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• Clay mineral and elemental compositions of surface sediments were analyzed. • The old Yellow River and Yangtze River are the main sediment sources. • The influence of Yangtze sediments reaches up 35°N west of the study area. • Yangtze sediments are transported in different ways during summer and winter. The southwestern South Yellow Sea (SYS) is influenced by tremendous sediment loads derived from the Yellow River (Huanghe) and the Yangtze River (Changjiang). However, the influence of Yangtze River sediments and their transport mechanism in this area remain unresolved. In this study, we present the grain size, clay minerals, and elemental compositions of surface sediments from the southwestern SYS, together with an analysis of field observation seawater salinity and suspended sediment data, to investigate the provenance and transport mechanism of the sediments. Discrimination diagrams of clay minerals, Cr/Th vs. Sc/Al, and rare earth elements (REEs) indicate that the southwestern SYS sediments are mainly derived from the old Yellow River subaqueous delta and the Yangtze River. Interestingly, Yangtze sediments enter the SYS in ways that differ seasonally. In summer, Yangtze sediments may be transported into the central SYS by the dispersion of Changjiang Diluted Water (CDW) and may also be transported northwestward by the Subei Coastal Current (SCC) to the area off the Jiangsu coast. In winter, the Yangtze-derived sediments deposited off the Jiangsu coast in summer are transported into the central and/or even north SYS under the combined effects of the SCC, Yellow Sea Coastal Current (YSCC), and Yellow Sea Warm Current (YSWC). Throughout the transport processes, there is an alternation between a source and sink of Yangtze sediments off the Jiangsu coast; the coast serves as a sink of Yangtze sediments in summer but as a source of SYS sedimentation in winter. The depositional and transport mechanisms of Yangtze-derived sediments are closely associated with seasonal variations in the circulation system of the SYS. [ABSTRACT FROM AUTHOR]

Abstract Sedimentary responses to the cross-shelf transport on the East China Sea continental shelf are ascertained based on analyses of the sediment grain size and detrital mineral components of surficial sediments. Sedimentological data show that fine-grained sediments can be transported across the continental shelf and have formed a tongue-shaped zone with an axis located near 29°N that extends from the coast to 124°40′E or beyond. The sediments in this tongue-shaped zone are rich in very fine silt and clay, as are the dominant sediment fractions discharged by the modern Yangtze River indicating a modern terrigenous source. Sediment with grain sizes 7–9 Φ is the main fraction that is transported across the continental shelf. In contrast to the regions in the same longitude, in the tongue-shaped zone the relatively low heavy mineral content, high schistose mineral content and high dolomite content and the mixture of fresh and weathered minerals show that modern Yangtze River sediment has been widely transported to this region. Meanwhile, the simultaneous existence of the fine-grained tongue and a coarse-grained area immediately south of the base of the tongue coincident with the nearshore Kuroshio branch current intrusion area indicate that the Kuroshio intrusion plays an important role in triggering the cross-shelf flows. Graphical abstract Unlabelled Image Highlights • Sedimentological data demonstrate cross-shelf transport in the East China Sea. • Sediment grain size and mineral distributions show apparent cross-shelf transport. • Cross-shelf transport occurs in a relatively fixed location near 29°N. • Fine-grained sediment can be transported cross-shelf to 124°40′E or even farther. • Kuroshio intrusion is an important factor that triggers the cross-shelf flows. [ABSTRACT FROM AUTHOR]

Abstract The sea-level curve during the last deglaciation is characterized by two episodes of rapid sea-level rise, termed Meltwater Pulses (MWPs) 1A (14.6–14.3 kyr BP) and 1B (11.45–11.1 kyr BP), as well as an episode of relatively slow sea-level rise during the Younger Dryas stadial (YD; 12.85–11.65 kyr BP). However, the relative sea-level changes during the YD and MWP-1B periods are still not well defined. Here, we use precisely dated intertidal sediments derived from 6 sediment cores on the tectonically stable continental shelf of the East China Sea (ECS) to reconstruct a high-resolution sea-level curve between 14.0 kyr BP and 10.0 kyr BP. Although linear regression analysis suggests that the sea level rose continuously, with an average rate of 10.6 ± 0.6 mm/yr (r = −0.87, p(a) < 0.01, n = 95), the mode of sea-level rise differs before, during, and after the YD stadial. A rapid sea-level rise of 30.5 ± 4.9 mm/yr (r = −0.79, p(a) < 0.05, n = 25) occurred during 14.0–12.85 kyr BP. Subsequently, the rate of sea-level rise decreased significantly in response to the YD stadial, and it increased smoothly to 12.0 ± 1.4 mm/yr (r = −0.86, p(a) < 0.01, n = 29) from 11.65–10.0 kyr BP, indicating that MWP-1B was absent on the ECS shelf. Furthermore, based on comparisons of these data with other high-resolution curves of sea level or elevation at different latitudes, we suggest that the poleward seawater migration from intertropical broad oceans occurred because glacial isostatic adjustment could have generated a relatively consistent global sea-level height during the last deglaciation, especially during the YD, when the rate of sea-level rise was slowed. Highlights • Sea-level rise is constrained by East China Sea intertidal sediments. • A possible rapid sea-level rise occurred during 13.6–13.0 kyr BP. • Sea-level rise slowed remarkably in response to the Younger Dryas. • Meltwater Pulse 1B is not recorded on the East China Sea shelf. • The poleward migration of seawater can lead to global sea levels remaining the same. [ABSTRACT FROM AUTHOR]

Abstract Gypsum (CaSO 4 ∙2H 2 O) precipitated in nonevaporative marine environments is rarely reported, and the related diagenetic process and its implications for the sulfur cycle (e.g., sulfide reoxidation) are still not well known. We employ coupled sulfur and oxygen isotopes of authigenic gypsum, as well as sulfur isotopic compositions of pyrite, from core EC2005, which is drilled on the inner shelf of the East China Sea, to constrain the sulfur and oxygen sources for gypsum precipitation. The δ34S gypsum values range from −24.8 to −12.2‰, which are much more depleted in 34S than modern seawater sulfate, suggesting additional 34S-depleted sulfur sources, i.e., co-existing pyrites produced by microbial sulfate reduction. According to a mixing model for paired sulfur isotopes of gypsum and pyrite, >70% of gypsum sulfur is derived from pyrite reoxidation. The δ18O gypsum values, ranging from 1.1 to 4.6‰, suggest that the oxygen isotopes of porewater sulfate should fall between −2.4 and 1.1‰, which are more depleted than seawater sulfate in 18O. Two mechanisms are proposed to explain the reoxidation of pyrite at different depths: in the lower section (10–4 m; Unit II), pyrite is oxidized by metal oxides under anaerobic conditions, producing 18O-depleted oxygen from seawater; while in the upper section (4–0 m; Unit I), pyrite reoxidation may occur under aerobic conditions, involving atmospheric oxygen. Either the aerobic or anaerobic mechanisms could cause drops in the porewater pH, leading to carbonate dissolution. These processes could therefore elevate the concentrations of sulfate and calcium ions in porewater, in which authigenic gypsum crystals are precipitated. In addition, both sulfur and oxygen isotopic signals of gypsum indicate a possible influence of methane on sulfate reduction in the mud sediments of core EC2005, which may be related to biogenic gas (dominated by CH 4) in this region. Our new findings thus indicate that sulfide reoxidation in marine sediments plays an important role in the biogeochemical sulfur cycle on the continental margin. Highlights • Coexistence of pyrite and gypsum in mud sediments on the East China Sea shelf. • Pyrite oxidation is the primary sulfur source for gypsum precipitation. • Gypsum oxygen derived from seawater oxygen rather than seawater sulfate. • Gypsum formation accompanied by carbonate dissolution caused by sulfide oxidation. [ABSTRACT FROM AUTHOR]

The East China Sea continental shelf is a unique area for the study of land-sea interactions and paleoenvironmental change because it receives a large amount of terrestrial material inputs. In recent decades, human activities and global climate change have greatly affected river discharges into the sea. However, changes in the deposition process caused by these factors in the East China Sea continental shelf are unclear. We collected eight short sediment cores from the East China Sea inner shelf (ECSIS) using a box core sampler in 2012 and 2015. The grainsize, 210 Pb, and 137 Cs of these cores were analyzed in order to reconstruct the deposition history since the 1950s, and to reveal human activity and climate change influences on sediment deposition in the ECSIS. Results indicated that sediment grain size became finer after 1969, turned coarser after 1987, and then further coarser since 2003, corresponding well to the three steps of sediment load drop in the Changjiang (Yangtze) River, which are mainly caused by human activities (particularly the closure of the Three Gorges Dam). Simultaneously, the East Asian Monsoon influenced the deposition process in the ECSIS by changing the intensity of coastal currents. Mean grain size variations in the fine-grained population (divided by grain size vs. standard deviation method) coincided with that of the East Asian Winter Monsoon strength and reflected its weakness in 1987. Abrupt changes in sediment grain size over a short time scale in these sediment cores were generally caused by floods and typhoons. Spectral analyses of the sediment cores showed periodicities of 10–11 and 20–22 years, corresponding to the periodicity of solar activity (Schwabe cycle and Hale cycle). Mean grain size time series also displayed a 3–8 year periodicity corresponding to El Niño Southern Oscillation periodic change. [ABSTRACT FROM AUTHOR]

In the past decade, the 800 km elongated mud belt off Zhejiang-Fujian coast, East China Sea (ECS), has been extensively studied for understanding the source to sink processes on the East Asian continental margin in the context of the Asian monsoon. However, to better understand the sediment source and dispersal pattern, the existing mineralogical and geochemical data of adjacent river systems, including the Changjiang River (CJR) and local rivers in Zhejiang, Fujian and Taiwan, need to be systematically reviewed. Therefore, various indicators from published literatures for the provenance discrimination in the mud belt have been summarised in this article. The results show that high diversity of clay mineral assemblages in fluvial sediments being supplied into the mud belt, e.g., dominant illite and chlorite in the CJR, absence of smectite in Taiwan rivers, similar amounts of the four clay mineral species in Zhejiang rivers, and dominant kaolinite in Fujian rivers. On heavy mineralogy, the CJR is dominated by dolomite, hornblende, and flaky minerals; and among of them, dolomite is distinctive for the CJR. For geochemical approaches, elemental compositions, combined with strontium and neodymium isotopes, reflect strong provenance control. However, geochemical and mineralogical compositions are found to vary with grain size, and thus extra caution should be taken when using these parameters as provenance indicator to discriminate the marine sediments with variety of grain-size fractions. In addition, pyrrhotite, occurred in fluvial sediments from western Taiwan, has not been found in sediments derived from mainland China, indicating that magnetic parameters could be used to discriminate sediment provenance. The mud belt formed during sea-level highstand, when modern current system in the ECS has been established, resulting in sediments derived from the CJR have been transported southward since 8 ka. In addition, sediment provenances have not been constant since initiation of the mud belt in response to climatic and oceanographic changes during the Holocene, which has been documented by mineral and geochemical signals. Nevertheless significant studies have been carried out, to better understand the formation mechanism for the mud belt and its implications for environmental changes, further studies on sediment provenance throughout the Holocene, in situ observation, and sedimentation dynamical modelling are required. [ABSTRACT FROM AUTHOR]

The Kuroshio Current (KC) is the northward branch of the North Pacific subtropical gyre (NPG) and exerts influence on the exchange of physical, chemical, and biological properties of downstream regions in the Pacific Ocean. Resolving long-term changes in the flow of the KC water masses is, therefore, crucial for advancing our understanding of the Pacific's role in global ocean and climate variability. Here, we reconstruct changes in KC dynamics over the past 20 ka based on grain-size spectra, clay mineral, and Sr–Nd isotope constraints of sediments from the northern Okinawa Trough. Combined with published sediment records surrounding the NPG, we suggest that the KC remained in the Okinawa Trough throughout the Last Glacial Maximum. Together with Earth-System-Model simulations, our results additionally indicate that KC intensified considerably during the early Holocene (EH). The synchronous establishment of the KC “water barrier” and the modern circulation pattern during the EH highstand shaped the sediment transport patterns. This is ascribed to the precession-induced increase in the occurrence of La Niña-like state and the strength of the East Asian summer monsoon. The synchronicity of the shifts in the intensity of the KC, Kuroshio extension, and El Niño/La Niña-Southern Oscillation (ENSO) variability may further indicate that the western branch of the NPG has been subject to basin-scale changes in wind stress curl over the North Pacific in response to low-latitude insolation. Superimposed on this long-term trend are high-amplitude, large century, and millennial-scale variations during last 5 ka, which are ascribed to the advent of modern ENSO when the equatorial oceans experienced stronger insolation during the boreal winter. [ABSTRACT FROM AUTHOR]

Okinawa Trough receives a large amount of fluvial sediment transported by complex oceanographic circulations, and is an ideal location for the study of paleoceanography and paleoenvironment changes. However, our knowledge of the sediment provenance and paleoenvironment evolution in the Trough during the past 17 ka is still limited. Based on high-resolution grain size, clay minerals and AMS 14 C data of the Core OKI04, we present new evidences of the provenances and paleoenvironment evolution in the middle Okinawa Trough during the last 17 ka. Our results indicate that clay-sized terrigenous sediment deposited in the middle Okinawa Trough is mainly from those rivers flowing into East China Sea and Yellow Sea (e.g., Yangtze and Yellow Rivers) and Taiwanese Rivers. Their contributions varied greatly in space and time during the past 17 ka. From 16.5 to 13.8 ka, sediment was mainly derived from the Yangtze and Yellow Rivers, with little contribution from Taiwan. From 13.8 to 5.4 ka, the contributions from the Yangtze and Yellow Rivers oscillated multiple times: low in 13.8–11.6 ka, high in 11.6–7.6 ka, and back to low in 7.6–5.4 ka, whereas the pattern of Taiwanese contribution was opposite. After 5.4 ka when the sea level was high and shoreline was far away from the Okinawa Trough, the Yangtze River and eastern Taiwanese Rivers became the main provenances. The contribution from the Yellow River decreased, which is probably because Yellow River mouth was far away from the middle Trough. Sediment grain size data show that two environmentally sensitive populations are 71–7 μm and 7–0.5 μm. The variation of the populations' mean grain size and content shows that the strength of Kuroshio Current was weak during 16.5–11.6 ka, and became strong in 11.6–5.4 ka, in which Tsushima Warm Current and Yellow Sea Warm Current formed around 8.5 and 6.5 ka, respectively. The strength of Kuroshio Current decreased in 5.4 ka and increased since 3.2 ka. Based on clay mineralogical analysis, we find that the kaolinite/chlorite could be used as a new effective indicator for the East Asian Winter Monsoon's evolution in the Trough since 17 ka. [ABSTRACT FROM AUTHOR]

The Okinawa Trough is a natural laboratory for the study of air-sea interaction and paleoenvironmental change. It has been demonstrated that present offshore export of particles in the bottom nepheloid layer occur primarily with downwelling from the northeast winter monsoon, which is inhibited by a transverse circulation pattern in summer. This current system was very different during the Last Glacial Maximum owing to low sea level (−120 m) and exposure of a large shelf area. We collected sediment core Oki01 from the middle Okinawa Trough during 2012 using R/V Kexue No. 1 to elucidate the timing and cause of the current system transition in the East China Sea. Clay mineral, dry density, and elemental (Ti, Ca) composition of core Oki01 was analyzed. The results indicate that clay minerals derived mainly from the Huanghe (Yellow) and the Changjiang (Yangtze) Rivers during 16.0-11.6 ka, and the modern current system in the East China Sea formed beginning in the early Holocene. Therefore, mixing of East China Sea continental shelf, Changjiang River and partially Taiwan Island sediment are the major contributors. The decrease of log(Ti/Ca) and alternating provenance since the early Holocene indicate less sediment from the East China in summer because of resistance of the modern current system, i.e., a 'water barrier' and upwelling. Conversely, sediment delivery persists in winter and log(Ti/Ca) indicates the winter monsoon signal since the early Holocene. Our evidence also suggests that sediment from Taiwan Island could be transported by the Kuroshio Current to the middle Okinawa Trough, where it mingles with winter monsoon-induced export of sediment from the Changjiang River and East China Sea continental shelf. Although the present research advances understanding of the evolutionary history of paleoenvironmental change in the Okinawa Trough, more sediment cores should be retrieved over wide areas to construct a larger scenario. [ABSTRACT FROM AUTHOR]

The influence of hydrodynamics on the chemical composition of sediments is based on the uneven distribution of element abundances in different size fractions. In this study, 72 size-fractional sediments from the Huanghe (Yellow River) and Changjiang (Yangtze River) riverbeds were measured with XRD, SEM, ICP-AES and ICP-MS. The analysis results show that the mineral and chemical characteristics change with grain size in the Huanghe and Changjiang sediments. According to the principal components analysis, three independent geochemical factors were found. The first factor elements, Zr, Hf, Th, U, Y, La and TiO2 are influenced by the existence of heavy minerals. The second factor elements, Al2O3, alkalis, alkaline earth (excluding Ca and Sr) and most of the transitional metals are dominated by clay minerals. The third factor group includes Ca and Sr, which were controlled by calcium-bearing mineral contents and chemical weathering intensities. The various grain size distributions greatly affect the mineralogical and chemical compositions of bulk sediments. Compared to other size fractions, the 5-6PHI size fractions of the Huanghe and Changjiang sediments have special mineralogical and chemical compositions, and intermediate volume percentages. Weight or volume percentage of each size fraction may be more suitable than mean grain-size of the bulk sediment to elucidate the grain size effects. Chemical Index of Alteration (CIA) values increase steeply with decreasing grain size, while Weathering Index of Parker (WIP) values are relatively stable. Because of the big influence of the abundance of clay minerals on CIA values, it is questionable to use CIA as a proxy of weathering intensity. Considering the clay mineral effects, stability in values and heterogeneous material properties, WIP has the potential to indicate the chemical weathering intensity of sediments. Copyright © 2014 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

The South Yellow Sea (SYS) is strongly influenced by the substantial sediment loads of the Huanghe (Yellow) (including the modern Huanghe and abandoned old Huanghe subaqueous delta) and Changjiang (Yangtze) Rivers. However, the dispersal patterns of these sediments, especially in the western SYS, have not been clearly illustrated. In this study, we have analyzed clay minerals, detrital minerals, and grain sizes for 245 surface sediment samples (0-5 cm) collected from the western SYS. The clay minerals, on average, consist of 67% illite, 14% smectite, 11% chlorite, and 8% kaolinite. Clay minerals, detrital minerals, and grain size analyses of surface sediments, combined with water mass hydrology analysis, reveal that sediments in the western SYS are mainly derived from the modern Huanghe River, the abandoned subaqueous delta of the old Huanghe River, some material from the Changjiang, and coastal erosion. The clay minerals (especially illite and smectite) and quartz/feldspar ratio distribution patterns, reveal that the influence of modern Huanghe sediments can reach 35°N in the northwestern part of the study area, an influence that can be enhanced especially in winter owing to northerly winds. Conversely, sediments along the Jiangsu coast are mixed, in summer, with material from the Changjiang arriving via northward flow of Changjiang Diluted Water. The Subei Coastal Current carries the refreshed sediments northward into the western SYS. Sediment distribution and transport in the western SYS are mainly controlled by the oceanic circulation system that is primarily related to the monsoon. [ABSTRACT FROM AUTHOR]

This paper presents a paleoflood study to determine the flood frequency of the Changjiang River, based on core cj0702, taken from the Changjiang River subaqueous delta. We identified flood deposits by means of high-resolution grain-size variation, sensitive population, geochemical indexes and magnetic susceptibility. The core covers a time span of 120 years by Pb dating and was sampled at 1-2 cm intervals. Grain size, geochemical elements, and physical parameters were analyzed. The results indicate that the sediment of the core is mainly composed of silt and clay, as well as groups of interbedded silt, clay silt, and clay. Vertically, the grain size pattern was controlled by seasonal variations in water discharge and by the sediment input in winter from the abandoned Huanghe River delta. River flooding caused extreme values in all our measured parameters. We identified more than 20 flood events that occurred since 1887 using the physical parameter analysis method. The environmentally sensitive component of sediment grain size (14.32-96.39 μm) contribution>30%, Zr/Rb ratio>1.5, and magnetic susceptibility>16 were selected as the criteria for flood identification generally. We also found that floods that had taken place in the upstream, midstream, or downstream parts of the river were clearly identified by these indexes while the large-scale floods that covered the whole drainage area did not leave clear indications in the sediment record. This study for identification of flood events is of great significance for understanding hyperpycnal current sedimentation as well as for forecasting of floods. [ABSTRACT FROM AUTHOR]

To understand the provenance and evolution of eolian input in the last 1.95 Ma in the Parece Vela Basin in the eastern Philippine Sea, the clay mineral assemblage of a gravity core PV090510 from the basin was investigated using paleogeomagnetic dating and X-ray diffraction. The assemblage of the core mainly consisted of smectite (∼46%) and illite (∼40%), with some chlorite (∼10%) and kaolinite (∼4%). Analysis of the provenance of these minerals suggested that smectite was mainly derived from volcanic rocks of the Mariana Arc, while illite, chlorite, and kaolinite were mainly transported as eolian dust by the East Asian monsoon from central Asia. We used the ratio of (illite+chlorite+kaolinite)/smectite as a proxy for Asian eolian input to the Parece Vela Basin since 1.95 Ma. This ratio followed glacial and interglacial cycles and was consistent with the intensity of the East Asian monsoon and aridity of central Asia since 1.95 Ma. The changes of the ratio reflected three different stages of the East Asian monsoon and provenance climate. [ABSTRACT FROM AUTHOR]

Surface sediment and box core samples collected from the East China Sea (ECS) inner shelf mud area before and after Typhoon Talim (2017) were analyzed for grain size, chemical elements, and heavy metals (Cr, Ni, Cu, Zn, and Pb). By comparing the results of the survey in May with those in September, we distinguished the possible sources of heavy metals, assessed heavy metal contamination status, and elucidated the impacts of summer typhoons on the distribution of heavy metals. The results of the enrichment factor (EF) and geoaccumulation index (I geo) showed that Cr, Ni, Zn and Pb were mainly derived from natural sources, while Cu was partly influenced by anthropogenic activities and showed minor to moderate pollution. The difference between the minimum and maximum values of heavy metals became larger after the typhoon. The distribution of heavy metals in surface sediments was positively correlated with grain sizes of 11–18 μm, while the distribution in box cores was positively correlated with grain sizes of 0.8–12 μm. Additionally, the correlation between heavy metals (except Cu in box cores) and specific grain sizes increased after the typhoon passage. The thickness of the storm layer caused by Typhoon Talim was 16 cm, and the erosion depth was 4 cm. The stations with high and low values of the enrichment factor of typhoons (EF t) were separated from each other, indicating that heavy metal pollution increased at some stations and decreased at others after Typhoon Talim. The impact of typhoons on heavy metal pollution is related to seabed erosion and deposition. Summer typhoons can play a great role in the redistribution and burial of heavy metals, which is significant in the marine environment of the ECS. ● Grain size and heavy metals were analyzed before and after Typhoon Talim. ● Copper was partly influenced by anthropogenic activities. ● The thickness of the storm layer caused by Typhoon Talim was 16 cm. ● The typhoon impact on heavy metals was related to seabed erosion and deposition. [ABSTRACT FROM AUTHOR]

Abstract: Surficial grain-size and down-core clay mineralogical data show that sediment along the inner-most part of the continental shelf in East China Sea is mainly derived from the Yangtze River (Changjiang), spanning from the Yangtze mouth (33°N) ~1000km southward to the southwestern corner of the Taiwan Strait (24°N). High-resolution CHIRP seismic profiles reveal an elongated mud wedge extending along the inner shelf, with a northern depocenter on the modern Yangtze delta and a southern depocenter at 27.5°N. Four distinct acoustic units are delineated within the mud wedge (from bottom up): unit I (late-Pleistocene, mainly valley fills), unit II (formed by transgressions, thin strata), unit III (11–2kyr BP, downlapping strata) and unit IV (2–0kyr BP, flat and opaque strata). Incised valleys, up to 15-m deep, are filled by flat-lying or inclined strata in unit I. The thin (<3m) and acoustically transparent unit II is only seen between 30 and 26°N in water depths between 40 and 90m. Separated by acoustically opaque strata or unconformities, units III and IV are widely distributed. During the past 11kyr Yangtze sediment accumulation has been unsteady, showing two high and one low accumulation-rate periods. The high-accumulation period at 5–8kyr BP may be related to maximum East Asian summer monsoon precipitation in the Yangtze basin; the other high-accumulation period, 0–2kyr BP, probably reflects intensive human activities in the river''s watershed. The low-accumulation-rate period at 2–5kyr BP, which is seen in both northern and southern Yangtze depocenters, is probably related to low river discharge and/or intensified Taiwan Warm Current and China Coastal Current. [Copyright &y& Elsevier]

To decipher the sedimentary evolution and environmental changes since the late Last Deglaciation, two gravity cores were analyzed from the western North Yellow Sea (NYS). The two cores (B-L44 and B-U35) were sampled for grain size, clay minerals, detrital minerals, and C dating. They are comparable in lithofaies, and the observed succession was divided into four depositional units based on lithology and mineral assemblages, which recorded the postglacial transgression. Depositional unit 4 (DU 4) (before 11.5 ka) was characterized with enrichment in sand, and was interpreted as nearshore deposits in shallow water during the Younger Dryas Event. DU 3 (11.5-9.6 ka) displayed a fining-upward succession composed of sediments from local rivers, such as the Huanghe (Yellow) River, and from coastal erosion, which clearly were related to the Early Holocene transgression. Stable muddy deposition (DU 2) in NYS began to form at about 9.6 ka, which received direct supply of fine materials from the Shandong subaqueous clinoform. It is believed that the Yellow Sea circulation system played a major role in controlling the formation of fine sediment deposition in DU 1 (after 6.4 ka) after the sea level maximum. [ABSTRACT FROM AUTHOR]

Abstract: Changes in paleoenvironments over the last 17,500yr have been documented by a high-resolution clay mineralogy and grain–size records of Core KNG5 from the northern slope of the South China Sea. Our results indicate that clay minerals are mainly from the Pearl River from 17,500 to12,500calyr BP, and the South China Sea modern current system began to form since 12,500calyr BP, as a result, Taiwan turns to be the major contributor of clay minerals after 12,500calyr BP. Two grain-size populations with high variability through time were identified in the 13–28μm and 1–2.2μm grain-size intervals. The 1–2.2μm grain-size population are mainly controlled by provenance supply and current transport. The 13–28μm grain-size fraction could be controlled mainly by the sea-level change. The 1–2.2μm grain-size population record demonstrates that East Asian Summer Monsoon intensity generally follows changes in insolation and that the response is similar for a large area of China and other northern low-latitude records, implying the globality of the monsoon evolution since Holocene. The anomalous environmental conditions in the northern South China Sea may imply intensified ENSO activity during the late Holocene. [Copyright &y& Elsevier]

Abstract: Major and trace elements, loss on ignition (LOI), and grain-size distributions were determined on 190 surface sediment samples collected from the continental shelf, slope and the north Okinawa Trough in the East China Sea, at water depths of 100–200, 200–600 and more than 600m respectively. The sediments are composed mainly of sand and silt, generally low clay contents (average 10.5%), increasing over the range of 0.12–53.6% from the shelf and slope to the trough. Sediments were sandier on the continental shelf, particularly in the northern shelf sector. Spatial distributions in chemical compositions show that the contents of SiO2, CaO, Sr, and LOI values were relatively high on the sandy continental shelf. By contrast, the contents of Al2O3, MgO, Na2O, MnO, FeO, TiO2, Cu, Zn, Co, Ni and Cr were relatively high in the trough and along the central western shelf margin, where the sediments were composed mainly of silt. Fe2O3, P2O5 and Zr enrichment was highest in the slope sediments. Three factors were extracted by means of an R-mode factor analysis of chemical composition. Factor 1 has two inversely correlated elemental assemblages: (1) SiO2, K2O, TiO2, Al2O3 and Zr, which can be associated with terrigenous debris input and show high positive factor scores in the southern sector of the shelf; and (2) CaO, Sr, and LOI, which can be related with biogenic debris enrichment and show high negative factor scores in the northern shelf sector as well as in a more restricted area along the slope. CaO, SiO2, K2O and Sr represent the element assemblage of the shelf. Factor 2 comprises Na2O, FeO, Al2O3, TiO2, Cu, Zn and Ni, and shows high scores in the trough sediments. Na2O, Cu, Zn and Ni represent the elemental assemblage of the Okinawa Trough, and can be associated with volcanic matter. Factor 3 comprises Fe2O3, MgO, Cr and Co, with high factor scores on the slope and along the central western shelf margin of the study area, due to upwelling-induced enrichments in nutrients and biogenic shells. Fe2O3 and MgO are the slope elements. Based on the results of the distribution of the chemical compositions and the elemental assemblage of the surface sediment in the source-to-sink system, the influence of the Yellow River on the continental shelf is stronger than that of the Yangtze River. From the continental shelf and slope to the trough, the influence of the Yellow River decreased. From north to south in the Okinawa Trough, the sediment from the Yellow River decreases and from the Yangtze River increases, and the chemical compositions changed. [Copyright &y& Elsevier]

Abstract: Seismic profiles provide evidence that there has been strong transport by deep-water bottom currents and drift deposition on the northern slope of the South China Sea. Earlier geochemical studies suggest that the drift sediments originated primarily from Taiwan. However, the transport process, history and origin of the deep-water bottom deposition in the northern South China Sea, on both glacial–interglacial and tectonic time scales, remain unclear. Here, we show new high-resolution records of clay minerals, grain size and mass accumulation rate (MAR) of terrigenous materials from Ocean Drilling Program (ODP) Site 1144, together with trace element concentrations in siliciclastic sediments from ODP Site 1146. Combined with other published data, we find that the primary source for sediments at ODP Sites 1144–1148 since 3Ma is from Taiwan, and not from Pearl River as previously thought. Before 3Ma, however, sediment source to ODP Sites 1146 and 1148 was mainly from the Pearl River. Increased contribution of terrigenous supply from Taiwan to the northern South China Sea since ~3Ma may be related to the formation of the Taiwan orogen and strengthening of deep-water bottom current transport in the northern South China Sea. Variations in clay mineralogy and sedimentology at ODP Site 1144, located on a sediment drift, shows strong glacial–interglacial cyclicity. This suggests that bottom current deposition is highly dependent on sea-level fluctuations, which control the terrigenous supply to the deep sea. [ABSTRACT FROM AUTHOR]

Abstract: Samples of one core in the Bohai Sea mud area (BSMA) were analyzed in grain size, magnetic susceptibility (MS), major minerals, foraminifera, ostracod, stable isotopes, and 14C dating to reconstruct sedimentary environment and impact of the Yellow River sediments on deposition in the Bohai Sea during the last deglaciation. The central Bohai Sea was river mouth or swamp environment before 12.9ka BP, when sediments with low MS values had high sand content. Appearance of two peat layers at 11.2 and 12.9ka BP at Core M7-6 showed that seawater had not yet entered the central Bohai Sea, where the limnetic ostracod was frequently existed and foraminifera were hardly seen. Abundance and diversity of foraminifera began to increase sharply, while their oxygen and carbon isotopes became heavier from ∼9.3ka BP due to seawater entrance into the central Bohai Sea. Related to intrusion of the Yellow Sea Warm Current (YSWC) extension into the central Bohai Sea, oxygen and carbon isotopes reached the maximum at ∼6.5ka BP. MS values between 2.4 and 8.3ka BP increased continually together with slow sedimentation rate, revealing that the impact of the Yellow River sediments was limited because of strong hydrodynamic condition and small sediment discharge. At the last 2.4ka, the influence of the Yellow River reached the maximum due to large sediment discharge into the Bohai Sea. However, the BSMA had slow sedimentation rate compared with other mud areas in the Chinese marginal seas despite of its close distance from the Yellow River mouth, indicating that although the BSMA was the primary sink of the Yellow River sediments, most of the Yellow River sediments were deposited at other areas (e.g. deltaic areas and Shandong mud wedge). [Copyright &y& Elsevier]

The East China Sea (ECS) is susceptible to summer typhoons, which play an important role in sediment transport and reworking on the continental shelf. However, because observations during typhoon passage are difficult to carry out even at present, the influence of typhoons on sedimentary records in the ECS is not fully understood. In this study, we compared the elemental compositions and grain-size distributions of surface sediments collected before and after the passage of Typhoon Talim. Through end-member modeling algorithm (EMMA) analysis, the variations in sediment composition due to the typhoon passage were characterized, and the impacts of typhoons on sediment migration, redistribution and sedimentary records on the ECS continental shelf were elucidated. Comparison of the results revealed that after the passage of Typhoon Talim, the clay distributions were generally parallel to the coastline, the sand contents in the northeast and southeast of the study area decreased, and the sorting coefficient decreased in the inner shelf mud area and increased in the relict sand area. The three-end-member model was capable of adequately reproducing all variables, and the three end members were interpreted to be the fine-grained components of river terrigenous sediments (EM1), mixed sediments (EM2), and relict sands (EM3) according to the grain-size and chemical element composition characteristics of surface sediments. Summer typhoons can interrupt the cross-shelf transport of fine-grained sediments caused by cross-shelf penetrating fronts (CPFs) and can promote exchange between fine-grained sediments and relict sands on the ECS continental shelf. Thus, summer typhoons play a vital role in retaining the mud on the ECS inner shelf and redistributing the sediments on the ECS continental shelf. • Grain sizes of surface sediments were analyzed before and after Typhoon Talim. • Three grain-size end members were discerned by EMMA analysis. • The cross-shelf transport of sediments could be interrupted by summer typhoons. • Summer typhoons promoted the exchange of sediments on the ECS shelf. [ABSTRACT FROM AUTHOR]

The heavy mineral composition and sensitive grain size changes from core SS4 retrieved from the mud wedge on the East China Sea inner shelf have been studied for better understanding provenance variations in the sediment and climate changes during the last ~1500 yr. High dolomite content and occurrence of ubiquitous polysynthetic mica indicate that the sediments in core SS4 were mainly derived from the Yangtze River, while the relatively high epidote content represent the contribution of small local rivers from Zhejiang and Fujian provinces. The substantial decrease in the epidote/hornblende ratio since ~730 yr BP manifests a decline in the relative contribution of sediment from the small local rivers to the core. We propose that the changes in drought/flood conditions in response to the East Asian winter monsoon (EAWM) and human activities might have been mainly responsible for changes in sedimentary characteristics. During 1400–730 yr BP, the core sediments were characterized by relatively finer sensitive grain size and high epidote/hornblende ratio, due to a possibly weaker EAWM (i.e., less Yangtze River-derived sediment transported by the southward coast current). This time interval coincides with the Sui-Tang Warm Period (1400–1130 yr BP) in China and the Medieval Warm Period (1000–730 yr BP) on a broader regional scale. The prolonged warm periods were, however, interrupted by three short cold phases at 1350–1280 yr BP, 1130–1000 yr BP and 870–750 yr BP, characterized by coarse sensitive grain size and decreased epidote/hornblende ratio. Between 360 and 150 yr BP, the sensitive grain size significantly coarsened, which corresponded to the Little Ice Age. Our new findings suggest that sedimentation processes of mud wedge formation are responsive to natural environmental change and human activity. ∙ Provenance and climate changes have been detected in the East China Sea ∙Significant changes in the ratio of epidote/hornblende indicate source variations ∙The contribution of small local rivers has declined since 730 yr BP ∙Climate-driven drought/flood conditions and human activities are the main causes ∙The alternation of the warm and cold period is well recorded by heavy minerals [ABSTRACT FROM AUTHOR]

Abstract: Samples of two cores, Cores M5-5 and M7-4 in the Bohai Sea were analyzed in isotopes, grain size, heavy minerals, chemical compositions, and 14C dating to reconstruct the sedimentation during the Holocene. Abrupt change in carbon and oxygen stable isotopes was recognized at Core M5-5 at about 6400aBP, which was likely due to the intrusion of the Yellow Sea Warm Current (YSWC) extension into the Bohai Sea. At Core M7-4, sediments between 5900 and 6600aBP (150–260cm depth) became coarse-grained, containing rich garnet, high manganese content, and nil autogenic pyrite, indicating a very dynamic sedimentary event during which the ambience was transformed from reductive to oxidative, and sedimentation boosted. Meanwhile, the YSWC had invaded into the Bohai Sea indicated by rich planktonic foraminifera in this event. [Copyright &y& Elsevier]

Based upon analyses of grain-size, rare earth element (REE) compositions, elemental occurrence phases of REE, and U-series isotopic dating, the sediment characteristics and material sources of the study area were examined for the recently formed deep-sea clays in the eastern Philippine Sea. The analytical results are summarized as follows. (1) Low accumulation rate, poor sorting and roundness, and high contents of grains coarser than fine silt indicate relatively low sediment input, with localized material source without long distance transport. (2) The REE Contents are relatively high. Shale-normalized patterns of REE indicate weak enrichment in heavy REE (HREE), Ce-passive anomaly, and Eu-positive anomaly. (3) Elemental occurrence phases of REE between the sediments with and without crust are similar. REE mainly concentrate in residual phase and then in ferromanganese oxide phase. The light REE (LREE) enrichment, Ce-positive anomaly, and Eu-positive anomaly occur in residual phase. Ferromanganese oxide phase shows the characteristics of relatively high HREE content and Ce-passive anomaly. (4) There are differences in each above mentioned aspect between the sediments with and without ferromanganese crust. (5) Synthesizing the above characteristics and source discriminant analysis, the study sediments are deduced to mainly result from the alteration of local and nearby volcanic materials. Continental materials transported by wind and/or river (ocean) flows also have minor contributions. [ABSTRACT FROM AUTHOR]

Abstract: We here reconstruct the past change of the East Asian monsoon since 20 Ma using samples from Ocean Drilling Program (ODP) Site 1146 in the northern South China Sea based on a multi-proxy approach including a monomineralic quartz isolation procedure, identification of clay minerals by X-ray Diffraction (XRD) and grain-size analysis of isolated terrigenous materials. Terrigenous supply to ODP Site 1146 was dominated by changes in the strength of multiple sources and transport processes. Grain-size data modeled by an end-member modeling algorithm indicate that eolian dust from the arid Asian inland and fluvial input have contributed on average 20% and 80% of total terrigenous material to ODP Site 1146, respectively. Specifically, about 40–53% of the total (quartz+feldspar) and only 6–11% of the total clay is related to eolian supply at the study site. Detailed analysis of the sedimentary environment, and clay minerals combined with previous studies shows that smectite originates mainly from Luzon, kaolinite from the Pearl River and illite and chlorite from the Pearl River, Taiwan and/or the Yangtze River. The proportion and mass accumulation rate (MAR) of the coarsest end-member EM1 (interpreted as eolian dust), ratios of (illite+chlorite)/smectite, (quartz+feldspar)% and mean grain-size of terrigenous materials at ODP Site 1146 were adopted as proxies for East Asian monsoon evolution. The consistent variation of these independent proxies since 20 Ma shows three profound shifts in the intensity of East Asian winter monsoon relative to summer monsoon, as well as aridity of the Asian continent, occurred at ∼15 Ma, ∼8 Ma and the youngest at about 3 Ma. In comparison, the summer monsoon intensified contemporaneously with the winter monsoon at 3 Ma. The phased uplift of the Himalaya–Tibetan plateau may have played a significant role in strengthening the Asian monsoon at ∼15 Ma, 8 Ma and 3 Ma. [Copyright &y& Elsevier]

Abstract: 128 samples from Ocean Drilling Program (ODP) Site 1143 in the southern South China Sea were analyzed for grain size, clay minerals, biogenic opal content and quartz in order to reconstruct changes in East Asian monsoon climate since 8.5 Ma. An abrupt change of terrigenous mass accumulation rate (MAR), clay mineral assemblage, median grain size and biogenic opal MAR about 5.2 Ma suggests that between 8.5–5.2 Ma the source of terrigenous sediment was mainly in the region of surface uplift and basaltic volcanism in southern Vietnam. A simple model of East Asian summer monsoon evolution was based on the clay/feldspar ratio, kaolinite/chlorite ratio and biogenic opal MAR. The summer monsoon has two periods of maximum strength at 8.5–7.6 Ma and 7.1–6.2 Ma. Subsequently, there was a relatively stable period at 6.2–3.5 Ma, continued intensification about 3.5–2.5 Ma, and gradually weakening after 2.5 Ma. Since 1 Ma the monsoon has intensified, with remarkable high-frequency and amplitude variability. Simultaneous increase in sedimentation rates at ODP Sites 1143, 1146 and 1148, as well as in MAR of terrigenous materials, quartz, feldspar and clay minerals at ODP Site 1143 at 3.5–2.5 Ma, may be the erosional response to both global climatic deterioration and the strengthening of the East Asian summer monsoon after about 3–4 Ma. [Copyright &y& Elsevier]

Abstract: AMS14C dating and grain-size analysis for Core PC-6, located in the middle of a mud area on the inner shelf of the East China Sea (ECS), were used to rebuild the Holocene history of the East Asian winter monsoon (EAWM). The 7.5-m core recorded the history of environmental changes during the postglacial transgression. The core’s mud section (the upper 450 cm) has been formed mainly by suspended sediment delivered from the Yangtze River mouth by the ECS Winter Coastal Current (ECSWCC) since 7.6 kyr BP. Using a mathematical method called “grain size vs. standard deviation”, we can divide the Core PC-6’s grain-size distribution into two populations at about 28 μm. The fine population (<28 μm) is considered to be transported by the ECSWCC as suspended loads. Content of the fine population changes little and represents a stable sedimentary environment in accord with the present situation. Thus, variation of mean grain-size from the fine population would reflect the strength of ECSWCC, which is mainly controlled by the East Asian winter monsoon. Abrupt increasing mean grain size in the mud section is inferred to be transported by sudden strengthened ECSWCC, which was caused by the strengthened EAWM. Thus, the high resolution mean grain-size variation might serve as a proxy for reconstruction of the EAWM. A good correlation between sunspot change and the mean grain-size of suspended fine population suggests that one of the primary controls on centennial- to decadal-scale changes of the EAWM in the past 8 ka is the variations of sun irradiance, i.e., the EAWM will increase in intensity when the number of sunspots decreases. Spectral analyses of the mean grain-size time series of Core PC-6 show statistically significant periodicities centering on 2463, 1368, 128, 106, 100, 88-91, 76-78, and 70-72 years. The EAWM and the East Asian summer monsoon (EASM) agree with each other well on these cycles, and the East Asian Monsoon (EAM) and the Indian Monsoon also share in concurrent cycles in Holocene, which are in accord with the changes of the sun irradiance. [Copyright &y& Elsevier]

AMS14C dating and grain-size analysis for Core DD2, located at the north of the Yangtze River-derived mud off the Zhejiang-Fujian coasts in the inner shelf of the East China Sea, provide us a high-resolution grain-size distribution curve varying with depth and time. Data in the upper mud layer of Core DD2 indicate that there are at least 9 abrupt grain-size increasing in recent 2000 years, with each corresponding very well with the low-temperature events in Chinese history, which might result from the periodical strengthening of the East Asian Winter Monsoon (EAWM), including the first-revealed maximum temperature lowering event at around 990 a BP. At the same time, the finer grain size section in Core DD2 agrees well with the Sui-Tang Warming Period (600–1000 a AD) defined previously by Zhu Kezhen, during which the climate had a warm, cold and warm fluctuation, with a dominated cooling period of 750–850 a AD. The Little Ice Age (LIA) can also be identified in the core. It starts around 1450 a AD and was followed by a subsequent cooling events at 1510, 1670 and 1840 a AD. Timing of these cold events revealed here still needs to be further verified owing to some current uncertainty of dating we used in this study. [ABSTRACT FROM AUTHOR]

AMS14C dating and grain-size analysis for Core DD2, located at the north of the Yangtze River-derived mud off the Zhejiang-Fujian coasts in the inner shelf of the East China Sea, provide us a high-resolution grain-size distribution curve varying with depth and time. Data in the upper mud layer of Core DD2 indicate that there are at least 9 abrupt grain-size increasing in recent 2000 years, with each corresponding very well with the low-temperature events in Chinese history, which might result from the periodical strengthening of the East Asian Winter Monsoon (EAWM), including the first-revealed maximum temperature lowering event at around 990 a BP. At the same time, the finer grain size section in Core DD2 agrees well with the Sui-Tang Warming Period (600–1000 a AD) defined previously by Zhu Kezhen, during which the climate had a warm, cold and warm fluctuation, with a dominated cooling period of 750–850 a AD. The Little Ice Age (LIA) can also be identified in the core. It starts around 1450 a AD and was followed by a subsequent cooling events at 1510, 1670 and 1840 a AD. Timing of these cold events revealed here still needs to be further verified owing to some current uncertainty of dating we used in this study. [ABSTRACT FROM AUTHOR]

Both the East Asian winter monsoon (EAWM) and El Niño (EN) activities are vital climate modes that regulate the Pacific hydrologic cycle. However, the Holocene interactions among the EAWM, EN activities, and tropical Pacific precipitation remain unclear due to the lack of appropriate EAWM proxies. Here, we present high-resolution grain size records from the East China Sea shelf along with a transient climate model simulation to study the Holocene EAWM evolution and compare the findings with paleo-EN precipitation-related proxies records. The millennial-scale oscillations of grain size records, which are indicative of the intensity of the EAWM-driven coastal current, reveal an anti-phase coupling between the EAWM and EN-related tropical Pacific precipitation on a millennial timescale since 5.8 ka. These results, which are consistent with simulation results, indicate that the intensified EAWM could not only reduce equatorial western Pacific precipitation by reducing the sea surface temperature but also likely change boundary conditions in the tropical Pacific (i.e., the east-west Pacific temperature gradient and westerly anomaly) to favor the formation of subsequent intensive EN activities. The enhanced EN activities, inferred by the positive tropical eastern Pacific precipitation anomalies, could subsequently suppress the EAWM through anomalous low-level anticyclones and associated southerly anomalies, thereby generating intensified tropical western Pacific (mainly tropical monsoon areas) precipitation. Our study highlights these intrinsic interactions during the mid- to late Holocene and has useful implications for understanding this millennial-scale climate oscillation, which may represent periodic atmospheric exchange between high- and low-latitude climate systems by mediating the EAWM. • Holocene millennial-scale oscillation of the EAWM is recorded by grain size data. • Anti-phase interaction between EAWM and tropical Pacific rainfall since 5.8 ka. • The intensified EAWM could suppress the tropical Pacific precipitation. • The high El Niño activities enhance the western Pacific rainfall by weakening the EAWM. [ABSTRACT FROM AUTHOR]

[Display omitted] • Al/Si ratios can be used to correct CIA values to avoid the influence of grain-size sorting. • CIA values decreased during the YD, 8.2 ka, and 4.2 ka cold events during the Holocene. • Chemical weathering could be enhanced due to shelf exposure when the sea level is low. • Chemical weathering shelf sediments could rapidly respond to abrupt climate events. Chemical weathering of shelf sediments is important in driving the global elemental cycle and climate to maintain the earth's habitability. However, the response mechanism between chemical weathering of shelf sediments and climate and sea-level changes is still unclear. This study focuses on core ECMZ located in the mud area of the East China Sea (ECS) inner shelf. The results indicate that the mechanisms controlling chemical weathering in the sediment of the ECS inner shelf differ at different timescales. On the orbital time scale, the Chemical Index of Alteration (CIA) indicates that the intensity of chemical weathering in sediments during the deglacial period was significantly higher than that during the Holocene. This was caused by shelf exposure during low sea-level periods when the sediments were fully exposed and the residence time in the weathering zone was long, leading the shelf sediments to undergo consistent and complete weathering under supply-limited conditions. In comparison, during cold events on the millennium-centennial time scale, such as Younger Dryas, 8.2 ka, and 4.2 ka, chemical weathering was weaker (lower CIA values) due to accelerated erosion as a result of lower temperatures and higher precipitation, which shortened the rocks' residence in the weathering zone, resulting in the control of chemical weathering shifted from supply factors to kinetic ones, such as temperature and precipitation. Our findings suggest that on the orbital time scale, glacial shelf exposure could enhance chemical weathering, thereby reducing atmospheric CO 2 ; on the millennium-centennial time scale, chemical weathering could rapidly respond to abrupt climate events. [ABSTRACT FROM AUTHOR]

Studies a floating dust weather occurrence over the Qingdao region in China. Atmospheric dust concentration; Source and formation mechanism; Elemental comparison of the air-borne floating dust; Satellite photos of the cloud.

To better understand the depositional constraints on the sulfate reduction process, we present a set of sulfur isotope data for hand-picked pyrites (δ34S pyr) from the coarse fraction (63–250 μm) of bulk sediments, coupled with the contents of carbonate, total organic carbon (TOC) and nitrogen (TN), as well as δ13C values of the TOC, from sediments of core EC2005 on the inner shelf of the East China Sea (ECS) since 16.4 ka. Our results show that core sediments were deposited in a terrestrial environment before 13.1 ka (stage I) when pyrite rarely occurred. During stages II (13.1–12.3 ka) and III (12.3–12.1 ka) seawater began to influence the core location, forming a tidal flat environment where abundant pyrites are well preserved. Then the inner shelf of the ECS was fully flooded, and two intervals with high (stage IV:12.1–6.0 ka; stage VI: 5.2–1.5 ka) and low sedimentation rate (stage V: 6.0–5.2; stage VII: 1.5 ka-present) are identified respectively. When compared with previous δ34S values of chromium-reducible sulfur (δ34S CRS) derived from the bulk sediments, δ34S pyr values are usually higher, indicating the macroscopic pyrites form in the later stages of sedimentary diagenesis when ongoing sulfate reduction has distilled porewater sulfate to a high degree. Considering the wide occurrence of biogenic shallow gas (dominated by CH 4) in these sediments, sulfate-driven anaerobic oxidation of methane (SO 4 -AOM) and organoclastic sulfate reduction (OSR) are expected to be two competitive pathways for sulfate reduction. We propose that the changes in sedimentation rate controls the pace of migration of the sulfate methane transition zone (SMTZ). When sedimentation rate is low, the SMTZ may be fixed in a certain depth (e.g., sediments deposited in stage III and V), where H 2 S is produced by SO 4 -AOM. In contrast, when sedimentation rate is very high (> 1 cm/yr), the SMTZ would be deep, and H 2 S is mostly produced by OSR. Further, our results imply that sulfur diagenesis in recent (since 1.5 ka) ECS mud sediments might be influenced by physical reworking (e.g., typhoon) and/or biological activity (bioturbation), resulting in partial reoxidation of pyrite crystals in fluid mud. Our findings therefore demonstrate that pyrite sulfur isotope compositions (bulk δ34S CRS & hand-picked δ34S pyr) are sensitive to local environmental evolution and the combined use of these two indicators can provide new insights into pathway of sulfate reduction in unsteady environments. • Constructing the depositional evolution of the East China Sea since16.4 ka. • Extreme pyrite sulfur isotopic fluctuation regulated by sedimentation rate. • Sulfur isotope of coarse pyrite is heavier than that of bulk sediments (CRS). • Sulfate reduction (OSR vs. AOM) is controlled by the pace of SMTZ migration. [ABSTRACT FROM AUTHOR]

The climate response of tropical Southeast Asia to abrupt climate change originating from high northern latitudes remains poorly understood. Here, marine sediments recovered from the Northwest Borneo Trough are analyzed to trace variations in terrigenous material composition associated with sea level and palaeoflood activities over the past 40 ka. We describe for the first time the influence of sea level change on terrigenous deposition from a tropical island with small mountainous rivers surrounded by narrow continental shelves and the coupling between North Atlantic dynamics and climate feedbacks in tropical Southeast Asia during the Dansgaard‐Oeschger stadials. This study demonstrates that climate oscillations occurring at high northern latitudes can be transmitted to tropical Southeast Asia through the functions of sea level, the East Asian winter monsoon and the Intertropical Convergence Zone. Such information is fundamental to correctly assessing future sea level rise and flood risks in tropical Southeast Asia. Plain Language Summary: Sea level rise and extreme climate events are two global climate issues currently faced by humanity under the background of global warming. However, the climate feedbacks in tropical Southeast Asia remain unknown, although portions of this region are now densely populated. Here, a gravity core retrieved from the Northwest (NW) Borneo Trough is employed to reveal variations in terrigenous material composition and their controlling factors over the past 40 ka. We found that the terrigenous sediments delivered to the NW Borneo Trough are primarily sourced from NW Borneo, and their deposition is mainly controlled by sea level change and flooding. Further in‐depth analysis reveals that northern high‐latitude cooling could cause floods in NW Borneo both in the modern and during the past by influencing the East Asian winter monsoon (EAWM) and/or the Intertropical Convergence Zone (ITCZ). Furthermore, our new records suggest that a stronger EAWM during cold stadials could have transported high levels of northerly moisture to NW Borneo, resulting in relatively higher speleothem δ18O values in NW Borneo. In short, abrupt climate changes in the high‐latitude Northern Hemisphere can be transmitted to tropical Southeast Asia through the functions of sea level, the EAWM and the ITCZ. Key Points: Sea level change and flooding are the main controlling factors for terrigenous deposition from tropical Southeast AsiaNorthern high‐latitude cooling could lead to the outbreak of floods in Northwest Borneo via atmospheric teleconnectionClimate oscillations occurring at high northern latitudes can be transmitted to tropical Southeast Asia [ABSTRACT FROM AUTHOR]

Recent research has suggested that East Asia has experienced a prevailing monsoon climate since the Eocene. However, there is little knowledge about the development of the East Asian monsoon system before the Miocene, particularly in southern China, due to a lack of well‐dated continuous sediment records. Here, we present new magnetic proxy records from International Ocean Discovery Program Site U1501 in the northern South China Sea. We conducted rock magnetic experiments, made scanning electron microscopy observations and performed diffuse reflectance spectrum analysis on the late Eocene‐early Oligocene core sediments. The magnetic signal of the sediments is dominated by detrital magnetite and titanomagnetite formed during the silicate weathering and erosion processes, which were used to infer the evolution of summer monsoon precipitation in southern China. Our results along with geochemical and clay mineral data from Site U1501 strongly indicate that the East Asian summer monsoon generally weakened across the Eocene‐Oligocene transition. This change was linked to coeval global cooling rather than tectonic processes. Prior to the Eocene‐Oligocene transition, the summer monsoon intensified, likely due to the latest Eocene warming event caused by the enhancement of the Atlantic Meridional Overturning Circulation, which may have preconditioned the Earth system for the greenhouse‐to‐icehouse transition. Plain Language Summary: To date, there is little knowledge regarding the long‐term evolution of monsoon climate in South China before the Miocene due to a lack of well‐dated continuous sediment records. The recent International Ocean Discovery Program Expedition 368 retrieved continuous late Eocene‐early Oligocene sediments at Site U1501 within the northern South China Sea, thus providing an opportunity to fill this gap. In this study, we investigate the evolution of the East Asian summer monsoon in South China during the late Eocene‐early Oligocene through a comprehensive analysis of the magnetic properties of the sediments. The results strongly indicate that the summer monsoon generally weakened across the Eocene‐Oligocene transition, which was linked to coeval global cooling. A short‐term strengthening of the summer monsoon prior to the Eocene‐Oligocene transition was also recorded. This change is attributed to the warming caused by the latest Eocene strengthening of the Atlantic Meridional Overturning Circulation, which may have preconditioned the Earth system state before causing a transition into an icehouse Earth. Key Points: The environmental magnetic record in the northern South China Sea indicates monsoon evolution during the late Eocene to early OligoceneThe East Asian summer monsoon weakened across the Eocene‐Oligocene transitionGlobal cooling drove the long‐term weakening of East Asian summer monsoon [ABSTRACT FROM AUTHOR]

Quaternary East Asian winter monsoon (EAWM) evolution has long been attributed to high‐latitude Northern Hemisphere climate change. However, it cannot explain the distinct relationships of the EAWM in the northern and southern East Asian marginal sea in paleoclimatic records. Here we present an EAWM record of the northern East China Sea over the past 300 ka and a transient climate simulation with the Kiel Climate Model through the Holocene. Both proxy record and simulation suggest anticorrelated long‐term EAWM evolution between the northern East China Sea and the South China Sea. We suggest that this spatial discrepancy of EAWM can be interpreted as El Niño–Southern Oscillation (ENSO)‐like controlling, which generates cyclonic/anticyclonic wind anomalies in the northern/southern East Asian marginal sea. This research explains much of the controversy in nonorbital scale variability of Quaternary EAWM records in the East Asian marginal sea and supports a potent role of tropical forcing in East Asian winter climate change. Plain Language Summary: The modern East Asian winter monsoon (EAWM) is influenced by the combined effects of both the high‐latitude Northern Hemisphere (e.g., Siberian High) and the low‐latitude Western Pacific (e.g., El Niño–Southern Oscillation) and plays a major role in regulating atmospheric energy of East Asia and even the Northern Hemisphere. Its anomalies may cause extremely cold/warm winter weather or climate events, which result in profound societal and economic influences on the densely populated region of East Asia. Especially, some studies found the EAWM displays spatial discrepancies in northern and southern East Asia and can result in a colder/warmer north corresponding to a warmer/colder south. Our study shows anticorrelations of EAWM evolution between the northern East Asian marginal sea and the South China Sea since the late Quaternary. We suggest that such spatial discrepancies of EAWM evolution were controlled by El Niño–Southern Oscillation‐like processes in the tropical Pacific. During El Niño‐like conditions, the anomalous northwesterlies in the northern East Asian marginal sea led to a strengthened EAWM in this region. In contrast, anomalous southwesterlies in the South China Sea favored the occurrence of a weakened EAWM. The opposite situation occurred under La Niña‐like conditions. Key Points: Clay minerals in northern Okinawa Trough were derived from Yellow River and KyushuReversed EAWM evolution in the northern and southern East Asian marginal sea was revealedENSO‐like processes cause spatial discrepancy of Quaternary EAWM evolution [ABSTRACT FROM AUTHOR]

Abstract Isotopic compositions of coeval sulfide and sulfate have been widely employed to reconstruct the seawater chemistry evolution over geologic time; however, these signals can be modulated by other factors, such as the sedimentation rate. Here, we present a data set of pyrite sulfur isotopes (δ34S py) derived from 60-m drilled core sediments deposited on the inner shelf of the East China Sea since 16.5 ka. The resulting δ34S py values range from −38.2 to 15.0‰ (Vienna Canyon Diablo Troilite; V-CDT), representing a range of 53.2‰. Freshwater deposition before 12.3 ka produced a limited pyrite abundance and δ34S py values that fall within the typical range of freshwater environments. After the marine incursion in the study area at 12.3 ka, variations in the δ34S py values become significantly correlated with sedimentation rates (SRs; r = 0.78, p < 0.01), which were controlled by the intensity of coastal currents in response to the East Asian winter monsoon. Specifically, pyrite sulfur is markedly depleted in 34S during the intervals with low SRs (δ34S py < −30‰) relative to that observed during the intervals with high SRs (δ34S py > 0‰), suggesting that SRs exert controls on δ34S py values. We propose that these sedimentary controls are expressed by modulating the connectivity between porewaters and the overlying seawater. Low SRs tend to form an open diagenetic system, in which the pyrites are able to preserve the large biological fractionations associated with microbial sulfate reduction (and disproportionation). In contrast, high SRs favour a restricted diagenetic system, in which the distillation of porewater sulfate produces pyrites enriched in 34S, masking the magnitude of biological fractionation during microbial sulfur cycling. These findings highlight the critical effect of the local sedimentation regime on pyrite sulfur isotopic compositions, especially within shallow depositional environments, over geologic time. [ABSTRACT FROM AUTHOR]

As the second largest dust source on the globe, the tectonic and climatic evolution of continental Asia has an important impact on regional and global climate change. The West Pacific is the main sediment sink for eolian dust transported eastward from the Asian interior. Clay minerals, as the major fine-grained weathering products of continental rocks, can be readily transported by wind or currents over long distances and thus have been widely used in the reconstruction of paleoclimate and weathering history. However, the overall evolutionary tendency and response mechanism of clay mineral records over large spatial and long timescales across Asia remain unclear. Here, two continuous and high-resolution clay mineral records since 30 Ma were reconstructed from sediments at Deep Sea Drilling Program (DSDP) Sites 292 and 296 in the Philippine Sea. Clay minerals and Sr-Nd isotope compositions were used to constrain provenance and reconstruct the drying history of the dust source region since the Oligocene. The results show that the clay-sized detrital sediments in the Philippine Sea are a mixture of Asian eolian dust and volcanic materials from the West Pacific arcs. Based on the clay mineral compositions and eolian flux, we reveal that the Asian interior has been continuously drying since the late Oligocene and that stepwise enhanced aridification occurred at approximately 20, 14, 7, and 3 Ma. Compared with other regions of the world, the relative contents of illite and chlorite increased more dramatically in Asia during the late Cenozoic, and the inconsistency became more obvious at approximately 20 Ma. Since 3 Ma, illite and chlorite have increased consistently across the globe. Combined with the Asian tectonic and climatic history, we suggest that the increase in illite and chlorite from Asia between 20 and 3 Ma was mainly in response to the uplift of the Himalayan-Tibetan Plateau, whereas after 3 Ma, it was primarily controlled by global cooling driven by the expansion of the Arctic ice sheet. [ABSTRACT FROM AUTHOR]

Enhanced silicate weathering induced by the uplift of the Himalayan-Tibetan Plateau (HTP) has been considered as the major cause of p CO 2 decline and Cenozoic cooling. However, this hypothesis remains to be validated, largely due to the lack of a reliable reconstruction of the HTP weathering flux. Here, we present a 37-million-year record of the difference in the seawater radiogenic neodymium isotopic composition (Δ ε Nd) of Ocean Drilling Program (ODP) sites and Fe-Mn crusts between the northern and central Indian Ocean, which indicates the contribution of regional weathering input from the South Asian continent to the Indian Ocean. The results show a long-term increase in Δ ε Nd and thus provide the first critical evidence of enhanced South Asian weathering input since the late Eocene. The evolution coincided well with major pulses of surface uplift in the HTP and global climatic transitions. Our foraminiferal ε Nd record suggests that tectonic uplift and silicate weathering in South Asia, especially in the Himalayas, might have played a significant role in the late Cenozoic cooling. [ABSTRACT FROM AUTHOR]

Sedimentary pyrite and the ratio between organic carbon and pyrite sulfur (C/S ratio) have been widely used as paleosalinity indicators to distinguish between marine and freshwater environments. However, in unsteady marine environments with strong physical reworking, the formation of pyrite is limited, leading to a high C/S ratio, as is the case in freshwater environments; thus, whether C/S ratios can identify unsteady marine environments in sedimentary strata is still a controversial topic. To calculate the availability of these classic indicators in unsteady environments, we analysed multiple indicators of core sediments obtained from the inner shelf of the East China Sea. Our results show that there are no pyrite aggregates in the sediments deposited under terrestrial conditions before 13.1 ka. During this period, the C/S ratios are higher than 2.8, representing the characteristics of sediment deposited in freshwater environments, which is also supported by low Sr/Ba ratios. When the core site was initially affected by seawater intrusion at approximately 13.1 ka, pyrite aggregates appeared for the first time, accompanied by a rapid decrease in C/S ratios, indicating a brackish tidal flat environment. We find that the C/S ratio overlaps between tidal flat and inner shelf environments, but the relatively high content of pyrite aggregates and fine-grained sediments in the shelf sediments can effectively separate these two environments. Our results further reveal that the mud depocentre initially developed at approximately 7.5 ka when the sea level reached its highstand. These new findings suggest that geochemical indicators should always be used in conjunction with sedimentary and paleoecological evidence to prevent biased conclusions. • Revisiting the depositional evolution history of the East China Sea inner shelf. • C/S ratios and formed pyrites indicate the timing of initial marine transgression. • Abundant sedimentary pyrites in sediments indicate sea-level highstand at 7.5 ka. • C/S ratio should be carefully used with other sedimentary and ecological parameters. [ABSTRACT FROM AUTHOR]

Despite the importance of the westerlies to the global climate system, we still know little about their long‐term evolution and possible orographic controls during the late Cenozoic because of the lack of sedimentary records with precise chronological control. Eolian deposition in the North Pacific preserved past information about the westerlies, the major wind system delivering Asian dust to the Pacific. A continuous, high‐resolution eolian flux record since 23 Ma was reconstructed from sediments at Deep Sea Drilling Project Site 296 in the North Pacific. Combined with dust flux at Ocean Drilling Program Site 1208, variations in their difference indicated a northwards shift of the westerlies during 23‒9 Ma and a relatively stable state since then. We suggest that Tibetan uplift since the early Miocene began to drive the poleward shift of the westerlies until 9 Ma, after which the westerlies remained relatively stable over Asia on million‐year timescales. Plain Language Summary: The Northern Hemisphere Westerly wind is a significant component of planetary‐scale atmospheric circulation and has a large impact on regional and global climate change. Although numerous modern observations and orbital time‐scale studies of the Westerly wind have been conducted, we still know little about its evolution on million‐year time‐scales, which may modulate the overall amplitude of short‐term variations. Eolian deposition in the North Pacific has preserved precious information about the westerlies in the past. A continuous and high resolution eolian flux record dating from 23 Ma was reconstructed from sediments at Deep Sea Drilling Project Site 296 in the Northwest Pacific. Combined with dust records at Ocean Drilling Program Site 1208 to the east, we constrain how the path and strength of the Northern Hemisphere Westerlies have changed since the early Miocene. The two eolian records indicate a northwards shift of the westerlies between 23 and 9 Ma and a relatively stable state since then. We suggest that stepwise uplift of the Tibetan Plateau since at least the early Miocene began to drive the northwards shift of the Northern Hemisphere Westerlies until about 9 Ma, after which the westerlies remained relatively stable over Asia‐North Pacific on million‐year timescales. Key Points: We reconstruct the eolian flux record in the North Pacific since 23 Ma at high resolutionThe Northern Hemisphere Westerlies shifted northward between 23 and 9 Ma and have remained relatively stable since thenTibetan uplift drove the northward shift of Northern Hemisphere Westerlies in the early late Miocene [ABSTRACT FROM AUTHOR]

Human modifications of the Earth System have been getting increasing attention and this has resulted in the concept of the "Anthropocene". A complete sequence of human-environment interactions needs to be reconstructed to define the onset of the Anthropocene. To address the chronological gaps and provide a general history of human impact in South China during the Holocene, we present a comprehensive reconstruction of the vegetation, chemical weathering, and heavy metal emissions in the Pearl River and Hainan catchments since 7.0 cal ka BP, using a continuous record of black carbon, clay minerals, and major and trace element concentrations of sediment in Core ZK001 taken from the northwestern South China Sea. Based on high-resolution sediment records, combined with archaeological and historical documents, we propose that human impact in South China can be divided into three stages: a hunting-gathering age (7.0–2.9 cal ka BP), a transitional period (2.9–2.0 cal ka BP) and an intensive farming age (<2.0 cal ka BP). Climate controlled both the vegetation and chemical weathering intensity before 2.9 cal ka BP, after which forest clearance by human-induced fire became significant. Along with population growth and technological progress, enhanced human activities including deforestation, cultivation, and metallurgical activities, gradually superseded natural processes and profoundly impacted the environment in South China, especially after 2.0 cal ka BP. Combined with previous studies from the Pearl River catchment, the Anthropocene likely commenced at 2−3 cal ka BP at least in South China. • We present a comprehensive history of human-environment interactions in South China over the past 7 k.y.. • Anthropogenic impacts superseded the natural control on vegetation, weathering, and heavy metal emissions since 2.9 ka BP. • The start of the Anthropocene in South China might be at 2–3 ka BP. [ABSTRACT FROM AUTHOR]

[Display omitted] [ABSTRACT FROM AUTHOR]

The timing of tectonic uplift in the Himalayan orogen, the highest mountain range on the Earth, remains controversial due to a lack of long-term continuous records. Here, we provide a long-term marine sediment record from Ocean Drilling Program (ODP) Site 758 in the southern Bay of Bengal (BoB) since 37 Ma, as well as the stacked terrigenous flux of the BoB since the Oligocene, to constrain sediment provenance variation since the late Eocene. The provenance results indicate that the sediment supply to the study site has become dominated by the Himalayan rivers (Ganges, Brahmaputra and Irrawaddy) since the early Miocene (∼23 Ma). We also present a Nd Pb isotope mixing model combined with Monte-Carlo simulations to quantify the contributions of Himalayan rivers to ODP Site 758 sediments since 24 Ma. The simulations indicate that the Ganges, Brahmaputra and Irrawaddy rivers successively became the main sources of sediments in the southern BoB from the early to late Miocene. Our quantitative provenance analysis, combined with evidence of paleogeographic evolution of the Himalayas, suggest that the major uplift of the Himalayan orogen might have occurred no earlier than the Miocene. Furthermore, tectonic activity in the Himalayas persisted during the Miocene, with progressive west-to-east deformation, and the eventual formation of a mountain range resembling modern elevations by the late Miocene. • Himalayan rivers dominated the terrigenous input to the Southern Bay of Bengal since the early Miocene. • The Nd‒Pb isotope mixing model combined with Monte-Carlo simulations is a powerful quantitative method for measuring sediment source contributions. • The Ganges, Brahmaputra and the Irrawaddy rivers were the main sediment suppliers to ODP Site 758 in succession since the early to late Miocene. • The major and rapid uplift stage of the Himalayan orogen might have occurred during the early Miocene (∼23 Ma). • The Himalayan orogen might have undergone progressive west-to-east deformation during the Miocene. [ABSTRACT FROM AUTHOR]

Marine authigenic pyrite sulfur isotope (δ34S pyr) is one of the most important proxies for reconstructing remarkable changes of Earth's surface in deep time. Recent observations of unexpectedly large δ34S pyr variations in Quaternary sediments complicate the application of this isotopic proxy, and a mechanistic understanding of such variabilities is needed. In this study, we measured multiple sulfur isotopic compositions of pyrite in well dated sediments spanning the last 7500 years from the East China Sea (ECS) inner shelf to study the mechanism how Holocene climate controls pyrite sulfur isotopic compositions. We found that variabilities of pyrite multiple sulfur isotopes, δ34S pyr and Δ33S pyr (ranging from −38.3‰ to 2.3‰ and from −0.01‰ to 0.21‰, respectively) are significantly correlated with large fluctuations of sedimentation rates (0.03–2.09 cm/yr). In tandem with box model calculations and compiled data, the large δ34S pyr variations up to 40‰ are primarily ascribed to fluctuated anaerobic oxidation of methane coupled sulfate reduction (AOM-SR). Further analyses suggest that heightened distillation of interstitial sulfate, likely propelled by high methane flux coupled with increased sedimentation rates, can produce such negatively correlated δ34S pyr -Δ33S pyr pattern and large variations in δ34S pyr. Possible changes in isotope fractionation factors caused by varied cell-specific sulfate reduction rates result in a maximum δ34S pyr variation of <20‰ and therefore play a minor role in the large variation in δ34S pyr (>40‰). The major and minor isotopic compositions of pyrite align with sulfide produced through pure sulfate reduction, indicating little evidence of additional oxidative sulfur cycling. Sedimentation rates in the ECS are controlled by the East Asian winter monsoon that influences the sediment transport capacity from longshore currents on a multicentennial timescale, and also by the coupled East Asian summer monsoon that affects the sediment availability from the Yangtze River on a millennial timescale. Holocene climate changes alter sediment supplies at the ECS and therefore play a vital role in controlling multiple sulfur isotope compositions of sedimentary pyrite in this region. This study has the potential to provide new insights into δ34S excursions in seawater sulfate that occurred during periods of notable acceleration in sedimentation rates throughout the geological history. • ∼40‰ and 0.22‰ variations in δ34S and Δ33S of pyrite were observed in Holocene sediments. • AOM-SR account for the large sulfur isotope variations. • AOM-SR were dominated by sedimentation rate. • Climate changes regulate sulfur isotopes depending on sedimentation rate. [ABSTRACT FROM AUTHOR]

Abstract: X-ray diffraction (XRD) mineralogical and grain-size analyses indicate that inner continental shelf sediments in the East China Sea (ECS) represent a unique mixing of clays derived from the Yangtze River and silts/sands from small western Taiwanese rivers. Taiwanese (e.g., Choshui) clays (<2μm) display no smectite but the best illite crystallinity and are only distributed along southeastern Taiwan Strait. Both Yangtze and Taiwanese river clays are illite-dominated, but the poor illite crystallinity and the presence of smectite and kaolinite indicate that Taiwan Strait clays are mainly Yangtze-dominated. In contrast, medium silts (20–35μm) and very fine sands (63–90μm) in the Taiwan Strait are characterized by low feldspar/quartz, low K-feldspar/plagioclase and high kaolinite/quartz, indicating their provenance from Taiwanese rivers. Taiwanese silts and sands are introduced primarily by the way of typhoon-derived floods and transported northward by the Taiwan Warm Current during summer–fall months. Yangtze clays, in contrast, are widely dispersed southward about 1000km to the western Taiwan Strait, transported by the China Coastal Current during winter–spring months. Since most Taiwan Strait samples were collected in May 2006, clay results in this paper might only represent the winter–spring pattern of the dispersal of Yangtze sediments. [Copyright &y& Elsevier]

As a high-sedimentation rate depocenter along the path of the Kuroshio Current, the southwesternmost part of the Okinawa Trough is a key area to understand the Kuroshio history and sediments transportation. A 34.17-m-long sediment core was obtained by the advanced piston corer of Marco Polo/IMAGES XII MARION DUFRESNE during the May 2005 from the Southern Okinawa Trough at site MD05-2908. The recovered sediments were analyzed by AMS 14C dating, coarse size fraction (>63 pm) extraction and moisture content determination in order to study its sedimentation flux and provenance. The depth-age relationship of core MD05-2908 was well constrained by 17 14C dating points. The sediments span across the mid-Holocene (6.8 ka B.P.) and have remarkablely high sedimentation rates between 1.8 and 21.2 m ka-1, which is well consistent with the modern observations from sediment traps. We identified five 70-200 a periods of abnormally rapid sedimentation events at 6790-6600 a B.P., 5690-5600 a B.P., 4820-4720 a B.P., 1090-880 a B.P., and 260-190 a B.P., during which the highest sedimentation rate is up to 21.2 m/ka. In general, the lithology of the sediments were dominated by silt and clay, associated with less than 5% coarse size fraction (>63 pm). As the most significant sediment source, the Lanyang River in northeastern Taiwan annually deliver about 10Mt materials to the coastal and offshore region of northeast Taiwan, a portion of which could be carried northward by currents toward the study area. Therefore, we concluded that the 5 abnormally rapid sedimentation events may be related to intensified rainfall in Taiwan and thus increased materials to our study area at that time. However, a few extreme-rapid sedimentation events cannot be explained by normal river runoff alone. The large earth-quakes or typhoons induced hyperpycnal discharge of fluvial sediment to the ocean may also act as a potential source supply to the Okinawa Trough. [ABSTRACT FROM AUTHOR]

Carbon and sulfur preserved in estuary and shelf sediments play a critical role in controlling sediment diagenesis related to the global biogeochemical cycle. Their ratio (C/S = 2.8) in mud sediments has been widely used to distinguish freshwater from marine environments; however, this ratio can be influenced by depositional evolution, physical reworking, and other sedimentological parameters. We present a new C/S ratio data set from surface sediments of five rivers (Aojiang, Feiyunjiang, Jiaojiang, Oujiang, and Qiantangjiang Rivers), as well as core sediments offshore of the Oujiang Estuary (core EC2005, 60 m), to discuss how the evolution of the depositional environment influenced carbon and sulfur preservation since the last deglaciation. To this aim, we measured the contents of total organic carbon (TOC), total sulfur (TS), and carbonate in the collected samples. Our results demonstrate that a C/S ratio of 2.8 can effectively separate freshwater environments (river sediments and core sediments deposited before 13.1 ka), suggesting the initial impact of sulfate-enriched seawater on carbon and sulfur perseveration at ~13.1 ka. However, the TS content is independent of the TOC content after 13.1 ka, implying that pyrite sulfur is derived not only from organoclastic sulfate reduction (OSR) but also from sulfate-driven anaerobic oxidation of methane (AOM) under anoxic diagenetic conditions. In the shallowest core section (shallower than 5 m; < 1.5 ka), the C/S ratios gradually increase from 1 to 2.8, which corresponds to an interval with sulfide reoxidation under suboxic conditions caused by strong physical reworking. When the sediment is buried to a certain depth (deeper than 5 m; > 1.5 ka), a high sedimentation rate is conducive to an AOM reaction, resulting in the generation of a large amount of pyrite and finally causing the minimum value of the C/S ratio to be approximately 1. However, during the transitional period of 13.1–11.0 ka, sediments deposited in the tidal environment show overlap with those deposited in the marine shelf environment, and C/S ratios decrease from >10 to ~1. In addition, we propose that C/S and C/N ratios could be combined to reveal the depositional evolution from terrestrial to marine environments, which is sensitive to sea level and climatic changes. Therefore, our new findings suggest that the sedimentation process can modulate the diagenetic path of mud sediments (e.g., OSR versus AOM), and geochemical indicators of environmental evolution should be carefully used in combination with sedimentological parameters in shallow depositional environments. • We present a set of C/S data record from the East China See inner shelf since 16 ka. • C/S ratios could effectively distinguish between marine and freshwater environments. • The sedimentary process could affect the diagenetic process of authigenic pyrite. • C/S and C/N ratios could indicate the evolution of sedimentary environment. [ABSTRACT FROM AUTHOR]

Carbon release from the North Pacific in glacial‐interglacial cycles has been mainly linked to the North Pacific Intermediate Water (NPIW) formation and associated carbon/nutrient water upwelling and biological productivity changes. However, relationship between NPIW and atmospheric CO2 change in the early interglacial remains unclear. Here we report a high‐resolution sediment record of NPIW evolution based on paleo‐redox changes in the Western North Pacific during the last 400 ka. Our proxy and model results reveal a delayed collapse of NPIW after the glacial termination was coeval with decreased salinity of intermediate water and increased net rainfall in the North Pacific. Such weakened NPIW formation in the North Pacific probably make a contribution to maintain high atmospheric CO2 concentrations through weakened intermediate‐to‐deep ocean stratification and reduced subsurface biological pump net efficiency, countering the return to more stratified conditions in the Southern Ocean, which should drive down atmospheric CO2 during the early interglacial. Plain Language Summary: The high‐latitude North Pacific is an important region where ocean interacts with the atmospheric carbon cycle. CO2 outgassing from the interior ocean of North Pacific to the surface is mainly controlled by the upwelling as well as the biological productivity determined by the NPIW formation. Relationship between changes in the NPIW and atmospheric CO2 in the early interglacial remains unclear. Here we reconstructed the NPIW evolution during the last 400 ka, and combined with climate model results, we found a delayed collapse of NPIW compared with the Southern Ocean deglacial warming, which was synchronous with the decreased seawater salinity in response to increased net rainfall in the North Pacific. This NPIW collapse after glacial termination should weaken the intermediate‐to‐deep ocean stratification, and thus favored the upwelling of nutrient/carbon‐rich deep water to the surface. Besides, combined with the decreased nutrient‐poor subtropical waters supply from the weakened Pacific meridional overturning circulation, the biological pump net efficiency was reduced and thus consumed less CO2. These would counter the return to more stratified conditions in the Southern Ocean, which should drive down atmospheric CO2 during the early interglacial, and thus probably make a contribution to maintain high atmospheric CO2 concentration during the early interglacial. Key Points: NPIW evolution during the last 400 ka was reconstructed based on the paleo‐redox changes in the northern Okinawa TroughPrecessional changes of NPIW formation were mainly forced by the net rainfall in the North PacificDelayed collapse of NPIW probably contributed to maintain high atmospheric CO2 concentrations during the early interglacial [ABSTRACT FROM AUTHOR]

Carbon release from the North Pacific in glacial‐interglacial cycles has been mainly linked to the North Pacific Intermediate Water (NPIW) formation and associated carbon/nutrient water upwelling and biological productivity changes. However, relationship between NPIW and atmospheric CO2 change in the early interglacial remains unclear. Here we report a high‐resolution sediment record of NPIW evolution based on paleo‐redox changes in the Western North Pacific during the last 400 ka. Our proxy and model results reveal a delayed collapse of NPIW after the glacial termination was coeval with decreased salinity of intermediate water and increased net rainfall in the North Pacific. Such weakened NPIW formation in the North Pacific probably make a contribution to maintain high atmospheric CO2 concentrations through weakened intermediate‐to‐deep ocean stratification and reduced subsurface biological pump net efficiency, countering the return to more stratified conditions in the Southern Ocean, which should drive down atmospheric CO2 during the early interglacial. Plain Language Summary: The high‐latitude North Pacific is an important region where ocean interacts with the atmospheric carbon cycle. CO2 outgassing from the interior ocean of North Pacific to the surface is mainly controlled by the upwelling as well as the biological productivity determined by the NPIW formation. Relationship between changes in the NPIW and atmospheric CO2 in the early interglacial remains unclear. Here we reconstructed the NPIW evolution during the last 400 ka, and combined with climate model results, we found a delayed collapse of NPIW compared with the Southern Ocean deglacial warming, which was synchronous with the decreased seawater salinity in response to increased net rainfall in the North Pacific. This NPIW collapse after glacial termination should weaken the intermediate‐to‐deep ocean stratification, and thus favored the upwelling of nutrient/carbon‐rich deep water to the surface. Besides, combined with the decreased nutrient‐poor subtropical waters supply from the weakened Pacific meridional overturning circulation, the biological pump net efficiency was reduced and thus consumed less CO2. These would counter the return to more stratified conditions in the Southern Ocean, which should drive down atmospheric CO2 during the early interglacial, and thus probably make a contribution to maintain high atmospheric CO2 concentration during the early interglacial. Key Points: NPIW evolution during the last 400 ka was reconstructed based on the paleo‐redox changes in the northern Okinawa TroughPrecessional changes of NPIW formation were mainly forced by the net rainfall in the North PacificDelayed collapse of NPIW probably contributed to maintain high atmospheric CO2 concentrations during the early interglacial [ABSTRACT FROM AUTHOR]