Low-power wireless technology is a part and parcel of our daily life, shaping the way in which we behave, interact, and more generally live. The ubiquity of cheap, tiny, battery-powered devices augmented with sensing, actuation, and wireless communication capabilities has given rise to a ``smart" society, where people, machines, and objects are seamlessly interconnected, among themselves and with the environment. Behind the scenes, low-power wireless protocols are what enables and rules all interactions, organising these embedded devices into wireless networks, and orchestrating their communications. The recent years have witnessed a persistent increase in the pervasiveness and impact of low-power wireless. After having spawned a wide spectrum of powerful applications in the consumer domain, low-power wireless solutions are extending their influence over the industrial context, where their adoption as part of feedback control loops is envisioned to revolutionise the production process, paving the way for the Fourth Industrial Revolution. However, as the scale and relevance of low-power wireless systems continue to grow, so do the challenges posed to the communication substrates, required to satisfy ever more strict requirements in terms of reliability, responsiveness, and energy consumption. Harmonising these conflicting demands is far beyond what is enabled by current network stacks and control architectures; the need to timely bridge this gap has spurred a new wave of interest in low-power wireless networking, and directly motivated our work. In this thesis, we take on this challenge with a main conceptual and technical tool: concurrent transmissions (CTX), a technique that, by enforcing nodes to transmit concurrently, has been shown to unlock unprecedented fast, reliable, and energy efficient multi-hop communications in low-power wireless networks, opening new opportunities for protocol design. We first direct our research endeavour towards industrial applications, focusing on the popular IEEE 802.15.4 narrowband PHY layer, and advance the state of the art along two different directions: interference resilience and aperiodic wireless control. We tackle radio-frequency noise by extensively analysing, for the first time, the dependability of CTX under different types, intensities, and distributions of reproducible interference patterns, and by devising techniques to push it further. Specifically, we concentrate on CRYSTAL, a recently proposed communication protocol that relies on CTX to rapidly and dependably collect aperiodic traffic. By integrating channel hopping and noise detection in the protocol operation, we provide a novel communication stack capable of supporting aperiodic transmissions with near-perfect reliability and a per-mille radio duty cycle despite harsh external interference. These results lay the ground towards the exploitation of CTX for aperiodic wireless control; we explore this research direction by co-designing the Wireless Control Bus (WCB), our second contribution. WCB is a clean-slate CTX-based communication stack tailored to event-triggered control (ETC), an aperiodic control strategy holding the capability to significantly improve the efficiency of wireless control systems, but whose real-world impact has been hampered by the lack of appropriate networking support. Operating in conjunction with ETC, WCB timely and dynamically adapts the network operation to the control demands, unlocking an order-of-magnitude reduction in energy costs w.r.t. traditional periodic approaches while retaining the same control performance, therefore unleashing and concretely demonstrating the true ETC potential for the first time. Nevertheless, low-power wireless communications are rapidly evolving, and new radios striking novel trade-offs are emerging. Among these, in the second part of the thesis we focus on ultra-wideband (UWB). By providing hitherto missing networking primitives for multi-hop dissemination and collection over UWB, we shed light on the communication potentialities opened up by the high data throughput, clock precision, and noise resilience offered by this technology. Specifically, as a third contribution, we demonstrate that CTX not only can be successfully exploited for multi-hop UWB communications but, once embodied in a full-fledged system, provide reliability and energy performance akin to narrowband. Furthermore, the higher data rate and clock resolution of UWB chips unlock up to 80% latency reduction w.r.t. narrowband CTX, along with orders-of-magnitude improvements in network-wide time synchronization. These results showcase how UWB CTX could significantly benefit a multitude of applications, notably including low-power wireless control. With WEAVER, our last contribution, we make an additional step towards this direction, by supporting the key functionality of data collection with an ultra-fast convergecast stack for UWB. Challenging the internal mechanics of CTX, WEAVER interleaves data and acknowledgements flows in a single, self-terminating network-wide flood, enabling the concurrent collection of different packets from multiple senders with unprecedented latency, reliability, and energy efficiency. Overall, this thesis pushes forward the applicability and performance of low-power wireless, by contributing techniques and protocols to enhance the dependability, timeliness, energy efficiency, and interference resilience of this technology. Our research is characterized by a strong experimental slant, where the design of the systems we propose meets the reality of testbed experiments and evaluation. Via our open-source implementations, researchers and practitioners can directly use, extend, and build upon our contributions, fostering future work and research on the topic.