Search

Ongoing efforts aim to achieve a globally uniform and consistent International Height Reference System (IHRS), as a global standard for accurately determining physical (height-)coordinates worldwide. Near the Earth's surface, two stationary standard clocks separated by 1 cm in height have a redshift of about 10^-18 according to Einstein's theory of general relativity. Thus, clock comparison allows for accurate height determination in high-performance clock networks. In such networks, frequency differences observed between clock sites and corresponding gravity potential differences can be derived. The heights can be represented as geopotential numbers and measured potential differences between clock locations in a dedicated clock network can be used to estimate the transformation parameters between regional/national height reference frames and resolve distortions in individual height systems. Our study employs chronometric levelling in closed-loop simulations across two different regions, Europe and Brazil. A set of realistic offsets and tilts in the local height data is assumed by considering, e.g., systematic tilts in latitude and longitude direction, errors related to the distance from the tide gauges, the elevation of levelling points, and the presence of noisy levelling lines. External effects such as tidal effects (solid earth tide, ocean load tide, pole tide), propagation errors due to fibre and space link uncertainties, random noise, and outliers are included in the simulation of the unification process. The best configuration is determined by analyzing the standard deviations of the estimated error parameters, which vary based on the spatial distribution of the clocks. An optimal setup includes placing clocks at corners, tide gauges, and the highest points of the local height systems. The added value of chronometric levelling is demonstrated for the realization of an IHRS.

Optical clocks have improved their frequency stability and estimated accuracy by more than two orders of magnitude over the best caesium microwave clocks that realise the SI second. Accordingly, an optical redefinition of the second has been widely discussed, prompting a need for the consistency of optical clocks to be verified worldwide. While satellite frequency links are sufficient to compare microwave clocks, a suitable method for comparing high-performance optical clocks over intercontinental distances is missing. Furthermore, remote comparisons over frequency links face fractional uncertainties of a few $10^{-18}$ due to imprecise knowledge of each clock's relativistic redshift, which stems from uncertainty in the geopotential determined at each distant location. Here, we report a landmark campaign towards the era of optical clocks, where, for the first time, state-of-the-art transportable optical clocks from Japan and Europe are brought together to demonstrate international comparisons that require neither a high-performance frequency link nor information on the geopotential difference between remote sites. Conversely, the reproducibility of the clocks after being transported between countries was sufficient to determine geopotential height offsets at the level of 4 cm. Our campaign paves the way for redefining the SI second and has a significant impact on various applications, including tests of general relativity, geodetic sensing for geosciences, precise navigation, and future timing networks., Comment: 29 pages, 5 figures

Today's best optical lattice clocks are based on the spectroscopy of trapped alkaline-earth-like atoms such as ytterbium and strontium atoms. The development towards mobile or even space-borne clocks necessitates concepts for the compact laser-cooling and trapping of these atoms with reduced laser requirements. Here we present two compact and robust achromatic mirror structures for single-beam magneto-optical trapping of alkaline-earth-like atoms using two widely separated optical cooling frequencies. We have compared the trapping and cooling performance of a monolithic aluminium structure that generates a conventional trap geometry to a quasi-planar platform based on a periodic mirror structure for different isotopes of Yb. Compared to prior work with strontium in non-conventional traps, where only bosons were trapped on a narrow line transition, we demonstrate two-stage cooling and trapping of a fermionic alkaline-earth-like isotope in a single-beam quasi-planar structure., Comment: 7 pages, 9 figures

We present a novel achromatic, planar, periodic mirror structure for single-beam magneto-optical trapping and demonstrate its use in first- and second-stage cooling and trapping for different isotopes of strontium. We refer to it as Fresnel MOT as the structure is inspired by Fresnel lenses. By design, it avoids many of the problems that arise for multi-color cooling using planar structures based on diffraction gratings, which have been the dominant planar structures to be used for single-beam trapping thus far. In addition to a complex design process and cost-intensive fabrication, diffraction gratings suffer from their inherent chromaticity, which causes different axial displacements of trap volumes for the different wavelengths and necessitates tradeoffs in their diffraction properties and achievable trap depths. In contrast, the Fresnel reflector structure presented here is a versatile, easy-to-manufacture device that combines achromatic beam steering with the advantages of a planar architecture. It enables miniaturizing trapping systems for alkaline-earth-like atoms with multiple cooling transitions as well as multi-species trapping in the ideal tetrahedral configuration and within the same volume above the structure. Our design presents a novel approach for the miniaturization of cold-atom systems based on single-beam MOTs and enables the widespread adoption of these systems., Comment: 7 pages, 6 figures

To operate an optical lattice clock at a fractional uncertainty below $10^{-17}$, one must typically consider not only electric-dipole (E1) interaction between an atom and the lattice light field when characterizing the resulting lattice light shift of the clock transition but also higher-order multipole contributions, such as electric-quadrupole (E2) and magnetic-dipole (M1) interactions. However, strongly incompatible values have been reported for the E2-M1 polarizability difference of the clock states $(5s5p)\,{}^{3}\mathrm{P}_{0}$ and $(5s^2)\,{}^{1}\mathrm{S}_{0}$ of strontium [Ushijima et al., Phys. Rev. Lett. 121 263202 (2018); Porsev et al., Phys. Rev. Lett. 120, 063204 (2018)]. This largely precludes operating strontium clocks with uncertainties of few $10^{-18}$, as the resulting lattice light shift corrections deviate by up to $1 \times 10^{-17}$ from each other at typical trap depths. We have measured the E2-M1 polarizability difference using our ${}^{87}\mathrm{Sr}$ lattice clock and find a value of $\Delta \alpha_{\mathrm{qm}} = -987^{+174}_{-223} \; \mathrm{\mu Hz}$. This result is in very good agreement with the value reported by Ushijima et al., Comment: Submitted to Physical Review Research

We present a transportable ultra-stable clock laser system based on a Fabry-P\'erot cavity with crystalline Al$_{0.92}$Ga$_{0.08}$As/GaAs mirror coatings, fused silica (FS) mirror substrates and a 20~cm-long ultra-low expansion (ULE\textsuperscript{\textregistered}) glass spacer with a predicted thermal noise floor of $\mathrm{mod}\,\sigma_\mathrm{y} = 7 \times 10^{-17}$ in modified Allan deviation at one second averaging time. The cavity has a cylindrical shape and is mounted at ten points. Its measured sensitivity of the fractional frequency to acceleration for the three Cartesian directions are $2(1) \times 10^{-12}$/(ms$^{-2}$), $3(3) \times 10^{-12}$/(ms$^{-2}$) and $3(1) \times 10^{-12}$/(ms$^{-2}$), which belong to the lowest acceleration sensitivities published for transportable systems. The laser system's instability reaches down to $\mathrm{mod}\,\sigma_\mathrm{y} = 1.6 \times 10^{-16}$, Comment: copyright 2022 Optica Publishing Group. Users may use, reuse, and build upon the article, or use the article for text or data mining, so long as such uses are for non-commercial purposes and appropriate attribution is maintained. All other rights are reserved

We demonstrate for the first time the two-color cooling and trapping of alkaline-earth atoms in a grating magneto-optical trap (gMOT). The trap is formed by a single incident laser beam together with four secondary beams that are generated via diffraction from a nanostructured wafer. A grating structure for a gMOT operating with strontium atoms is optimized and fabricated. We trap $10^6$ $^{88}$Sr atoms on the $^1$S$_0$ $\rightarrow$ $^1$P$_1$ transition at $461\;\mathrm{nm}$ and transfer $25\;\%$ of these atoms to the second cooling stage on the narrower $^1$S$_0$ $\rightarrow$ $^3$P$_1$ intercombination transition at $689\;\mathrm{nm}$, preparing a sample of $2.5\times 10^5$ atoms at $5\;\mu$K. These results demonstrate for the first time the applicability of the gMOT technology in conjunction with two widely differing wavelengths and enable the continued miniaturization of alkaline-earth based quantum technologies like optical atomic clocks., Comment: 7 pages, 5 figures

We report direct measurements of the frequency ratio of the 642 THz ${}^2S_{1/2} (F=0)$--${}^2F_{7/2} (F=3)$ electric octupole transition in ${}^{171}\mathrm{Yb}^+$ and the 429 THz ${}^1S_0$--${}^3P_0$ transition in ${}^{87}\mathrm{Sr}$. A series of 107 measurements has been performed at the Physikalisch-Technische Bundesanstalt between December 2012 and October 2019. Long-term variations of the ratio are larger than expected from the individual measurement uncertainties of few $10^{-17}$. The cause of these variations remains unknown. Even taking these into account, we find a fractional uncertainty of the frequency ratio of $2.5 \times 10^{-17}$, which improves upon previous knowledge by one order of magnitude. The average frequency ratio is $\nu_{\mathrm{Yb}^+} / \nu_{\mathrm{Sr}} = 1.495\,991\,618\,544\,900\,537(38)$. This represents one of the most accurate measurements between two different atomic species to date., Comment: 9 pages, 4 figures, 1 table

We present an interrogation laser system for a transportable strontium lattice clock operating at 698 nm, which is based on an ultra-low-expansion glass reference cavity. Transportability is achieved by implementing a rigid, compact, and vibration insensitive mounting of the 12 cm-long reference cavity, sustaining shocks of up to 50 g. The cavity is mounted at optimized support points that independently constrain all degrees of freedom. This mounting concept is especially beneficial for cavities with a ratio of length $L$ over diameter $D$ $L/D>1$. Generally large $L$ helps to reduce thermal noise-induced laser frequency instability while small $D$ leads to small cavity volume. The frequency instability was evaluated, reaching its thermal noise floor of $\mathrm{mod}\,\sigma_{\rm y} \approx 3 \times 10^{-16}$ for averaging times between 0.5 s and 10 s. The laser system was successfully operated during several field studies.

The frequency stability achieved by an optical atomic clock ultimately depends on the coherence of its local oscillator. Even the best ultrastable lasers only allow interrogation times of a few seconds, at present. Here we present a universal measurement protocol that overcomes this limitation. Engineered dynamic decoupling of laser phase noise allows any optical atomic clock with high signal-to-noise ratio in a single interrogation to reconstruct the laser's phase well beyond its coherence limit. A compound clock is then formed in combination with another optical clock of any type, allowing the latter to achieve significantly higher frequency stability than on its own. We demonstrate implementation of the protocol in a realistic proof-of-principle experiment with a phase reconstruction fidelity of 99 %. The protocol enables minute-long interrogation for the best ultrastable laser systems. Likewise, it can improve clock performance where less stable local oscillators are used, such as in transortable systems., Comment: 14 pages, 4 figures

We have investigated the benefits of spin squeezed states for clocks operated with typical Brownian frequency noise-limited laser sources. Based on an analytic model of the closed servo-loop of an optical atomic clock, we can give quantitative predictions on the optimal clock stability for a given dead time and laser noise. Our analytic predictions are in very good agreement with numerical simulations of the closed servo-loop. We find that for usual cyclic Ramsey interrogation of single atomic ensembles with dead time, even with the current most stable lasers spin squeezing can only improve the clock stability for ensembles below a critical atom number of about one thousand in an optical Sr lattice clock. Even with a future improvement of the laser performance by one order of magnitude the critical atom number still remains below 100,000. In contrast, clocks based on smaller, non-scalable ensembles, such as ion clocks, can already benefit from squeezed states with current clock lasers., Comment: 7+6 pages, 6 figures, accepted at Nature Communications

There has been tremendous progress in the performance of optical frequency standards since the first proposals to carry out precision spectroscopy on trapped, single ions in the 1970s. The estimated fractional frequency uncertainty of today's leading optical standards is currently in the $10^{-18}$ range, approximately two orders of magnitude better than that of the best caesium primary frequency standards. This exceptional accuracy and stability is resulting in a growing number of research groups developing optical clocks. While good review papers covering the topic already exist, more practical guidelines are needed as a complement. The purpose of this document is therefore to provide technical guidance for researchers starting in the field of optical clocks. The target audience includes national metrology institutes (NMIs) wanting to set up optical clocks (or subsystems thereof) and PhD students and postdocs entering the field. Another potential audience is academic groups with experience in atomic physics and atom or ion trapping, but with less experience of time and frequency metrology and optical clock requirements. These guidelines have arisen from the scope of the EMPIR project "Optical clocks with $1 \times 10^{-18}$ uncertainty" (OC18). Therefore, the examples are from European laboratories even though similar work is carried out all over the world. The goal of OC18 was to push the development of optical clocks by improving each of the necessary subsystems: ultrastable lasers, neutral-atom and single-ion traps, and interrogation techniques. This document shares the knowledge acquired by the OC18 project consortium and gives practical guidance on each of these aspects., Comment: 130 pages, Table 5.3 corrected in v2

Optical lattice clocks with uncertainty and instability in the $10^{-17}$-range and below have so far been demonstrated exclusively using fermions. Here, we demonstrate a bosonic optical lattice clock with $3\times 10^{-18}$ instability and $2.0\times 10^{-17}$ accuracy, both values improving on previous work by a factor 30. This was enabled by probing the clock transition with an ultra-long interrogation time of 4 s, using the long coherence time provided by a cryogenic silicon resonator, by careful stabilization of relevant operating parameters, and by operating at low atom density. This work demonstrates that bosonic clocks, in combination with highly coherent interrogation lasers, are suitable for high-accuracy applications with particular requirements, such as high reliability, transportability, operation in space, or suitability for particular fundamental physics topics. As an example, we determine the $^{88}\textrm{Sr} - ^{87}$Sr isotope shift with 12 mHz uncertainty.

We review experimental progress on optical atomic clocks and frequency transfer, and consider the prospects of using these technologies for geodetic measurements. Today, optical atomic frequency standards have reached relative frequency inaccuracies below 10-17, opening new fields of fundamental and applied research. The dependence of atomic frequencies on the gravitational potential makes atomic clocks ideal candidates for the search for deviations in the predictions of Einstein's general relativity, tests of modern unifying theories and the development of new gravity field sensors. In this review, we introduce the concepts of optical atomic clocks and present the status of international clock development and comparison. Besides further improvement in stability and accuracy of today's best clocks, a large effort is put into increasing the reliability and technological readiness for applications outside of specialized laboratories with compact, portable devices. With relative frequency uncertainties of 10-18, comparisons of optical frequency standards are foreseen to contribute together with satellite and terrestrial data to the precise determination of fundamental height reference systems in geodesy with a resolution at the cm-level. The long-term stability of atomic standards will deliver excellent long-term height references for geodetic measurements and for the modelling and understanding of our Earth., Comment: 73 pages, 22 figures

We investigate scattering of lattice laser radiation in a strontium optical lattice clock and its implications for operating clocks at interrogation times up to several tens of seconds. Rayleigh scattering does not cause significant decoherence of the atomic superposition state near a magic wavelength. Among the Raman scattering processes, lattice-induced decay of the excited state $(5s5p)\,{}^{3}\mathrm{P}_{0}$ to the ground state $(5s^2)\,{}^{1}\mathrm{S}_{0}$ via the state $(5s5p)\,{}^{3}\mathrm{P}_{1}$ is particularly relevant, as it reduces the effective lifetime of the excited state and gives rise to quantum projection noise in spectroscopy. We observe this process in our experiment and find a decay rate of $556(15)\times 10^{-6}\,\mathrm{s}^{-1}$ per photon recoil energy $E_\mathrm{r}$ of effective lattice depth, which agrees well with the rate we predict from atomic data. We also derive a natural lifetime $\tau = 330(140)\,\mathrm{s}$ of the excited state ${}^{3}\mathrm{P}_{0}$ from our observations. Lattice-induced decay thus exceeds spontaneous decay at typical lattice depths used by present clocks. It eventually limits interrogation times in clocks restricted to high-intensity lattices, but can be largely avoided, e.g., by operating them with shallow lattice potentials.

The advent of novel measurement instrumentation can lead to paradigm shifts in scientific research. Optical atomic clocks, due to their unprecedented stability and uncertainty, are already being used to test physical theories and herald a revision of the International System of units (SI). However, to unlock their potential for cross-disciplinary applications such as relativistic geodesy, a major challenge remains. This is their transformation from highly specialized instruments restricted to national metrology laboratories into flexible devices deployable in different locations. Here we report the first field measurement campaign performed with a ubiquitously applicable $^{87}$Sr optical lattice clock. We use it to determine the gravity potential difference between the middle of a mountain and a location 90 km apart, exploiting both local and remote clock comparisons to eliminate potential clock errors. A local comparison with a $^{171}$Yb lattice clock also serves as an important check on the international consistency of independently developed optical clocks. This campaign demonstrates the exciting prospects for transportable optical clocks.

We present an analysis of the different types of noise from the detection and interrogation laser in our strontium lattice clock. We develop a noise model showing that in our setup quantum projection noise--limited detection is possible if more than 130~atoms are interrogated. Adding information about the noise spectrum of our clock laser with sub-$10^{-16}$ fractional frequency instability allows to infer the clock stability for different modes of operation. Excellent agreement with experimental observations for the instability of the difference between two interleaved stabilizations is found. We infer a clock instability of $1.6 \times 10^{-16}/\sqrt{\tau / \mathrm{s}}$ as a function of averaging time $\tau$ for normal clock operation.

The power spectral density in Fourier frequency domain, and the different variants of the Allan deviation (ADEV) in dependence on the averaging time are well established tools to analyse the fluctuation properties and frequency instability of an oscillatory signal. It is often supposed that the statistical uncertainty of a measured average frequency is given by the ADEV at a well considered averaging time. However, this approach requires further mathematical justification and refinement, which has already been done regarding the original ADEV for certain noise types. Here we provide the necessary background to use the modified Allan deviation (modADEV) and other two-sample deviations to determine the uncertainty of weighted frequency averages. The type of two-sample deviation used to determine the uncertainty depends on the method used for determination of the average. We find that the modADEV, which is connected with $\Lambda$-weighted averaging, and the two sample deviation associated to a linear phase regression weighting (parADEV) are in particular advantageous for measurements, in which white phase noise is dominating. Furthermore, we derive a procedure how to minimize the uncertainty of a measurement for a typical combination of white phase and frequency noise by adaptive averaging of the data set with different weighting functions. Finally, some aspects of the theoretical considerations for real-world frequency measurement equipment are discussed., Comment: 11 pages, 2 figures

We present a laser system based on a 48 cm long optical glass resonator. The large size requires a sophisticated thermal control and optimized mounting design. A self balancing mounting was essential to reliably reach sensitivities to acceleration of below $\Delta \nu / \nu$ < 2E-10 /g in all directions. Furthermore, fiber noise cancellations from a common reference point near the laser diode to the cavity mirror and to additional user points (Sr clock and frequency comb) are implemented. Through comparison to other cavity-stabilized lasers and to a strontium lattice clock an instability of below 1E-16 at averaging times from 1 s to 1000 s is revealed.

Cryogenic single-crystal optical cavities have the potential to provide highest dimensional stability. We have investigated the long-term performance of an ultra-stable laser system which is stabilized to a single-crystal silicon cavity operated at 124 K. Utilizing a frequency comb, the laser is compared to a hydrogen maser that is referenced to a primary caesium fountain standard and to the $^{87}\mathrm{Sr}$ optical lattice clock at PTB. With fractional frequency instabilities of $\sigma_y(\tau)\leq2\times10^{-16}$ for averaging times of $\tau=60\mathrm{~s}$ to $1000\mathrm{~s}$ and $\sigma_y(1 \mathrm{d})\leq 2\times10^{-15}$ the stability of this laser, without any aid from an atomic reference, surpasses the best microwave standards for short averaging times and is competitive with the best hydrogen masers for longer times of one day. The comparison of modeled thermal response of the cavity with measured data indicates a fractional frequency drift below $5\times 10^{-19}/\mathrm{s}$, which we do not expect to be a fundamental limit.

We have measured the absolute frequency of the optical lattice clock based on $^{87}$Sr at PTB with an uncertainty of $3.9\times 10^{-16}$ using two caesium fountain clocks. This is close to the accuracy of today's best realizations of the SI second. The absolute frequency of the 5s$^2$ $^1$S$_0$-5s5p $^3$P$_0$ transition in $^{87}$Sr is 429,228,004,229,873.13(17) Hz. Our result is in excellent agreement with recent measurements performed in different laboratories worldwide. We improved the total systematic uncertainty of our Sr frequency standard by a factor of five and reach $3\times 10^{-17}$, opening new prospects for frequency ratio measurements between optical clocks for fundamental research, geodesy, or optical clock evaluation., Comment: 20 pages, 5 figures

Here we describe a compact and efficient strontium oven well suited for laser-cooling experiments. Novel design solutions allowed us to produce a collimated strontium atomic beam with a flux of 1.0\times10^13 s^-1 cm^-2 at the oven temperature of 450 {\deg}C, reached with an electrical power consumption of 36 W. The oven is based on a stainless-steel reservoir, filled with 6 g of metallic strontium, electrically heated in a vacuum environment by a tantalum wire threaded through an alumina multi-bore tube. The oven can be hosted in a standard DN40CF cube and has an estimated continuous operation lifetime of 10 years. This oven can be used for other alkali and alkaline earth metals with essentially no modifications., Comment: 6 pages, 6 figures, Review of Scientific Instruments, in press

We have determined the frequency shift that blackbody radiation is inducing on the $5s^2$ $^1$S$_0$ -- $5s5p$ $^3$P$_0$ clock transition in strontium. Previously its uncertainty limited the uncertainty of strontium lattice clocks to $1\times10^{-16}$. Now the uncertainty associated to the black body radiation shift correction translates to $5\times 10^{-18}$ relative frequency uncertainty at room temperature. Our evaluation is based on a measurement of the differential dc-polarizability of the two clock states and on a modeling of the dynamic contribution using this value and experimental data for other atomic properties., Comment: 9 pages, 4 figures, including appendix with supplementary text. Version 2 with adjusted value of differential static polarizability due to field plate separation measurement

We present a novel method to transport ultra cold atoms in a focused optical lattice over macroscopic distances of many Rayleigh ranges. With this method ultra cold atoms were transported over 5 cm in 250 ms without significant atom loss or heating. By translating the interference pattern together with the beam geometry the trap parameters are maintained over the full transport range. Thus, the presented method is well suited for tightly focused optical lattices that have sufficient trap depth only close to the focus. Tight focusing is usually required for far-detuned optical traps or traps that require high laser intensity for other reasons. The transport time is short and thus compatible with the operation of an optical lattice clock in which atoms are probed in a well designed environment spatially separated from the preparation and detection region., Comment: 14 pages, 6 figures

In optical clocks, transitions of ions or neutral atoms are interrogated using pulsed ultra-narrow laser fields. Systematic phase chirps of the laser or changes of the optical path length during the measurement cause a shift of the frequency seen by the interrogated atoms. While the stabilization of cw-optical links is now a well established technique even on long distances, phase stable links for pulsed light pose additional challanges and have not been demonstrated so far. In addition to possible temperature or pressure drift of the laboratory, which may lead to a Doppler shift by steadily changing the optical path length, the pulsing of the clock laser light calls for short settling times of stabilization locks. Our optical path length stabilization uses retro-reflected light from a mirror that is fixed with respect to the interrogated atoms and synthetic signals during the dark time. Length changes and frequency chirps are compensated for by the switching AOM. For our strontium optical lattice clock we have ensured that the shift introduced by the fiber link including the pulsing acousto optic modulator is below $2\cdot 10^{-17}$., Comment: 10 pages, 8 figures; Applied Physics B - Lasers and Optics 2011

We present the setup and test of a transportable clock laser at 698 nm for a strontium lattice clock. A master-slave diode laser system is stabilized to a rigidly mounted optical reference cavity. The setup was transported by truck over 400 km from Braunschweig to D\"usseldorf, where the cavity-stabilized laser was compared to a stationary clock laser for the interrogation of ytterbium (578 nm). Only minor realignments were necessary after the transport. The lasers were compared by a Ti:Sapphire frequency comb used as a transfer oscillator. The thus generated virtual beat showed a combined linewidth below 1 Hz (at 1156 nm). The transport back to Braunschweig did not degrade the laser performance, as was shown by interrogating the strontium clock transition., Comment: 3 pages, 4 figures

A major obstacle for optical clocks is the frequency shift due to black body radiation. We discuss how one can tackle this problem in an optical lattice clock; in our case 87-Sr: firstly, by a measurement of the dc Stark shift of the clock transition and, secondly, by interrogating the atoms in a cryogenic environment. Both approaches rely on transporting ultracold atoms over several cm within a probe cycle. We evaluate this approach of mechanically moving the optical lattice and conclude that it is feasible to transport the atoms over 50 mm within 300 ms. With this transport a dc Stark shift measurement will allow to reduce the contribution of the blackbody radiation to the fractional uncertainty below 2 * 10^-17 at room temperature by improving the shift coefficient known only from atomic structure calculations up to now. We propose a cryogenic environment at 77 K that will reduce this contribution to few parts in 10^-18., Comment: 7 pages, 8 figures

We present precision measurements with MHz uncertainty of the energy gap between asymptotic and well bound levels in the electronic ground state X $^1\Sigma_{\mathrm{g}}^+$ of the $^{39}$K$_2$ molecule. The molecules are prepared in a highly collimated particle beam and are interrogated in a $\Lambda$-type excitation scheme of optical transitions to long range levels close to the asymptote of the ground state, using the electronically excited state A $^1\Sigma^+_{\rm u}$ as intermediate one. The transition frequencies are measured either by comparison with I$_2$ lines or by absolute measurements using a fs-frequency comb. The determined level energies were used together with Feshbach resonances from cold collisions of $^{39}$K and $^{40}$K reported from other authors to fit new ground state potentials. Precise scattering lengths are determined and tests of the validity of the Born-Oppenheimer approximation for the description of cold collisions at this level of precision are performed., Comment: 14 pages, 4 figures, 8 tables

We report on a frequency measurement of the $(3s^2)^1S_0\to(3s3p)^3P_1$ clock transition of $^{24}$Mg on a thermal atomic beam. The intercombination transition has been referenced to a portable primary Cs frequency standard with the help of a femtosecond fiber laser frequency comb. The achieved uncertainty is $2.5\times10^{-12}$ which corresponds to an increase in accuracy of six orders of magnitude compared to previous results. The measured frequency value permits the calculation of several other optical transitions from $^1S_0$ to the $^3P_J$-level system for $^{24}$Mg, $^{25}$Mg and $^{26}$Mg. We describe in detail the components of our optical frequency standard like the stabilized spectroscopy laser, the atomic beam apparatus used for Ramsey-Bord\'e interferometry and the frequency comb generator and discuss the uncertainty contributions to our measurement including the first and second order Doppler effect. An upper limit of $3\times10^{-13}$ in one second for the short term instability of our optical frequency standard was determined by comparison with a GPS disciplined quartz oscillator., Comment: 8 pages, 8 figures

Asymptotic levels of the A $^1\Sigma_u^+$ state of the two isotopomers $^{39}{\rm K}_2$ and $^{39}{\rm K}^{41}{\rm K}$ up to the dissociation limit are investigated with a Doppler-free high resolution laser-spectroscopic experiment in a molecular beam. The observed level structure can be reproduced correctly only if a mass dependent correction term is introduced for the interaction potential. The applied relative correction in the depth of the potential is $10^{-6}$, which is in the order of magnitude expected for corrections of the Born-Oppenheimer approximation. A similar change in ground state potentials might lead to significant changes of mass-scaled properties describing cold collisions like the s-wave scattering length., Comment: 8 pages, 6 figures

We have measured the ac-Stark shift of the 4s2 1S0 - 4s4p 3P1 line in 40Ca for perturbing laser wavelengths between 780 nm and 1064 nm with a time domain Ramsey-Borde atom interferometer. We found a zero crossing of the shift for the mS = 0 - mP = 0 transition and \sigma polarized perturbation at 800.8(22) nm. The data was analyzed by a model deriving the energy shift from known transition wavelengths and strengths. To fit our data, we adjusted the Einstein A coefficients of the 4s3d 3D - 4s4p 3P and 4s5s 3S - 4s4p 3P fine structure multiplets. With these we can predict vanishing ac-Stark shifts for the 1S0 m = 0 - 3P1 m = 1 transition and \sigma- light at 983(12) nm and at 735.5(20) nm for the transition to the 3P0 level., Comment: 8 pages, 5 figures, 2 tables