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The corrosion enhancement due to plasma post-oxidation subsequent to plasma nitriding of the samples of low alloy annealed steel AISI 4140 was evaluated. The plasma nitriding was carried out at ≈570 °C for 1-3 h in an atmosphere of 75% H2 and 25% N2. After this process post-oxidation at ≈450 °C in a gas mixture, air and dry air-like was conducted for an hour. The treated samples were characterized using the XRD, SEM, AFM, potentiodynamic polarization and Vickers microhardness tests. The outcome of combined processes showed the presence of ε and γ nitrided phases in the inner compound layer and in the outer one mostly of magnetite phase and barely visible of hematite one without using H2 in the post-oxidation process. Also in these processes, the corrosion potential proved to be lower in the treated specimens than the untreated ones, and the corrosion current decreased up to one order of magnitude when treated in environment air and air-like ambient. [ABSTRACT FROM AUTHOR]

The annealed low alloy 4140 steel samples have been nitrided for different treatment periods (1-6 h) in an RF inductive plasma discharge with very low bias voltage (≈400 V). The resulting nitrided layer has been observed by means of an optical microscope whereas the nitride phases have been characterised by X-ray analysis. The corrosion response, assessed by the potentiodynamic tests in the 3.5% NaCl solution, presents both higher noble potential values and lower corrosion rates when compared with the untreated sample. The Vickers microhardness tests values show an appreciable increment compared to that of the untreated sample. The process is characterized by a high overall e  ciency because similar average Vickers tests values were obtained, no matter for how long the treatment was extended. Likewise, the scanning electron micrographs confirmed no appreciable size evolution of the compound layer microstructure at different times of treatment. [ABSTRACT FROM AUTHOR]

Plasma immersion ion implantation (PIII) has proved to be a good method to implant ions into materials in order to modify their surface properties. In this article, we describe the design and construction of a small and low cost PIII device. The instrumentation consists of: (i) a simple plasma immersion experimental setup for ion implantation based on direct current glow discharges, (ii) a 25 kV pulse generator, (iii) an electrical probe system endowed with a guard to carry out diagnostics of the plasma parameters, and (iv) an automatic spectroscopy system for determining the plasma temperature. A study of the sheath expansion has been considered in order to fulfill the requirements of electron temperature, plasma density, high voltage bias, pulse frequency, and pulse duration for an adequate PIII process. [ABSTRACT FROM AUTHOR]

Background and Aims: The efficacy of a direct application of plasma needle to in vivo wound healing was experimentally studied in mice. This kind of plasma has achieved considerable success in blood coagulation and tissue restoration in mice. In the development of the present study, an argon plasma needle was chosen for coagulation purposes, whereas for healing purposes, a helium plasma needle was used. Methods: Treatment was applied with a plasma needle produced by argon and helium to a wound induced in laboratory mice. Tissue regeneration was carried out by three argon plasma treatments with 0.5 SLPM flow for 1 min and three treatments of helium with 1.5 SLPM flow. Intervals between each treatment were 5 min and 60 min for argon and helium plasmas, respectively, thus completing a total treatment time of 180 min. Histological sections were performed to corroborate the internal bleeding and tissue regeneration. Results: After three treatments with argon plasma, the blood produced in the wound was coagulated and protein material appeared. By means of treatment with helium plasma, an approach of the wound edges was produced until the conclusion thereof. These results were corroborated histologically. Conclusions: This type of acceleration during the skin wound healing process can be attributed to the formation of reactive species such as NO, which were increased in the helium plasma needle with respect to the argon plasma needle. [ABSTRACT FROM AUTHOR]

An experimental study of ATCC (American Type Culture Collection) 8739 Escherichia coli bacteria inactivation in water by means of pulsed dielectric barrier discharge (PDBD) atmospheric pressure plasmas is presented. Plasma is generated by an adjustable power source capable of supplying high voltage 25 kV puises, -30 Fs long and at a 500 Hz frequency. The process was conducted in a ~152 cm³ cylindrical stainless steel coaxial reactor, endowed with a straight central electrode and a gas inlet. The bacterial concentration in water was varied from 103 up to 108 E. coli cells per millilitre. The inactivation was achieved without gas flow in the order of 82% at 108 colony-forming units per millilitre (CFU mL-1) concentrations in 600 s. In addition, oxygen was added to the gas supply in order to increase the ozone content in the process, raising the inactivation percentage to the order of 90% in the same treatment time. In order to reach a higher efficiency however, oxygen injection modulation is applied, leading to inactivation percentages above 99.99%. These results are similarly valid for lower bacterial concentrations. [ABSTRACT FROM AUTHOR]

Samples of pure titanium have been treated by means a plasma immersed ion implantation (PIII) process in a DC glow discharge in pure oxygen and in different nitrogen-oxygen mixtures. In contrast with conventional voltage supply based glow PIII, the present study has been conducted with a novel specifically designed high current supply which allows a high electron density to be kept constant, regardless of gas pressure variations, within the operational ranks. Thus, the acquired sample characteristics can be more clearly ascribed to the chemical composition of the mixture. One stratified TiO2 (rutile) and TiN0.26 layer was identified from XRD and Raman spectroscopy, both of these compounds reputedly being highly biocompatible. The superficial hardness of the samples was improved up to more than five times that of the untreated reference sample, namely, ∼1600 Vickers microhardness (10 g load) thanks to a 2–6 μm deep implanted layer. These optimal results have been obtained from an 80% nitrogen 20% oxygen mixture at 1×10-2 torr. Furthermore, with this gas proportion, the best roughness finishing of the sample set was accomplished, which can be relevant for biocompatible applications. [ABSTRACT FROM AUTHOR]

We propose a novel combined system of pulsed dielectric barrier discharges (PDBDs) and silver-modified natural zeolite (Ag–zeolite) in liquid in bubbles. The system was tested with the Escherichia coli bacteria immersed in water. In order to evaluate the efficiency of the system in bacterial inactivation a microbiological analysis was carried out; 9.82-ln of bacterial reduction was obtained using the combined system, whereas 0.43-ln of bacterial reduction was obtained using Ag–zeolite alone, and 6.26-ln with PDBD. The elapsed time was 10 minutes for the three treatments. [ABSTRACT FROM AUTHOR]