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Coherent Elastic Neutrino-Nucleus (CE$\nu$NS) and Elastic Neutrino-Electron Scattering (E$\nu$ES) data are exploited to constrain "chiral" $U(1)_{X}$ gauged models with light vector mediator mass. These models fall under a distinct class of new symmetries called Dark Hypercharge Symmetries. A key feature is the fact that the $Z'$ boson can couple to all Standard Model fermions at tree level, with the $U(1)_X$ charges determined by the requirement of anomaly cancellation. Notably, the charges of leptons and quarks can differ significantly depending on the specific anomaly cancellation solution. As a result, different models exhibit distinct phenomenological signatures and can be constrained through various experiments. In this work, we analyze the recent data from the COHERENT experiment, along with results from Dark Matter (DM) direct detection experiments such as XENONnT, LUX-ZEPLIN, and PandaX-4T, and place new constraints on three benchmark models. Additionally, we set constraints from a performed analysis of TEXONO data and discuss the prospects of improvement in view of the next-generation DM direct detection DARWIN experiment., Comment: 44 pages, 13 figures, 3 tables

We investigate relativistic effects on the performance of a quantum battery in an open quantum framework. We consider an Unruh-DeWitt detector driven by a coherent classical pulse as a quantum battery that is interacting with a massless scalar field through a quadratic coupling. The battery follows a trajectory composed of uniform acceleration along one direction, combined with constant four-velocity components in the orthogonal plane to the acceleration. Accelerated motion degrades the performance of the quantum battery rapidly in the absence of the orthogonal velocity component. We show that the quadratic scalar field coupling enhances coherence and stability in the presence of orthogonal velocity. We observe that decoherence is mitigated significantly, resulting in remarkable improvement in the battery capacity and efficiency compared to the case of the usual linear field coupling. This opens up the possibility of nonlinear environmental coupling enabling stored energy to be retained over longer durations, leading to more efficient operation of quantum devices., Comment: 15 pages LaTeX; Comments are welcome

Artificial neural networks (ANNs) have fundamentally transformed the field of computer vision, providing unprecedented performance. However, these ANNs for image processing demand substantial computational resources, often hindering real-time operation. In this paper, we demonstrate an optical encoder that can perform convolution simultaneously in three color channels during the image capture, effectively implementing several initial convolutional layers of a ANN. Such an optical encoding results in ~24,000 times reduction in computational operations, with a state-of-the art classification accuracy (~73.2%) in free-space optical system. In addition, our analog optical encoder, trained for CIFAR-10 data, can be transferred to the ImageNet subset, High-10, without any modifications, and still exhibits moderate accuracy. Our results evidence the potential of hybrid optical/digital computer vision system in which the optical frontend can pre-process an ambient scene to reduce the energy and latency of the whole computer vision system., Comment: 21 pages, 4 figures, 2 tables

The effects of trees on urban flows are often determined using computational fluid dynamics approaches which typically use a quadratic drag formulation based on the leaf-area density $a$ and a volumetric drag coefficient $C_{d}^V$ to model vegetation. In this paper, we develop an analytical model for the flow within a vegetation canopy and identify that the drag length $\ell_d = (a C_d^V)^{-1}$ is the key metric to describe the local tree drag characteristics. A detailed study of the literature suggests that the median $\ell_d$ observed in field experiments is $21$ m for trees and $0.7$ m for low vegetation (crops). A total of $168$ large-eddy simulations are conducted to obtain a closed form of the analytical model. The model allows determining $a$ and $C_d^V$ from wind-tunnel experiments that typically present the drag characteristics in terms of the classical drag coefficient $C_d$ and the aerodynamic porosity $\alpha_L$. We show that geometric scaling of $\ell_d$ is the appropriate scaling of trees in wind tunnels. Evaluation of $\ell_d$ for numerical simulations and wind-tunnel experiments (assuming geometric scaling $1:100$) in literature shows that the median $\ell_d$ in both these cases is about $5$ m, suggesting possible overestimation of vegetative drag.

Large language models (LLMs) have exhibited remarkable reasoning and planning capabilities. Most prior work in this area has used LLMs to reason through steps from an initial to a goal state or criterion, thereby effectively reasoning in a forward direction. Nonetheless, many planning problems exhibit an inherent asymmetry such that planning backward from the goal is significantly easier -- for example, if there are bottlenecks close to the goal. We take inspiration from this observation and demonstrate that this bias holds for LLM planning as well: planning performance in one direction correlates with the planning complexity of the problem in that direction. However, our experiments also reveal systematic biases which lead to poor planning in the backward direction. With this knowledge, we propose a backward planning algorithm for LLMs that first flips the problem and then plans forward in the flipped problem. This helps avoid the backward bias, generate more diverse candidate plans, and exploit asymmetries between the forward and backward directions in planning problems -- we find that combining planning in both directions with self-verification improves the overall planning success rates by 4-24% in three planning domains., Comment: Under review

We study the relaxation of a diffusive particle confined in an arbitrary external potential and subject to a non-Markovian resetting protocol. With a constant rate $r$, a previous time $\tau$ between the initial time and the present time $t$ is chosen from a given probability distribution $K(\tau,t)$, and the particle is reset to the position that was occupied at time $\tau$. Depending on the shape of $K(\tau,t)$, the particle either relaxes toward the Gibbs-Boltzmann distribution or toward a non-trivial stationary distribution that breaks ergodicity and depends on the initial position and the resetting protocol. From a general asymptotic theory, we find that if the kernel $K(\tau,t)$ is sufficiently localized near $\tau=0$, i.e., mostly the initial part of the trajectory is remembered and revisited, the steady state is non-Gibbs-Boltzmann. Conversely, if $K(\tau,t)$ decays slowly enough or increases with $\tau$, i.e., recent positions are more likely to be revisited, the probability distribution of the particle tends toward the Gibbs-Boltzmann state at large times. However, the temporal approach to the stationary state is generally anomalously slow, following for instance an inverse power-law or a stretched exponential, if $K(\tau,t)$ is not too strongly peaked at the current time $t$. These findings are verified by the analysis of several exactly solvable cases and by numerical simulations., Comment: 22 pages, 2 figures

The KM3NeT Collaboration has tackled a common challenge faced by the astroparticle physics community, namely adapting the experiment-specific simulation software to work with the CORSIKA air shower simulation output. The proposed solution is an extension of the open-source code gSeaGen, allowing for the transport of muons generated by CORSIKA to a detector of any size at an arbitrary depth. The gSeaGen code was not only extended in terms of functionalities but also underwent a thorough redesign of the muon propagation routine, resulting in a more accurate and efficient simulation. This paper presents the capabilities of the new gSeaGen code as well as prospects for further developments., Comment: 27 pages, 13 figures

In October 2024, The object BL Lac experienced a brightest flaring event in gamma-ray ($>$100 MeV) with a historical $\gamma$-ray flux of $\sim$10$^{-5}$ erg cm$^{-2}$ s$^{-1}$. Soon after the event was followed across the waveband and in X-ray (0.3-10 keV) it was also found to be flaring with the maximum flux achieved during this event as 8.30$\times$10$^{-11}$ erg cm$^{-2}$ s$^{-1}$. The high gamma-ray significance enables us to probe the shortest time scale variability possible and for that, we produced the orbital binned light curve, 5 minutes binned light curve, and the 2 minutes binned light curve. A clear variation is seen in the 5-minute light curve and is fitted with the sum of exponentials to derive the rise and decay time scale which ranges between 3 to 12 minutes. The fastest variability time is also estimated to be an order of 1 minute from 2 minute. The estimated size of the emission region is very small (10$^{13}$ cm) compared to the size of the black hole event horizon. The location of the emission region is estimated to be very close to the supermassive black hole (10$^{14}$ cm) and much inside the BLR (0.1 pc). We discussed the possible way to explain this fast-flux variability in BL Lac., Comment: Submitted

In this work, we studied the broadband temporal and spectral properties of the flat-spectrum radio quasar (FSRQ) Ton 599 and explored the one-zone leptonic model to fit the broadband spectral energy distribution (SED). We collected the long-term data from June 2020 to August 2024 when the source was in a long flaring episode. We used the Bayesian block methodology to identify the various flux states which included three flares. The broadband fractional variability is estimated during two flaring states and in the total light curve. The Fvar distribution with respect to frequency shows a double hump structure similar to broadband SED. The Power spectral density (PSD) shows a pink-noise kind of stochastic variability in the light curve and we do not see any break in the power spectrum suggesting a much longer characteristic time scale is involved in gamma-ray variability. The flux distribution is well-fitted with a double log-normal flux distribution suggesting the variability of non-linear in nature. The gamma-ray, optical, and X-ray emissions were found to be highly correlated with a zero time lag suggesting a co-spatial origin. We used the one-zone leptonic model to reproduce the broad-band spectrum in the energy range from IR to very high-energy gamma-ray. The increase in the magnetic field and the Doppler factor were found to be the main cause for high flux states. The XMM-Newton spectra taken during one of the flaring durations exhibit a signature of black body emission from the accretion disk suggesting a possible disk-jet coupling. This has also been indicated by the gamma-ray flux distribution which shows the distribution as non-linear in nature mostly seen in galactic X-ray binaries or AGN where emission is dominated by the accretion disk. This possibility of disk-jet coupling will be explored in the coming works., Comment: Submitted

We study a flaring activity of the HSP Mrk421 that was characterized from radio to very-high-energy (VHE; E $>0.1$TeV) gamma rays with MAGIC, Fermi-LAT, Swift, XMM-Newton and several optical and radio telescopes. These observations included, for the first time for a gamma-ray flare of a blazar, simultaneous X-ray polarization measurements with IXPE. We find substantial variability in both X-rays and VHE gamma rays throughout the campaign, with the highest VHE flux above 0.2 TeV occurring during the IXPE observing window, and exceeding twice the flux of the Crab Nebula. However, the VHE and X-ray spectra are on average softer, and the correlation between these two bands weaker that those reported in previous flares of Mrk421. IXPE reveals an X-ray polarization degree significantly higher than that at radio and optical frequencies. The X-ray polarization angle varies by $\sim$100$^\circ$ on timescales of days, and the polarization degree changes by more than a factor 4. The highest X-ray polarization degree reaches 26%, around which a X-ray counter-clockwise hysteresis loop is measured with XMM-Newton. It suggests that the X-ray emission comes from particles close to the high-energy cutoff, hence possibly probing an extreme case of the Turbulent Extreme Multi-Zone model. We model the broadband emission with a simplified stratified jet model throughout the flare. The polarization measurements imply an electron distribution in the X-ray emitting region with a very high minimum Lorentz factor, which is expected in electron-ion plasma, as well as a variation of the emitting region size up to a factor of three during the flaring activity. We find no correlation between the fluxes and the evolution of the model parameters, which indicates a stochastic nature of the underlying physical mechanism. Such behaviour would be expected in a highly turbulent electron-ion plasma crossing a shock front., Comment: Submitted to Astronomy and Astrophysics. Corresponding authors: Axel Arbet-Engels, Lea Heckmann, David Paneque

OT 081 is a well-known, luminous blazar that is remarkably variable in many energy bands. We present the first broadband study of the source which includes very-high-energy (VHE, $E>$100\,GeV) $\gamma$-ray data taken by the MAGIC and H.E.S.S. imaging Cherenkov telescopes. The discovery of VHE $\gamma$-ray emission happened during a high state of $\gamma$-ray activity in July 2016, observed by many instruments from radio to VHE $\gamma$-rays. We identify four states of activity of the source, one of which includes VHE $\gamma$-ray emission. Variability in the VHE domain is found on daily timescales. The intrinsic VHE spectrum can be described by a power-law with index $3.27\pm0.44_{\rm stat}\pm0.15_{\rm sys}$ (MAGIC) and $3.39\pm0.58_{\rm stat}\pm0.64_{\rm sys}$ (H.E.S.S.) in the energy range of 55--300\,GeV and 120--500\,GeV, respectively. The broadband emission cannot be sucessfully reproduced by a simple one-zone synchrotron self-Compton model. Instead, an additional external Compton component is required. We test a lepto-hadronic model that reproduces the dataset well and a proton-synchrotron dominated model that requires an extreme proton luminosity. Emission models that are able to successfully represent the data place the emitting region well outside of the Broad Line Region (BLR) to a location at which the radiative environment is dominated by the infrared thermal radiation field of the dusty torus. In the scenario described by this flaring activity, the source appears to be an FSRQ, in contrast with past categorizations. This suggests that the source can be considered to be a transitional blazar, intermediate between BL~Lac and FSRQ objects., Comment: Accepted on MNRAS Corresponding authors: M. Manganaro, J. Becerra Gonz\'alez, M. Seglar-Arroyo, D. A. Sanchez

Large Language Models (LLMs) are seeing significant adoption in every type of organization due to their exceptional generative capabilities. However, LLMs are found to be vulnerable to various adversarial attacks, particularly prompt injection attacks, which trick them into producing harmful or inappropriate content. Adversaries execute such attacks by crafting malicious prompts to deceive the LLMs. In this paper, we propose a novel approach based on embedding-based Machine Learning (ML) classifiers to protect LLM-based applications against this severe threat. We leverage three commonly used embedding models to generate embeddings of malicious and benign prompts and utilize ML classifiers to predict whether an input prompt is malicious. Out of several traditional ML methods, we achieve the best performance with classifiers built using Random Forest and XGBoost. Our classifiers outperform state-of-the-art prompt injection classifiers available in open-source implementations, which use encoder-only neural networks.

In this paper, we address the exponential stabilization of the linearized FitzHugh-Nagumo system using an event-triggered boundary control strategy. Employing the backstepping method, we derive a feedback control law that updates based on specific triggering rules while ensuring the exponential stability of the closed-loop system. We establish the well-posedness of the system and analyze its input-to-state stability in relation to the deviations introduced by the event-triggered control. Numerical simulations demonstrate the effectiveness of this approach, showing that it stabilizes the system with fewer control updates compared to continuous feedback strategies while maintaining similar stabilization performance.

We study a simple one dimensional sluggish random walk model with subdiffusive growth. In the continuum hydrodynamic limit, the model corresponds to a particle diffusing on a line with a space dependent diffusion constant D(x)= |x|^{-\alpha} and a drift potential U(x)=|x|^{-\alpha}, where \alpha\geq 0 parametrizes the model. For \alpha=0 it reduces to the standard diffusion, while for \alpha>0 it leads to a slow subdiffusive dynamics with the distance scaling as x\sim t^{\mu} at late times with \mu= 1/(\alpha+2)\leq 1/2. In this paper, we compute exactly, for all \alpha\ge 0, the full probability distributions of three observables for a sluggish walker of duration T starting at the origin: (i) the occupation time t_+ denoting the time spent on the positive side of the origin, (ii) the last passage time t_{\rm l} through the origin before T, and (iii) the time t_M at which the walker is maximally displaced on the positive side of the origin. We show that while for \alpha=0 all three distributions are identical and exhibit the celebrated arcsine laws of L\'evy, they become different from each other for any \alpha>0 and have nontrivial shapes dependent on \alpha. This generalizes the L\'evy's three arcsine laws for normal diffusion (\alpha=0) to the subdiffusive sluggish walker model with a general \alpha\geq 0. Numerical simulations are in excellent agreement with our analytical predictions., Comment: 27 pages, 8 Figures

Enabling clinicians and researchers to directly interact with global genomic data resources by removing technological barriers is vital for medical genomics. AskBeacon enables Large Language Models to be applied to securely shared cohorts via the GA4GH Beacon protocol. By simply "asking" Beacon, actionable insights can be gained, analyzed and made publication-ready.

Long-range imaging in the thermal infrared band is critical for applications such as environmental monitoring, industrial inspections, and surveillance. To achieve high quality imaging, these systems typically require large apertures and many elements with complex shapes to correct aberrations, adding significant weight and cost. Large-area metasurface optics offer a promising solution for weight reduction; however, their substantial chromatic aberrations limit their effectiveness in the long-wave infrared (LWIR) band where broadband imaging is typically desired. In this work, we introduce a hybrid system comprising four refractive lenses and two all-silicon metasurface correctors (meta-correctors) to achieve high-quality, broadband thermal imaging at long range. Compared to a refractive-only assembly, our system demonstrates a three-fold contrast enhancement at the detector's half-Nyquist frequency. Testing outside the laboratory reveals noticeably sharper images, with human features clearly recognizable at distances of 250 meters. The assembly utilizes off-the-shelf refractive elements and avoids the use of germanium, which poses a supply chain risk. Our findings highlight the potential of hybrid meta-corrector systems to enable long-range, lightweight, and cost-effective LWIR imaging solutions.

Imaging atmospheric Cherenkov telescopes (IACTs) are used to observe very high-energy photons from the ground. Gamma rays are indirectly detected through the Cherenkov light emitted by the air showers they induce. The new generation of experiments, in particular the Cherenkov Telescope Array Observatory (CTAO), sets ambitious goals for discoveries of new gamma-ray sources and precise measurements of the already discovered ones. To achieve these goals, both hardware and data analysis must employ cutting-edge techniques. This also applies to the LST-1, the first IACT built for the CTAO, which is currently taking data on the Canary island of La Palma. This paper introduces a new event reconstruction technique for IACT data, aiming to improve the image reconstruction quality and the discrimination between the signal and the background from misidentified hadrons and electrons. The technique models the development of the extensive air shower signal, recorded as a waveform per pixel, seen by CTAO telescopes' cameras. Model parameters are subsequently passed to random forest regressors and classifiers to extract information on the primary particle. The new reconstruction was applied to simulated data and to data from observations of the Crab Nebula performed by the LST-1. The event reconstruction method presented here shows promising performance improvements. The angular and energy resolution, and the sensitivity, are improved by 10 to 20% over most of the energy range. At low energy, improvements reach up to 22%, 47%, and 50%, respectively. A future extension of the method to stereoscopic analysis for telescope arrays will be the next important step., Comment: Accepted in A&A

The field of meta-optics has grown to include metalenses spanning the ultraviolet to terahertz regimes. Imaging is a key application of meta-optics, with recent works demonstrating meta-optical imaging with advanced functionalities including wide field of view, broadband operation, and polarization sensitivity. In this review, we focus on meta-optical imaging for thermal wavelengths. Thermal meta-optics are less well-studied than those in the visible range but have vast potential applications spanning defense, health, and geological sensing. We first introduce these applications and their specific challenges. With compact form-factor and multi-functional capabilities, we suggest that meta-optics are particularly well-suited to meet the needs of imaging in the mid- and long-wave infrared. Then, we review published experimental demonstrations of thermal imaging via meta-optics. These meta-optics vary in complexity from simple hyperboloid metalenses to complex systems composed of engineered meta-atoms and multiple layers of optics. Finally, we suggest some areas where thermal meta-optics may be useful, and we identify some emerging approaches to solve lingering challenges of meta-optical imaging.

Binary oxide ferroelectrics like doped HfO2, compatible with complementary metal-oxide-semiconductor (CMOS) platforms, have gained significant interest for energy efficient, scalable, high-performance non-volatile memory and neuromorphic technologies. However, there is a gap in models for doped hafnia systems that can explain physical properties while being circuit simulation compatible and computationally efficient. We present a universal model based on the Jiles-Atherton equations to reproduce experimentally measured polarization switching in ferroelectric thin film capacitors under different electric field and temperature conditions. Additionally, device-to-device variation effect on the model parameters is presented, which will enable large-scale integration of the FE components to complex functional circuits. Due to increased interest in cryogenic electronics for quantum computing and space technologies, effect of temperatures on polarization switching is investigated down to 4 K. We show our model can reproduce the experimental polarization-voltage relation of Hafnium Zirconium Oxide (HZO) capacitors with nearly 100 % accuracy, for different electric fields and temperatures down to 4 K, including analog switching. We find cooling the devices below 100 K increases polarization update linearity and symmetry significantly. Our results represent an important advancement towards application of ferroelectric HZO capacitors for large-scale memory and neuromorphic circuits operating down to deep cryogenic temperatures.

Quantum computing, ultra-low-noise sensing, and high-energy physics experiments often rely on superconducting circuits or semiconductor qubits and devices operating at deep cryogenic temperatures (4K and below). Photonic integrated circuits and interconnects have been demonstrated for scalable communications and optical domain transduction in these systems. Due to energy and area constraints, many of these devices need enhanced light-matter interaction, provided by photonic resonators. A key challenge, however, for using these resonators is the sensitivity of resonance wavelength to process variations and thermal fluctuations. While thermo-optical tuning methods are typically employed at room temperature to mitigate this problem, the thermo-optic effect is ineffective at 4K. To address this issue, we demonstrate a non-volatile approach to tune the resonance of photonic resonators using integrated phase-change materials (PCMs) at cryogenic temperatures. In this work, we report a 10Gb/s free-carrier dispersion based resonant photonic modulator that can be tuned in a non-volatile fashion at sub-4K temperatures using a commercial silicon photonics process. This method paves the way for realizing scalable cryogenic integrated photonics with thousands of resonant devices for quantum and high-energy physics applications.

In this paper, we present intriguing findings that characterize both the closed (unbounded) and bounded EP operators on Hilbert spaces. Additionally, we demonstrate the result $\gamma(T) \leq r(T)$, where $T$ is a bounded EP operator, and $\gamma(T) \text{ and } r(T)$ represent the reduced minimum modulus and the spectral radius of $T$, respectively.

Heavy neutral leptons (HNLs) are constrained by requirements of Big Bang Nucleosynthesis (BBN) as their decays significantly impact the formation of the primordial elements. We propose here a model where the primary decay channel for the HNLs is to an axion-like particle (ALP) and a neutrino. Consequently, HNLs can decay earlier and evade the BBN bound for lower masses, provided the ALPs themselves decay considerably later. Further cosmological and astrophysical constraints limit severely the range of validity of the ALP properties. We find that a new parameter region opens up for HNLs with masses between 1 MeV and 1 GeV, and active-sterile neutrino mixing strengths between $10^{-9}$ and $10^{-6}$ that is consistent with constraints and can be probed in future searches. In such a scenario, current bounds as well as sensitivities of future direct HNL searches such as at NA62 and DUNE will be affected., Comment: 32 pages, 6 figures

We present a coverage-guided testing algorithm for distributed systems implementations. Our main innovation is the use of an abstract formal model of the system that is used to define coverage. Such abstract models are frequently developed in early phases of protocol design and verification but are infrequently used at testing time. We show that guiding random test generation using model coverage can be effective in covering interesting points in the implementation state space. We have implemented a fuzzer for distributed system implementations and abstract models written in TLA+. Our algorithm shows better coverage over purely random exploration as well as random exploration guided by different notions of scheduler coverage and mutation. In particular, we show consistently higher coverage and detect bugs faster on implementations of distributed consensus protocols such as those in Etcd-raft and RedisRaft. Moreover, we discovered 13 previously unknown bugs in their implementations, four of which could only be detected by model-guided fuzzing.

Neutrinos described as an open quantum system may interact with the environment which introduces stochastic perturbations to their quantum phase. This mechanism leads to a loss of coherence along the propagation of the neutrino $-$ a phenomenon commonly referred to as decoherence $-$ and ultimately, to a modification of the oscillation probabilities. Fluctuations in space-time, as envisaged by various theories of quantum gravity, are a potential candidate for a decoherence-inducing environment. Consequently, the search for decoherence provides a rare opportunity to investigate quantum gravitational effects which are usually beyond the reach of current experiments. In this work, quantum decoherence effects are searched for in neutrino data collected by the KM3NeT/ORCA detector from January 2020 to November 2021. The analysis focuses on atmospheric neutrinos within the energy range of a few GeV to $100\,\mathrm{GeV}$. Adopting the open quantum system framework, decoherence is described in a phenomenological manner with the strength of the effect given by the parameters $\Gamma_{21}$ and $\Gamma_{31}$. Following previous studies, a dependence of the type $\Gamma_{ij} \propto (E/E_0)^n$ on the neutrino energy is assumed and the cases $n = -2,-1$ are explored. No significant deviation with respect to the standard oscillation hypothesis is observed. Therefore, $90\,\%$ CL upper limits are estimated as $\Gamma_{21} < 4.6\cdot 10^{-21}\,$GeV and $\Gamma_{31} < 8.4\cdot 10^{-21}\,$GeV for $n = -2$, and $\Gamma_{21} < 1.9\cdot 10^{-22}\,$GeV and $\Gamma_{31} < 2.7\cdot 10^{-22}\,$GeV for $n = -1$, respectively., Comment: 17 pages, 5 figures

Ammonia is a key component of fertilizer and a potential clean fuel and hydrogen carrier. The Haber-Bosch process for ammonia synthesis consumes more than half of industrial hydrogen and contributes up to ~3% of global greenhouse gas emissions. Light-driven reactions via surface plasmon resonances offer a less energy-intensive pathway for ammonia production by altering reaction intermediates. Here, we report gold-ruthenium plasmonic bimetallic alloys for ammonia synthesis at room temperature and pressure, driven by visible light. We use colloidal synthesis to create AuRu$_x$ alloys (x=0.1, 0.2, 0.3) and disperse these nanoparticles on MgO supports for gas-phase ammonia synthesis. We observe a ~60 $\mu$mol/g/h reactivity and ~0.12% external quantum efficiency on a AuRu$_0$$_.$$_2$ sample under 100 mW/cm$^2$ visible light. In-situ diffuse reflective infrared Fourier transform spectroscopic measurements show that hydrogenation of nitrogen adsorbates is accelerated under light compared to thermocatalysis. Combining wavelength-dependent reactivity and spectroscopic findings with semi-classical electromagnetic modeling, we show plasmonic bimetallic alloys expedite ammonia synthesis by aiding hydrogenation of adsorbed nitrogen species via plasmon-mediated hot electrons. Quantum mechanical calculations reveal hydrogen-assisted N$_2$ splitting in the excited state is key to activating the reaction under ambient conditions. Therefore, light or H$_2$ alone cannot dissociate N$_2$ -- the key bottleneck to breaking N$_2$'s triple bond. Our findings are consistent with recent hypotheses on how nitrogenase enzymes catalyze ammonia production at mild conditions and provide insights for sustainable photochemical transformations., Comment: 21 pages, 4 figures, journal article submission soon

Vision-language-action (VLA) models trained on large-scale internet data and robot demonstrations have the potential to serve as generalist robot policies. However, despite their large-scale training, VLAs are often brittle to task-irrelevant visual details such as distractor objects or background colors. We introduce Bring Your Own VLA (BYOVLA): a run-time intervention scheme that (1) dynamically identifies regions of the input image that the model is sensitive to, and (2) minimally alters task-irrelevant regions to reduce the model's sensitivity using automated image editing tools. Our approach is compatible with any off the shelf VLA without model fine-tuning or access to the model's weights. Hardware experiments on language-instructed manipulation tasks demonstrate that BYOVLA enables state-of-the-art VLA models to nearly retain their nominal performance in the presence of distractor objects and backgrounds, which otherwise degrade task success rates by up to 40%. Website with additional information, videos, and code: https://aasherh.github.io/byovla/ ., Comment: Website: https://aasherh.github.io/byovla/

Instruments for gamma-ray astronomy at Very High Energies ($E>100\,{\rm GeV}$) have traditionally derived their scientific results through proprietary data and software. Data standardisation has become a prominent issue in this field both as a requirement for the dissemination of data from the next generation of gamma-ray observatories and as an effective solution to realise public data legacies of current-generation instruments. Specifications for a standardised gamma-ray data format have been proposed as a community effort and have already been successfully adopted by several instruments. We present the first production of standardised data from the Major Atmospheric Gamma-ray Imaging Cherenkov (MAGIC) telescopes. We converted $166\,{\rm h}$ of observations from different sources and validated their analysis with the open-source software Gammapy. We consider six data sets representing different scientific and technical analysis cases and compare the results obtained analysing the standardised data with open-source software against those produced with the MAGIC proprietary data and software. Aiming at a systematic production of MAGIC data in this standardised format, we also present the implementation of a database-driven pipeline automatically performing the MAGIC data reduction from the calibrated down to the standardised data level. In all the cases selected for the validation, we obtain results compatible with the MAGIC proprietary software, both for the manual and for the automatic data productions. Part of the validation data set is also made publicly available, thus representing the first large public release of MAGIC data. This effort and this first data release represent a technical milestone toward the realisation of a public MAGIC data legacy., Comment: Accepted for publication in the Journal of High Energy Astrophysics

This paper introduces the hypothetical track-length fitting algorithm, a novel method for measuring the kinetic energies of ionizing particles in liquid argon time projection chambers (LArTPCs). The algorithm finds the most probable offset in track length for a track-like object by comparing the measured ionization density as a function of position with a theoretical prediction of the energy loss as a function of the energy, including models of electron recombination and detector response. The algorithm can be used to measure the energies of particles that interact before they stop, such as charged pions that are absorbed by argon nuclei. The algorithm's energy measurement resolutions and fractional biases are presented as functions of particle kinetic energy and number of track hits using samples of stopping secondary charged pions in data collected by the ProtoDUNE-SP detector, and also in a detailed simulation. Additional studies describe impact of the dE/dx model on energy measurement performance. The method described in this paper to characterize the energy measurement performance can be repeated in any LArTPC experiment using stopping secondary charged pions.

The carbon isotope ratio is a powerful tool for studying the evolution of stellar systems. Recent detections of CO isotopologues in disks and exoplanet atmospheres pointed towards significant fractionation in these systems. In order to understand the evolution of this quantity, it is crucial to trace the isotope abundance from stellar nurseries to planetary systems. During the protostellar stage the multiple vibrational modes of CO$_2$ and CO ice provide a unique opportunity to examine the carbon isotope ratio in the solid state. Now with the sensitivity of the \textit{James Webb Space Telescope}, these absorption features have become accessible at high S/N in Solar-mass systems. We quantify the $^{12}$CO$_2$/$^{13}$CO$_2$ and the $^{12}$CO/$^{13}$CO isotope ratios in 17 class 0/I low mass protostars from the $^{12}$CO$_2$ combination modes (2.70 ${\mu}$m and 2.77 ${\mu}$m), the $^{12}$CO$_2$ stretching mode (4.27 ${\mu}$m), the $^{13}$CO$_2$ stretching mode (4.39 ${\mu}$m), the $^{12}$CO$_2$ bending mode (15.2 ${\mu}$m), the $^{12}$CO stretching mode (4.67 ${\mu}$m) and the $^{13}$CO stretching mode (4.78 ${\mu}$m) using JWST observations. We also report a detection of the $^{12}$CO overtone mode at 2.35 ${\mu}$m. The $^{12}$CO$_2$/$^{13}$CO$_2$ ratios are in agreement and we find mean ratios of 85 $\pm$ 23, 76 $\pm$ 12 and 97 $\pm$ 17 for the 2.70 ${\mu}$m, 4.27 ${\mu}$m and the 15.2 ${\mu}$m bands, respectively. The main source of uncertainty stem from the error on the band strengths. The $^{12}$CO/$^{13}$CO ratios derived from the 4.67 ${\mu}$m bands are consistent, albeit elevated with respect to the $^{12}$CO$_2$/$^{13}$CO$_2$ ratios and we find a mean ratio of 165 $\pm$ 52. These findings indicate that ices leave the pre-stellar stage with elevated carbon isotope ratios relative to the interstellar medium and that fractionation becomes significant during the later stages.

We study a one-dimensional run-and-tumble particle (RTP), which is a prototypical model for active system, moving within an arbitrary external potential. Using backward Fokker-Planck equations, we derive the differential equation satisfied by its mean first-passage time (MFPT) to an absorbing target, which, without any loss of generality, is placed at the origin. Depending on the shape of the potential, we identify four distinct ``phases'', with a corresponding expression for the MFPT in every case, which we derive explicitly. To illustrate these general expressions, we derive explicit formulae for two specific cases which we study in detail: a double-well potential and a logarithmic potential. We then present different applications of these general formulae to (i) the generalization of the Kramer's escape law for an RTP in the presence of a potential barrier, (ii) the ``trapping'' time of an RTP moving in a harmonic well and (iii) characterizing the efficiency of the optimal search strategy of an RTP subjected to stochastic resetting. Our results reveal that the MFPT of an RTP in an external potential exhibits a far more complex and, at times, counter-intuitive behavior compared to that of a passive particle (e.g., Brownian) in the same potential., Comment: 34 pages, 16 figures

A numerical model based on hydrodynamic approach has been developed to emulate the device dynamics of active target Time Projection Chamber which is utilized for studying nuclear reaction through three dimensional tracking of concerned low energy particles. The proposed model has been used to investigate the performance of a prototype active target Time Projection Chamber, namely SAT-TPC, to be fabricated at Saha Institute of Nuclear Physics, for its application in nuclear physics experiments. A case study of non-relativistic elastic scattering $^4He+^{12}C$ with beam energy $25~MeV$ and current $2.3~pA$ has been opted for this purpose. The effect of beam induced space charge on the tracking performance the SAT-TPC prototype has been studied to optimize the beam current and scheme of the anode readout segmentation. The model has been validated by comparing its results to that of a particle model used to explain observed distortion in scattered particle tracks in a low energy nuclear physics experiment.

Monolayer semiconductor transferred on nanopillar arrays provides site-controlled, on-chip single photon emission, which is a scalable light source platform for quantum technologies. However, the brightness of these emitters reported to date often falls short of the perceived requirement for such applications. Also, the single photon purity usually degrades as the brightness increases. Hence, there is a need for a design methodology to achieve enhanced emission rate while maintaining high single photon purity. Using WSe$_2$ on high-aspect-ratio ($\sim 3$ - at least two-fold higher than previous reports) nanopillar arrays, here we demonstrate $>10$ MHz single photon emission rate in the 770-800 nm band that is compatible with quantum memory and repeater networks (Rb-87-D1/D2 lines), and satellite quantum communication. The emitters exhibit excellent purity (even at high emission rates) and improved out-coupling due to the use of a gold back reflector that quenches the emission away from the nanopillar., Comment: Accepted in Nano Letters

We explore constraints on the parameter space of the alternative left-right model originating from the leptonic sector. We analyse focuses on both lepton-flavour conserving observables, particularly the anomalous magnetic moment of the muon, and lepton-flavour-violating processes like $\mu \to e \gamma $ decay and $\mu-e$ conversions in nuclei. While contributions to the anomalous magnetic moment fall below the measured values at 2$\sigma$, current and future experimental sensitivities to flavour-violating branching rations of the Standard Model leptons are expected to impose lower bounds on the mass of the peculiar $SU(2)_R$ gauge boson of the model. This provides complementary constraints relative to existing limits, which are indirect and derived from collider bounds on the mass of the associated neutral gauge boson $Z^\prime$., Comment: 23 pages, 12 figures, 8 tables

The class of graph deletion problems has been extensively studied in theoretical computer science, particularly in the field of parameterized complexity. Recently, a new notion of graph deletion problems was introduced, called deletion to scattered graph classes, where after deletion, each connected component of the graph should belong to at least one of the given graph classes. While fixed-parameter algorithms were given for a wide variety of problems, little progress has been made on the kernelization complexity of any of them. In this paper, we present the first non-trivial polynomial kernel for one such deletion problem, where, after deletion, each connected component should be a clique or a tree - that is, as densest as possible or as sparsest as possible (while being connected). We develop a kernel consisting of O(k^5) vertices for this problem., Comment: 20 pages, 4 figures, An extended abstract accepted to ISAAC-2024

We demonstrate that precision measurements of cosmological parameters from the Planck Satellite Observatory (2018) can be accurately reproduced by calculating the masses of gauge bosons and their superpartners within the Minimal Supersymmetric Standard Model (MSSM). Our approach utilizes combined decay product equations from these gauge supermultiplets. These results strongly support the Lambda-CDM cosmological standard model. Moreover, our equations predict the masses of the ordinary nucleon, a proposed anti-supersymmetric nucleon (as a dark matter candidate), and the Higgs boson in agreement with experimental values. Our theory addresses baryon number violation, lepton number violation, and the matter-antimatter asymmetry of the universe. We anticipate that the masses of winos and anti-supersymmetric nucleons will be verified through Higgs boson decay in top-anti-top quark interactions at future high-energy hadron collider experiments.

While there has been progress towards aligning Large Language Models (LLMs) with human values and ensuring safe behaviour at inference time, safety-aligned LLMs are known to be vulnerable to training-time attacks such as supervised fine-tuning (SFT) on harmful datasets. In this paper, we ask if LLMs are vulnerable to adversarial reinforcement learning. Motivated by this goal, we propose Reverse Preference Attacks (RPA), a class of attacks to make LLMs learn harmful behavior using adversarial reward during reinforcement learning from human feedback (RLHF). RPAs expose a critical safety gap of safety-aligned LLMs in RL settings: they easily explore the harmful text generation policies to optimize adversarial reward. To protect against RPAs, we explore a host of mitigation strategies. Leveraging Constrained Markov-Decision Processes, we adapt a number of mechanisms to defend against harmful fine-tuning attacks into the RL setting. Our experiments show that ``online" defenses that are based on the idea of minimizing the negative log likelihood of refusals -- with the defender having control of the loss function -- can effectively protect LLMs against RPAs. However, trying to defend model weights using ``offline" defenses that operate under the assumption that the defender has no control over the loss function are less effective in the face of RPAs. These findings show that attacks done using RL can be used to successfully undo safety alignment in open-weight LLMs and use them for malicious purposes.

We provide a uniform framework to compute the exact distribution of the number of minima/maxima in three different random walk landscape models in one dimension. The landscape is generated by the trajectory of a discrete-time continuous space random walk with arbitrary symmetric and continuous jump distribution at each step. In model I, we consider a ``free'' random walk of $N$ steps. In model II, we consider a ``meander landscape'' where the random walk, starting at the origin, stays non-negative up to $N$ steps. In model III, we study a ``first-passage landscape'' which is generated by the trajectory of a random walk that starts at the origin and stops when it crosses the origin for the first time. We demonstrate that while the exact distribution of the number of minima is different in the three models, for each model it is universal for all $N$, in the sense that it does not depend on the jump distribution as long as it is symmetric and continuous. In the last two cases we show that this universality follows from a non trivial mapping to the Sparre Andersen theorem known for the first-passage probability of discrete-time random walks with symmetric and continuous jump distribution. Our analytical results are in excellent agreement with our numerical simulations., Comment: 16 pages, 9 figures

Motivated by the fractal form of the compact chromatin in vivo, we study the melting of a lattice DNA on the infinite cluster backbone near the three-dimensional site percolation critical point $(p_c=0.3116)$, which exhibits fractal-like properties, using Monte Carlo simulations. Further, we extend our study to other values of atmospheric disorder $(p_c\leq p \leq 1)$ and show how the melting temperature varies with a decrease in the availability of lattice sites mimicking the crowded environment inside the cell nucleus. Importantly, we found that the melting transition sharpens with a linear increase in the denaturation temperature as we increase the degree of disorder. Two separate disorder regimes showing weak and strong effects on melting can be identified. For simulations, we use the pruned and enriched Rosenbluth method in conjunction with a depth-first implementation of the Leath algorithm to generate the underlying disorder., Comment: 9 pages; 6 figures

This paper describes an efficient, open source PyTorch implementation of the Spectral Transform Unit. We investigate sequence prediction tasks over several modalities including language, robotics, and simulated dynamical systems. We find that for the same parameter count, the STU and its variants outperform the Transformer as well as other leading state space models across various modalities.

Neuromorphic spintronics combines two advanced fields in technology, neuromorphic computing and spintronics, to create brain-inspired, efficient computing systems that leverage the unique properties of the electron's spin. In this book chapter, we first introduce both fields - neuromorphic computing and spintronics and then make a case for neuromorphic spintronics. We discuss concrete examples of neuromorphic spintronics, including computing based on fluctuations, artificial neural networks, and reservoir computing, highlighting their potential to revolutionize computational efficiency and functionality., Comment: Neuromorphic Spintronics is a chapter of a book titled "Artificial Intelligence and Intelligent Matter". This is not the final version of the chapter. For the final version, please go to the book published by Springer (the DOI and other details will be put here once the book has been published.)

We present a theoretical framework for temperature imaging from long-wavelength infrared thermal radiation (e.g. 8-12 $\mu$m) through the end-to-end design of a metasurface-optics frontend and a computational-reconstruction backend. We introduce a new nonlinear reconstruction algorithm, ``Planck regression," that reconstructs the temperature map from a grayscale sensor image, even in the presence of severe chromatic aberration, by exploiting blackbody and optical physics particular to thermal imaging. We combine this algorithm with an end-to-end approach that optimizes a manufacturable, single-layer metasurface to yield the most accurate reconstruction. Our designs demonstrate high-quality, noise-robust reconstructions of arbitrary temperature maps (including completely random images) in simulations of an ultra-compact thermal-imaging device. We also show that Planck regression is much more generalizable to arbitrary images than a straightforward neural-network reconstruction, which requires a large training set of domain-specific images., Comment: 17 pages, 4 figures

The ICPR 2024 Competition on Safe Segmentation of Drive Scenes in Unstructured Traffic and Adverse Weather Conditions served as a rigorous platform to evaluate and benchmark state-of-the-art semantic segmentation models under challenging conditions for autonomous driving. Over several months, participants were provided with the IDD-AW dataset, consisting of 5000 high-quality RGB-NIR image pairs, each annotated at the pixel level and captured under adverse weather conditions such as rain, fog, low light, and snow. A key aspect of the competition was the use and improvement of the Safe mean Intersection over Union (Safe mIoU) metric, designed to penalize unsafe incorrect predictions that could be overlooked by traditional mIoU. This innovative metric emphasized the importance of safety in developing autonomous driving systems. The competition showed significant advancements in the field, with participants demonstrating models that excelled in semantic segmentation and prioritized safety and robustness in unstructured and adverse conditions. The results of the competition set new benchmarks in the domain, highlighting the critical role of safety in deploying autonomous vehicles in real-world scenarios. The contributions from this competition are expected to drive further innovation in autonomous driving technology, addressing the critical challenges of operating in diverse and unpredictable environments., Comment: 15 pages, 7 figures, ICPR Competition Paper

In a Mott insulator, a laser pulse with frequency tuned to the gap scale can create a holon-doublon plasma, suppressing the magnetic moment ${\vec m}_i$ and destroying magnetic order. While this disruptive effect is well established experimentally on a square lattice, we investigate the effect of laser pumping on the triangular lattice, where geometric frustration leads to a richer set of ordering possibilities. We work with the Mott-Hubbard problem at a coupling where $120^{\circ}$ order is just stable and employ spatio-temporal mean field dynamics to study the pump response. Moderate pump amplitude just leads to the reduction of $120^{\circ}$ order, but at larger amplitude the suppression of $120^{\circ}$ order is followed by the appearance of `spiral order'. On the electronic side the density of `excited carriers' $n_{exc}$ in the upper Hubbard band increases monotonically with pump amplitude. We show that the long time ordering possibilities in the pumped system, e.g., the emergence of spiral order, can be inferred from a nonequilibrium `energy landscape'. We analyse the growth of spiral order by using an exact diagonalisation based Langevin equation on large lattices and discover that the new order can take $\sim 10^3-10^4$ times the electronic timescale to appear. The threefold combination, of mean field dynamics, landscape construction, and Langevin dynamics, readily generalises to the search for pump induced `hidden order' in other gapped systems., Comment: 13 pages, 9 figures

The neutral hydrogen (HI) power spectrum, measured from intensity fluctuations in the 21-cm background, offers insights into the large-scale structures (LSS) of our Universe in the post-reionization era (redshift $z<6$). A significant amount of HI is expected to reside in low- and intermediate-density environments, but the power spectrum mainly captures information from high-density regions. To more fully extract the information contained in the HI field, we investigate the use of a marked power spectrum statistic. Here, the power spectrum is effectively re-weighted using a non-linear mark function which depends on the smoothed local density, such that low- or high-density regions are up- or down-weighted. This approach may also capture information on some higher-order statistical moments of the field. We model the HI distribution using semi-numerical simulations and for the first time study the marked HI power spectrum, across $1 \leq z \leq 5$. Our analysis indicates that there is considerable evolution of the HI field during the post-reionization era. Over a wide range of length scales (comoving wave numbers $0.05\leq k \leq 1.0$ Mpc$^{-1}$) we expectedly find that the HI evolves slowly at early times, but more rapidly at late times. This evolution is not well-captured by the power spectrum of the standard (unmarked) HI field. We also study how the evolution of the HI field depends on the chosen smoothing scale for the mark, and how this affects the marked power spectrum. We conclude that the information about the HI content at low and intermediate densities is important for a correct and consistent analysis of HI content and evolution based on the 21-cm background. The marked power spectrum can thus provide a less biased statistic for parameter constraints than the normal power spectrum., Comment: 32 pages, 10 figures, comments are welcome, prepared for submission to JCAP

High-quality (Q)-factor optical resonators with extreme temporal coherence are of both technological and fundamental importance in optical metrology, continuous-wave lasing, and semiconductor quantum optics. Despite extensive efforts in designing high-Q resonators across different spectral regimes, the experimental realization of very large Q-factors at visible wavelengths remains challenging due to the small feature size that is sensitive to fabrication imperfections, and thus is typically implemented in integrated photonics. In the pursuit of free-space optics with the benefits of large space-bandwidth product and massive parallel operations, here we design and fabricate a visible-wavelength etch-free metasurface with minimized fabrication defects and experimentally demonstrate a million-scale ultrahigh-Q resonance. A new laser-scanning momentum-space-resolved spectroscopy technique with extremely high spectral and angular resolution is developed to characterize the record-high Q-factor as well as the dispersion of the million-Q resonance in free space. By integrating monolayer WSe2 into our ultrahigh-Q meta-resonator, we further demonstrate laser-like highly unidirectional and narrow-linewidth exciton emission, albeit without any operating power density threshold. Under continuous-wave laser pumping, we observe pump-power-dependent linewidth narrowing at room temperature, indicating the potential of our meta-optics platform in controlling coherent quantum light-sources. Our result also holds great promise for applications like optical sensing, spectral filtering, and few-photon nonlinear optics.

Ethanethiol (C$_2$H$_5$SH), a molecule detected in the interstellar medium (ISM), indicates the rich chemistry involving sulfur atoms. However, its behavior at low temperatures remains elusive, particularly the reported transition from an amorphous phase to a crystal. This study employs classical molecular dynamics (MD) simulations to reproduce the liquid-state properties of ethanethiol and to simulate the initial amorphous state of ethanethiol films deposited on a KBr substrate. The amorphous ethanethiol did not show spontaneous crystallization upon increasing temperature. Also, ethanethiol ice crystals exhibit melting behavior on KBr substrate at elevated temperatures. Our MD simulations of thin ice samples do not show any signature reversible phase change. It will be interesting to continue this study with a thicker sample, which is beyond our current computational means. These findings underscore the complexity of icy mantle morphology on cold ISM dust grains., Comment: Manuscript accepted for publication in "Astrophysics and Space Science Proceedings", Springer nature (Symposium: ISRA 2023)

Speech foundation models have achieved state-of-the-art (SoTA) performance across various tasks, such as automatic speech recognition (ASR) in hundreds of languages. However, multi-speaker ASR remains a challenging task for these models due to data scarcity and sparsity. In this paper, we present approaches to enable speech foundation models to process and understand multi-speaker speech with limited training data. Specifically, we adapt a speech foundation model for the multi-speaker ASR task using only telephonic data. Remarkably, the adapted model also performs well on meeting data without any fine-tuning, demonstrating the generalization ability of our approach. We conduct several ablation studies to analyze the impact of different parameters and strategies on model performance. Our findings highlight the effectiveness of our methods. Results show that less parameters give better overall cpWER, which, although counter-intuitive, provides insights into adapting speech foundation models for multi-speaker ASR tasks with minimal annotated data., Comment: Accepted by SLT 2024

Bugs in popular distributed protocol implementations have been the source of many downtimes in popular internet services. We describe a randomized testing approach for distributed protocol implementations based on reinforcement learning. Since the natural reward structure is very sparse, the key to successful exploration in reinforcement learning is reward augmentation. We show two different techniques that build on one another. First, we provide a decaying exploration bonus based on the discovery of new states -- the reward decays as the same state is visited multiple times. The exploration bonus captures the intuition from coverage-guided fuzzing of prioritizing new coverage points; in contrast to other schemes, we show that taking the maximum of the bonus and the Q-value leads to more effective exploration. Second, we provide waypoints to the algorithm as a sequence of predicates that capture interesting semantic scenarios. Waypoints exploit designer insight about the protocol and guide the exploration to ``interesting'' parts of the state space. Our reward structure ensures that new episodes can reliably get to deep interesting states even without execution caching. We have implemented our algorithm in Go. Our evaluation on three large benchmarks (RedisRaft, Etcd, and RSL) shows that our algorithm can significantly outperform baseline approaches in terms of coverage and bug finding.

Heavy computational demands from artificial intelligence (AI) leads the research community to explore the design space for functional materials that can be used for high performance memory and neuromorphic computing hardware. Novel device technologies with specially engineered properties are under intense investigation to revolutionize information processing with brain-inspired computing primitives for ultra energy-efficient implementation of AI and machine learning tasks. Ferroelectric memories with ultra-low power and fast operation, non-volatile data retention and reliable switching to multiple polarization states promises one such option for non-volatile memory and synaptic weight elements in neuromorphic hardware. For quick adaptation of industry, new materials need complementary metal oxide semiconductor (CMOS) process compatibility which brings a whole new set of challenges and opportunities for advanced materials design. In this work, we report on designing of back-end-of-line compatible ferroelectric Hf0.5Zr0.5O2 capacitors that are capable of recovery from fatigue multiple times reaching 2Pr > 40 microC cm-2 upon each retrieval. Our results indicate that with specifically engineered material stack and annealing protocols, it is possible to reach endurance exceeding 10^9 cycles at room temperature that can lead to ultralow power ferroelectric non-volatile memory components or synaptic weight elements compatible with online training or inference tasks for neuromorphic computing.