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Generation of the monochromatic electromagnetic radiation in the terahertz (THz) range of frequencies for many decades remanes a chellenging task. Here we demonstrate the emission of monochromatic sub-THz radiation by coherent optical phonons in dielectric material KY(MoO4)2. The layered crystal structure of KY(MoO4)2 leads to infrared-active shear lattice vibrations with energies below 3.7 meV, which corresponds to the frequencies low than 900 GHz where solid-state compounds based monochromatic radiation sources are rare. Coherent infrared-active optical phonons are excited by broadband THz pulses lasting for tens of picoseconds and re-emit narrow-band subTHz radiation pulses with a decay time of 33 picoseconds, which is exceptionally long for the oscillators with frequencies below 1 THz. Such a long coherent emission allows for the detection of more than 50 periods of radiation with frequencies of 568 and 860 GHz. The remarkably long decay time together with the chemical stability of the employed materials suggest a variety of possible applications in THz laser technology.

Using Raman and infrared spectroscopies the spontaneous ferriquadrupolar ordering has been observed in the rare-earth-based system KDy(MoO$_4$)$_2$. Ordered quadrupoles in the electron subsystem attend non-equivalent distortions of rare-earth ions in the ordered phase. The mean field theory explaining the onset of such a type of ordering has been constructed., Comment: 6 pages, 4 figures