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A multi-instrument study of the regolith of Jezero crater floor units by the Perseverance rover has identified three types of regolith: fine-grained, coarse-grained, and mixed-type. Mastcam-Z, Wide Angle Topographic Sensor for Operations and eNgineering, and SuperCam Remote Micro Imager were used to characterize the regolith texture, particle size, and roundedness where possible. Mastcam-Z multispectral and SuperCam laser-induced breakdown spectroscopy data were used to constrain the composition of the regolith types. Fine-grained regolith is found surrounding bedrock and boulders, comprising bedforms, and accumulating on top of rocks in erosional depressions. Spectral and chemical data show it is compositionally consistent with pyroxene and a ferric-oxide phase. Coarse-grained regolith consists of 1-2 mm well-sorted gray grains that are found concentrated around the base of boulders and bedrock, and armoring bedforms. Its chemistry and spectra indicate it is olivine-bearing, and its spatial distribution and roundedness indicate it has been transported, likely by saltation-induced creep. Coarse grains share similarities with the olivine grains observed in the S & eacute;& iacute;tah formation bedrock, making that unit a possible source for these grains. Mixed-type regolith contains fine-and coarse-grained regolith components and larger rock fragments. The rock fragments are texturally and spectrally similar to bedrock within the M & aacute;az and S & eacute;& iacute;tah formations, indicating origins by erosion from those units, although they could also be a lag deposit from erosion of an overlying unit. The fine and coarse-grained types are compared to their counterparts at other landing sites to inform global, regional, and local inputs to regolith formation within Jezero crater. The regolith characterization presented here informs the regolith sampling efforts underway by Perseverance.Plain Language Summary We used multiple instruments on the Perseverance rover to describe three populations of loose sediments found on the floor of Jezero crater by their grain sizes and chemical compositions. The smallest population has grains that are small sand-sized (80-530 mu m) and a mixture of minerals commonly found on Mars, including pyroxene that is present in local rocks and airborne dust found globally. These grains are the easiest to move by wind, so could have distal regional sources as well. Larger gray grains that are 1-2 mm in size and rounded contain olivine. These grains move along the surface, pushed by the impacts of smaller grains that are lifted by the wind. Their size and composition are very similar to olivine grains found in nearby in-place rocks, indicating that they may have a more local source. Finally, there are larger pieces of rocks that have broken down from the erosion of local in-place rocks over time and mix with the other types of grains. Loose sediments within the Jezero crater described here can be compared to loose sediments studied at other landing sites on Mars to help understand how Jezero sediments are formed and transported.

The origin and age of opaline silica deposits discovered by the Spirit rover adjacent to the Home Plate feature in the Columbia Hills of Gusev crater remains debated, in part because of their proximity to sulfur-rich soils. Processes related to fumarolic activity and to hot springs and/or geysers are the leading candidates. Both processes are known to produce opaline silica on Earth, but with differences in composition, morphology, texture, and stratigraphy. Here, we incorporate new and existing observations of the Home Plate region with observations from field and laboratory work to address the competing hypotheses. The results, which include new evidence for a hot spring vent mound, demonstrate that a volcanic hydrothermal system manifesting both hot spring/geyser and fumarolic activity best explains the opaline silica rocks and proximal S-rich materials, respectively. The opaline silica rocks most likely are sinter deposits derived from hot spring activity. Stratigraphic evidence indicates that their deposition occurred before the emplacement of the volcaniclastic deposits comprising Home Plate and nearby ridges. Because sinter deposits throughout geologic history on Earth preserve evidence for microbial life, they are a key target in the search for ancient life on Mars.

The Mars Science Laboratory Curiosity rover has explored over 400 m of vertical stratigraphy within Gale crater to date. These fluvio-deltaic, lacustrine, and aeolian strata have been well-documented by Curiosity's in situ and remote science instruments, including the Mast Camera (Mastcam) pair of multispectral imagers. Mastcam visible to near-infrared spectra can broadly distinguish between iron phases and oxidation states, and in combination with chemical data from other instruments, Mastcam spectra can help constrain mineralogy, depositional origin, and diagenesis. However, no traverse-scale analysis of Mastcam multispectral data has yet been performed. We compiled a database of Mastcam spectra from >600 multispectral observations and quantified spectral variations across Curiosity's traverse through Vera Rubin ridge (sols 0-2302). From principal component analysis and an examination of spectral parameters, we identified nine rock spectral classes and five soil spectral classes. Rock classes are dominated by spectral differences attributed to hematite and other oxides (due to variations in grain size, composition, and abundance) and are mostly confined to specific stratigraphic members. Soil classes fall along a mixing line between soil spectra dominated by fine-grained Fe-oxides and those dominated by olivine-bearing sands. By comparing trends in soil versus rock spectra, we find that locally derived sediments are not significantly contributing to the spectra of soils. Rather, varying contributions of dark, mafic sands from the active Bagnold Dune field is the primary spectral characteristic of soils. These spectral classes and their trends with stratigraphy provide a basis for comparison in Curiosity's ongoing exploration of Gale crater.

Perseverance images of a delta on Mars The Perseverance rover landed in Jezero crater, Mars, in February 2021. Earlier orbital images showed that the crater contains an ancient river delta that was deposited by water flowing into a lake billions of years ago. Mangold et al . analyzed rover images taken shortly after landing that show distant cliff faces at the edge of the delta. The exposed stratigraphy and sizes of boulders allowed them to determine the past lake level and water discharge rates. An initially steady flow transitioned into intermittent floods as the planet dried out. This history of the delta’s geology provides context for the rest of the mission and improves our understanding of Mars’ ancient climate. —KTS

The NASA Perseverance rover Mast Camera Zoom (Mastcam-Z) system is a pair of zoomable, focusable, multi-spectral, and color charge-coupled device (CCD) cameras mounted on top of a 1.7 m Remote Sensing Mast, along with associated electronics and two calibration targets. The cameras contain identical optical assemblies that can range in focal length from 26 mm ($25.5^{\circ }\, \times 19.1^{\circ }\ \mathrm{FOV}$ 25.5 ∘ × 19.1 ∘ FOV ) to 110 mm ($6.2^{\circ } \, \times 4.2^{\circ }\ \mathrm{FOV}$ 6.2 ∘ × 4.2 ∘ FOV ) and will acquire data at pixel scales of 148-540 μm at a range of 2 m and 7.4-27 cm at 1 km. The cameras are mounted on the rover’s mast with a stereo baseline of $24.3\pm 0.1$ 24.3 ± 0.1 cm and a toe-in angle of $1.17\pm 0.03^{\circ }$ 1.17 ± 0.03 ∘ (per camera). Each camera uses a Kodak KAI-2020 CCD with $1600\times 1200$ 1600 × 1200 active pixels and an 8 position filter wheel that contains an IR-cutoff filter for color imaging through the detectors’ Bayer-pattern filters, a neutral density (ND) solar filter for imaging the sun, and 6 narrow-band geology filters (16 total filters). An associated Digital Electronics Assembly provides command data interfaces to the rover, 11-to-8 bit companding, and JPEG compression capabilities. Herein, we describe pre-flight calibration of the Mastcam-Z instrument and characterize its radiometric and geometric behavior. Between April 26$^{th}$ t h and May 9$^{th}$ t h , 2019, ∼45,000 images were acquired during stand-alone calibration at Malin Space Science Systems (MSSS) in San Diego, CA. Additional data were acquired during Assembly Test and Launch Operations (ATLO) at the Jet Propulsion Laboratory and Kennedy Space Center. Results of the radiometric calibration validate a 5% absolute radiometric accuracy when using camera state parameters investigated during testing. When observing using camera state parameters not interrogated during calibration (e.g., non-canonical zoom positions), we conservatively estimate the absolute uncertainty to be $ < 10 % . Image quality, measured via the amplitude of the Modulation Transfer Function (MTF) at Nyquist sampling (0.35 line pairs per pixel), shows $\mathrm{MTF}_{\mathit{Nyquist}}=0.26-0.50$ MTF Nyquist = 0.26 − 0.50 across all zoom, focus, and filter positions, exceeding the $>0.2$ > 0.2 design requirement. We discuss lessons learned from calibration and suggest tactical strategies that will optimize the quality of science data acquired during operation at Mars. While most results matched expectations, some surprises were discovered, such as a strong wavelength and temperature dependence on the radiometric coefficients and a scene-dependent dynamic component to the zero-exposure bias frames. Calibration results and derived accuracies were validated using a Geoboard target consisting of well-characterized geologic samples.

Mastcam-Z is a multispectral, stereoscopic imaging investigation on the Mars 2020 mission’s Perseverance rover. Mastcam-Z consists of a pair of focusable, 4:1 zoomable cameras that provide broadband red/green/blue and narrowband 400-1000 nm color imaging with fields of view from 25.6° × 19.2° (26 mm focal length at 283 μrad/pixel) to 6.2° × 4.6° (110 mm focal length at 67.4 μrad/pixel). The cameras can resolve (≥ 5 pixels) ∼0.7 mm features at 2 m and ∼3.3 cm features at 100 m distance. Mastcam-Z shares significant heritage with the Mastcam instruments on the Mars Science Laboratory Curiosity rover. Each Mastcam-Z camera consists of zoom, focus, and filter wheel mechanisms and a 1648 × 1214 pixel charge-coupled device detector and electronics. The two Mastcam-Z cameras are mounted with a 24.4 cm stereo baseline and 2.3° total toe-in on a camera plate ∼2 m above the surface on the rover’s Remote Sensing Mast, which provides azimuth and elevation actuation. A separate digital electronics assembly inside the rover provides power, data processing and storage, and the interface to the rover computer. Primary and secondary Mastcam-Z calibration targets mounted on the rover top deck enable tactical reflectance calibration. Mastcam-Z multispectral, stereo, and panoramic images will be used to provide detailed morphology, topography, and geologic context along the rover’s traverse; constrain mineralogic, photometric, and physical properties of surface materials; monitor and characterize atmospheric and astronomical phenomena; and document the rover’s sample extraction and caching locations. Mastcam-Z images will also provide key engineering information to support sample selection and other rover driving and tool/instrument operations decisions.

Visible/short‐wave infrared spectral data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) show absorptions attributed to hematite at Vera Rubin ridge (VRR), a topographic feature on northwest Mt. Sharp. The goals of this study are to determine why absorptions caused by ferric iron are strongly visible from orbit at VRR and to improve interpretation of CRISM data throughout lower Mt. Sharp. These goals are achieved by analyzing coordinated CRISM and in situ spectral data along the Curiosity Mars rover's traverse. VRR bedrock within areas that have the deepest ferric absorptions in CRISM data also has the deepest ferric absorptions measured in situ. This suggests strong ferric absorptions are visible from orbit at VRR because of the unique spectral properties of VRR bedrock. Dust and mixing with basaltic sand additionally inhibit the ability to measure ferric absorptions in bedrock stratigraphically below VRR from orbit. There are two implications of these findings: (1) Ferric absorptions in CRISM data initially dismissed as noise could be real, and ferric phases are more widespread in lower Mt. Sharp than previously reported. (2) Patches with the deepest ferric absorptions in CRISM data are, like VRR, reflective of deeper absorptions in the bedrock. One model to explain this spectral variability is late‐stage diagenetic fluids that changed the grain size of ferric phases, deepening absorptions. Curiosity's experience highlights the strengths of using CRISM data for spectral absorptions and associated mineral detections and the caveats in using these data for geologic interpretations and strategic path planning tools., Key Points Areas on Vera Rubin ridge with deep ferric absorptions from orbit also have deep ferric absorptions in Curiosity spectral data setsFerric phases are more widespread on Mt. Sharp than originally reported. Diagenesis deepened ferric absorptions in several locationsCombining orbital and in situ observations enhances planetary exploration

The Mars Exploration Rovers (MER) Spirit and Opportunity have systematically used their Panoramic Camera (Pancam) instruments to estimate the Lambert albedo of the surface across their traverses in Gusev crater and Meridiani Planum. The 360˚ “albedo pan” observations acquired with Pancam's broadband (739 ± 338 nm) L1 filter allow for quantitative estimates of the overall surface albedo and measurements of individual surface features. As of November 2016, over nearly six Mars years of the MER mission, Spirit acquired 20 albedo pans (over 7,730 m of traverse distance) and Opportunity acquired 117 albedo pans (over 42,368 m of traverse distance). For Spirit, this comprises the rover's complete dataset. The ranges of Pancam-derived albedos at Gusev crater (0.14–0.24) and at Meridiani Planum (0.11–0.22, with one anomalously high measurement of 0.27 during the July 2007 global dust storm) are consistent with large-scale albedos of the sites as previously determined by the Viking Orbiter Infrared Thermal Mapper (IRTM), Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES), MGS Mars Orbiter Camera (MOC), Mars Odyssey Thermal Emission Imaging System (THEMIS), Mars Reconnaissance Orbiter (MRO) Context Camera (CTX) and MRO Mars Color Imager (MARCI) instruments. Through comparisons with atmospheric opacity measurements, temporal changes in Pancam albedo values provide insights into interactions between the Martian surface and atmosphere. Pancam observations are also used to “ground truth” measurements from orbit and validate radiometric calibrations, and we present comparisons across the full rover traverses to MOC, CTX, and MRO High Resolution Imaging Science Experiment (HiRISE) data. Albedo averages from the same regions observed by Pancam and all three orbital instruments generally agree to within ± 15%. The few instances found where cross-instrument comparisons exceed the estimated instrument calibration uncertainties can be attributed to atmospheric effects and/or differences in viewing geometries.

Diagenetic silica enrichment in fracture-associated halos that crosscut lacustrine and unconformably overlying aeolian sedimentary bedrock is observed on the lower north slope of Aeolis Mons in Gale crater, Mars. The diagenetic silica enrichment is colocated with detrital silica enrichment observed in the lacustrine bedrock yet extends into a considerably younger, unconformably draping aeolian sandstone, implying that diagenetic silica enrichment postdates the detrital silica enrichment. A causal connection between the detrital and diagenetic silica enrichment implies that water was present in the subsurface of Gale crater long after deposition of the lacustrine sediments and that it mobilized detrital amorphous silica and precipitated it along fractures in the overlying bedrock. Although absolute timing is uncertain, the observed diagenesis likely represents some of the most recent groundwater activity in Gale crater and suggests that the timescale of potential habitability extended considerably beyond the time that the lacustrine sediments of Aeolis Mons were deposited.

The Dynamic Albedo of Neutrons instrument aboard the Mars Science Laboratory rover, Curiosity, has been used to map a stratigraphically conformable layer of high-SiO (Formula presented.) material in Gale crater. Previous work has shown that this material contains tridymite, a high-temperature/low-pressure felsic mineral, interpreted to have a volcanic source rock. We describe several characteristics including orientation, extent, hydration, and geochemistry, consistent with a volcaniclastic material conformably deposited within a lacustrine mudstone succession. Relationships with widely dispersed alteration features and orbital detections of hydrated SiO (Formula presented.) suggest that this high-SiO (Formula presented.) layer extends at least 17 km laterally. Mineralogical abundances previously reported for this high-SiO (Formula presented.) material indicated that hydrous species were restricted to the amorphous (non-crystalline) fraction, which is dominated by SiO (Formula presented.). The low mean bulk hydration of this high-SiO (Formula presented.) layer (1.85 (Formula presented.) 0.13 wt.% water-equivalent hydrogen) is consistent with silicic glass in addition to opal-A and opal-CT. Persistent volcanic glass and tridymite in addition to opal in an ancient sedimentary unit indicates that the conversion to more ordered forms of crystalline SiO (Formula presented.) has not proceeded to completion and that this material has had only limited exposure to water since it originally erupted, despite having been transported in a fluviolacustrine system. Our results, including the conformable nature, large areal extent, and presence of volcanic glass, indicate that this high-SiO (Formula presented.) material is derived from the product of evolved magma on Mars. This is the first identification of a silicic volcaniclastic layer on another planet and has important implications for magma evolution mechanisms on single-plate planets.

The Mastcam-Z Camera is a stereoscopic, multispectral camera with zoom ca pability on NASA’s Mars-2020 Perseverance rover. The Mastcam-Z relies on a set of two deck-mounted radiometric calibration targets to validate camera performance and to provide an instantaneous estimate of local irradiance and allow conversion of image data to units of reflectance (R∗ or I/F) on a tactical timescale. Here, we describe the heritage, design, and optical characterization of these targets and discuss their use during rover operations. The Mastcam-Z primary calibration target inherits features of camera calibration targets on the Mars Exploration Rovers, Phoenix and Mars Science Laboratory missions. This target will be regularly imaged during flight to accompany multispectral observations of the martian surface. The primary target consists of a gold-plated aluminum base, eight strong hollow cylinder Sm2Co17 alloy permanent magnets mounted in the base, eight ceramic color and grayscale patches mounted over the magnets, four concentric, ceramic grayscale rings and a central aluminum shadow post (gnomon) painted with an IR-black paint. The magnets are expected to keep the central area of each patch relatively free of Martian aeolian dust. The Mastcam-Z secondary calibration target is a simple angled aluminum shelf carrying seven vertically mounted ceramic color and grayscale chips and seven identical, but hori zontally mounted ceramic chips. The secondary target is intended to augment and validate the calibration-related information derived from the primary target. The Mastcam-Z radio metric calibration targets are critically important to achieving Mastcam-Z science objectives for spectroscopy and photometric properties, Proyecto MINECO Retos de la Sociedad. Ref. ESP2017-87690-C3-1-R

Images from the Mars Science Laboratory (MSL) mission of lacustrine sedimentary rocks of Vera Rubin ridge on “Mt. Sharp” in Gale crater, Mars, have shown stark color variations from red to purple to gray. These color differences crosscut stratigraphy and are likely due to diagenetic alteration of the sediments after deposition. However, the chemistry and timing of these fluid interactions is unclear. Determining how diagenetic processes may have modified chemical and mineralogical signatures of ancient Martian environments is critical for understanding the past habitability of Mars and achieving the goals of the MSL mission. Here we use visible/near‐infrared spectra from Mastcam and ChemCam to determine the mineralogical origins of color variations in the ridge. Color variations are consistent with changes in spectral properties related to the crystallinity, grain size, and texture of hematite. Coarse‐grained gray hematite spectrally dominates in the gray patches and is present in the purple areas, while nanophase and fine‐grained red crystalline hematite are present and spectrally dominate in the red and purple areas. We hypothesize that these differences were caused by grain‐size coarsening of hematite by diagenetic fluids, as observed in terrestrial analogs. In this model, early primary reddening by oxidizing fluids near the surface was followed during or after burial by bleaching to form the gray patches, possibly with limited secondary reddening after exhumation. Diagenetic alteration may have diminished the preservation of biosignatures and changed the composition of the sediments, making it more difficult to interpret how conditions evolved in the paleolake over time., Key Points Vera Rubin ridge exhibits strong color differences that crosscut stratigraphy, consistent with postdepositional alteration (diagenesis)Color differences correspond to variations in spectral signatures of nanophase, fine‐grained, and coarse‐grained hematiteBased on terrestrial analogs, these variations can be explained by early oxidation and later coarsening of hematite by diagenetic fluids

The Mars Science Laboratory (MSL) Curiosity rover completed a detailed investigation at the Kimberley waypoint within Gale crater from sols 571-634 using its full science instrument payload. From orbital images examined early in the Curiosity mission, the Kimberley region had been identified as a high-priority science target based on its clear stratigraphic relationships in a layered sedimentary sequence that had been exposed by differential erosion. Observations of the stratigraphic sequence at the Kimberley made by Curiosity are consistent with deposition in a prograding, fluvio-deltaic system during the late Noachian to early Hesperian, prior to the existence of most of Mt. Sharp. Geochemical and mineralogic analyses suggest that sediment deposition likely took place under cold conditions with relatively low water-to-rock ratios. Based on elevated K_2O abundances throughout the Kimberley formation, an alkali feldspar protolith is likely one of several igneous sources from which the sediments were derived. After deposition, the rocks underwent multiple episodes of diagenetic alteration with different aqueous chemistries and redox conditions, as evidenced by the presence of Ca-sulfate veins, Mn-oxide fracture-fills, and erosion-resistant nodules. More recently, the Kimberley has been subject to significant aeolian abrasion and removal of sediments to create modern topography that slopes away from Mt. Sharp, a process that has continued to the present day.

This study provides the first systematic comparison of orbital facies maps with detailed ground-based geology observations from the Mars Science Laboratory (MSL) Curiosity rover to examine the validity of geologic interpretations derived from orbital image data. Orbital facies maps were constructed for the Darwin, Cooperstown, and Kimberley waypoints visited by the Curiosity rover using High Resolution Imaging Science Experiment (HiRISE) images. These maps, which represent the most detailed orbital analysis of these areas to date, were compared with rover image-based geologic maps and stratigraphic columns derived from Curiosity's Mast Camera (Mastcam) and Mars Hand Lens Imager (MAHLI). Results show that bedrock outcrops can generally be distinguished from unconsolidated surficial deposits in high-resolution orbital images and that orbital facies mapping can be used to recognize geologic contacts between well-exposed bedrock units. However, process-based interpretations derived from orbital image mapping are difficult to infer without known regional context or observable paleogeomorphic indicators, and layer-cake models of stratigraphy derived from orbital maps oversimplify depositional relationships as revealed from a rover perspective. This study also shows that fine-scale orbital image-based mapping of current and future Mars landing sites is essential for optimizing the efficiency and science return of rover surface operations.

K-Ar and noble gas surface exposure age measurements were carried out on the Windjana sandstone, Kimberley region, Gale Crater, Mars, by using the Sample Analysis at Mars instrument on the Curiosity rover. The sandstone is unusually rich in sanidine, as determined by CheMin X-ray diffraction, contributing to the high K_2O concentration of 3.09 ± 0.20 wt % measured by Alpha-Particle X-ray Spectrometer analysis. A sandstone aliquot heated to ~915°C yielded a K-Ar age of 627 ± 50 Ma. Reheating this aliquot yielded no additional Ar. A second aliquot heated in the same way yielded a much higher K-Ar age of 1710 ± 110 Ma. These data suggest incomplete Ar extraction from a rock with a K-Ar age older than 1710 Ma. Incomplete extraction at ~900°C is not surprising for a rock with a large fraction of K carried by Ar-retentive K-feldspar. Likely, variability in the exact temperature achieved by the sample from run to run, uncertainties in sample mass estimation, and possible mineral fractionation during transport and storage prior to analysis may contribute to these discrepant data. Cosmic ray exposure ages from ^3He and ^(21)Ne in the two aliquots are minimum values given the possibility of incomplete extraction. However, the general similarity between the ^3He (57 ± 49 and 18 ± 32 Ma, mean 30 Ma) and ^(21)Ne (2 ± 32 and 83 ± 24 Ma, mean 54 Ma) exposure ages provides no evidence for underextraction. The implied erosion rate at the Kimberley location is similar to that reported at the nearby Yellowknife Bay outcrop.

Multispectral visible and near infrared (VNIR) observations from the Mars Exploration Rover Pancam multispectral stereo camera systems are consistent with materials having been subjected to various aqueous processes. Ferric oxides in the form of hematite in the Burns and Grasberg formations of Meridiani Planum have been well characterized by Opportunity on the basis of strong 535 and 864 nm absorptions and positive 754–1009 nm and 934–1009 nm slopes. On the rim of Noachian-aged Endeavour crater, Opportunity has observed light-toned veins with high Ca and S, as determined by the rover’s Alpha Particle X-ray Spectrometer (APXS), and a negative 934–1009 nm slope in VNIR spectra extracted from Pancam data, indicative of a 1000 nm H2O overtone absorption. Together these observations indicate that the veins are composed of gypsum. Rocks overturned by Opportunity on the Murray Ridge portion of the Endeavour crater rim display dark- and light-toned coatings. The dark-toned coatings have a red, featureless slope that is consistent with the slope observed in laboratory spectra of high-valence manganese oxide minerals. Potential Mn oxide coatings may also be associated with some exposures of the Grasberg formation. APXS results for high Mg and S in the light-toned coatings of the Murray Ridge overturned rocks and a negative 934–1009 nm slope are consistent with hydrated Mg-sulfates. Opportunity has also observed spectral features in rocks that are consistent with orbital observations of Fe-smectites, as well as Al-smectites and possible hydrated silica in light-toned fracture-fill materials. The Spirit rover observed sulfate-rich light-toned soils exposed by the rover’s wheels. Several of these soil observations contained spectral features, such as a broad absorption centered near 800 nm, consistent with ferric sulfate minerals, a finding confirmed by the rover’s Mossbauer spectrometer. Spirit also excavated light-toned Si-rich soils. These soils have a flat near-infrared spectrum with a drop in reflectance from 934–1009 nm that is consistent with free water contained in voids or adsorbed onto the surface of the silica.

We have developed a refined geologic map and stratigraphy for lower Mt. Sharp using coordinated analyses of new spectral, thermophysical, and morphologic orbital data products. The Mt. Sharp group consists of seven relatively planar units delineated by differences in texture, mineralogy, and thermophysical properties. These units are (1-3) three spatially adjacent units in the Murray formation which contain a variety of secondary phases and are distinguishable by thermal inertia and albedo differences, (4) a phyllosilicate-bearing unit, (5) a hematite-capped ridge unit, (6) a unit associated with material having a strongly sloped spectral signature at visible-near infrared wavelengths, and (7) a layered sulfate unit. The Siccar Point group consists of the Stimson formation and two additional units that unconformably overlie the Mt. Sharp group. All Siccar Point group units are distinguished by higher thermal inertia values and record a period of substantial deposition and exhumation that followed the deposition and exhumation of the Mt. Sharp group. Several spatially extensive silica deposits associated with veins and fractures show late stage silica enrichment within lower Mt. Sharp was pervasive. At least two laterally extensive hematitic deposits are present at different stratigraphic intervals, and both are geometrically conformable with lower Mt. Sharp strata. The occurrence of hematite at multiple stratigraphic horizons suggests redox interfaces were widespread in space and/or in time, and future measurements by the Mars Science Laboratory Curiosity rover will provide further insights into the depositional settings of these and other mineral phases.

The Curiosity rover observed high Mn abundances (>25 wt % MnO) in fracture-filling materials that crosscut sandstones in the Kimberley region of Gale crater, Mars. The correlation between Mn and trace metal abundances plus the lack of correlation between Mn and elements such as S, Cl, and C, reveals that these deposits are Mn oxides rather than evaporites or other salts. On Earth, environments that concentrate Mn and deposit Mn minerals require water and highly oxidizing conditions; hence, these findings suggest that similar processes occurred on Mars. Based on the strong association between Mn-oxide deposition and evolving atmospheric dioxygen levels on Earth, the presence of these Mn phases on Mars suggests that there was more abundant molecular oxygen within the atmosphere and some groundwaters of ancient Mars than in the present day.

Key Points: • Mean K2O abundance in sedimentary rocks >5 times higher than that of the average Martian crust • Presence of alkali feldspars and K-phyllosilicates in basaltic sedimentary rocks along the traverse • The K-bearing minerals likely have a detrital origin

The ca. 2.45–2.22 Ga Turee Creek Group, Western Australia, contains carbonate-rich horizons that postdate earliest Proterozoic iron formations, bracket both Paleoproterozoic glaciogenic beds and the onset of the Great Oxidation Event (GOE), and predate ca. 2.2–2.05 Ga Lomagundi-Jatuli C-isotopic excursion(s). As such, Turee Creek carbonate strata provide an opportunity to characterize early Paleoproterozoic carbonate sedimentation and carbon cycle dynamics in the context of significant global change. Here, we report on the stratigraphy, sedimentology, petrology, carbon isotope chemostratigraphy, and stromatolite development for carbonate-rich successions within the pre-glacial part of the Kungarra Formation and the postglacial Kazput Formation. Kungarra carbonate units largely occur as laterally discontinuous beds within a thick, predominantly siliciclastic shelf deposit. While this succession contains thin microbialite horizons, most carbonates consist of patchy calcite overgrowths within a siliciclastic matrix. C-isotopic values show marked variation along a single horizon and even within hand samples, reflecting spatially and temporally variable mixing between dissolved inorganic carbon in seawater and isotopically light inorganic carbon generated via syn- and post-depositional remineralization of organic matter. In contrast, the Kazput carbonates consist of subtidal stromatolites, grainstones, and micrites deposited on a mixed carbonate–siliciclastic shelf. These carbonates exhibit moderate δ13C values of −2‰ to +1.5‰ and likely preserve a C-isotopic signature of seawater. Kazput carbonates, thus, provide some of the best available evidence that an interval of unexceptional C-isotopic values separates the Lomagundi-Jatuli C-isotopic excursion(s) from the initiation of the GOE as inferred from multiple sulfur isotopes (loss of mass independent fractionation). The Kazput Formation also contains unusual, m-scale stromatolitic buildups, which are composed of sub-mm laminae and discontinuous, convex upward lenticular precipitates up to a few mm in maximum thickness. Laminae, interpreted as microbial mat layers, contain quartz and clay minerals as well as calcite, whereas precipitate lenses consist of interlocking calcite anhedra, sometimes showing faint mm-scale banding. These cements formed either as infillings of primary voids formed by gas emission within penecontemporaneously lithified mats, or as local seafloor precipitates that formed on, or within, surface mats. It is possible that both mechanisms interacted to form the unique Kazput stromatolites. These microbialites speak to a distinctive interaction between life and environment early in the Paleoproterozoic Era.

Neonatal nutrition adequacy is often determined by infant weight gain. The aim of this review is to summarize what is currently known about neonatal body composition and the use of body composition as a measure for adequate neonatal nutrition. Unlike traditional anthropometric measures of height and weight, body composition measurements account for fat vs nonfat mass gains. This provides a more accurate picture of neonatal composition of weight gain. Providing adequate neonatal nutrition in the form of quantity and composition can be a challenge, especially when considering the delicate balance of providing adequate nutrition to preterm infants for catch-up growth. Monitoring weight gain as fat mass and nonfat mass while documenting dietary intake of fat, protein, and carbohydrate in formulas may help provide the medical community the tools to provide optimal nutrition for catch-up growth and for improved neurodevelopmental outcomes. Tracking body composition in term and preterm infants may also provide critical future information concerning the nutritional state of infants who go on to develop future disease such as obesity, hypertension, and hyperlipidemia as adolescents or adults.

The Mastcam CCD cameras on the Mars Science Laboratory Curiosity Rover each use an 8-position filter wheel in acquiring up to 1600 × 1200 pixel images. The filter set includes a broadband near-infrared cutoff filter for RGB Bayer imaging on each camera and 12 narrow-band geology filters distributed between the two cameras, spanning the wavelength range 445–1013 nm. This wavelength region includes the relatively broad charge-transfer and crystal-field absorption bands that are most commonly due to the presence of iron-bearing minerals. To identify such spectral features, sequences of images taken with identical pointings through different filters have been calibrated to relative reflectance using pre-flight calibration coefficients and in-flight measurements of an onboard calibration target. Within the first 1000 sols of the mission, Mastcam observed a spectrally diverse set of materials displaying absorption features consistent with the presence of iron-bearing silicate, iron oxide, and iron sulfate minerals. Dust-coated surfaces as well as soils possess a strong positive reflectance slope in the visible, consistent with the presence of nanophase iron oxides, which have long been considered the dominant visible-wavelength pigmenting agent in weathered martian surface materials. Fresh surfaces, such as tailings produced by the drill tool and the interiors of rocks broken by the rover wheels, are grayer in visible wavelengths than their reddish, dust-coated surfaces but possess reflectance spectra that vary considerably between sites. To understand the mineralogical basis of observed Mastcam reflectance spectra, we focus on a subset of the multispectral data set for which additional constraints on the composition of surface materials are available from other rover instruments, with an emphasis on sample sites for which detailed mineralogy is provided by the results of CheMin X-ray diffraction analyses. We also discuss the results of coordinated observations with the ChemCam instrument, whose passive mode of operation is capable of acquiring reflectance spectra over wavelengths that considerably overlap the range spanned by the Mastcam filter set (Johnson et al. 2016). Materials that show a distinct 430 nm band in ChemCam data also are observed to have a strong near-infrared absorption band in Mastcam spectral data, consistent with the presence of a ferric sulfate mineral. Long-distance Mastcam observations targeted toward the flanks of the Gale crater central mound are in agreement with both ChemCam spectra and orbital results, and in particular exhibit the spectral features of a crystalline hematite layer identified in MRO/CRISM data. Variations observed in Mastcam multi-filter images acquired to date have shown that multispectral observations can discriminate between compositionally different materials within Gale Crater and are in qualitative agreement with mineralogies from measured samples and orbital data.

Noachian-aged Jezero crater is the only known location on Mars where clear orbital detections of carbonates are found in close proximity to clear fluvio-lacustrine features indicating the past presence of a paleolake; however, it is unclear whether or not the carbonates in Jezero are related to the lacustrine activity. This distinction is critical for evaluating the astrobiological potential of the site, as lacustrine carbonates on Earth are capable of preserving biosignatures at scales that may be detectable by a landed mission like the Mars 2020 rover, which is planned to land in Jezero in February 2021. In this study, we conduct a detailed investigation of the mineralogical and morphological properties of geological units within Jezero crater in order to better constrain the origin of carbonates in the basin and their timing relative to fluvio-lacustrine activity. Using orbital visible/near-infrared hyperspectral images from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) along with high resolution imagery and digital elevation models, we identify a distinct carbonate-bearing unit, the “Marginal Carbonates,” located along the inner margin of the crater, near the largest inlet valley and the western delta. Based on their strong carbonate signatures, topographic properties, and location in the crater, we propose that this unit may preserve authigenic lacustrine carbonates, precipitated in the near-shore environment of the Jezero paleolake. Comparison to carbonate deposits from terrestrial closed basin lakes suggests that if the Marginal Carbonates are lacustrine in origin, they could preserve macro- and microscopic biosignatures in microbialite rocks like stromatolites, some of which would likely be detectable by Mars 2020. The Marginal Carbonates may represent just one phase of a complex fluvio-lacustrine history in Jezero crater, as we find that the spectral diversity of the fluvio-lacustrine deposits in the crater is consistent with a long-lived lake system cataloging the deposition and erosion of regional geologic units. Thus, Jezero crater may contain a unique record of the evolution of surface environments, climates, and habitability on early Mars.

The morphologies of wind-formed features on Mars provide diagnostic information about ancient and modern surface winds. Aeolian erosional features include decimeter-scale ventifacts and kilometer-scale yardangs, but intermediate-scale erosional features are less well-understood. Understanding aeolian erosion may be critical to identifying ancient martian biosignatures. Cosmogenic radiation destroys complex organic molecules during prolonged exposure at the martian surface, but outcrops freshly re-exposed by aeolian erosion provide potential sites where biosignatures could have been protected and made recently available for sampling. Wind-driven scarp retreat has been cited as the cause for young exposure ages measured in Gale crater. Upcoming exploration by the Mars 2020 rover will focus on Jezero crater, another location of extensive aeolian erosion and meter-scale scarps. This work is motivated by the hypothesis that retreating scarps on Mars may prefer orientations that reflect the direction of erosive winds. We mapped scarps in Jezero and Gale craters and compared their orientation distributions with local wind regimes interpreted from other aeolian indicators. No strong correlation between wind direction and scarp orientation was identified. The near-random distribution of scarp orientations suggests that in the locations studied the dominant processes controlling scarp orientation are either processes that do not prefer an orientation (e.g., impact or thermal fracturing processes), or that turbulent flow structures form at the scale of scarp topography and obscure the regional-scale signals of erosion with scarp-scale eddies and flow deflection.

The Opportunity rover's exploration of the portion of the rim of Endeavour crater known as Cape York included examination of the sulfate-bearing Grasberg formation and the Matijevic Hill region. Multispectral visible and near-infrared (VNIR) Pancam observations were used to characterize reflectance properties of rock units. Using spectral end-member detection and classification approaches including a principal components/n-dimensional visualization, automatic sequential maximum angle convex cone method, and classification through hierarchical clustering, six main spectral classes of rock surfaces were identified: light-toned veins, Grasberg fm., the smectite-bearing Matijevic formation, the hematitic “blueberry” spherules, resistant spherules within the Matijevic fm. dubbed “newberries,” and the Shoemaker formation impact breccia. Some of these could be divided into spectral subclasses. There were three types of veins: veins in the bench unit of Cape York, thinner veins in the Matijevic fm., and boxwork pattern-forming veins. The bench unit veins had higher 535 nm band depths than the other two vein subclasses and a steeper 934 to 1009 nm slope. The Grasberg fm. has VNIR spectral features that are interpreted to indicate higher fractions of red hematite than in the sulfate-bearing Burns Fm. The Matijevic fm. includes both light-toned, fine-grained matrix, and dark-toned veneers. The latter has a weak near-infrared absorption band centered near 950 nm consistent with nontronite. Observations of Rock Abrasion Tool brushed and ground newberries indicated that cuttings from the RAT grind had a longer wavelength reflectance maximum and deeper 535 nm band depth, consistent with more oxidized materials. Greater oxidation of cementing materials in the newberries is consistent with a diagenetic concretion origin.

The Curiosity rover has analyzed abundant light-toned fracture-fill material within the Yellowknife Bay sedimentary deposits. The ChemCam instrument, coupled with Mastcam and ChemCam/Remote Micro Imager images, was able to demonstrate that these fracture fills consist of calcium sulfate veins, many of which appear to be hydrated at a level expected for gypsum and bassanite. Anhydrite is locally present and is found in a location characterized by a nodular texture. An intricate assemblage of veins crosses the sediments, which were likely formed by precipitation from fluids circulating through fractures. The presence of veins throughout the entire similar to 5 m thick Yellowknife Bay sediments suggests that this process occurred well after sedimentation and cementation/lithification of those sediments. The sulfur-rich fluids may have originated in previously precipitated sulfate-rich layers, either before the deposition of the Sheepbed mudstones or from unrelated units such as the sulfates at the base of Mount Sharp. The occurrence of these veins after the episodes of deposition of fluvial sediments at the surface suggests persistent aqueous activity in relatively nonacidic conditions.

The Sheepbed member of the Yellowknife Bay formation in Gale crater contains millimeter-scale nodules that represent an array of morphologies unlike those previously observed in sedimentary deposits on Mars. Three types of nodules have been identified in the Sheepbed member in order of decreasing abundance: solid nodules, hollow nodules, and filled nodules, a variant of hollow nodules whose voids have been filled with sulfate minerals. This study uses Mast Camera (Mastcam) and Mars Hand Lens Imager (MAHLI) images from the Mars Science Laboratory Curiosity rover to determine the size, shape, and spatial distribution of the Sheepbed nodules. The Alpha Particle X-Ray Spectrometer (APXS) and ChemCam instruments provide geochemical data to help interpret nodule origins. Based on their physical characteristics, spatial distribution, and composition, the nodules are interpreted as concretions formed during early diagenesis. Several hypotheses are considered for hollow nodule formation including origins as primary or secondary voids. The occurrence of concretions interpreted in the Sheepbed mudstone and in several other sedimentary sequences on Mars suggests that active groundwater systems play an important role in the diagenesis of Martian sedimentary rocks. When concretions are formed during early diagenetic cementation, as interpreted for the Sheepbed nodules, they have the potential to create a taphonomic window favorable for the preservation of Martian organics.

Spring and evaporite deposits are considered two of the most promising environments for past habitability on Mars and preservation of biosignatures. Manitoba, Canada hosts the East German Creek (EGC) hypersaline spring complex, and the post impact evaporite gypsum beds of the Lake St. Martin (LSM) impact. The EGC complex has microbial mats, sediments, algae and biofabrics, while endolithic communities are ubiquitous in the LSM gypsum beds. These communities are spectrally detectable based largely on the presence of a chlorophyll absorption band at 670 nm; however, the robustness of this feature under Martian surface conditions was unclear. Biological and biology-bearing samples from EGC and LSM were exposed to conditions similar to the surface of present day Mars (high UV flux, 100 mbar, anoxic, CO2 rich) for up to 44 days, and preservation of the 670 nm chlorophyll feature and chlorophyll red-edge was observed. A decrease in band depth of the 670 nm band ranging from ∼16 to 80% resulted, with correlations seen in the degree of preservation and the spatial proximity of samples to the spring mound and mineral shielding effects. The spectra were deconvolved to Mars Exploration Rover (MER) Pancam and Mars Science Laboratory (MSL) Mastcam science filter bandpasses to investigate the detectability of the 670 nm feature and to compare with common mineral features. The red-edge and 670 nm feature associated with chlorophyll can be distinguished from the spectra of minerals with features below ∼1000 nm, such as hematite and jarosite. However, distinguishing goethite from samples with the chlorophyll feature is more problematic, and quantitative interpretation using band depth data makes little distinction between iron oxyhydroxides and the 670 nm chlorophyll feature. The chlorophyll spectral feature is observable in both Pancam and Mastcam, and we propose that of the proposed EXOMARS Pancam filters, the PHYLL filter is best suited for its detection.

From its arrival at the portion of the rim of Endeavour crater known informally as Cape York, the Mars Exploration Rover Opportunity has made numerous visible and near infrared (VNIR) multispectral observations of rock surfaces. This paper describes multispectral observations from Opportunity’s arrival at Cape York to its winter-over location at Greeley Haven. Averages of pixels from the Pancam’s left and right eyes were joined to form 11 point spectra from numerous observations and were examined via a number of techniques. These included principal components analysis, a sequential maximum angle convex cone approach, examination of spectral parameters, and a hierarchical clustering approach. The end result of these analyses was the determination of six primary spectral (PS) classes describing spectrally unique materials observed on Cape York. These classes consisted of a “standard” outcrop spectrum that was observed on the clasts and matrix comprising the upper unit of the Shoemaker formation, a class representing rock surfaces exposed around Odyssey crater and typified by the rocks of the Tisdale series, pebbles occurring in and weathered out of the upper unit of the Shoemaker formation that appear red in 1009, 904, 754 nm color composites, patches on Tisdale rocks exhibiting a 864 nm band minimum that were spectrally anomalous in root mean square error images derived from spectral mixture analyses, clasts with a high 904 nm band depth occurring in the Greeley Haven location, and gypsum veins typified by the vein Homestake. Comparisons of three of these classes that had well defined band minima between 800 and 1009 nm with spectral library spectra of ferrous silicates and ferric oxide, oxyhydroxide and ferric sulfate minerals indicated tentative matches of the “red” pebbles with orthopyroxenes, of the spectrally anomalous 864 nm band minimum material with hematite or ferric sulfates, and of the high 904 nm band depth material with an orthopyroxene–clinopyroxene mixture. The spectral properties of rock surfaces on Cape York are distinct from those of Burns Formation outcrops observed on the Meridiani Plains. The Cape York outcrop is Noachian in age and study of these materials provides insight into less acidic environmental conditions extant before the formation of the Burns Formation.

Several commercially available color standards exist, generated by a variety of manufacturers including LabSphere, Lucideon, and Avian Technologies. Previous work has characterized the photometric properties of LabSphere Spectralon targets. Here, we measure the visible and shortwave infrared (VSWIR; 0.4 to 2.5 μm) reflectance at multiple angles and determine the photometric properties of materials manufactured by Lucideon and Avian Technologies for potential use as calibration target materials for the Mars 2020 Mastcam-Z instrument. The Lucideon black, gray 33, green, and cyan samples are found to be significantly forward scattering. The yellow, red, and gray 70 samples are found to be weakly forward scattering. The Avian Technologies AluWhite98 sample was found to be weakly backward scattering. We characterize the absorptions observable and note the occurrence of wavelength-dependent photometric properties. The reflectance and photometric data collected and released here enable the use of these color standards for calibration of data from Mastcam-Z and other Mars-2020 rover instruments as well as provide key information for many other imaging and spectroscopy applications that require the calibration of data from multiple lighting or viewing geometries.

We present an updated survey of Mercury’s putative polar ice deposits, based on high-resolution (1.5-km) imaging with the upgraded Arecibo S-band radar during 1999–2005. The north pole has now been imaged over a full range of longitude aspects, making it possible to distinguish ice-free areas from radar-shadowed areas and thus better map the distribution of radar-bright ice. The new imagery of the south pole, though derived from only a single pair of dates in 2005, improves on the pre-upgrade Arecibo imagery and reveals many additional ice features. Some medium-size craters located within 3° of the north pole show near-complete ice coverage over their floors, central peaks, and southern interior rim walls and little or no ice on their northern rim walls, while one large (90 km) crater at 85°N shows a sharp ice-cutoff line running across its central floor. All of this is consistent with the estimated polar extent of permanent shading from direct sunlight. Some craters show ice in regions that, though permanently shaded, should be too warm to maintain unprotected surface ice owing to indirect heating by reflected and reradiated sunlight. However, the ice distribution in these craters is in good agreement with models invoking insulation by a thin dust mantle. Comparisons with Goldstone X-band radar imagery indicate a wavelength dependence that could be consistent with such a dust mantle. More than a dozen small ice features have been found at latitudes between 67° and 75°. All of this low-latitude ice is probably sheltered in or under steep pole-facing crater rim walls, although, since most is located in the Mariner-unimaged hemisphere, confirmation must await imaging by the MESSENGER orbiter. These low-latitude features are concentrated toward the “cold longitudes,” possibly indicating a thermal segregation effect governed by indirect heating. The radar imagery places the corrected locations of the north and south poles at 7°W, 88.35°N and 90°W, 88.7°S, respectively, on the original Mariner-based maps.

The Mars Exploration Rover (MER) Spirit has discovered surprisingly high concentrations of amorphous silica in soil and nodular outcrops in the Inner Basin of the Columbia Hills. In Pancam multispectral observations, we find that an absorption feature at the longest Pancam wavelength (1009 nm) appears to be characteristic of these silica-rich materials; however, spectral analyses of amorphous silica suggest that the ∼1009 nm spectral feature is not a direct reflection of their silica-rich nature. Based on comparisons with spectral databases, we hypothesize that the presence of H 2 O or OH, either free (as water ice), adsorbed or bound in a mineral structure, is responsible for the spectral feature observed by Pancam. The Gertrude Weise soil, which is nearly pure opaline silica, may have adsorbed water cold-trapped on mineral grains. The origin of the ∼1009 nm Pancam feature observed in the silica-rich nodular outcrops may result from the presence of additional hydrated minerals (specific sulfates, halides, chlorides, sodium silicates, carbonates or borates). Using the ∼1009 nm feature with other spectral parameters as a “hydration signature” we have mapped the occurrence of hydrated materials along the extent of Spirit’s traverse across the Columbia Hills from West Spur to Home Plate (sols 155–1696). We have also mapped this hydration signature across large panoramic images to understand the regional distribution of materials that are spectrally similar to the silica-rich soil and nodular outcrops. Our results suggest that hydrated materials are common in the Columbia Hills.