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We present the first observation of ultracold LiCs molecules. The molecules are formed in a two-species magneto-optical trap and detected by two-photon ionization and time-of-flight mass spectrometry. The production rate coefficient is found to be in the range $10^{-18}\unit{cm^3s^{-1}}$ to $10^{-16}\unit{cm^3s^{-1}}$, at least an order of magnitude smaller than for other heteronuclear diatomic molecules directly formed in a magneto-optical trap., Comment: 8 pages, 2 figures

Ultracold collisions between Cs atoms and Cs2 dimers in the electronic ground state are observed in an optically trapped gas of atoms and molecules. The Cs2 molecules are formed in the triplet ground state by cw-photoassociation through the outer well of the 0g-(P3/2) excited electronic state. Inelastic atom-molecule collisions converting internal excitation into kinetic energy lead to a loss of Cs2 molecules from the dipole trap. Rate coefficients are determined for collisions involving Cs atoms in either the F=3 or F=4 hyperfine ground state and Cs2 molecules in either highly vibrationally excited states (v'=32-47) or in low vibrational states (v'=4-6) of the a ^3 Sigma_u^+ triplet ground state. The rate coefficients beta ~10^{-10} cm^3/s are found to be largely independent of the vibrational and rotational excitation indicating unitary limited cross sections., Comment: 4 pages, 3 figures, submitted for publication

We have realized a high-resolution time-of-flight mass spectrometer combined with a magneto-optical trap. The spectrometer enables excellent optical access to the trapped atomic cloud using specifically devised acceleration and deflection electrodes. The ions are extracted along a laser beam axis and deflected onto an off axis detector. The setup is applied to detect atoms and molecules photoassociated from ultracold atoms. The detection is based on resonance-enhanced multi-photon ionization. Mass resolution up to m/Delta m_rms = 1000 at the mass of 133Cs is achieved. The performance of this spectrometer is demonstrated in the detection of photoassociated ultracold 7Li133Cs molecules near a large signal of 133Cs ions., Comment: Appl. Phys. B, in press