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2. EMIMBF4–GBL binary electrolyte working at −70 °C and 3.7 V for a high performance graphene-based capacitor

Author

Jin Ying, Xue Chi, Baohua Guo, Tian Jiarui, Miao Yonghua, Zhang Gang, Xie Qing, Chaojie Cui, and Weizhong Qian

Subjects
Materials science, Renewable Energy, Sustainability and the Environment, Graphene, Analytical chemistry, 02 engineering and technology, General Chemistry, Electrolyte, Atmospheric temperature range, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Capacitance, 0104 chemical sciences, law.invention, chemistry.chemical_compound, chemistry, law, Propylene carbonate, Electrode, Melting point, Ionic conductivity, General Materials Science, 0210 nano-technology
Abstract

Developing an ionic-liquid (IL) type electrolyte with both high voltage window and wide temperature window, especially the low temperature range, is crucial to increase the energy density of the associated electrical double layer capacitors. We proposed the addition of γ-butyrolactone (GBL) in EMIMBF4 to form a binary electrolyte. The melting point (∼15 °C) of EMIMBF4 disappeared and the glass transition point decreased from −95 °C (for pure EMIMBF4) to −126 °C for the binary electrolyte. The binary electrolyte also exhibited improved ionic conductivity (26 and 0.31 mS cm−1 at 20 and −70 °C, respectively) and allowed an electrode of mesoporous graphene to exhibit a capacitance of 131 F g−1 and energy density of 61 W h kg−1 at −70 °C and 3.7 V, the highest values reported so far. NMR and ATR-IR characterization validated the strong interaction between GBL and EMIMBF4 for breaking the ion pairs of the latter but without forming the solvated ions, as in the system of EMMIBF4 with propylene carbonate.

Published
2018
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4. EMIMBF4–GBL binary electrolyte working at −70 °C and 3.7 V for a high performance graphene-based capacitor.

Author

Tian, Jiarui, Cui, Chaojie, Xie, Qing, Qian, Weizhong, Xue, Chi, Miao, Yonghua, Jin, Ying, Zhang, Gang, and Guo, Baohua

Abstract

Developing an ionic-liquid (IL) type electrolyte with both high voltage window and wide temperature window, especially the low temperature range, is crucial to increase the energy density of the associated electrical double layer capacitors. We proposed the addition of γ-butyrolactone (GBL) in EMIMBF4 to form a binary electrolyte. The melting point (∼15 °C) of EMIMBF4 disappeared and the glass transition point decreased from −95 °C (for pure EMIMBF4) to −126 °C for the binary electrolyte. The binary electrolyte also exhibited improved ionic conductivity (26 and 0.31 mS cm−1 at 20 and −70 °C, respectively) and allowed an electrode of mesoporous graphene to exhibit a capacitance of 131 F g−1 and energy density of 61 W h kg−1 at −70 °C and 3.7 V, the highest values reported so far. NMR and ATR-IR characterization validated the strong interaction between GBL and EMIMBF4 for breaking the ion pairs of the latter but without forming the solvated ions, as in the system of EMMIBF4 with propylene carbonate. [ABSTRACT FROM AUTHOR]

Published
2018
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