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The sulfur content in dense molecular regions of the interstellar medium is highly depleted in comparison to diffuse clouds. The reason of this phenomenon is unclear, thus it is necessary to carry out observational studies of sulfur-bearing species towards dense regions, mainly at early evolutive stages to uncover the early sulfur chemistry. Using data from the Atacama Large Millimeter Array (ALMA) data archive, we investigated a sample of 37 dense cores embedded in the most massive infrared-quiet molecular clumps from the ATLASGAL survey. Lines of 34SO, SO2, NS, SO, SO+, and H2CS were analyzed and column densities of each molecular species were obtained. From the continuum emission, and two CH3OH lines, the 37 cores were characterized in density and temperature, and the corresponding H2 column densities were derived. The abundances of such sulfur-bearing species were derived and studied. We find that the abundances of the analyzed species increase with the growth of the gas temperature, suggesting that the chemistry involved in the formation of each of the analyzed molecule may have a similar dependence with Tk in the range 20 to 100 K. We find that the comparisons among abundances are, in general, highly correlated. Given that such correlation decreases in more evolved sources, we suggest that the sulfur-bearing species here analyzed should have a similar chemical origin. From the measured line widths we point out that molecules with oxygen content (34SO, SO2, SO, and SO+) may be associated with warmer and more turbulent gas than the other ones. H2CS and NS are associated with more quiescent gas, probably in the external envelopes of the cores. This work gives quantitative information about abundances that could be useful in chemical models pointing to explain the sulfur chemistry in the interstellar medium., Comment: Accepted for publication in A&A (October 31, 2024)

In previous works, we have investigated the star-forming region G29.96$-$0.02 where the massive young stellar object (MYSO) G29.862$-$0.0044 (hereafter G29) is embedded in a hot molecular core. In one of them, of multiwavelength nature, using data from the Atacama Submillimeter Telescope Experiment (ASTE), data from the Atacama Large Millimeter Array (ALMA), and photometric data from NIRI-Gemini, G29 was investigated at different spatial scales. However, the intriguing morphology of G29 in the near-infrared, together with the distribution of the associated molecular gas, reveals that the star-formation scenario is far from being understood. This work incorporates the analysis of the emission of several molecular lines acquired with ALMA that were not previously examined (eg.,~CH$_{3}$OH, HC$_{3}$N, H$_{ 2}$CO, C$^{34}$S, H$_{2}$CS) as well as a new determination of the temperature of the region. Additionally, we present the progress of results obtained through new observations in the near-infrared, in this case spectroscopic, using NIFS-Gemini, and in radio continnum obtained with the Karl G. Jansky Very Large Array (JVLA). This research allows us to carry out a detailed chemical study of the region, which will contribute to the understanding of the physical processes involved in the high-mass star formation., Comment: accepted to be published in Bolet\'in de la Asociaci\'on Argentina de Astronom\'ia

The star forming processes strongly influence the ISM chemistry. Nowadays, there are available many high-quality databases at millimeter wavelengths. Using them, it is possible to carry out studies that review and deepen previous results. If these studies involve large samples of sources, it is preferred to use direct tools to study the molecular gas. With the aim of testing these tools such as the use of the HCN/HNC ratio as a thermometer, and the use of H$^{13}$CO$^{+}$, HC$_{3}$N, N$_{2}$H$^{+}$, and C$_{2}$H as "chemical clocks", we present a molecular line study towards 55 sources representing massive young stellar objects (MYSOs) at different evolutive stages: infrared dark clouds (IRDCs), high-mass protostellar objects (HMPOs), hot molecular cores (HMCs) and ultracompact HII regions (UCHII). We found that the use of HCN/HNC ratio as an universal thermometer in the ISM should be taken with care because the HCN optical depth is a big issue that can affect the method. Hence, this tool should be used only after a careful analysis of the HCN spectrum, checking that no line, neither the main nor the hyperfine ones, present absorption features. We point out that the analysis of the emission of H$^{13}$CO$^{+}$, HC$_{3}$N, N$_{2}$H$^{+}$, and C$_{2}$H could be useful to trace and distinguish regions among IRDCs, HMPOs and HMCs. The molecular line widths of these four species increase from the IRDC to the HMC stage, which can be a consequence of the gas dynamics related to the star-forming processes taking place in the molecular clumps. Our results do not only contribute with more statistics regarding to probe such chemical tools, useful to obtain information in large samples of sources, but also complement previous works through the analysis on other types of sources., Comment: accepted to be published in Research in Astronomy & Astrophysics, October 13, 2023

We present a comprehensive physical and chemical study of the fragmentation and star formation activity towards the massive clump AGAL G338.9188+0.5494 harbouring the extended green object EGO 338.92+0.55(b). The presence of an EGO embedded in a massive clump, suggests, at clump scale, that high-mass star formation is occurring. The main goal of this work is to find evidence of such high-mass star formation, but at core scale. Using mm observations of continuum and lines obtained from the ALMA database at Bands 6 and 7, we study the substructure of the massive clump. The angular resolution of the data is about 0.5'', which allow us to resolve structures of about 0.01pc ($\sim$ 2000 au) at the distance of 4.4 kpc. The continuum emission at 340 GHz reveals that the molecular clump is fragmented in five cores, labeled from C1 to C5. The $^{12}$CO J=3--2 emission shows the presence of molecular outflows related to three of them. The analysis of the CH$_3$CN and CH$_3$CCH emissions suggests temperatures of about 340 and 72~K, respectively, for C1, showing that the methyl cyanide would trace a gas layer closer to the protostar than the methyl acetylene. The obtained mass of core C1 ranges from 3 to 10 M$_{\odot}$. We found that the discovered molecular outflow arising from core C1 should be the main responsible for the 4.5 $\mu$m extended emission. The average mass and energy of such a molecular outflow is about 0.5 M$_{\odot}$~and $10^{46}$~erg, respectively, which suggest that 10 M$_{\odot}$ is the most likely mass value for core C1. Additionally we found that the region is chemically very rich with several complex molecular species. Particularly, from the analysis of the CN emission we found strong evidence that such a radical is indirectly tracing the molecular outflows, more precisely the border of the cavity walls carved out by such outflows., Comment: Accepted for publication in A&A (July 5, 2023)

The study of molecules and their chemistry in star-forming regions is fundamental to understand the physical process occurring in such regions. The HCN and HNC J=1-0 emissions were used to derive their integrated line intensities (I), to probe a relation recently appeared in the literature between the kinetic temperatures (T$_{K}$) and the isomeric (I) ratio, and to obtain the isomers abundances (X) in 55 high-mass star-forming regions. These last ones are classified, according to the evolutive stage, as infrared dark clouds, high-mass protostellar objects, hot molecular cores, and ultracompact HII regions. It is inferred that the T$_{K}$ obtained from the isomeric integrated intensity ratio (I$^{HCN/HNC}$) are underestimated, and hence we suggest that this relation cannot be employed as an universal thermometer in the interstellar medium. The isomers abundances show a behavior that can be explained from the chemistry occurring as the temperature and the UV radiation increase according to the evolutive stage. We found that the abundance ratio (X$^{HCN/HNC}$) hardly could be used as a chemical clock, and we suggest that it can be approximated by I$^{HCN/HNC}$. This work is part of an on-going study of multiple molecules that stand in the sample of analyzed regions which intends to contribute in the chemical knowledge of high-mass star formation., Comment: to appear in Bolet\'in de la Asociaci\'on Argentina de Astronom\'ia

In addition to the large surveys and catalogs of massive young stellar objects and outflows, dedicated studies of particular sources, in which high-angular observations (mainly at near-IR and mm) are analyzed in depth, are needed to shed light on the processes involved in the formation of massive stars. The galactic source G079.1272+02.2782 (G79), a MYSO at about 1.4 kpc, is an ideal source to carry out this kind of studies. Near-IR integral field spectroscopic observations were carried out using NIFS at Gemini-North. The spectral and angular resolutions, allow us to perform a detailed study of the source and its southern jet, resolving structures with sizes between 200 and 300 au. As a complement, millimeter data retrieved from the JCMT and the IRAM 30m telescope databases were analyzed to study the molecular gas at a larger spatial scale. The analysis of a jet extending southwards shows cork-screw like structures at 2.2 um continuum, strongly suggesting that the jet is precessing. The jet velocity is estimated in 30-43 km/s and it is coming to us along the line of sight. We suggest that the precession may be produced by the gravitational tidal effects generated in a probable binary system, and we estimate a jet precession period of about 10^3 yr, indicating a slow-precessing jet, which is in agreement with the observed helical features. An analysis of H2 lines along the jet allows us to investigate in detail a bow-shock produced by this jet. We find that this bow-shock is indeed generated by a C-type shock and it is observed coming to us, with some inclination angle, along the line of sight. This is confirmed by the analysis of molecular outflows at a larger spatial scale. A brief analysis of several molecular species at millimeter wavelengths indicates a complex chemistry developing at the external layers of the molecular clump in which MYSO G79 is embedded., Comment: Accepted to be published in A&A (August 4, 2022)

At the first Galactic quadrant, at l=33.134, b=-0.091, an extended photodissociation region generated by an HII region complex lies. This region is related to abundant molecular gas, and particularly, a hot molecular core, known as G33.133-mm3, appears embedded in a molecular clump. Using data from the James Clerk Maxwell Telescope with an angular resolution of about 15", we studied the 13CO/C18O abundance ratio towards the mentioned molecular clump and its relation with the ultraviolet radiation. At smaller spatial scales, using data from the Atacama Large Millimeter Array (angular resolution about 0.7\arcsec), the hot molecular core G33.133-mm3, that has a size of about 2600 au, and is an appropriate site to form stars, was characterized. In particular, some points about its chemistry are mentioned based on the emission of the cyanide or nitrile radical (CN) and others more complex molecules, such as CH3OH, CH3CN, CH3OCHO, and CH3CCH., Comment: accepted to be published in Bolet\'in de la Asociaci\'on Argentina de Astronom\'ia (BAAA)