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The Milos, Christiana-Santorini-Kolumbo (CSK) and Kos-Yali-Nisyros (KYN) volcanic complexes of the Aegean Volcanic Arc have repeatedly produced highly explosive eruptions from at least ∼360 ka into historic times and still show recent unrest. We present the marine tephra record from an array of 50, up to 7.4 m long, sediment cores along the arc collected in 2017 during RV Poseidon cruise POS513, which complements earlier work on distal to ultra-distal eastern Mediterranean sediment cores. A unique set of glass-shard trace element (LA-ICPMS) compositions complements our major element (EMP) data on 220 primary ash layers and 40 terrestrial samples to support geochemical fingerprinting for correlations with 19 known tephras from all three volcanic complexes and with the 39 ka Campanian Ignimbrite from the Campi Flegrei, Italy. The correlations include eleven eruptions from CSK (Kameni, Kolumbo 1650, Minoan, Cape Riva, Cape Tripiti, Upper Scoriae 1 and 2, Middle Pumice, Cape Thera, Lower Pumice, Cape Therma 3). We identify a previously unknown widespread tephra from a plinian eruption on Milos (Firiplaka Tephra). Near the KYN we correlate marine tephras with the Kos Plateau Tuff, the Yali 1 and Yali 2 tephras, and the Upper and Lower Pumice on Nisyros. Between these two major tephras, we found two tephras from Nisyros not yet observed on land. The four Nisyros tephras form a systematic trend toward more evolved magma compositions. In the companion paper we use the tephrostratigraphic framework established here to constrain new eruption ages and magnitudes as a contribution to volcanic hazard assessment.

We use the tephrostratigraphic framework along the Aegean Volcanic Arc established in part 1 of this contribution to determine hemipelagic sedimentation rates, calculate new tephra ages, and constrain the minimum magnitudes of (sub)plinian eruptions of the last 200 kyrs. Hemipelagic sedimentation rates range from ∼0.5 cm/kyr up to ∼40 cm/kyr and vary laterally as well as over time. Interpolation between dated tephras yields an eruption age of ∼37 ka for the Firiplaka tephra, showing that explosive volcanism on Milos is ∼24 kyrs younger than previously thought. The four marine Nisyros tephras (N1 to N4) identified in part 1 (including the Upper (N1) and Lower (N4) Pumice) have ages of ∼57 ka, ∼63 ka, ∼69 ka, and ∼76 ka, respectively. Eruption ages for the Yali-1 and Yali-2 tephras are ∼55 ka and ∼34 ka, respectively. The Yali-2 tephra comprises two geochemically and laterally distinct marine facies. The southern facies is identical to the Yali-2 fall deposit on land but the western facies has slightly less evolved glass compositions. Overall, erupted plinian and co-ignimbrite fall tephra volumes range from <1 to 56 km3 (excluding possible caldera fillings and ignimbite volumes), and 80% of the eruptions had magnitude 5.5

The origins of many supergiant ore deposits remain unresolved because the factors responsible for such extreme metal enrichments are not understood. One factor of critical importance is the timing of mineralization. However, timing information is commonly confounded by the difficulty of dating ore minerals. The world's largest uranium resource at Olympic Dam, South Australia, is exceptional because the high abundance of U allows U-Pb dating of ore minerals. The Olympic Dam U(-Cu-Au-Ag) ore deposit is hosted in ca. 1.59 Ga rocks, and the consensus has been that the supergiant deposit formed at the same time. We argue that, in fact, two stages of mineralization were involved. Paired in situ U-Pb and trace element analyses of texturally distinct uraninite populations show that the supergiant size and highest-U-grade zones are the result of U addition at 0.7–0.5 Ga, at least one billion years after initial formation. This conclusion is supported by a remarkable clustering of thousands of radiogenic 207Pb/206Pb model ages of Cu sulfide grains at this time. Upgrading of the original ca. 1.59 Ga U deposit to its present size at 0.7–0.5 Ga may have resulted from perturbation of regional fluid flow triggered by global climatic (deglaciation) and tectonic (breakup of Rodinia) events.

The felsic-dominant Gawler Range Volcanics and cogenetic Hiltaba Suite granitoids constitute the ca. 1590 Ma Gawler silicic large igneous province in the Gawler Craton, South Australia. The province includes minor occurrences of olivine-phyric basalt at Kokatha and Mount Gunson. In this study, we describe additional olivine-phyric basalts and dykes intersected by drill holes at the Olympic Dam Iron Oxide Cu–U–Au–Ag deposit and the Wirrda Well Cu–Au prospect. Laser Ablation Inductively Coupled Plasma Mass Spectrometry U–Pb dating results (un-anchored) of apatite in the basalts and dykes at Mount Gunson (1576 ± 33 Ma), Wirrda Well (1596 ± 17 Ma), and Olympic Dam (1621 ± 20 Ma) confirm their effective temporal correlation with the ca. 1590 Ma Gawler silicic large igneous province. Compositions of Cr-spinel inclusions enclosed in former olivine phenocrysts (forsterite number >80) in basalts at Mount Gunson, Wirrda Well and Olympic Dam imply derivation from a heterogeneous mantle source that may have been modified by subduction. Least-altered olivine-phyric basalts at Mount Gunson and Kokatha are characterized by negative Nb and Ta anomalies, which are typical of arc basalts but are also common in back-arc basin basalts, in accordance with the result suggested by the Cr-spinel source indicator. The mafic components of the Gawler Range Volcanics generally have higher Zr contents and Zr/TiO2 ratios than those of high-Mg basalts and picrites produced in variable tectonic settings worldwide, possibly reflecting continental crustal components involved in their mantle source.High abundances (typically ~20 vol.%) of former olivine phenocrysts in the basalt at Olympic Dam imply high-Mg whole-rock compositions and a high temperature of the primary magma. This result is consistent with previous models in which the heat flux from mantle magmas caused large-scale partial melting of crustal rocks that subsequently gave rise to silicic magmas erupted and intruded to form the Gawler si

The >800-m-thick, Oligocene Ohanapecosh Formation records voluminous sedimentation of volcanic clasts in the Ancestral Cascades arc (Washington State, USA). Most volcaniclastic beds are dominated by angular pumice clasts and fiamme of andesitic composition, now entirely devitrified and altered. All beds are laterally continuous and have uniform thickness; fine sandstone and mudstone beds have features typical of deposits from low-density turbidity currents and suspension settling. Erosion surfaces, cross-beds, and evidence of bi-directional oscillatory currents (i.e., wave ripples and swaley and hummocky cross-stratification) are almost entirely absent. We infer that the setting was subaqueous and below wave base. The abundance of angular pumice clasts, crystals and dense volcanic clasts, and the extreme thickness of several facies, suggest they were derived from magmatic volatile-driven explosive eruptions. The extremely thick beds are ungraded or weakly graded, and lack evidence of hot emplacement, suggesting deposition from subaqueous, water-supported, high-concentration volcaniclastic density currents. Some of the thickest beds contain coarse, rounded, dense clasts at their base and are interbedded with accretionary lapilli–bearing mudstone; these beds are interpreted to be deposits from subaqueous density currents fed by subaerial pyroclastic flows that crossed the shoreline. Shallow basaltic intrusions and mafic volcanic breccia composed of scoria lapilli indicate the presence of intra-basinal scoria cones that may have been partly subaerial. The range in facies in the Ohanapecosh Formation is typical of below-wave-base, continental (lacustrine) basins that form in proximity to active volcanic arcs, and includes eruption-fed and resedimented facies. Extreme instantaneous aggradation rates are related directly to explosive eruptions, and sediment pathways reflect the locations of active volcanoes, in contrast to conventional sedimentation processes acting in no

The Gawler Range Volcanics (GRV) and the Hiltaba Suite (HS) of South Australia form a silicic-dominated large igneous province (the Gawler SLIP) emplaced in an intracontinental setting during the Mesoproterozoic. Emplacement of the GRV lasted for a short period of time (~2 Ma), and can be separated into two main phases. The first phase (lower GRV) is composed of thick (≤3 km) sequences erupted from distinct centres, and includes small to moderate volume (up to >150 km3) felsic lavas, ignimbrites, and minor mafic and intermediate lavas. The upper GRV include extensive felsic lavas that are up to >1000 of km3 in volume and >200 km across. Using well preserved, quartz-hosted melt inclusions, we investigated the composition of the lower GRV, including major, trace, and volatile elements. The results indicate high concentrations of K2O (≤7–8 wt.%), rare earth and high field strength elements, and low concentrations of Ca, Mg, Ni, Cr, Sr and Ba in comparison with felsic continental crust. Overall, melt inclusion compositions match whole-rock geochemical characteristics. We demonstrate that the GRV magma was F-rich (≤1.3 wt.%), and had high temperature for a silicic magma. High F concentrations and high temperature would have resulted in lower than usual polymerisation of the melt and relatively low viscosity. These characteristics help explain how very voluminous felsic magma was erupted effusively and emplaced as lavas. Other intracontinental SLIP contain extensive felsic lavas and ignimbrites which appear to share similar geochemical characteristics. We also show that selective alteration caused depletion of whole-rock compositions in some trace elements, namely Pb, U, and Sn.

Silicic-dominated large igneous provinces (SLIP) represent vast amounts of magma (≥ 105 km3) erupted onto the Earth's surface or injected into the crust over short time spans, and are important components of the continental crust. The conditions of formation and evolution of these large magmatic provinces and their magma chambers are still poorly constrained. In this contribution, we examine cathodoluminescence textures and trace element (Al, Ti, Fe) zoning of quartz in a Mesoproterozoic SLIP, the Gawler Range Volcanics (GRV), South Australia. We describe intra-granular textures such as truncation of growth textures and reverse zoning (rimwards increase of Ti content). These characteristics of quartz, together with remelting of already crystallised portions of the magma chamber (felsic enclaves), suggest a complex history of crystallisation and resorption, and fluctuating magma temperature. Titanium-in-quartz geothermometry indicates that adjacent quartz zones record temperature variations (ΔT) up to 70 °C in volcanic units. We also report contrasting (non-correlatable) zoning patterns amongst quartz crystals, each indicating different crystallisation conditions. The juxtaposition of quartz crystals with contrasting zoning patterns is consistent with a dynamic regime (convection, stirring, overturning) of the GRV magma chamber. These results point to pulsating magmatic conditions, compatible with a non-linear evolution of the GRV magma chamber. Heat, necessary to explain both intra-granular and infra-granular textural variations, may have been provided in different pulses by underplating of mafic magma.

Olympic Dam is a supergiant Fe oxide Cu-U-Au-Ag ore deposit (~9 × 109 t) that is also enriched in rare earth elements (REEs) and fluorine (F). The immediate host to the ore is hydrothermal breccia within granite and volcanic rocks of a Mesoproterozoic silicic large igneous province. Analyses of melt inclusions in quartz phenocrysts in rhyolite show that the silicic magmas of this province were unusually rich in F (up to 1.3 wt%). Fluorite and other F-rich minerals that crystallized from these magmas provided a gigantic reservoir of F. As a result, the Olympic Dam ore-forming fluid was F-rich and had exceptional capacity to transport diverse elements. Further, we infer that hydrofluoric acid, the most corrosive acid known, contributed to hydrothermal breccia formation by dissolution that in turn increased permeability and accelerated the rate of fluid-rock interaction. It is no accident that the world's largest hydrothermal ore deposit occurs in an F-rich silicic large igneous province.

Rhyolites of the Mesoproterozoic Gawler Range Volcanics (GRV) of South Australia are characterised by high concentrations of some trace elements (REE, Y, HFSE, Rb and F, in particular). Whole rock geochemical data suggest that these elements were incompatible during magma crystallisation. Accessory minerals (fluorite, zircon, REE-F-carbonate, Ti oxide, apatite, and titanite) can account for most of the trace element content of the rocks. These minerals occur in vesicles, micromiaroles, lithophysal vugs and in interstices between major mineral phases (quartz and feldspar as both phenocrysts and groundmass). Such textural evidence indicates that accessory minerals crystallised late in the history of the magma and that they were deposited from a volatile-rich (fluid) phase. These features are explained by the following sequence of events: 1) F dissolved in the magma lowered the crystallisation temperature of accessory minerals, causing trace elements (REE, Y, and HFSE) to behave as incompatible elements. 2) Protracted crystallisation of major mineral phases (quartz, feldspar, and oxides) formed a volatile- and trace element-enriched residual liquid. 3) A volatile element (H2O, F, and CO2)-rich phase (late-stage magmatic fluid) evolved from the magma. High concentration of fluorine and other complexing agents in this phase allowed trace elements to be transported in solution. 4) Accessory minerals crystallised from such a phase in vesicles, micromiaroles and interstices between the major mineral phases. © 2010 Elsevier B.V.

Lihir Gold mines the Ladolam gold deposit on Lihir Island, Papua New Guinea. With an average grade of 2.42 g/tonne, the deposit contains 40 000 000 oz gold. The gold is associated with epithermal-style alteration and mineralisation, and is mainly contained in refractory pyrite. The deposit is made up of four ore bodies; the Minifie, Leinetz, Coastal and Kapit. The results of an ongoing research project into the first two are discussed, highlighting the differences in geology and the paragenetic history., Lihir Gold mines the Ladolam gold deposit on Lihir Island, Papua New Guinea. With an average grade of 2.42 g/tonne, the deposit contains 40 000 000 oz gold. The gold is associated with epithermal-style alteration and mineralisation, and is mainly contained in refractory pyrite. The deposit is made up of four ore bodies; the Minifie, Leinetz, Coastal and Kapit. The results of an ongoing research project into the first two are discussed, highlighting the differences in geology and the paragenetic history.

The Chatree epithermal silver-gold deposit is located in Thailand in the central part of the Leoi Fold Belt. Current total resource at Chatree is 74 600 000 tonnes at 1.6 g/t gold and 13 g/t silver. The mineralisation occurs as veins/veinlets and stockworks in minor breccia in volcaniclastic and volcano-sedimentary rocks of andesitic to basaltic andesite composition and Permo-Triassic age. An initial oxygen isotope study on vein quartz showed that the values increased outwards from the centre of the main ore zones, and this could be used as a vector to ore., The Chatree epithermal silver-gold deposit is located in Thailand in the central part of the Leoi Fold Belt. Current total resource at Chatree is 74 600 000 tonnes at 1.6 g/t gold and 13 g/t silver. The mineralisation occurs as veins/veinlets and stockworks in minor breccia in volcaniclastic and volcano-sedimentary rocks of andesitic to basaltic andesite composition and Permo-Triassic age. An initial oxygen isotope study on vein quartz showed that the values increased outwards from the centre of the main ore zones, and this could be used as a vector to ore.

The presence of peperite, formed by dynamic mixing of magma with wet, unconsolidated sediment, is important in distinguishing sills from lavas or post-volcanic intrusions into solid rock. At the Onedin prospect in the Koongie Park Formation, Western Australia, high-grade massive sulphide is hosted in a carbonate lens up to 10 m below an extensive aphyric sill with peperitic upper and lower margins. The sill may have been an important heat source and also provided a cap to fluid flow. The remains of pumice-rich textures, largely destroyed during alteration and compaction, are also associated with carbonate alteration at the prospect, while relic perlite occurs at the margins of aphyric rhyolite sills. The high porosity, permeability and reactivity of the glassy pumice and intensely fractured glass of perlite may have focused hydrothermal flow, while the same properties will have promoted early alteration and loss of porosity., The presence of peperite, formed by dynamic mixing of magma with wet, unconsolidated sediment, is important in distinguishing sills from lavas or post-volcanic intrusions into solid rock. At the Onedin prospect in the Koongie Park Formation, Western Australia, high-grade massive sulphide is hosted in a carbonate lens up to 10 m below an extensive aphyric sill with peperitic upper and lower margins. The sill may have been an important heat source and also provided a cap to fluid flow. The remains of pumice-rich textures, largely destroyed during alteration and compaction, are also associated with carbonate alteration at the prospect, while relic perlite occurs at the margins of aphyric rhyolite sills. The high porosity, permeability and reactivity of the glassy pumice and intensely fractured glass of perlite may have focused hydrothermal flow, while the same properties will have promoted early alteration and loss of porosity.