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Abstract: This study deals with As speciation in white wine. Arsenic species were selectively determined by liquid chromatography–inductively coupled plasma–mass spectrometry (LC–ICP–MS). Separation of As species was performed using an anion exchange column with ammonium phosphate solution (pH 6.00) as mobile phase. Samples of 14 white wine produced in South America were analysed. They were 10-fold diluted in the mobile phase prior to analysis by LC–ICP–MS. Accuracy was evaluated by recovery tests, whereas As species recovery ranged from 95% to 106%. Additionally, the sum of arsenic species concentration found by LC–ICP–MS was in agreement with the total arsenic concentration determined by ICP–MS after sample digestion. Arsenic species detected were arsenite [As(III)], arsenate [As(V)] and dimethylarsinic acid (DMA). As(III) and As(V) were detected in all analysed wine samples and DMA was detected only in wines produced in Argentina. Results for As determination in samples were from 2.9 to 10.3, 8.6 to 17.8, and<0.45 to 1.07μgL−1 for As(III), As(V) and DMA, respectively. [ABSTRACT FROM AUTHOR]