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To further explore the fracture initiation mechanism of fracture grouting in typical sandy mudstone from Huainan and Huaibei mining areas in China, a conventional triaxial fracture grouting test device was developed, and the model test of fracture initiation pressure of slurry fracturing in similar material of sandy mudstone was carried out. Based on the test results, the influences of rock strength and stress state on grouting fracture initiation pressure and fracture propagation pattern were analyzed, and the fracture initiation mechanism of fracture grouting in sandy mudstone was revealed. The results show that there is a positive correlation between the initiation pressure and the compressive strength of rock; the larger the compressive strength of the rock is, the more complex the fracturing path is. The sensitivity of fracture initiation pressure to confining pressure is much greater than that of axial pressure; the larger the stress difference Δσ =σV −σH is, the more regular the fracture shape is. Under the triaxial condition of pore pressure, the rock tensile strength determined by slurry fracturing method in sealed open hole section is approximately 2.5 times the uniaxial tensile strength. The research results can provide a reference for the design and construction of fracture grouting in similar rock strata in the future.

To address the issue of randomness in the mechanical properties of the hydroxyl‐terminated polybutadiene (HTPB) propellant, a stochastic constitutive model (SCM) with a lognormally distributed random parameter Λ was proposed to describe their mechanical behaviors, and the structural integrity of a HTPB propellant grain was analyzed based on it. The results indicate that the stress‐strain curves predicted by the SCM have a good agreement with the experimental curves, and the experimental curves fall within a 95 % probability interval predicted by the SCM. The mechanical response of HTPB propellant grain under ignition pressurization is associated with the random parameters Λ. The maximum equivalent stress and safety factor increase approximately linearly with the increase of random parameters Λ, while the maximum equivalent strain and maximum damage coefficient decrease approximately linearly with the increase of random parameters Λ. The error in the mechanical response of the grain obtained based on the SCM and the experimental constitutive model is basically not more than 2 %, the SCM can effectively characterize the randomness in the mechanical response of propellant grain caused by the dispersion of HTPB propellant mechanical properties. [ABSTRACT FROM AUTHOR]

Herein, we employed a developed linear response time dependent density functional theory-based nonadiabatic dynamics simulation method that explicitly takes into account the excitonic effects to investigate photoinduced excitation energy transfer dynamics of a double-walled carbon nanotube (CNT) model with different excitation energies. The E11 excitation of the outer CNT will generate a local excitation (LE) |out*〉 exciton due to its low energy, which does not induce any charge separation. In contrast, the E11 excitation of the inner CNT can generate four kinds of excitons with the LE exciton |in*〉 dominates. In the 500-fs dynamics simulation, the LE exciton |in*〉 and charge transfer (CT) excitons |out−in+〉 and |out+in−〉 are all gradually converted to the |out*〉 exciton, corresponding to a photoinduced excitation energy transfer, which is consistent with experimental studies. Finally, when the excitation energy is close to the E22 state of the outer CNT (∼1.05 eV), a mixed population of different excitons, with the |out*〉 exciton dominated, is generated. Then, photoinduced energy transfer from the outer to inner CNTs occurs in the first 50 fs, which is followed by an inner to outer excitation energy transfer that is completed in 400 fs. The present work not only sheds important light on the mechanistic details of wavelength-dependent excitation energy transfer of a double-walled CNT model but also demonstrates the roles and importance of CT excitons in photoinduced excitation energy transfer. It also emphasized that explicitly including the excitonic effects in electronic structure calculations and nonadiabatic dynamics simulations is significant for correct understanding/rational design of optoelectronic properties of periodically extended systems. [ABSTRACT FROM AUTHOR]