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This study quantifies the influences of climate variation and vegetation greening on the changes in evapotranspiration (ET) over 110 humid catchments of China from 1982 to 2016. A process‐based model considering climate and vegetation changes is employed to estimate ET. The simulated ET compared well with the observed values based on the flux measurements and water balance equation, with the coefficients of determination above 0.62. During the study period, environmental change of the study area was characterized by the increases in air temperature and leaf area index, that is, climate warming and vegetation greening. Annual ET increased at 104 catchments with the trends ranging from 0.01 to 6.2 mm yr−2. The numerical experiment approach and sensitivity method are used to attribute ET changes to climate variation and vegetation greening. The results show that the contributions of climate variation to ET changes estimated by the two methods are 90.6% and 91.3%, respectively, whereas the contributions of vegetation greening to ET changes are only 9.4% and 8.7%, indicating that climate variation controls ET changes in the study area. However, vegetation greening alters the proportions of ET components, which contributes 59.0%–62.0% to the increase in the ratio of transpiration to ET. This study quantifies the roles of climate and vegetation changes in the dynamics of ET, suggesting that more concerns should be paid on the interactions between ecological processes and hydrological cycle in humid regions. Key Points: Evapotranspiration changes are attributed to climate variation and vegetation greening over 110 humid catchments in ChinaClimate variation controls the dynamics of evapotranspiration over the humid regionVegetation greening has limited influences on evapotranspiration but mainly alters evapotranspiration partitioning [ABSTRACT FROM AUTHOR]

Chemical solution deposition as a simple method for preparation of oxide films is used to fabricate misfit structured Ca3Co4O9 thermoelectric films using cheap precursors, Ca and Co acetates, which opens up a simple route to fabricate large-area Co-based oxide thermoelectric films. The results show that when the annealing temperature is higher than 800 °C crystallized Ca3Co4O9 films can be obtained on single-crystal LaAlO3 substrates, whereas the Ca3Co4O9 films are amorphous for lower annealing temperatures. Experimental evidence shows that the amorphous Ca3Co4O9 films behave like semiconductors with enhanced resistivity and Seebeck coefficient within the measured temperature range. The magnetoresistance is positive indicating the absence of long-range order of the Co-ion spins. For the crystallized Ca3Co4O9 films, it can be seen that the thinner films show the characteristics of spontaneous dewetting induced by the stress, which suggests that it is possible to prepare nanostructured Ca3Co4O9 films through tailoring the film thickness and the lattice mismatch; whereas, for the thicker films the temperature dependence of the resistivity and the Seebeck coefficient shows that it is possible to prepare excellent Ca3Co4O9 thermoelectric films using chemical solution deposition route, which will broaden the range of preparation methods for misfit structured Co-based thermoelectric films. [ABSTRACT FROM AUTHOR]