usable amount of CNT is scaled down considerably from 0.5% to 0.025% by weight of the cement and the fluctuation caused by these phenomena is assessed. It is observed that the properties and exact quantities of incorporated CNTs influence the hydration and consistency of the composites. In order to address these issues, the surface functionalization of CNTs and rheological studies of the composites are performed. The hydration products and functional groups are carefully optimized and characterized by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and a Zeta potential analyzer. For Mixes 6 and 7, the compressive and tensile strength of CNTs incorporated in mortar specimens caused77% and 48% increases in split tensile strength, respectively, and 17% and 35% increases in compressive strength, respectively, after 28 days of curing and compared withthe control Mix.
- Published
- 2017
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28. Recent Advances in the Synthesis of Metal Oxide Nanofibers and Their Environmental Remediation Applications
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Kunal Mondal
- Subjects
metal oxide nanofiber ,nanofiber photocatalyst ,electrospun nanofibers ,photocatalysis ,wastewater treatment ,UV light ,visible light photocatalysis ,solar energy ,photocatalytic reactor ,water disinfection ,recycling of photocatalyst ,Engineering machinery, tools, and implements ,TA213-215 ,Technological innovations. Automation ,HD45-45.2 - Abstract
Recently, wastewater treatment by photocatalytic oxidation processes with metal oxide nanomaterials and nanocomposites such as zinc oxide, titanium dioxide, zirconium dioxide, etc. using ultraviolet (UV) and visible light or even solar energy has added massive research importance. This waste removal technique using nanostructured photocatalysts is well known because of its effectiveness in disintegrating and mineralizing the unsafe organic pollutants such as organic pesticides, organohalogens, PAHs (Polycyclic Aromatic Hydrocarbons), surfactants, microorganisms, and other coloring agents in addition to the prospect of utilizing the solar and UV spectrum. The photocatalysts degrade the pollutants using light energy, which creates energetic electron in the metal oxide and thus generates hydroxyl radical, an oxidative mediator that can oxidize completely the organic pollutant in the wastewater. Altering the morphologies of metal oxide photocatalysts in nanoscale can further improve their photodegradation efficiency. Nanoscale features of the photocatalysts promote enhance light absorption and improved photon harvest property by refining the process of charge carrier generation and recombination at the semiconductor surfaces and in that way boost hydroxyl radicals. The literature covering semiconductor nanomaterials and nanocomposite-assisted photocatalysis—and, among those, metal oxide nanofibers—suggest that this is an attractive route for environmental remediation due to their capability of reaching complete mineralization of organic contaminants under mild reaction conditions such as room temperature and ambient atmospheric pressure with greater degradation performance. The main aim of this review is to highlight the most recent published work in the field of metal oxide nanofibrous photocatalyst-mediated degradation of organic pollutants and unsafe microorganisms present in wastewater. Finally, the recycling and reuse of photocatalysts for viable wastewater purification has also been conferred here and the latest examples given.
- Published
- 2017
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29. Surface Feature Recognition and Grasped Object Slip Prevention With a Liquid Metal Tactile Sensor for a Prosthetic Hand.
- Author
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Moaed A. Abd, Mostapha Al-Saidi, Maohua Lin, Genevieve Liddle, Kunal Mondal, and Erik D. Engeberg
- Published
- 2020
- Full Text
- View/download PDF
30. An review of research on liquid hydrogen leakage: regarding China's hydrogen refueling stations.
- Author
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Yangyiming Rong, Wenhao Yuan, Jianbin Peng, Jiaxin Hou, Jun Gao, Xiang Zhang, Jianye Chen, Shunyi Chen, Libin Lei, and Kunal Mondal
- Subjects
LIQUID hydrogen ,HYDROGEN as fuel ,LITERATURE reviews ,WIND speed ,ENERGY futures - Abstract
Hydrogen is regarded as the premier energy source for future sustainability and renewability. However, its distinct physicochemical properties render it prone to explosions in the event of a leak. Therefore, there is a need for more comprehensive research dealing with hydrogen leakage, explosion scenarios, and risk assessment. This paper provides an overview of the current hydrogen policies adopted in China. It reviews the processes of hydrogen refueling station construction and the thermophysical mechanisms of liquid hydrogen leakage. In this regard, the effects of various factors, including leakage rate, leakage time, leakage hole size, wind direction and speed, and building location, on the hydrogen leakage rate are analyzed and evaluated. Additionally, the impacts of different factors on hydrogen explosion overpressure are reported, including hydrogen concentration, wind speed, obstacles, and ignition position, in addition to the current applications of quantitative risk assessment methods in hydrogen refueling stations. Finally, the limitations of current research on liquid hydrogen leakage and explosion accidents are highlighted, along with the shortcomings of current risk assessment methods for liquid hydrogen refueling stations. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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31. Solution Processed Schottky Diodes Enabled by Silicon Carbide Nanowires for Harsh Environment Applications
- Author
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Kuan-Yu Chen, Prabhat K. Tripathy, Kunal Mondal, Hongliang Zhang, Adrien Couet, and Joseph B. Andrews
- Subjects
Mechanical Engineering ,General Materials Science ,Bioengineering ,General Chemistry ,Condensed Matter Physics - Published
- 2023
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32. An evaluative study to find the correlation between semitendinosus graft dimension with respect to patient’s anthropometry
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null Tanmay Datta, null Dibyendu Biswas, null Kunal Mondal, and null Santu Sarkar
- Subjects
General Agricultural and Biological Sciences - Abstract
Background: A prospective study of a cohort of anterior cruciate ligament (ACL) reconstructed patients 7 years after surgery revealed degenerative radiographic changes in 95% of patients, and only 47% were able to return to their previous activity level following ACL reconstruction. Aims and Objectives: The aims of this study were to find the correlation between Semitendinosus graft dimension with respect to patients anthropometry such as age, height, weight, body mass index (BMI), and true leg length (TLL). Materials and Methods: The proposed study was the patients coming to orthopedics-outpatient department and emergency with30 complete thickness ACL tears which were screened and recruited based on fulfillment of inclusion and exclusion criteria from January 2020 to August 2021 (20 months duration). The sample size was sufficient to draw conclusive findings. Correlation was calculated by Pearson correlation analysis. The Pearson product-moment correlation coefficient was a measure of the linear dependence between two variables X and Y. P≤0.05 was considered for statistically significant. Results: The age has positive correlation with graft length (r=0.11) and relatively strong positive correlation with graft diameter (r=0.437). Height has relatively strong positive correlation with graft length (r=0.4258) and graft diameter (r=0.1375). Weights have strong positive correlation with graft length (r=0.604). TLL also had positive correlation with graft length (0.23) and graft diameter (r=0.1). Conclusion: In selective cases, graft may be reinforced with additional Hamstring tendon harvest like gracilis or any alternative graft such as Bone–patellar tendon–bone (BPB) and Peroneus longus tendon autograft that may be taken to prevent graft failure and future complications. This current data can be a reference for surgeons in preoperative planning and counseling to patients about alternative autograft selection.
- Published
- 2022
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33. Versatile Carbon Nanofiber-Based Sensors
- Author
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Kunal Mondal, Ashutosh Sharma, Tejraj Aminabhavi, Soumen Basu, Nagaraj P. Shetti, and Aayushi Kundu
- Subjects
Biomaterials ,Biochemistry (medical) ,Biomedical Engineering ,General Chemistry - Abstract
Carbon nanofibers (CNFs) display colossal potential in different fields like energy, catalysis, biomedicine, sensing, and environmental science. CNFs have revealed extensive uses in various sensing platforms due to their distinctive structure, properties, function, and accessible surface functionalization capabilities. This review presents insight into various fabrication methods for CNFs like electrospinning, chemical vapor deposition, and template methods with merits and demerits of each technique. Also, we give a brief overview of CNF functionalization. Their unique physical and chemical properties make them promising candidates for the sensor applications. This review offers detailed discussion of sensing applications (strain sensor, biosensor, small molecule detection, food preservative detection, toxicity biomarker detection, and gas sensor). Various sensing applications of CNF like human motion monitoring and energy storage and conversion are discussed in brief. The challenges and obstacles associated with CNFs for futuristic applications are discussed. This review will be helpful for readers to understand the different fabrication methods and explore various applications of the versatile CNFs.
- Published
- 2022
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34. Si-based MEMS resonant sensor: A review from microfabrication perspective.
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Gulshan Verma, Kunal Mondal, and Ankur Gupta
- Published
- 2021
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35. Versatile Graphitized Carbon Nanofibers in Energy Applications
- Author
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Kunal Mondal, Ashutosh Sharma, Tejraj Aminabhavi, Soumen Basu, SURBHI SHARMA, and Nagaraj P. Shetti
- Subjects
Renewable Energy, Sustainability and the Environment ,General Chemical Engineering ,Environmental Chemistry ,General Chemistry - Published
- 2022
- Full Text
- View/download PDF
36. Management of Shepherd’s Crook Deformity by Proximal Femoral Osteotomy without Bone Graft - A Case Report
- Author
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Avijit Basak, Kunal Mondal, Pinaki Das, Raunak Agarwal, and Subhasish Manna
- Subjects
General Medicine - Published
- 2022
- Full Text
- View/download PDF
37. Neurodegenerative disorders management: state-of-art and prospects of nano-biotechnology
- Author
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Ajeet Kaushik, Seeram Ramakrishna, David Oupicky, Raj Kumar, Kunal Mondal, Yogendra Kumar Mishra, and Keshaw Ram Aadil
- Subjects
business.industry ,Neurodegenerative Diseases ,Neural degeneration ,General Medicine ,Disease ,Applied Microbiology and Biotechnology ,Brain Cell ,Variety (cybernetics) ,Nanomedicine ,Drug Delivery Systems ,Risk analysis (engineering) ,Brain stimulation ,State of art ,Humans ,Nanoparticles ,Nanotechnology ,Medicine ,Lack of knowledge ,Personalized medicine ,business ,Aged ,Biotechnology - Abstract
Neurodegenerative disorders (NDs) are highly prevalent among the aging population. It affects primarily the central nervous system (CNS) but the effects are also observed in the peripheral nervous system. Neural degeneration is a progressive loss of structure and function of neurons, which may ultimately involve cell death. Such patients suffer from debilitating memory loss and altered motor coordination which bring up non-affordable and unavoidable socio-economic burdens. Due to the unavailability of specific therapeutics and diagnostics, the necessity to control or manage NDs raised the demand to investigate and develop efficient alternative approaches. Keeping trends and advancements in view, this report describes both state-of-the-art and challenges in nano-biotechnology-based approaches to manage NDs, toward personalized healthcare management. Sincere efforts are being made to customize nano-theragnostics to control: therapeutic cargo packaging, delivery to the brain, nanomedicine of higher efficacy, deep brain stimulation, implanted stimulation, and managing brain cell functioning. These advancements are useful to design future therapy based on the severity of the patient's neurodegenerative disease. However, we observe a lack of knowledge shared among scientists of a variety of expertise to explore this multi-disciplinary research field for NDs management. Consequently, this review will provide a guideline platform that will be useful in developing novel smart nano-therapies by considering the aspects and advantages of nano-biotechnology to manage NDs in a personalized manner. Nano-biotechnology-based approaches have been proposed as effective and affordable alternatives at the clinical level due to recent advancements in nanotechnology-assisted theragnostics, targeted delivery, higher efficacy, and minimal side effects.
- Published
- 2021
- Full Text
- View/download PDF
38. What We Need to Know about Quantum Dots Nanoparticles
- Author
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Dr. Shiv Prakash Singh, Sudheer Kumar Yadav, and Kunal Mondal
- Published
- 2022
- Full Text
- View/download PDF
39. Zinc Oxide–Graphene Nanocomposite-Based Sensor for the Electrochemical Determination of Cetirizine
- Author
-
Rakesh R. Sawkar, Mahesh M. Shanbhag, Suresh M. Tuwar, Kunal Mondal, and Nagaraj P. Shetti
- Subjects
cetirizine ,graphene ,zinc oxide nanoparticles ,electrochemical oxidation ,detection limit ,Physical and Theoretical Chemistry ,Catalysis ,General Environmental Science - Abstract
A nanocomposite electrode of graphene (Gr) and zinc oxide (ZnO) nanoparticles was fabricated to study the electrochemical oxidation behavior of an anti-inflammatory drug, i.e., cetirizine (CET). The voltametric response of CET for bare CPE, Gr/CPE, ZnO/CPE, and the ZnO-Gr nanocomposite electrode was studied. The modifier materials were characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray powder diffraction (XRD) to comprehend the surface morphology of the utilized modifiers. The influence of pH, scan rate, and accumulation time on the electrooxidation of CET was examined. It was found that the electrochemical oxidation of CET was diffusion-controlled, in which two protons and two electrons participated. The detection limit was found to be 2.8 × 10−8 M in a linearity range of 0.05–4.0 µM. Study of excipients was also performed, and it was found that they had negligible interference with the peak potential of CET. The validation and utility of the fabricated nanocomposite sensor material were examined by analyzing clinical and biological samples. Stability testing of the nanocomposite electrode was conducted to assess the reproducibility, determining that the developed biosensor has good stability and high efficiency in producing reproducible results.
- Published
- 2022
- Full Text
- View/download PDF
40. Metal Oxide Nanostructures for Gas Sensing Applications
- Author
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Anoop Mampazhasseri Divakaran and Kunal Mondal
- Published
- 2022
- Full Text
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41. Sodium Dodecyl Sulfate-Mediated Graphene Sensor for Electrochemical Detection of the Antibiotic Drug: Ciprofloxacin
- Author
-
Rakesh R. Sawkar, Mahesh M. Shanbhag, Suresh M. Tuwar, Kunal Mondal, and Nagaraj P. Shetti
- Subjects
ciprofloxacin ,voltammetry ,graphene ,sodium dodecyl sulfate ,detection limit ,General Materials Science - Abstract
The present study involves detecting and determining CIP by a new electrochemical sensor based on graphene (Gr) in the presence of sodium dodecyl sulfate (SDS) employing voltammetric techniques. Surface morphology studies of the sensing material were analyzed using a scanning electron microscope (SEM) and atomic force microscope (AFM). In the electroanalysis of CIP at the developed electrode, an enhanced anodic peak response was recorded, suggesting the electro-oxidation of CIP at the electrode surface. Furthermore, we evaluated the impact of the electrolytic solution, scan rate, accumulation time, and concentration variation on the electrochemical behavior of CIP. The possible electrode mechanism was proposed based on the acquired experimental information. A concentration variation study was performed using differential pulse voltammetry (DPV) in the lower concentration range, and the fabricated electrode achieved a detection limit of 2.9 × 10−8 M. The proposed sensor detected CIP in pharmaceutical and biological samples. The findings displayed good recovery, with 93.8% for tablet analysis and 93.3% to 98.7% for urine analysis. The stability of a developed electrode was tested by inter- and intraday analysis.
- Published
- 2022
42. On the Sintering Behavior of Nb2O5 and Ta2O5 Mixed Oxide Powders
- Author
-
Maureen P. Chorney, Kunal Mondal, Jerome P. Downey, and Prabhat K. Tripathy
- Subjects
tantalum pentoxide ,niobium pentoxide ,energy materials ,oxide precursor ,sintering ,green manufacturing ,General Materials Science - Abstract
A mixed oxide system consisting of Nb2O5 and Ta2O5, was subjected to annealing in air/hydrogen up to 950 °C for 1–4 h to study its sintering behavior. The thermogravimetric–differential scanning calorimetry (TGA–DSC) thermograms indicated the formation of multiple endothermic peaks at temperatures higher than 925 °C. Subsequently, a 30% Ta2O5 and 70% Nb2O5 (mol%) pellet resulted in good sintering behavior at both 900 and 950 °C. The scanning electron microscope (SEM) images corroborated these observations with necking and particle coarsening. The sintered pellets contained a 20.4 and 20.8% mixed oxide (Nb4Ta2O15) phase, along with Ta2O5 and Nb2O5, at both 900 and 950 °C, indicating the possibility of the formation of a solid solution phase. In situ high-temperature X-ray diffraction (XRD) scans also confirmed the formation of the ternary oxide phase at 6 and 19.8% at 890 and 950 °C, respectively. The Hume–Rothery rules could explain the good sintering behavior of the Ta2O5 and Nb2O5 mixed oxides. An oxide composition of 30% Ta2O5 and 70% Nb2O5 (mol%) and a sintering temperature of 950 °C appeared adequate for fabricating well-sintered oxide precursors for subsequent electrochemical polarization studies in fused salts.
- Published
- 2022
- Full Text
- View/download PDF
43. Thermal Barrier Coatings Overview: Design, Manufacturing, and Applications in High-Temperature Industries
- Author
-
Luis Nuñez, Kunal Mondal, Calvin M. Downey, and Isabella J. van Rooyen
- Subjects
Engineering ,Fabrication ,business.industry ,General Chemical Engineering ,Automotive industry ,02 engineering and technology ,General Chemistry ,engineering.material ,021001 nanoscience & nanotechnology ,Durability ,Engineering physics ,Industrial and Manufacturing Engineering ,Thermal barrier coating ,Life extension ,020401 chemical engineering ,Coating ,Electronics ,0204 chemical engineering ,0210 nano-technology ,business ,Aerospace - Abstract
Today’s competitive world economy is creating an indispensable demand for increased efficiency of engineering components that operate in harsh environments (i.e., very high-temperature, corrosive, or neutron irradiation environments), for applications in the energy, automotive, aerospace, electronics, and power industries. Increased research is being done on thermal barrier coatings (TBCs) for protecting such components, since the versatility of manufacturing techniques and the scale of deployment result in increased life, economics, performance, and durability. This review focuses on the advances that led to using TBCs for component life extension and, more recently, as an integral part of advanced component design for high-temperature and other types of harsh environments, such as those found in nuclear-related applications. Factors that led to state-of-the-art advanced coating-fabrication techniques [e.g., electron-beam physical vapor deposition (EB-PVD), plasma spray deposition, and electrophoretically deposited TBCs, as well as functionally graded material (FGM) manufacturing] have also been emphasized in current coating R&D. This review explores the current state of TBCs, i.e., the latest advances regarding their fabrication and performance, associated challenges, and recommendations for their future use in aerospace, nuclear, high-temperature, or otherwise harsh environments.
- Published
- 2021
- Full Text
- View/download PDF
44. Stretchable and wearable polymeric heaters and strain sensors fabricated using liquid metals
- Author
-
Sihyun Kim, Masato Saito, Yuwen Wei, Priyanuj Bhuyan, Minjae Choe, Toshinori Fujie, Kunal Mondal, and Sungjune Park
- Subjects
Metals and Alloys ,Electrical and Electronic Engineering ,Condensed Matter Physics ,Instrumentation ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials - Published
- 2023
- Full Text
- View/download PDF
45. Advanced Manufacturing of Printed Melt Wire Chips for Cheap, Compact Passive In-Pile Temperature Sensors
- Author
-
Michael D. McMurtrey, Kunal Mondal, and Kiyo Fujimoto
- Subjects
Fabrication ,Materials science ,Test design ,0211 other engineering and technologies ,General Engineering ,Mechanical engineering ,Hardware_PERFORMANCEANDRELIABILITY ,02 engineering and technology ,021001 nanoscience & nanotechnology ,GeneralLiterature_MISCELLANEOUS ,Hardware_INTEGRATEDCIRCUITS ,Advanced Test Reactor ,Advanced manufacturing ,General Materials Science ,Instrumentation (computer programming) ,0210 nano-technology ,Pile ,021102 mining & metallurgy - Abstract
Melt wires are a passive sensor used to determine peak temperatures. Traditional melt wires are commonly used in test reactor experiments, such as in the Advanced Test Reactor. However, the conditions within a reactor present significant challenges towards test design, due to space limitations and the harsh environment. For example, some test capsules have only a couple millimeters in diameter available for instrumentation, which is too small to accommodate a traditional melt wire package. To enable instrumentation for space-limited applications, peak temperature sensors have been developed using additive manufacture to form printed melt wires. This paper reports on the design and fabrication of miniaturized melt wire chips with printed melt wires. This study advances the development of unique, compact temperature sensors capable of sensing user specified temperature ranges within the harsh environment of irradiation testing.
- Published
- 2020
- Full Text
- View/download PDF
46. Application of a Laser Cutter to Pattern Wrinkles on Polymer Films
- Author
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Kunal Mondal, Ying Liu, Tim Shay, Jan Genzer, and Michael D. Dickey
- Subjects
chemistry.chemical_classification ,Materials science ,Polymers and Plastics ,business.industry ,Process Chemistry and Technology ,Organic Chemistry ,chemistry.chemical_element ,Polymer ,Laser ,law.invention ,chemistry.chemical_compound ,chemistry ,Cleanroom ,law ,Aluminium ,Optoelectronics ,Polystyrene ,Thin film ,business ,Lithography ,Microscale chemistry - Abstract
Wrinkling of thin films is a simple way to fabricate microscale topographical structures without the use of expensive lithographic processes or clean rooms. Such wrinkles have applications in surfa...
- Published
- 2020
- Full Text
- View/download PDF
47. 110th Anniversary: Particle Size Effect on Enhanced Graphitization and Electrical Conductivity of Suspended Gold/Carbon Composite Nanofibers
- Author
-
Gorakh Pawar, Alok Kumar Srivastava, Ashutosh Sharma, Michael D. McMurtrey, Kunal Mondal, and Tanmoy Maitra
- Subjects
Fabrication ,Materials science ,General Chemical Engineering ,Polyacrylonitrile ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,021001 nanoscience & nanotechnology ,Industrial and Manufacturing Engineering ,Electrospinning ,chemistry.chemical_compound ,020401 chemical engineering ,chemistry ,Chemical engineering ,Electrical resistivity and conductivity ,Composite nanofibers ,Particle size ,0204 chemical engineering ,0210 nano-technology ,Carbon - Abstract
The fabrication of suspended gold/carbon composite nanofibers on carbon microposts by electrospinning of a gold/polyacrylonitrile (AuNP/PAN) blend precursor is proposed. The fibers were spun on a r...
- Published
- 2020
- Full Text
- View/download PDF
48. A Molten Salt Electrochemical Process for the Preparation of Cost-Effective p-Block (Coating) Materials
- Author
-
Kunal Mondal and Prabhat Tripathy
- Subjects
Inorganic Chemistry ,molten salt ,three-electrode set up ,galvanostatic deposition ,p-block elements ,coated component ,General Chemical Engineering ,General Materials Science ,Condensed Matter Physics - Abstract
Solar energy applications rely heavily on p-block elements and transition metals. Silicon is, by far, the most commonly used material in photovoltaic cells and accounts for about 85% of modules sold presently. Of late, thin film photovoltaic cells have gained momentum because of their higher efficiencies. Most of these thin film devices are made out of just five elements, namely, cadmium, tellurium, selenium, indium, gallium and copper. The present manuscript describes an elegant and inexpensive molten salt-based electrolytic process for fabricating a tellurium-coated metallic substrate. A three-electrode set up was employed to coat iridium with tellurium from a molten bath containing lithium chloride, lithium oxide and tellurium tetrachloride (LiCl-Li2O-TeCl4) at 650 °C for a duration ranging from 30 to 120 min under a galvanostatic mode. The tellurium coating was observed to be thick, uniform, smooth and homogeneous. Additionally, the deposited tellurium did not chemically react with the iridium substrate to form intermetallic compounds, which is a good feature from the standpoint of the device’s performance characteristics. The present process, being generic in nature, shows the potential for the manufacture of both the coated substates and high-purity elements not just for tellurium but also for other p-block elements.
- Published
- 2022
- Full Text
- View/download PDF
49. List of contributors
- Author
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Keshaw Ram Aadil, Md. Azahar Ali, Bhuvaneshwari Balasubramaniam, Tandrima Banerjee, Souravi Bardhan, Jayesh Bellare, Snehasis Biswas, Naveen Bunekar, Richa Chaturvedi, Abhishek Chaudhary, Gaurav Chauhan, Mohit Chawla, Antonella V. Dan Córdoba, Sukhen Das, Alokmay Datta, Anca Dinischiotu, Sunil Dutt, Suparna Dutta-Sinha, Nirmal G. R., Mónica C. García, Bidipta Ghosh, Agnivo Gosai, Kishan Gugulothu, Abhishek Gupta, Abhishek Kumar Gupta, Ankur Gupta, Raju Kumar Gupta, Uttam Gupta, James Hartmann, Monsur Islam, Vinay Kishnani, Jan G. Korvink, Ashwani Kumar, Raj Kumar, Rudra Kumar, Yogeenth Kumaresan, Lingeshwar Reddy Kumbam, Genevieve M. Liddle, Marcela Longhi, Dario Mager, Shweta J. Malode, Venkateswarulu Mangili, Miguel Manso Silvan, Sergio O. Martinez-Chapa, Vivek K. Mishra, Jaba Mitra, Joyee Mitra, Mousumi Mitra, Kunal Mondal, Nagaraju Nakka, Ionela Cristina Nica, Yegor Piskarev, Praveen Kumar Poola, Guruprasad Reddy Pulikanti, Nitin Puri, Yuhao Qiang, Darsi Rambabu, Shubham Roy, Ahsana Sadaf, Prateep Singh Sagara, Abhijit Samanta, Deepika Sandil, Konathala Ravi Shankar, Nagaraj P. Shetti, Jun Shintake, Miruna Silvia Stan, null Suchitra, Jazmín Torres, Paula M. Uberman, Jianning Wei, Anshul Yadav, and Midathala Yogesh
- Published
- 2022
- Full Text
- View/download PDF
50. Introduction to metal oxide-based biosensing
- Author
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Vinay Kishnani, Kunal Mondal, and Ankur Gupta
- Published
- 2022
- Full Text
- View/download PDF
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