1. Nanostructured Magnetite Coated with BiOI Semiconductor: Readiness Level in Advanced Solar Photocatalytic Applications for the Remediation of Phenolic Compounds in Wastewater from the Wine and Pisco Industry.
- Author
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Gallegos-Alcaíno, Alejandra, Barría, Gabriela Paz, Moreno, Yanko, Fernández, Iván, Poblete, Rodrigo, Maureira-Cortés, Héctor, Figueroa Alvarado, Antonia Cristal, Hernández, Constanza Belén, and Flores, José
- Subjects
FOURIER transform infrared spectroscopy ,CLEAN energy ,WASTEWATER treatment ,REFLECTANCE spectroscopy ,CAFFEIC acid - Abstract
Heterogeneous photocatalysis is an advanced, efficient oxidation process that uses solar energy to be sustainable and low-cost compared to conventional wastewater treatments. This study synthesized BiOI/Fe
3 O4 using the solvothermal technique, evaluating stoichiometric ratios of Bi/Fe (2:1, 3:1, 5:1, and 7:1) under simulated solar irradiation to optimize the degradation of caffeic acid, a pollutant found in wastewater from the wine and pisco industry. The nanomaterial with a 5:1 ratio (BF-5) was the most effective, achieving a degradation of 77.2% in 180 min. Characterization by X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Brunauer–Emmett–Teller (BET), Barrett–Joyner–Halenda (BJH), Fourier Transform Infrared Spectroscopy (FTIR), Diffuse Reflectance Spectroscopy (DRS), and Vibrating Sample Magnetometry (VSM) showed that BF-5 has a porous three-dimensional structure with BiOI nanosheets coating the Fe3 O4 surface, while retaining the pristine BiOI properties. The magnetite provided magnetic properties that facilitated the recovery of the photocatalyst, reaching 89.4% recovery. These findings highlight the potential of BF-5 as an efficient and recoverable photocatalyst for industrial applications. The technical, economic, and environmental feasibility were also evaluated at the technological readiness level (TRL) to project solar photocatalysis in real applications. [ABSTRACT FROM AUTHOR]- Published
- 2024
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