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Poly(3-alkylthiophene)s are known to self-assemble into well-ordered supramolecular assemblies. The organization influences the optical and electronic properties of these polymers. One way to induc...

The supramolecular organization of star-shaped polythiophenes was investigated in a solvent/nonsolvent system and upon cooling. Both systems yield entirely different supramolecular aggregates. Clas...

In the past decade, the structural and electronic properties of monolayer-protected metal clusters, which can be produced size-selected in macroscopic amounts, have received a lot of attention. Their great potential for optical applications has been identified. In the high intensity regime, monolayer-protected metal clusters show pronounced nonlinear absorption and refraction. Naturally, these phenomena are wavelength-dependent, however, such dependence is largely unexplored. Here, we quantify the wavelength-dependent non-linear optical absorption and refraction cross sections of atomically precise Au

An understanding of macroscopic vortex-induced chirality can provide insights into the origin of the homochirality of life. While circular dichroism measurements in stirred solutions are useful for the analysis of chiral supramolecular structures induced by vortex motion, there are no reports on the application of other spectroscopic methods. To obtain a deeper understanding of macroscopic vortex-induced chirality, it is essential to develop novel

A simple and cost-effective method based on multi-photon microscopy is presented for the preliminary screening of the general morphology, size range and heterogeneity of Ir(III) nano-aggregate formulations. ispartof: RSC Advances vol:11 issue:2 pages:657-661 ispartof: location:England status: published

Solubilized poly(3-alkylthiophene)s are known to self-assemble into well-ordered supramolecular aggregates upon lowering the solvent quality. This supramolecular organization largely determines the optical and electronic properties of these polymers. However, despite numerous studies the exact mechanism and kinetics of the aggregation process and the role of external stimuli are still poorly understood. Classical characterization techniques such as electronic spectroscopy, dynamic light scattering, and diffraction-based techniques have not been able to provide a full understanding. Here we use second-harmonic scattering (SHS) and third-harmonic scattering (THS) techniques to investigate this supramolecular aggregation mechanism. Our results indicate that the actual supramolecular aggregation is preceded by the formation of structured polymer-solvent clusters consistent with a nonclassical crystallization pathway. The optoelectronic and photophysical properties of conjugated polymers are strongly influenced by the formation of supramolecular aggregates. Here the authors use second- and third-harmonic scattering techniques to elucidate the mechanism and kinetics of the aggregation process and the role of external stimuli in the supramolecular organization.

Organometal halide perovskites show promising features for cost-effective application in photovoltaics. The material instability remains a major obstacle to broad application because of the poorly understood degradation pathways. Here, we apply simultaneous luminescence and electron microscopy on perovskites for the first time, allowing us to monitor in situ morphology evolution and optical properties upon perovskite degradation. Interestingly, morphology, photoluminescence (PL), and cathodoluminescence of perovskite samples evolve differently upon degradation driven by electron beam (e-beam) or by light. A transversal electric current generated by a scanning electron beam leads to dramatic changes in PL and tunes the energy band gaps continuously alongside film thinning. In contrast, light-induced degradation results in material decomposition to scattered particles and shows little PL spectral shifts. The differences in degradation can be ascribed to different electric currents that drive ion migration. Moreover, solution-processed perovskite cuboids show heterogeneity in stability which is likely related to crystallinity and morphology. Our results reveal the essential role of ion migration in perovskite degradation and provide potential avenues to rationally enhance the stability of perovskite materials by reducing ion migration while improving morphology and crystallinity. It is worth noting that even moderate e-beam currents (86 pA) and acceleration voltages (10 kV) readily induce significant perovskite degradation and alter their optical properties. Therefore, attention has to be paid while characterizing such materials using scanning electron microscopy or transmission electron microscopy techniques. ispartof: Journal of Physical Chemistry Letters vol:7 issue:3 pages:561-566 ispartof: location:United States status: published