1. Superconductivity induced by gate-driven hydrogen intercalation in the charge-density-wave compound 1T-TiSe2
- Author
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Piatti, Erik, Prando, Giacomo, Meinero, Martina, Tresca, Cesare, Putti, Marina, Roddaro, Stefano, Lamura, Gianrico, Shiroka, Toni, Carretta, Pietro, Profeta, Gianni, Daghero, Dario, and Gonnelli, Renato S.
- Subjects
Condensed Matter - Superconductivity ,Condensed Matter - Mesoscale and Nanoscale Physics ,Condensed Matter - Materials Science - Abstract
Hydrogen (H) plays a key role in the near-to-room temperature superconductivity of hydrides at megabar pressures. This suggests that H doping could have similar effects on the electronic and phononic spectra of materials at ambient pressure as well. Here, we demonstrate the non-volatile control of the electronic ground state of titanium diselenide (1T-TiSe$_2$) via ionic liquid gating-driven H intercalation. This protonation induces a superconducting phase, observed together with a charge-density wave through most of the phase diagram, with nearly doping-independent transition temperatures. The H-induced superconducting phase is possibly gapless-like and multi-band in nature, in contrast with those induced in TiSe$_2$ via copper, lithium, and electrostatic doping. This unique behavior is supported by ab initio calculations showing that high concentrations of H dopants induce a full reconstruction of the bandstructure, although with little coupling between electrons and high-frequency H phonons. Our findings provide a promising approach for engineering the ground state of transition metal dichalcogenides and other layered materials via gate-controlled protonation., Comment: Main text: 13 pages, 5 figures; Supplementary: 12 pages, 12 figures
- Published
- 2022
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