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• We developed a new semi-distributed hydrological model for a high mountain catchment with complex hydrogeology. • The model structure incorporates both the bedrock aquifer in the mountain block and the porous aquifer at the valley floor. • The model provides a better understanding of the collective behavior of the bedrock and porous aquifers. • We developed a multi-step model evaluation workflow to identify weakness in the model structure. Mountainous groundwater systems are usually characterized by great geological complexity and highly heterogeneous hydraulic properties. For that reason, proper system characterization, monitoring and modelling remain challenging. In this study, we investigated a geologically complex alpine catchment (from 1400 to 2900 m asl) in the Dolomites (Italian Alps) by combining hydrogeological field investigation, hydrological monitoring and modelling. A semi-distributed process-based hydrological model was applied to simulate the continuous measured catchment discharge in a period of three years, which covers a large variation of hydrodynamic conditions. The model structure couples the sequential hydrogeological units within the studied catchment: (1) the fractured dolomitic rocks as bedrock aquifer and 2) the unconsolidated deposits accumulating on the slopes and at the valley floor as porous aquifer. In order to evaluate the model structure and parameterization in depth, we applied a multi-step evaluation approach considering both parameter sensitivity and uncertainty. The modelling results demonstrate that the newly developed model can reproduce most discharge behavior of aquifers. The model indicates a seasonal dynamic linkage between surface and subsurface storage units during different flow conditions. Besides the matrix and conduit flow in fractured dolomitic aquifer, it highlights the important role of unconsolidated sediments (porous aquifer) to the storage and discharge behavior of the entire groundwater system. Furthermore, with the comprehensive model evaluation we learned the model performance deficit during extreme high flow conditions and proposed a more detailed hydrogeological conceptual model. We believe that the proposed modelling approach can be transferred to other high mountain catchments with similar hydro(geo)logical characteristics to characterize the collective behavior of aquifer systems, explore conceptual model weakness and optimize catchment monitoring work. [ABSTRACT FROM AUTHOR]

The calculation of runoff and infiltration parameters is a fundamental task for water budget estimation and water resources management. The "Kenessey method" allows these values to be calculated and its use is widespread among water scientists and practitioners. Due to language barriers and inefficient translation in past decades, the method has undergone some misinterpretations and is now far from its original usefulness and purpose. The use of the modified method can give unreal results for specific climatic zones. The purpose of this paper is to point out these methodological variations and to return to the original approach, improving it with modern technology. [ABSTRACT FROM AUTHOR]

Groundwater pollution threatens human and ecosystem health in many regions around the globe. Fast flow to the groundwater through focused recharge is known to transmit short-lived pollutants into carbonate aquifers, endangering the quality of groundwaters where one quarter of the world's population lives. However, the large-scale impact of such focused recharge on groundwater quality remains poorly understood. Here, we apply a continentalscale model to quantify the risk of groundwater contamination by degradable pollutants through focused recharge in the carbonate rock regions of Europe, North Africa, and the Middle East. We show that focused recharge is the primary reason for widespread rapid transport of contaminants to the groundwater. Where it occurs, the concentration of pollutants in groundwater recharge that have not yet degraded increases from <1% to around 20 to 50% of their concentrations during infiltration. Assuming realistic application rates, our simulations show that degradable pollutants like glyphosate can exceed their permissible concentrations by 3 to 19 times when reaching the groundwater. Our results are supported by independent estimates of young water fractions at 78 carbonate rock springs over Europe and a dataset of observed glyphosate concentrations in the groundwater. They imply that in times of continuing and increasing industrial and agricultural productivity, focused recharge may result in an underestimated and widespread risk to usable groundwater volumes. [ABSTRACT FROM AUTHOR]