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In this study, a thenoyltriflouroacetone ligand (TTA) with a Tb3+ MOF was synthesized (Tb=10 and 50% mol) and its structural and luminescent properties were analyzed. The metalorganic compound was generated in a simple one-pot reaction from terbium nitrate and 2-thenoyltrifluoroacetone precursors at room temperature. By means of FTIR, it was confirmed the presence of carbon groups, which made possible the terbium ion chelation, and also the Tb-O bonds vibration modes. HNMR results confirm that the complex with 10% mol of Tb3+ contains three coordinates molecules of TTA and two waters molecules. The powders exhibit rod-like morphology with size about 170 nm of diameter and a length about 2 {\mu}m, the rod-like nature of powders was confirmed by SEM and TEM analyses. By XRD it was concluded that at higher terbium concentration (TTA-50Tb sample) higher the crystallite size and crystallinity, in fact the TTA-10Tb sample shows a partial-amorphous nature. By photoluminescence analyses, the 5D4-7FJ (J=3, 4, 5 and 6) emissions were recorded for both synthesized samples ({\lambda}exc=376 nm). Furthermore, it was observed that the emission intensity was enhanced in a factor of 3.5 for the TTA-50Tb. The energy transfer efficiency from TTA to Tb3+ (antenna effect) was 0.984 for TTA-10Tb and 0.993 for TTA-50Tb. Decay time analyses indicate effective lifetime of 1.45 and 1.60ms for the samples doped at 10 and 50%, respectively, indicating that the forbidden transition rules are stronger at higher crystallinity. The integrated intensities of the 5D4 - 7F5 (green at 541 nm) and 5D4 - 7F6 (blue at 486 nm) emissions and their intensity ratios IG/IB upon 376 nm excitation have been evaluated for TTA-10Tb andTTA-50Tb samples., Comment: Optical Materials (2018)

Magnetic flux circulation is a primary mode of energy transfer from the solar wind into the ionosphere and inner magnetosphere. For southward interplanetary magnetic field (IMF), magnetic flux circulation is described by the Dungey cycle (dayside merging, night side reconnection, and magnetospheric convection), and both the ionosphere and inner magnetosphere receive energy. For dawn-dusk oriented IMF, magnetic flux circulation is not well understood, and the inner magnetosphere does not receive energy. Several models have been suggested for possible reconnection patterns; the general pattern is: dayside merging; reconnection on the dayside or along the dawn/dusk regions; and, return flow on dayside only. These models are consistent with the lack of energy in the inner magnetosphere. We will present evidence that the Dungey cycle does not explain the energy transfer during dawn-dusk oriented IMF. We will also present evidence of how magnetic flux does circulate during dawn-dusk oriented IMF, specifically how the magnetic flux reconnects and circulates back.

The Geospace Magnetospheric Dynamics (GMD) mission is designed to provide very closely spaced, multipoint measurements in the thin current sheets of the magnetosphere to determine the relation between small scale processes and the global dynamics of the magnetosphere. Its trajectory is specifically designed to optimize the time spent in the current layers and to minimize radiation damage to the spacecraft. Observations are concentrated in the region 8 to 40 R(sub E) The mission consists of three phases. After a launch into geostationary transfer orbit the orbits are circularized to probe the region between geostationary orbit and the magnetopause; next the orbit is elongated keeping perigee at the magnetopause while keeping the line of apsides down the tail. Finally, once apogee reaches 40 R(sub E) the inclination is changed so that the orbit will match the profile of the noon-midnight meridian of the magnetosphere. This mission consists of 4 solar electrically propelled vehicles, each with a single NSTAR thruster utilizing 100 kg of Xe to tour the magnetosphere in the course of a 4.4 year mission, the same thrusters that have been successfully tested on the Deep Space-1 mission.

In this study we examine observations made by AMPTE/CCE of energetic ion bursts during seven substorm periods when the satellite was located near the neutral sheet, and CCE observed the disruption cross-tail current in situ. We compare ion observations to analytic calculations of particle acceleration. We find that the acceleration region size, which we assume to be essentially the current disruption region, to be on the order of 1 R(sub E). Events exhibiting weak acceleration had either relatively small acceleration regions (apparently associated with pseudobreakup activity on the ground) or relatively small changes in the local magnetic field (suggesting that the magnitude of the local current disruption region was limited). These results add additional support for the view that the particle bursts observed during turbulent current sheet disruptions are due to inductive acceleration of ions.

Recent simulations of magnetotail reconnection have pointed to a link between plasma flows, dipolarization, and the substorm current wedge. In particular, Hesse and Birn (1991) have proposed that earthward jetting of plasma from the reconnection region transports flux into the near-Earth region. At the inner edge of the plasma sheet this flux piles up, producing a dipolarization of the magnetic field. The vorticity produced by the east-west deflection of the flow at the inner edge of the plasma sheet gives rise to field-aligned currents that have region 1 polarity. Thus in this scenario the earthward flow from the reconnection region produces the dipolarization ad the current wedge in a self-consistent fashion. In this study we examine observations made on April 8, 1985 by the Active Magnetospheric Particle Tracer Explorers (AMPTE)/Ion Release Module (IRM), the geosynchronous satellites 1979-053, 1983-019, and 1984-037, and Syowa station, as well as AE. This event is unique because IRM was located near the neutral sheet in the midnight sector for am extended period of time. Ground data show that there was ongoing activity in the IRM local time sector for several hours, beginning at 1800 UT and reaching a crescendo at 2300 UT. This activity was also accompanied by energetic particle variations, including injections, at geosynchronous orbit in the nighttime sector. Significantly, there were no fast flows at the neutral sheet until the great intensification of activity at 2300 UT. At that time, IRM recorded fast eartheard flow simultaneous with a dipolatization of the magetic field. We conclude that while the aforementioned scenario for the creation of the current wedge encounters serious problems explaining the earlier activity, the observations at 2300 UT are consistent with the scenario of Hesse and Birn (1191). On that basis it is argued that the physics of substorms is not exclusively rooted in the development of a global tearing mode. Processes at the inner edge of the cross-tail current that cause a disruption of the current and a consequent dipolarization and current wedge may be unrelated to the formation of a macroscale reconnection region. Thus the global evolution of a substorm is probably a complicated superposition of such processes operating on a very localized scale and a global macroscale process that allows for such things as releasing te energy stored in lobe flux and creation of plasmoids.

This paper reports the multisatellite and ground observations of two pseudo-substorm onset events that occurred successively at 0747 UT and 0811 UT, May 30, 1985, with more attention to the 0747 UT onset. The distinguishing features of the 0747 UT event are as follows. (1) The substorm-associated tail reconfiguration started in a very localized region in the near-Earth magnetotail. (2) The magnitude of the current disruption decreased markedly as the disruption region expanded tailward. (3) On the ground the onset of a very small negative bay (approx. 40 nT) was observed simultaneously with the onset of the current disruption, but over a much wider local time sector than the near-Earth tail reconfiguration. Positive bay onsets at mid-latitudes also had a longitudinally wide distribution. From these features we infer than in the present event the current disruption took place filamentarily near AMPTE/CCE at approx. 8.8 R(sub E). It is also inferred that pseudo-substorm onsets are distinguished from standard substorm onsets by the absence of a global expansion of the current disruption, and that the spatial scales of the onset region in the magnetosphere is not a major difference between the two. The present study suggests that the spatial distribution of the magnetic distortion before onsets is an important factor to determine the expansion scale of the current disruption. It is also suggested that the current disruption is basically an internal process of the magnetosphere.

A substorm that occurred on 7 June 1985 at 2209 UT for which simultaneous measurements from ground stations and CCE are available is considered. The event occurred during a close conjunction between CCE, the EISCAT magnetometer cross, and the STARE radar, allowing a detailed comparison of satellite and ground-based data. Two discrete activations took place during the first few minutes of this substorm: the expansion phase onset at 2209 UT and an intensification at 2212 UT, corresponding to a poleward expansion of activity. The energetic particle data indicate that the active region of the magnetotail during the 2212 UT intensification was located tailward of the active region at 2209 UT. This is direct evidence for a correspondence between tailward expansion of localized activity in the near-earth magnetotail (current disruption and particle energization) and poleward expansion of activity (electrojet formation) in the ionosphere.

Observations made during the growth phase and the onset of a substorm on August 31, 1986 are presented. About 20 min after the epsilon parameter at the magnetopause had exceeded 10 exp 11 W, magnetic field dipolarization with an increase of energetic particle fluxes was observed by the AMPTE Charge Composition Explorer (CCE) spacecraft at the geocentric distance of 8.7 R(E) close to magnetic midnight. The event exhibited local signatures of a substorm onset at AMPTE CCE and a weak wedgelike current system in the midnight sector ionosphere, but did not lead to a full-scale substorm expansion; neither did it produce large particle injections at GEO. Only after another 20 min of continued growth phase could the entire magnetosphere-ionosphere system allow the onset of a regular substorm expansion. The initial activation is interpreted as a 'pseudobreakup'. We examine the physical conditions in the near-Earth plasma sheet and analyze the development in the ionosphere using ground-based magnetometers and electric field observations from the STARE radar.

An intense geomagnetic substorm event on May 3, 1986, occurring toward the end of a strong storm period, is studied. The auroral electrojet indices and global imaging data from both the Northern and Southern Hemispheres clearly revealed the growth phase and expansion phase development for a substorm with an onset at 0111 UT. An ideally located constellation of four spacecraft allowed detailed observation of the substorm growth phase in the near-tail region. A realistic time-evolving magnetic field model provided a global representation of the field configuration throughout the growth and early expansion phase of the substorm. Evidence of a narrowly localized substorm onset region in the near-earth tail is found. This region spread rapidly eastward and poleward after the 0111 UT onset. The results are consistent with a model of late growth phase formation of a magnetic neutral line. This reconnection region caused plasma sheet current diversion before the substorm onset and eventually led to cross-tail current disruption at the time of the substorm onset.

The particle scattering and current sheet stability features in the geomagnetic tail during the phase of substorm growth were investigated using Tsyganenko's (1989) magnetic field model. In a study of four substorm events which were observed both in the high-altitude nightside tail and in the auroral ionosphere, the model magnetic field was adjusted to each case so as to represent the global field development during the growth phase of the substorms. The model results suggest that the auroral brightenings are connected with processes taking place in the near-earth region inside about 15 earth radii. The results also suggest that there is a connection between the chaotization of the electrons and the auroral brightenings at substorm onset.

The principles of the current sheet catastrophe models are briefly reviewed, and observations of some of the signatures predicted by the theory are presented. The data considered here include AMPTE/CCE observations of fifteen current sheet disruption events. According to the model proposed here, the root cause of the current disruption is some process, as yet unknown, that leads to an increase in the k sub A parameter. Possible causes for the increase in k sub A are discussed.

A pseudobreakup is a phenomenon similar to the substorm expansive phase onset, including an activation of an auroral arc, a burst of Pi2 micropulsations, and enhancement of the westward electrojet. However, these effects are weak and a pseudobreak is generally assumed to be very localized. The pseudobreakups are discussed based on simultaneous observations made in space and on the ground during the substorm growth phase. In the events studied the main features listed above are found, but the significance of the localization is unclear. The optical pseudobreakup, with associated magnetic perturbations, is highly localized, but simultaneously a wide local time sector of the auroral oval may be activated. The major differences between pseudobreakups and substorm expansive phase onsets are concluded to be the intensity and the development that follows. Careful study of pseudobreakups may help to determine phase initiation, and the role of the ionosphere-magnetosphere coupling in the substorm process.

Current disruption events observed by the Charge Composition Explorer during 1985 and 1986 are examined. Occurrence of current disruption was accompanied by large magnetic field turbulence and frequently with reversal in the sign of the field component normal to the neutral sheet. Current disruptions in the near-earth region are found to be typically shortlived (about 1-5 min), and their onsets coincide well with the ground onsets of substorm expansion or intensification in the local time sector of the footpoint of the spacecraft. These events are found almost exclusively close to the field reversal plane of the neutral sheet (within about 0.5 RE). Prior to current disruption the field strength can be reduced to as low as one seventh of the dipole field value and can recover to nearly the dipole value after disruption. The temporal evolution of particle pressure in the near-earth neutral sheet during the onset of current disruption indicates that the current buildup during the substorm growth phase is associated with enhancement in the particle pressure at the neutral sheet.

The CDAW-9 Event C focused upon the early part of 3 May 1986 when a large substorm onset occurred at 0111 UT. By modifying the Tsyganenko 1989 magnetic field model, a model is constructed in which the near-earth current systems are enhanced with time to describe the observed development of the tail magnetic field during the growth phase. The cross-tail current intensity and the thickness of the current sheet are determined by comparison with three spacecraft in the near-earth tail. The location of the auroral bulge as recorded by the Viking imager is mapped to the equatorial current sheet. The degree of chaotization of the thermal electrons is estimated, and the consequences to the tail stability towards on tearing are discussed. It is concluded that the mapping of the brightening region in the auroral oval corresponds to the regions in the tail where the current sheet may be unstable towards ion tearing.

Observations are described of a substorm field-aligned current (FAC) system traversed by the DMSP F7 spacecraft just after 0300 UT on April 25, 1985. It is shown that the substorm FAC portion of the current system was located equatorward of the boundary between open and closed field lines. The equatorward boundary of the substorm FAC into the magnetotail was mapped using the Tsyganenko (1987) model, showing that the boundary corresponds to 6.9 earth radii. The result is consistent with the suggestion of Akasofu (1972) and Lopez and Lui (1990) that the region of substorm initiation lies relatively close to the earth and the concept that an essential feature of substorms is the disruption and diversion of the near-earth current sheet.

A data set of 1821 magnetopause crossings was assembled. Separate fits to subsets of this data set determine the magnetopause location as a function of solar wind dynamic pressure and interplanetary magnetic field orientation. Solar wind dynamic pressure variations produce self-similar magnetopause motion on time scales of one hour or longer. In this paper, the pressure balance relationship between the solar wind dynamic pressure and the location of the subsolar magnetopause are verified. The relationship between the IMF Bz, region 1 Birkeland current strength, the position of the subsolar magnetopause, and the shape of the dayside magnetosphere is quantified. Cross sections of the dayside magnetopause in planes perpendicular to the earth-sun line are oblate.

Results are presented of multipoint observations of a small substorm which occurred at about 0110 UT on April 25, 1985, carried out by AMPTE CCE, AMPTE IRM, DMSP F6, and DMSP F7, as well as by ground auroral stations and midlatitude stations. These data yield information on the latitudinal extent of the polar cap and provide visual identification of substorm aurorae, magnetic perturbations produced directly beneath aurorae, and the situ magnetic field. In addition, they provide magnetic-particle observations of the disruption of the cross-tail current sheet and observations concerning the spatial expansion of the current disruption region. Evidence is presented that the current sheet disruption observed by CCE in the neutral sheet was located on field lines which mapped to the westward traveling surge observed directly overhead of the ground station at Syowa.

Simultaneous magnetic field and particle measurements by AMPTE/CCE with magnetic field measurements by GOES 5 and GOES 6 clarify the structure of the field-aligned Birkeland current system in the post-midnight region of the near-earth magnetotail. The current system, consisting of current sheets flowing in opposite directions, exists near the boundary region of the plasma sheet; its magnetic effects are confined mainly to the current region because of its structure. During the expansion phase of substorms, a single-sheet current system is formed in the boundary region of the plasma sheet and net current is probably present in one meridian plane. This type of current system produces the substorm-related transient variations in the azimuthal (D) component normally observed at synchronous orbit.

It is generally thought that the local effects associated with substorm onset in the near-earth magnetotail (R less than about 10 earth radii) have a component of propagation which is radially earthward. This study presents a case during which it is possible that the local effects of substorm onset propagated radially antisunward, examining energetic-ion and magnetic-field data from AMPTE/CCE and energetic-particle data from the GEO satellite 1982-019 during a period of weak substorm activity on June 11, 1985. Although the effects of this event on the ground were very weak, the substorm had a dramatic effect on at least one portion of the near-earth magnetotail. During the period the spacecraft were in an unusually close radial alignment. The data show that phenomena associated with the local effects of substorm onset began at or near GEO before they were observed at CCE. This event is best explained by a near-earth disruption of the cross-tail current sheet and the consequent formation of a substorm current wedge, with a component of expansion antisunward down the tail.

Results are presented on observations from four satellites (GOES 5, GOES 6, AMPTE CCE, and AMPTE IRM) and two ground stations (San Juan and Tucson) on a substorm that occurred on April 19, 1985 at about 0830 UT. The four spacecraft were arrayed in a configuration that made it possible to separate the effects arising from the longitudinal versus the radial expansion of the substorm current wedge and thus to examine its spatial evolution. The sequence of events that was observed suggests that, during this substorm, the disruption of the cross-tail current sheet, the formation of the substorm current wedge, and the expansion of the plasma sheet began in the near-earth region, and subsequently spread tailward as well as longitudinally.

In this paper, 167 dispersionless energetic ion injections which were observed by AMPTE CCE are identified. The radial and local time distribution of the events as a function of kp is qualitatively similar to that envisioned in the injection boundary model of Mauk and McIlwain (1974). It is argued that particles observed during dispersionless injections are locally energized during the disruption of the cross-tail current sheet. Therefore, the injection boundary is identified as derived from the spatial distribution of dispersionless injections, with the earthward edge of the region of the magnetotail which undergoes current sheet disruption during the substorm expansion phase. It is shown that this qualitative model for the generation of the injection boundary can provide an explanation for the dispersionless nature, the double spiral shape, and the Kp dependence of the boundary.

Using AMPTE/CCE data taken in 1985 and 1986 when the CCE apogee (8.8 earth radii) was within 4.5 hours of midnight, 167 injection events in the near-earth magnetotail have been cataloged. These events are exactly or nearly dispersionless on a 72-sec time scale from 25 keV to 285 keV. The changes in the field magnitude are found to be consistent with the expected effects of the diversion/disruption of the cross-tail current during a substorm, and the latitudinal position of the current sheet is highly variable within the orbit of CCE. The local time variation of the magnetic-field changes implies that the substorm current wedge is composed of longitudinally broad Birkeland currents.

The relationship between the morphology of energetic particle substorm injections and the change in the magnetic field magnitude over the course of the event is examined. Using the statistical relationships between the magnetic field during the growth phase and the change in the field magnitude during substorms calculated by Lopez et al. (1988), a limited number of dispersionless ion injections observed by AMPTE CCE are selected. It is argued that this limited set is representative of a large set of events and that the conclusions drawn from examining those events are valid for substorms in general in the inner magnetosphere. It is demonstrated that in an event when CCE directly observed the disruption of the current sheet, the particle and field data show that the region of particle acceleration was highly turbulent and was temporally, and perhaps spatially, limited and that the high fluxes of energetic particles are qualitatively associated with intense inductive electric fields.