1. 4E evaluations of salt hydrate-based solar thermochemical heat transformer system used for domestic hot water production.
- Author
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Li, Wei, Markides, Christos N., Zeng, Min, and Peng, Jian
- Subjects
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THERMODYNAMICS , *HEATING , *HOT water , *SOLAR heating , *CARBON emissions , *ENERGY development - Abstract
A critical step toward the widespread use of renewables is the development of effective energy storage technology. An impressive solution for energy storage and heat upgrade is the salt hydrate-based solar thermochemical heat transformer (THT). The article aims at the temperature lift effects of pressurization-assisted THT systems employing different salts to fulfill the heat requirements of domestic hot water (DHW) generation. To grasp the sustainability of the GJ-level THT systems, energy, exergy, economic, and environmental (4E) assessments are performed under various working conditions. Results manifest that the majority of THT systems enable discharging temperatures (T dis) to surpass 65 °C, matching regular DHW production. T dis can be further boosted by the two-stage pressurization whereas at the expense of lowering thermodynamic properties. The SrBr 2 -based system almost exhibits the best 4E performances with a T dis of 74.3 °C, although its levelized energy cost (LEC) of 0.1162 $/kWh is slightly higher than that of the LiOH-based system (0.1147 $/kWh). Both systems yield great useable heat, up to 11,667 MJ and 11,140 MJ, respectively, with maximum exergy efficiency of 89.16 % and 63.41 %. Albeit capable of generating higher temperature DHW (≥90 °C), the useable heat and thermodynamic performances of the FeCl 2 and CaCl 2 based systems are unsatisfactory. By contrast, the K 2 CO 3 and LiOH based systems render higher temperature DHW while ensuring acceptable thermodynamic properties and useable heat. Targeting the regular and higher temperature DHW productions, the lowest CO 2 emissions are separately achieved by the SrBr 2 and LiCl based systems, i.e., 15 kg/MWh and 56.2 kg/MWh; and the former shows the slowest growth rate in carbon emission with increased T dis. Augmenting solar irradiation and duration contributes to reducing LEC , and the ideal operating conditions in thermo-economic performance may differ from system to system. [Display omitted] • A GJ scale solar-thermochemical heat transformer system for DHW production. • Pressure regulation achieves heat upgrade of output temperature above 65 °C. • 4E analyses of the thermochemical heat transformer system are conducted. • The minimum LEC of 0.1147 $/kWh is reached when using LiOH·H 2 O as TCM. • The SrBr 2 -based system has the highest energy and exergy efficiencies of 76.32 % and 89.16 %. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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