1. Enhancement of sulfathiazole removal: The synergism of Cu(II) and MoS2@PANI in peroxymonosulfate activation.
- Author
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Liu, Guohui, Wang, Qiongfang, Dong, Lei, Zhang, Xin, Zhang, Min, Rao, Pinhua, Gao, Naiyun, Sun, Yangang, and Deng, Jing
- Subjects
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COPPER , *PEROXYMONOSULFATE , *ENVIRONMENTAL remediation , *BODIES of water , *POLLUTANTS , *MOLYBDENUM sulfides - Abstract
[Display omitted] • It was firstly demonstrated that the synergistic activation of PMS by MoS 2 @PANI and Cu(II). • High removal rate of sulfathiazole (≥85 %) achieved within a wide range of pH (3–10) in Cu(II)/MoS 2 @PANI/PMS. • H O ∙ , Cu(Ⅲ) and 1 O 2 were generated in Cu(II)/MoS 2 @PANI/PMS, while SO 4 ∙ - was negligible. • Compared with Fe(II), Cu(II) improved reusability and applicability of MoS 2 @PANI in activation of PMS. • The absorption of Cu(II) on MoS 2 @PANI improved the stability of MoS 2 @PANI. This paper synergistically combined MoS 2 @PANI (coating MoS 2 on polyaniline (PANI)) with Cu(II) to obtain effective activation of PMS in a wide range of pH (3–10). The removal rate of sulfathiazole (ST) in Cu(II)/MoS 2 @PANI/PMS (98 %) in 60 min was higher than in Cu(II)/PMS (50 %) and MoS 2 @PANI/PMS (70 %). Besides, the PMS consumption rate was 100 % within 30 min in Cu(II)/MoS 2 @PANI/PMS. Different concentrations of Cl - and HCO 3 - promoted the degradation of ST in varying degrees. And NO 3 - slightly inhibited the degradation of ST (removal rate more than 84 %). Notably, Cu(II)/MoS 2 @PANI/PMS could remove more than 80 % ST in different water bodies. The special structure of MoS 2 @PANI increased many activity sites of Mo(IV) to promote the cycle of Cu(II)/Cu(I) for activating PMS which generated H O ∙ , Cu(III) and 1 O 2. Twenty-seven degradation intermediates were identified and four possible degradation paths of ST were proposed. Moreover, Cu(II)/MoS 2 @PANI/PMS possessed a good non-selectivity for various organic pollutants. After three consecutive cycles, the removal rate still retained more than 90 % in Cu(II)/MoS 2 @PANI/PMS system. Compared with Fe(II), MoS 2 @PANI was more stable in Cu(II)/MoS 2 @PANI/PMS. The synergy of Cu and Mo broke the limitation of PMS activation under environmental aquatic conditions. Given that Cu(II) widely existed in wastewater, the new research strategy increased the application scope for homogeneous PMS activation with inherently Cu(II) in wastewater in environmental remediation. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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