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This volume serves as a companion to the "Lessons from the First Statewide Family Engagement Centers: Alignment with Federal Priorities and Factors Influencing Implementation" report. The report focuses on the Statewide Family Engagement Centers (SFEC) program and provides insights into its implementation and alignment with federal priorities on family engagement. This appendix provides additional information to supplement the main report, with its content referenced throughout the report. Appendix A presents the study design and analysis. Appendix B includes supporting and supplemental tables that provide additional information about the SFEC program and its implementation.

This report describes the implementation efforts of the first grantees under the Statewide Family Engagement Centers (SFEC) and how they aligned with program priorities. Begun in 2018, SFEC is one of the key U.S. Department of Education programs designed to address disparities in family engagement in schools. The program provides grants to selected partnerships of education organizations and their states to deliver services and disseminate technical assistance resources to further family-school engagement. The study was designed to provide early lessons about the program, including the extent to which implementation reflected the 2018 federal emphasis on providing services directly to families and schools, using specific approaches, topics, and ways of collaborating among partners, and serving mostly disadvantaged families and districts with high concentrations of students from such families. The study also examined the factors that influenced grantee implementation, including challenges in carrying out their program efforts that coincided with the height of the COVID-19 pandemic and immediately after.

Vanadium silicide, V\(_3\)Si, is a promising superconductor for silicon-based superconducting (SC) devices due to its compatibility with silicon substrates and its potential for integration into existing semiconductor technologies. However, to date there have been only a limited number of studies of the formation of SC V\(_3\)Si thin films and the associated structural and superconducting properties. This work aims to explore the structural characteristics and SC properties of V\(_3\)Si films, paving the way for the development of functional SC devices for quantum technology applications. We have investigated the formation of V\(_3\)Si films by directly depositing vanadium (V) onto thermally grown SiO\(_2\) on Si, followed by high-vacuum annealing to induce the phase transformation into V\(_3\)Si. Rutherford Backscattering Spectrometry(RBS) was employed throughout the sample growth process to analyze the material composition as a function of depth using a 4He+ ion beam. Analysis of the RBS data confirmed that the V layer fully reacted with the SiO\(_2\) substrate to form V\(_3\)Si at the interface, in addition to a vanadium oxide (VO\(_x\)) layer forming atop the V\(_3\)Si film. The thickness of the V\(_3\)Si layer ranges from 63 to 130 nm, with annealing temperatures between 750\(^{\circ}\)C and 800\(^{\circ}\)C. A sharp SC transition was observed at T\(_c\) = 13 K in the sample annealed at 750{\deg}C, with a narrow transition width (\(\Delta T_c\)) of 0.6 K. Initial reactive ion etching (RIE) studies yielded promising results for local removal of the VO\(_x\) to facilitate electrical contact formation to the SC layer., Comment: 7 pages, 3 figures. Submitted to Nuclear Instruments and Methods in Physics Research Section B

We describe updated scientific goals for the wide-field, millimeter-wave survey that will be produced by the Simons Observatory (SO). Significant upgrades to the 6-meter SO Large Aperture Telescope (LAT) are expected to be complete by 2028, and will include a doubled mapping speed with 30,000 new detectors and an automated data reduction pipeline. In addition, a new photovoltaic array will supply most of the observatory's power. The LAT survey will cover about 60% of the sky at a regular observing cadence, with five times the angular resolution and ten times the map depth of Planck. The science goals are to: (1) determine the physical conditions in the early universe and constrain the existence of new light particles; (2) measure the integrated distribution of mass, electron pressure, and electron momentum in the late-time universe, and, in combination with optical surveys, determine the neutrino mass and the effects of dark energy via tomographic measurements of the growth of structure at $z < 3$; (3) measure the distribution of electron density and pressure around galaxy groups and clusters, and calibrate the effects of energy input from galaxy formation on the surrounding environment; (4) produce a sample of more than 30,000 galaxy clusters, and more than 100,000 extragalactic millimeter sources, including regularly sampled AGN light-curves, to study these sources and their emission physics; (5) measure the polarized emission from magnetically aligned dust grains in our Galaxy, to study the properties of dust and the role of magnetic fields in star formation; (6) constrain asteroid regoliths, search for Trans-Neptunian Objects, and either detect or eliminate large portions of the phase space in the search for Planet 9; and (7) provide a powerful new window into the transient universe on time scales of minutes to years, concurrent with observations from Rubin of overlapping sky., Comment: 44 pages, 7 figures; abstract slightly abridged. Author contributions to this paper are available at https://simonsobservatory.org/wp-content/uploads/2025/02/Author-contribution-statement-20250228.pdf

Personalized item recommendation typically suffers from data sparsity, which is most often addressed by learning vector representations of users and items via low-rank matrix factorization. While this effectively densifies the matrix by assuming users and movies can be represented by linearly dependent latent features, it does not capture more complicated interactions. For example, vector representations struggle with set-theoretic relationships, such as negation and intersection, e.g. recommending a movie that is "comedy and action, but not romance". In this work, we formulate the problem of personalized item recommendation as matrix completion where rows are set-theoretically dependent. To capture this set-theoretic dependence we represent each user and attribute by a hyper-rectangle or box (i.e. a Cartesian product of intervals). Box embeddings can intuitively be understood as trainable Venn diagrams, and thus not only inherently represent similarity (via the Jaccard index), but also naturally and faithfully support arbitrary set-theoretic relationships. Queries involving set-theoretic constraints can be efficiently computed directly on the embedding space by performing geometric operations on the representations. We empirically demonstrate the superiority of box embeddings over vector-based neural methods on both simple and complex item recommendation queries by up to 30 \% overall.

Colour centres hosted in solid-state materials such as silicon carbide and diamond are promising candidates for integration into chip-scale quantum systems. Specifically, the incorporation of these colour centres within photonic integrated circuits may enable precise control over their inherent photo-physical properties through strong light-matter interaction. Here, we investigate ion-implanted erbium ($\text{Er}^{3+}$) defects embedded in thin-film 4H-silicon-carbide-on-insulator (4H-SiCOI). Optimized implantation conditions and thermal annealing processes designed to enhance the emission characteristics of the $\text{Er}^{3+}$-defect are reported. By examining key properties such as photoluminescence intensity, optical lifetime, and polarization, we present an analysis of ensemble $\text{Er}^{3+}$-defects within 4H-SiCOI, providing insights into their potential for future quantum applications., Comment: 9 pages, 5 figures

This paper introduces a new instrument enabling a novel combination of Earth measuring techniques: direct observations with the radio astronomical instruments to satellites of the global navigation satellite systems. Inter-technique biases are a major error source in the terrestrial reference frame. Combining two major space-geodetic techniques, GNSS and VLBI, through observations to identical sensors has been considered infeasible due to their seemingly incompatible operating frequencies. The newly accessible L-band capability of the Australian VGOS telescopes is shown here, invalidating this prevailing opinion. A series of test observations demonstrates geodetic VLBI observations to GPS satellites for a continental-wide IVS telescope array, with the potential for observations at a critical scale. We anticipate immediate impact for the geodetic community, through first-ever inter-technique ties between VLBI and GNSS in the Australian region and via the opportunity for critical test observations towards the Genesis mission, geodesy's flagship project in the area of space ties set for launch in 2028., Comment: 9 pages, 4 figures. Submitted to Publications of the Astronomical Society of the Pacific on the 17th of December 2024

The o1 model series is trained with large-scale reinforcement learning to reason using chain of thought. These advanced reasoning capabilities provide new avenues for improving the safety and robustness of our models. In particular, our models can reason about our safety policies in context when responding to potentially unsafe prompts, through deliberative alignment. This leads to state-of-the-art performance on certain benchmarks for risks such as generating illicit advice, choosing stereotyped responses, and succumbing to known jailbreaks. Training models to incorporate a chain of thought before answering has the potential to unlock substantial benefits, while also increasing potential risks that stem from heightened intelligence. Our results underscore the need for building robust alignment methods, extensively stress-testing their efficacy, and maintaining meticulous risk management protocols. This report outlines the safety work carried out for the OpenAI o1 and OpenAI o1-mini models, including safety evaluations, external red teaming, and Preparedness Framework evaluations.

Vanadium silicide (V$_3$Si) is a promising superconductor for integration with silicon-based electronics, however the interfacial growth kinetics have a strong influence on the resulting superconducting properties and are not yet fully understood. In this study, we have used neutron reflectometry to reveal the phase transformation during thin film growth driven by different annealing strategies. We examined the silicide formation when a thin layer of vanadium undergoes reactive diffusion with a silicon dioxide film on silicon at temperatures from 650-800 {\deg}C. To further investigate the time evolution of different phases under various annealing temperatures, a chemical model was developed and subsequent simulations were performed. The results of this model were validated using X-ray diffraction and cross-sectional TEM analysis. Correlations were observed between the structure and superconducting properties. Over-annealing films leads to complete depletion of the SiO$_2$ barrier layer, forming diffuse interfaces and driving the formation of undesirable silicon-rich silicides. Avoiding this by controlling time and temperature, allows higher quality superconducting films to be achieved. The $T_c$ of the films was found to be 13 K, and the annealing conditions influenced the critical fields and the paramagnetic Meissner effect near $T_c$. For optimally-annealed films, superconducting order parameters were calculated. Ginzberg-Landau theory was applied to explain flux penetration., Comment: 13 pages, 9 Figures

We extend our time-dependent hydrogen ionization simulations of diffuse ionized gas to include metals important for collisional cooling and diagnostic emission lines. The combination of heating from supernovae and time-dependent collisional and photoionization from midplane OB stars produces emission line intensities (and emission line ratios) that follow the trends observed in the Milky Way and other edge-on galaxies. The long recombination times in low density gas result in persistent large volumes of ions with high ionization potentials, such as O III and Ne III. In particular, the vertically extended layers of Ne III in our time-dependent simulations result in [Ne III] 15$\mu$m/[Ne II] 12$\mu$m emission line ratios in agreement with observations of the edge-on galaxy NGC 891. Simulations adopting ionization equilibrium do not allow for the persistence of ions with high ionization states and therefore cannot reproduce the observed emission lines from low density gas at high altitudes., Comment: 14 pages, 16 figures, accepted for publication in MNRAS

Personalized search represents a problem where retrieval models condition on historical user interaction data in order to improve retrieval results. However, personalization is commonly perceived as opaque and not amenable to control by users. Further, personalization necessarily limits the space of items that users are exposed to. Therefore, prior work notes a tension between personalization and users' ability for discovering novel items. While discovery of novel items in personalization setups may be resolved through search result diversification, these approaches do little to allow user control over personalization. Therefore, in this paper, we introduce an approach for controllable personalized search. Our model, CtrlCE presents a novel cross-encoder model augmented with an editable memory constructed from users historical items. Our proposed memory augmentation allows cross-encoder models to condition on large amounts of historical user data and supports interaction from users permitting control over personalization. Further, controllable personalization for search must account for queries which don't require personalization, and in turn user control. For this, we introduce a calibrated mixing model which determines when personalization is necessary. This allows system designers using CtrlCE to only obtain user input for control when necessary. In multiple datasets of personalized search, we show CtrlCE to result in effective personalization as well as fulfill various key goals for controllable personalized search., Comment: Work in progress

GPT-4o is an autoregressive omni model that accepts as input any combination of text, audio, image, and video, and generates any combination of text, audio, and image outputs. It's trained end-to-end across text, vision, and audio, meaning all inputs and outputs are processed by the same neural network. GPT-4o can respond to audio inputs in as little as 232 milliseconds, with an average of 320 milliseconds, which is similar to human response time in conversation. It matches GPT-4 Turbo performance on text in English and code, with significant improvement on text in non-English languages, while also being much faster and 50\% cheaper in the API. GPT-4o is especially better at vision and audio understanding compared to existing models. In line with our commitment to building AI safely and consistent with our voluntary commitments to the White House, we are sharing the GPT-4o System Card, which includes our Preparedness Framework evaluations. In this System Card, we provide a detailed look at GPT-4o's capabilities, limitations, and safety evaluations across multiple categories, focusing on speech-to-speech while also evaluating text and image capabilities, and measures we've implemented to ensure the model is safe and aligned. We also include third-party assessments on dangerous capabilities, as well as discussion of potential societal impacts of GPT-4o's text and vision capabilities.

Spherical proportional counters (SPCs) are gaseous particle detectors sensitive to single ionization electrons in their target media, with large detector volumes and low background rates. The $\mbox{NEWS-G}$ collaboration employs this technology to search for low-mass dark matter, having previously performed searches with detectors at the Laboratoire Souterrain de Modane (LSM), including a recent campaign with a 135 cm diameter SPC filled with methane. While in situ calibrations of the detector response were carried out at the LSM, measurements of the mean ionization yield and fluctuations of methane gas in SPCs were performed using a 30 cm diameter detector. The results of multiple measurements taken at different operating voltages are presented. A UV laser system was used to measure the mean gas gain of the SPC, along with $\mathrm{^{37}Ar}$ and aluminum-fluorescence calibration sources. These measurements will inform the energy response model of future operating detectors., Comment: 11 pages, 8 figures

Training Neural ODEs requires backpropagating through an ODE solve. The state-of-the-art backpropagation method is recursive checkpointing that balances recomputation with memory cost. Here, we introduce a class of algebraically reversible ODE solvers that significantly improve upon both the time and memory cost of recursive checkpointing. The reversible solvers presented calculate exact gradients, are high-order and numerically stable -- strictly improving on previous reversible architectures., Comment: Preprint

In dense retrieval, deep encoders provide embeddings for both inputs and targets, and the softmax function is used to parameterize a distribution over a large number of candidate targets (e.g., textual passages for information retrieval). Significant challenges arise in training such encoders in the increasingly prevalent scenario of (1) a large number of targets, (2) a computationally expensive target encoder model, (3) cached target embeddings that are out-of-date due to ongoing training of target encoder parameters. This paper presents a simple and highly scalable response to these challenges by training a small parametric corrector network that adjusts stale cached target embeddings, enabling an accurate softmax approximation and thereby sampling of up-to-date high scoring "hard negatives." We theoretically investigate the generalization properties of our proposed target corrector, relating the complexity of the network, staleness of cached representations, and the amount of training data. We present experimental results on large benchmark dense retrieval datasets as well as on QA with retrieval augmented language models. Our approach matches state-of-the-art results even when no target embedding updates are made during training beyond an initial cache from the unsupervised pre-trained model, providing a 4-80x reduction in re-embedding computational cost., Comment: ICML 2024

In text generation, hallucinations refer to the generation of seemingly coherent text that contradicts established knowledge. One compelling hypothesis is that hallucinations occur when a language model is given a generation task outside its parametric knowledge (due to rarity, recency, domain, etc.). A common strategy to address this limitation is to infuse the language models with retrieval mechanisms, providing the model with relevant knowledge for the task. In this paper, we leverage the planning capabilities of instruction-tuned LLMs and analyze how planning can be used to guide retrieval to further reduce the frequency of hallucinations. We empirically evaluate several variations of our proposed approach on long-form text generation tasks. By improving the coverage of relevant facts, plan-guided retrieval and generation can produce more informative responses while providing a higher rate of attribution to source documents.

We present new JWST observations of the nearby, prototypical edge-on, spiral galaxy NGC 891. The northern half of the disk was observed with NIRCam in its F150W and F277W filters. Absorption is clearly visible in the mid-plane of the F150W image, along with vertical dusty plumes that closely resemble the ones seen in the optical. A $\sim 10 \times 3~{\rm kpc}^2$ area of the lower circumgalactic medium (CGM) was mapped with MIRI F770W at 12 pc scales. Thanks to the sensitivity and resolution of JWST, we detect dust emission out to $\sim 4$ kpc from the disk, in the form of filaments, arcs, and super-bubbles. Some of these filaments can be traced back to regions with recent star formation activity, suggesting that feedback-driven galactic winds play an important role in regulating baryonic cycling. The presence of dust at these altitudes raises questions about the transport mechanisms at play and suggests that small dust grains are able to survive for several tens of million years after having been ejected by galactic winds in the disk-halo interface. We lay out several scenarios that could explain this emission: dust grains may be shielded in the outer layers of cool dense clouds expelled from the galaxy disk, and/or the emission comes from the mixing layers around these cool clumps where material from the hot gas is able to cool down and mix with these cool cloudlets. This first set of data and upcoming spectroscopy will be very helpful to understand the survival of dust grains in energetic environments, and their contribution to recycling baryonic material in the mid-plane of galaxies., Comment: Accepted for publication in Astronomy & Astrophysics; 16 pages, 8 figures

The diagnosis of bronchiectasis requires measuring abnormal bronchial dilation. It is confirmed using a chest CT scan, where the key feature is an increased broncho-arterial ratio (BAR) (>0.8 in children), often with bronchial wall thickening. Image processing methods facilitate quicker interpretation and detailed evaluations by lobes and segments. Challenges like inclined nature, oblique orientation, and partial volume effect make it difficult to obtain accurate measurements in the upper and middle lobes using the same algorithms. Therefore, accurate detection and measurement of airway and artery regions for BAR and wall thickness in each lobe require different image processing/machine learning methods. We propose methods for: 1. Separating the right lower lobe (RLL) region from full-length CT scans using the tracheal bifurcation (Carina) point as a central marker; 2. Locating the inner diameter of airways and outer diameter of arteries for BAR measurement; and 3. Measuring airway wall thickness (WT) by identifying the outer and inner diameters of airway boundaries. Analysis of 13 HRCT scans with varying thicknesses (0.67mm, 1mm, 2mm) shows the tracheal bifurcation frame can be detected accurately, with a deviation of +/- 2 frames in some cases. A Windows app was developed for measuring inner airway diameter, artery diameter, BAR, and wall thickness, allowing users to draw boundaries around visible BA pairs in the RLL region. Measurements of 10 BA pairs revealed accurate results comparable to those of a human reader, with deviations of +/- 0.10-0.15mm. Additional studies and validation are needed to consolidate inter- and intra-rater variability and enhance the methods., Comment: 14 pages

The NEWS-G direct detection experiment uses spherical proportional counters to search for light dark matter candidates. New results from a 10 day physics run with a $135\,\mathrm{cm}$ in diameter spherical proportional counter at the Laboratoire Souterrain de Modane are reported. The target consists of $114\,\mathrm{g}$ of methane, providing sensitivity to dark matter spin-dependent coupling to protons. New constraints are presented in the mass range $0.17$ to $1.2\,\mathrm{GeV/c^2}$, with a 90% confidence level cross-section upper limit of $30.9\,\mathrm{pb}$ for a mass of $0.76\,\mathrm{GeV/c^2}$., Comment: 7 pages, 3 figures

Topic models are widely used to analyze document collections. While they are valuable for discovering latent topics in a corpus when analysts are unfamiliar with the corpus, analysts also commonly start with an understanding of the content present in a corpus. This may be through categories obtained from an initial pass over the corpus or a desire to analyze the corpus through a predefined set of categories derived from a high level theoretical framework (e.g. political ideology). In these scenarios analysts desire a topic modeling approach which incorporates their understanding of the corpus while supporting various forms of interaction with the model. In this work, we present EdTM, as an approach for label name supervised topic modeling. EdTM models topic modeling as an assignment problem while leveraging LM/LLM based document-topic affinities and using optimal transport for making globally coherent topic-assignments. In experiments, we show the efficacy of our framework compared to few-shot LLM classifiers, and topic models based on clustering and LDA. Further, we show EdTM's ability to incorporate various forms of analyst feedback and while remaining robust to noisy analyst inputs., Comment: Pre-print; Work in progress

Large language models have demonstrated impressive performance on commonsense tasks; however, these tasks are often posed as multiple-choice questions, allowing models to exploit systematic biases. Commonsense is also inherently probabilistic with multiple correct answers. The purpose of "boiling water" could be making tea and cooking, but it also could be killing germs. Existing tasks do not capture the probabilistic nature of common sense. To this end, we present commonsense frame completion (CFC), a new generative task that evaluates common sense via multiple open-ended generations. We also propose a method of probabilistic evaluation that strongly correlates with human judgments. Humans drastically outperform strong language model baselines on our dataset, indicating this approach is both a challenging and useful evaluation of machine common sense., Comment: ACL 2024 Camera Ready

A common retrieve-and-rerank paradigm involves retrieving relevant candidates from a broad set using a fast bi-encoder (BE), followed by applying expensive but accurate cross-encoders (CE) to a limited candidate set. However, relying on this small subset is often susceptible to error propagation from the bi-encoders, which limits the overall performance. To address these issues, we propose the Comparing Multiple Candidates (CMC) framework. CMC compares a query and multiple embeddings of similar candidates (i.e., neighbors) through shallow self-attention layers, delivering rich representations contextualized to each other. Furthermore, CMC is scalable enough to handle multiple comparisons simultaneously. For example, comparing ~10K candidates with CMC takes a similar amount of time as comparing 16 candidates with CE. Experimental results on the ZeSHEL dataset demonstrate that CMC, when plugged in between bi-encoders and cross-encoders as a seamless intermediate reranker (BE-CMC-CE), can effectively improve recall@k (+4.8%-p, +3.5%-p for R@16, R@64) compared to using only bi-encoders (BE-CE), with negligible slowdown (<7%). Additionally, to verify CMC's effectiveness as the final-stage reranker in improving top-1 accuracy, we conduct experiments on downstream tasks such as entity, passage, and dialogue ranking. The results indicate that CMC is not only faster (11x) but also often more effective than CE, with improved prediction accuracy in Wikipedia entity linking (+0.7%-p) and DSTC7 dialogue ranking (+3.3%-p)., Comment: accepted to EMNLP 2024 main track

Cross-encoder (CE) models which compute similarity by jointly encoding a query-item pair perform better than embedding-based models (dual-encoders) at estimating query-item relevance. Existing approaches perform k-NN search with CE by approximating the CE similarity with a vector embedding space fit either with dual-encoders (DE) or CUR matrix factorization. DE-based retrieve-and-rerank approaches suffer from poor recall on new domains and the retrieval with DE is decoupled from the CE. While CUR-based approaches can be more accurate than the DE-based approach, they require a prohibitively large number of CE calls to compute item embeddings, thus making it impractical for deployment at scale. In this paper, we address these shortcomings with our proposed sparse-matrix factorization based method that efficiently computes latent query and item embeddings to approximate CE scores and performs k-NN search with the approximate CE similarity. We compute item embeddings offline by factorizing a sparse matrix containing query-item CE scores for a set of train queries. Our method produces a high-quality approximation while requiring only a fraction of CE calls as compared to CUR-based methods, and allows for leveraging DE to initialize the embedding space while avoiding compute- and resource-intensive finetuning of DE via distillation. At test time, the item embeddings remain fixed and retrieval occurs over rounds, alternating between a) estimating the test query embedding by minimizing error in approximating CE scores of items retrieved thus far, and b) using the updated test query embedding for retrieving more items. Our k-NN search method improves recall by up to 5% (k=1) and 54% (k=100) over DE-based approaches. Additionally, our indexing approach achieves a speedup of up to 100x over CUR-based and 5x over DE distillation methods, while matching or improving k-NN search recall over baselines., Comment: ICLR 2024

Widespread, high altitude, diffuse ionized gas with scale heights of around a kiloparsec is observed in the Milky Way and other star forming galaxies. Numerical radiation-magnetohydrodynamic simulations of a supernova-driven turbulent interstellar medium show that gas can be driven to high altitudes above the galactic midplane, but the degree of ionization is often less than inferred from observations. For computational expediency, ionizing radiation from massive stars is often included as a post-processing step assuming ionization equilibrium. We extend our simulations of a Milky Way-like interstellar medium to include the combined effect of supernovae and photoionization feedback from midplane OB stars and a population of hot evolved low mass stars. The diffuse ionized gas has densities below 0.1 ${\rm cm^{-3}}$, so recombination timescales can exceed millions of years. Our simulations now follow the time-dependent ionization and recombination of low density gas. The long recombination timescales result in diffuse ionized gas that persists at large altitudes long after the deaths of massive stars that produce the vast majority of the ionized gas. The diffuse ionized gas does not exhibit the large variability inherent in simulations that adopt ionization equilibrium. The vertical distribution of neutral and ionized gas is close to what is observed in the Milky Way. The volume filling factor of ionized gas increases with altitude resulting in the scale height of free electrons being larger than that inferred from H$\alpha$ emission, thus reconciling the observations of ionized gas made in H$\alpha$ and from pulsar dispersion measurements., Comment: 17 pages, 16 figures, accepted for publication in MNRAS

We develop an efficient algorithm to find optimal observation times by maximizing the Fisher information for the birth rate of a partially observable pure birth process involving $n$ observations. Partially observable implies that at each of the $n$ observation time points for counting the number of individuals present in the pure birth process, each individual is observed independently with a fixed probability $p$, modeling detection difficulties or constraints on resources. We apply concepts and techniques from generating functions, using a combination of symbolic and numeric computation, to establish a recursion for evaluating and optimizing the Fisher information. Our numerical results reveal the efficacy of this new method. An implementation of the algorithm is available publicly.

Accurate detection and analysis of traces of persistent organic pollutants in water is important in many areas, including environmental monitoring and food quality control, due to their long environmental stability and potential bioaccumulation. While conventional analysis of organic pollutants requires expensive equipment, surface enhanced Raman spectroscopy (SERS) has demonstrated great potential for accurate detection of these contaminants. However, SERS analytical difficulties, such as spectral preprocessing, denoising, and substrate-based spectral variation, have hindered widespread use of the technique. Here, we demonstrate an approach for predicting the concentration of sample pollutants from messy, unprocessed Raman data using machine learning. Frequency domain transform methods, including the Fourier and Walsh Hadamard transforms, are applied to sets of Raman spectra of three model micropollutants in water (rhodamine 6G, chlorpyrifos, and triclosan), which are then used to train machine learning algorithms. Using standard machine learning models, the concentration of sample pollutants are predicted with more than 80 percent cross-validation accuracy from raw Raman data. cross-validation accuracy of 85 percent was achieved using deep learning for a moderately sized dataset (100 spectra), and 70 to 80 percent cross-validation accuracy was achieved even for very small datasets (50 spectra). Additionally, standard models were shown to accurately identify characteristic peaks via analysis of their importance scores. The approach shown here has the potential to be applied to facilitate accurate detection and analysis of persistent organic pollutants by surface-enhanced Raman spectroscopy.

We have conducted an extensive towed-magnetic-sled survey during the period of June 14-28, 2023, over the seafloor about 85 km north of Manus Island, Papua New Guinea, centered around the calculated path of the bolide CNEOS 2014-01-08 (IM1). We found about 850 spherules of diameter 0.1-1.3 millimeters in our samples. The samples were analyzed by micro-XRF, Electron Probe Microanalyzer and ICP Mass spectrometry. Here we report major and trace element compositions of the samples and classify spherules based on that analysis. Spherules comprising 22% of the collection, appear to all reflect planetary igneous differentiation and are all different from previously described spherules. A subset of the differentiated-spherules show an excess of Be, La and U, by up to three orders of magnitude relative to the solar system standard of CI chondrites. Detailed mass spectrometry of 12 of these "BeLaU"-type spherules, the population of which may constitute up to ~10% of our entire collected sample, suggests that they are derived from material formed by planetary igneous fractionation. Their chemical composition is unlike any known solar system material. The "BeLaU"-type spherules reflect a highly differentiated, extremely evolved composition of an unknown source., Comment: Accepted for publication in Chemical Geology

Extractive opinion summarization involves automatically producing a summary of text about an entity (e.g., a product's reviews) by extracting representative sentences that capture prevalent opinions in the review set. Typically, in online marketplaces user reviews accumulate over time, and opinion summaries need to be updated periodically to provide customers with up-to-date information. In this work, we study the task of extractive opinion summarization in an incremental setting, where the underlying review set evolves over time. Many of the state-of-the-art extractive opinion summarization approaches are centrality-based, such as CentroidRank (Radev et al., 2004; Chowdhury et al., 2022). CentroidRank performs extractive summarization by selecting a subset of review sentences closest to the centroid in the representation space as the summary. However, these methods are not capable of operating efficiently in an incremental setting, where reviews arrive one at a time. In this paper, we present an efficient algorithm for accurately computing the CentroidRank summaries in an incremental setting. Our approach, CoverSumm, relies on indexing review representations in a cover tree and maintaining a reservoir of candidate summary review sentences. CoverSumm's efficacy is supported by a theoretical and empirical analysis of running time. Empirically, on a diverse collection of data (both real and synthetically created to illustrate scaling considerations), we demonstrate that CoverSumm is up to 36x faster than baseline methods, and capable of adapting to nuanced changes in data distribution. We also conduct human evaluations of the generated summaries and find that CoverSumm is capable of producing informative summaries consistent with the underlying review set., Comment: Accepted at TMLR