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Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $\mu$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$\sigma$ upper limit of 1-6 parts per million, depending on model assumptions)., Comment: 61 pages, 13 figures, 4 tables. This preprint has been submitted to and accepted in principle for publication in Nature Astronomy without significant changes

We present a comprehensive analysis of the Hubble Space Telescope observations of the atmosphere of WASP-121 b, a ultra-hot Jupiter. After reducing the transit, eclipse, and phase-curve observations with a uniform methodology and addressing the biases from instrument systematics, sophisticated atmospheric retrievals are used to extract robust constraints on the thermal structure, chemistry, and cloud properties of the atmosphere. Our analysis shows that the observations are consistent with a strong thermal inversion beginning at ~0.1 bar on the dayside, solar to subsolar metallicity Z (i.e., -0.77 < log(Z) < 0.05), and super-solar C/O ratio (i.e., 0.59 < C/O < 0.87). More importantly, utilizing the high signal-to-noise ratio and repeated observations of the planet, we identify the following unambiguous time-varying signals in the data: i) a shift of the putative hotspot offset between the two phase-curves and ii) varying spectral signatures in the transits and eclipses. By simulating the global dynamics of WASP-121 b atmosphere at high-resolution, we show that the identified signals are consistent with quasi-periodic weather patterns, hence atmospheric variability, with signatures at the level probed by the observations (~5% to ~10%) that change on a timescale of ~5 planet days; in the simulations, the weather patterns arise from the formation and movement of storms and fronts, causing hot (as well as cold) patches of atmosphere to deform, separate, and mix in time., Comment: Accepted for publication in ApJS. 43 pages, 31 figures, 2 animations (available online at the journal)

Over the last decade, precise exoplanet transmission spectroscopy has revealed the atmospheres of dozens of exoplanets, driven largely by observatories like the Hubble Space Telescope. One major discovery has been the ubiquity of atmospheric aerosols, often blocking access to exoplanet chemical inventories. Tentative trends have been identified, showing that the clarity of planetary atmospheres may depend on equilibrium temperature. Previous work has often grouped dissimilar planets together in order to increase the statistical power of any trends, but it remains unclear from observed transmission spectra whether these planets exhibit the same atmospheric physics and chemistry. We present a re-analysis of a smaller, more physically similar sample of 15 exo-Neptune transmission spectra across a wide range of temperatures (200-1000 K). Using condensation cloud and hydrocarbon haze models, we find that the exo-Neptune population is best described by low cloud sedimentation efficiency ($\mathrm{f_{sed}}\sim0.1$) and high metallicity ($100\times$ Solar). There is an intrinsic scatter of $\sim0.5$ scale height, perhaps evidence of stochasticity in these planets' formation processes. Observers should expect significant attenuation in transmission spectra of Neptune-size exoplanets, up to 6 scale heights for equilibrium temperatures between 500 and 800 K. With JWST's greater wavelength sensitivity, colder (<500 K) planets should be high-priority targets given their clearer atmospheres, and the need to distinguish between the "super-puffs" and more typical gas-dominated planets., Comment: Published in ApJL. 11 pages, 3 figures, 4 tables

Recent work on the characterization of small exoplanets has allowed us to accumulate growing evidence that the sub-Neptunes with radii greater than $\sim2.5\,R_\oplus$ often host H$_2$/He-dominated atmospheres both from measurements of their low bulk densities and direct detections of their low mean-molecular-mass atmospheres. However, the smaller sub-Neptunes in the 1.5-2.2 R$_\oplus$ size regime are much less understood, and often have bulk densities that can be explained either by the H$_2$/He-rich scenario, or by a volatile-dominated composition known as the "water world" scenario. Here, we report the detection of water vapor in the transmission spectrum of the $1.96\pm0.08$ R$_\oplus$ sub-Neptune GJ9827d obtained with the Hubble Space Telescope. We observed 11 HST/WFC3 transits of GJ9827d and find an absorption feature at 1.4$\mu$m in its transit spectrum, which is best explained (at 3.39$\sigma$) by the presence of water in GJ9827d's atmosphere. We further show that this feature cannot be caused by unnoculted star spots during the transits by combining an analysis of the K2 photometry and transit light-source effect retrievals. We reveal that the water absorption feature can be similarly well explained by a small amount of water vapor in a cloudy H$_2$/He atmosphere, or by a water vapor envelope on GJ9827d. Given that recent studies have inferred an important mass-loss rate ($>0.5\,$M$_\oplus$/Gyr) for GJ9827d making it unlikely to retain a H-dominated envelope, our findings highlight GJ9827d as a promising water world candidate that could host a volatile-dominated atmosphere. This water detection also makes GJ9827d the smallest exoplanet with an atmospheric molecular detection to date., Comment: Published in ApJL, 11 pages, 6 figures

We present ground and space-based photometric observations of TOI-270 (L231-32), a system of three transiting planets consisting of one super-Earth and two sub-Neptunes discovered by TESS around a bright (K-mag=8.25) M3V dwarf. The planets orbit near low-order mean-motion resonances (5:3 and 2:1), and are thus expected to exhibit large transit timing variations (TTVs). Following an extensive observing campaign using 8 different observatories between 2018 and 2020, we now report a clear detection of TTVs for planets c and d, with amplitudes of $\sim$10 minutes and a super-period of $\sim$3 years, as well as significantly refined estimates of the radii and mean orbital periods of all three planets. Dynamical modeling of the TTVs alone puts strong constraints on the mass ratio of planets c and d and on their eccentricities. When incorporating recently published constraints from radial velocity observations, we obtain masses of $M_{\mathrm{b}}=1.48\pm0.18\,M_\oplus$, $M_{c}=6.20\pm0.31\,M_\oplus$ and $M_{\mathrm{d}}=4.20\pm0.16\,M_\oplus$ for planets b, c and d, respectively. We also detect small, but significant eccentricities for all three planets : $e_\mathrm{b} =0.0167\pm0.0084$, $e_{c} =0.0044\pm0.0006$ and $e_{d} = 0.0066\pm0.0020$. Our findings imply an Earth-like rocky composition for the inner planet, and Earth-like cores with an additional He/H$_2$O atmosphere for the outer two. TOI-270 is now one of the best-constrained systems of small transiting planets, and it remains an excellent target for atmospheric characterization., Comment: 22 pages, 7 figures

JWST has ushered in an era of unprecedented ability to characterize exoplanetary atmospheres. While there are over 5,000 confirmed planets, more than 4,000 TESS planet candidates are still unconfirmed and many of the best planets for atmospheric characterization may remain to be identified. We present a sample of TESS planets and planet candidates that we identify as "best-in-class" for transmission and emission spectroscopy with JWST. These targets are sorted into bins across equilibrium temperature $T_{\mathrm{eq}}$ and planetary radius $R{_\mathrm{p}}$ and are ranked by transmission and emission spectroscopy metric (TSM and ESM, respectively) within each bin. In forming our target sample, we perform cuts for expected signal size and stellar brightness, to remove sub-optimal targets for JWST. Of the 194 targets in the resulting sample, 103 are unconfirmed TESS planet candidates, also known as TESS Objects of Interest (TOIs). We perform vetting and statistical validation analyses on these 103 targets to determine which are likely planets and which are likely false positives, incorporating ground-based follow-up from the TESS Follow-up Observation Program (TFOP) to aid the vetting and validation process. We statistically validate 23 TOIs, marginally validate 33 TOIs to varying levels of confidence, deem 29 TOIs likely false positives, and leave the dispositions for 4 TOIs as inconclusive. 14 of the 103 TOIs were confirmed independently over the course of our analysis. We provide our final best-in-class sample as a community resource for future JWST proposals and observations. We intend for this work to motivate formal confirmation and mass measurements of each validated planet and encourage more detailed analysis of individual targets by the community., Comment: Submitted to AJ. Machine-readable versions of Tables 2 and 3 are included. 40 pages, 7 figures, 3 tables

One of the most well-studied exoplanets to date, HD 189733 b, stands out as an archetypal hot Jupiter with many observations and theoretical models aimed at characterizing its atmosphere, interior, host star, and environment. We report here on the results of an extensive campaign to observe atmospheric escape signatures in HD 189733 b using the Hubble Space Telescope and its unique ultraviolet capabilities. We have found a tentative, but repeatable in-transit absorption of singly-ionized carbon (C II, $5.2\% \pm 1.4\%$) in the epoch of June-July/2017, as well as a neutral hydrogen (H I) absorption consistent with previous observations. We model the hydrodynamic outflow of HD 189733 b using an isothermal Parker wind formulation to interpret the observations of escaping C and O nuclei at the altitudes probed by our observations. Our forward models indicate that the outflow of HD 189733 b is mostly neutral within an altitude of $\sim 2$ R$_\mathrm{p}$ and singly ionized beyond that point. The measured in-transit absorption of C II at 133.57 nm is consistent with an escape rate of $\sim 1.1 \times 10^{11}$ g$\,$s$^{-1}$, assuming solar C abundance and outflow temperature of $12\,100$ K. Although we find a marginal neutral oxygen (O I) in-transit absorption, our models predict an in-transit depth that is only comparable to the size of measurement uncertainties. A comparison between the observed Lyman-$\alpha$ transit depths and hydrodynamics models suggests that the exosphere of this planet interacts with a stellar wind at least one order of magnitude stronger than solar., Comment: 22 pages, 14 figures, 5 tables. Accepted for publication in the Astronomical Journal

Carbon monoxide (CO) is predicted to be the dominant carbon-bearing molecule in giant planet atmospheres, and, along with water, is important for discerning the oxygen and therefore carbon-to-oxygen ratio of these planets. The fundamental absorption mode of CO has a broad double-branched structure composed of many individual absorption lines from 4.3 to 5.1 $\mathrm{\mu}$m, which can now be spectroscopically measured with JWST. Here we present a technique for detecting the rotational sub-band structure of CO at medium resolution with the NIRSpec G395H instrument. We use a single transit observation of the hot Jupiter WASP-39b from the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) program at the native resolution of the instrument ($R \,{\sim} 2700$) to resolve the CO absorption structure. We robustly detect absorption by CO, with an increase in transit depth of 264 $\pm$ 68 ppm, in agreement with the predicted CO contribution from the best-fit model at low resolution. This detection confirms our theoretical expectations that CO is the dominant carbon-bearing molecule in WASP-39b's atmosphere, and further supports the conclusions of low C/O and super-solar metallicities presented in the JTEC ERS papers for WASP-39b., Comment: 11 pages, 5 figures, accepted for publication in ApJL

We present the first exoplanet phase curve measurement made with the JWST NIRSpec instrument, highlighting the exceptional stability of this newly-commissioned observatory for exoplanet climate studies. The target, WASP-121b, is an ultrahot Jupiter with an orbital period of 30.6 hr. We analyze two broadband light curves generated for the NRS1 and NRS2 detectors, covering wavelength ranges of 2.70-3.72 micron and 3.82-5.15 micron, respectively. Both light curves exhibit minimal systematics, with approximately linear drifts in the baseline flux level of 30 ppm/hr (NRS1) and 10 ppm/hr (NRS2). Assuming a simple brightness map for the planet described by a low-order spherical harmonic dipole, our light curve fits suggest that the phase curve peaks coincide with orbital phases $3.36 \pm 0.11$ deg (NRS1) and $2.66 \pm 0.12$ deg (NRS2) prior to mid-eclipse. This is consistent with the strongest dayside emission emanating from eastward of the substellar point. We measure planet-to-star emission ratios of $3,924 \pm 7$ ppm (NRS1) and $4,924 \pm 9$ ppm (NRS2) for the dayside hemisphere, and $136 \pm 8$ ppm (NRS1) and $630 \pm 10$ ppm (NRS2) for the nightside hemisphere. The latter nightside emission ratios translate to planetary brightness temperatures of $926 \pm 12$ K (NRS1) and $1,122 \pm 10$ K (NRS2), which are low enough for a wide range of refractory condensates to form, including enstatite and forsterite. A nightside cloud deck may be blocking emission from deeper, hotter layers of the atmosphere, potentially helping to explain why cloud-free 3D general circulation model simulations systematically over-predict the nightside emission for WASP-121b., Comment: Accepted for publication in Astrophysical Journal Letters on December 29, 2022

TOI-270d is a temperate sub-Neptune discovered by the Transiting Exoplanet Survey Satellite (TESS) around a bright (J=9.1mag) M3V host star. With an approximate radius of 2RE and equilibrium temperature of 350K, TOI-270d is one of the most promising small exoplanets for atmospheric characterisation using transit spectroscopy. Here we present a primary transit observation of TOI-270d made with the Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3) spectrograph across the 1.126-1.644 micron wavelength range, and a 95% credible upper limit of $8.2 \times 10^{-14}$ erg s$^{-1}$ cm$^{-2}$ A$^{-1}$ arcsec$^{-2}$ for the stellar Ly-alpha emission obtained using the Space Telescope Imaging Spectrograph (STIS). The transmission spectrum derived from the TESS and WFC3 data provides evidence for molecular absorption by a hydrogen-rich atmosphere at 4-sigma significance relative to a featureless spectrum. The strongest evidence for any individual absorber is obtained for H2O, which is favoured at 3-sigma significance. When retrieving on the WFC3 data alone and allowing for the possibility of a heterogeneous stellar brightness profile, the detection significance of H2O is reduced to 2.8-sigma. Further observations are therefore required to robustly determine the atmospheric composition of TOI-270d and assess the impact of stellar heterogeneity. If confirmed, our findings would make TOI-270d one of the smallest and coolest exoplanets to date with detected atmospheric spectral features., Comment: Accepted for publication in AAS journals on November 22, 2022 (received July 5, 2022; revised October 30, 2022)

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 \mu$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator., Comment: 48 pages, 12 figures, 2 tables. Under review at Nature

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $\mu$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $\mu$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$\sigma$) and G395H (4.5$\sigma$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations., Comment: 39 pages, 14 figures, accepted to be published in Nature

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $\mu$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $\mu$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere., Comment: 35 pages, 13 figures, 3 tables, Nature, accepted

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range., Comment: 44 pages, 11 figures, 3 tables. Resubmitted after revision to Nature

The magnetosphere of an exoplanet has yet to be unambiguously detected. Investigations of star-planet interaction and neutral atomic hydrogen absorption during transit to detect magnetic fields in hot Jupiters have been inconclusive, and interpretations of the transit absorption non-unique. In contrast, ionized species escaping a magnetized exoplanet, particularly from the polar caps, should populate the magnetosphere, allowing detection of different regions from the plasmasphere to the extended magnetotail, and characterization of the magnetic field producing them. Here, we report ultraviolet observations of HAT-P-11b, a low-mass (0.08 MJ) exoplanet showing strong, phase-extended transit absorption of neutral hydrogen (maximum and tail transit depths of 32 \pm 4%, 27 \pm 4%) and singly ionized carbon (15 \pm 4%, 12.5 \pm 4%). We show that the atmosphere should have less than six times the solar metallicity (at 200 bars), and the exoplanet must also have an extended magnetotail (1.8-3.1 AU). The HAT-P-11b equatorial magnetic field strength should be about 1-5 Gauss. Our panchromatic approach using ionized species to simultaneously derive metallicity and magnetic field strength can now constrain interior and dynamo models of exoplanets, with implications for formation and evolution scenarios., Comment: 68 pages, 12 figures. Published in Nature Astronomy on December 16 2021. Main draft and Supplementary information are included in a single file. Full-text access to a view-only version of the paper via : https://rdcu.be/cDlYv

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 {\mu}m in wavelength and show a prominent CO2 absorption feature at 4.3 {\mu}m (26{\sigma} significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 {\mu}m that is not reproduced by these models., Comment: 27 pages, 6 figures, Accepted for publication in Nature, data and models available at https://doi.10.5281/zenodo.6959427

The increasing numbers of rocky, terrestrial exoplanets known to orbit nearby stars (especially M dwarfs) has drawn increased attention to the possibility of studying these planets' surface properties, and atmospheric compositions & escape histories. Here we report the detection of the secondary eclipse of the terrestrial exoplanet GJ1252b using the Spitzer Space Telescope's IRAC2 4.5 micron channel. We measure an eclipse depth of 149(+25/-32) ppm, corresponding to a day-side brightness temperature of 1410(+91/-125) K and consistent with the prediction for no atmosphere. Comparing our measurement to atmospheric models indicates that GJ1252b has a surface pressure of <10 bar, substantially less than Venus. Assuming energy-limited escape, even a 100 bar atmosphere would be lost in <1 Myr, far shorter than estimated age of 3.9+/-0.4 Gyr. The expected mass loss could be overcome by mantle outgassing, but only if the mantle's carbon content were >7% by mass - over two orders of magnitude greater than that found in Earth. We therefore conclude that GJ1252b has no significant atmosphere. Model spectra with granitoid or feldspathic surface composition, but with no atmosphere, are disfavored at >2 sigma. The eclipse occurs just +1.4(+2.8/-1.0) min after orbital phase 0.5, indicating e cos omega=+0.0025(+0.0049/-0.0018), consistent with a circular orbit. Tidal heating is therefore likely to be negligible to GJ1252b's global energy budget. Finally, we also analyze additional, unpublished TESS transit photometry of GJ1252b which improves the precision of the transit ephemeris by a factor of ten, provides a more precise planetary radius of 1.180+/-0.078 R_E, and rules out any transit timing variations with amplitudes <1 min., Comment: ApJL in press. 16 pages, 12 figures, 10 eclipses, 1 bandpass. Models will be available at journal website

We present new analysis of infrared transmission spectroscopy of the cloud-free hot-Saturn WASP-96b performed with the Hubble and Spitzer Space Telescopes (HST and Spitzer). The WASP-96b spectrum exhibits the absorption feature from water in excellent agreement with synthetic spectra computed assuming a cloud-free atmosphere. The HST-Spitzer spectrum is coupled with Very Large Telescope (VLT) optical transmission spectroscopy which reveals the full pressure-broadened profile of the sodium absorption feature and enables the derivation of absolute abundances. We confirm and correct for a spectral offset of $\Delta R_{{\rm p}}/R_{\ast}=(-4.29^{+0.31}_{-0.37})\,\times10^{-3}$ of the VLT data relative to the HST-Spitzer spectrum. This offset can be explained by the assumed radius for the common-mode correction of the VLT spectra, which is a well-known feature of ground-based transmission spectroscopy. We find evidence for a lack of chromospheric and photometric activity of the host star which, therefore, make a negligible contribution to the offset. We measure abundances for Na and O that are consistent with solar to supersolar, with abundances relative to solar values of $21^{+27}_{-14}$ and $7^{+11}_{-4}$, respectively. We complement the transmission spectrum with new thermal emission constraints from Spitzer observations at 3.6 and $4.5\mu$m, which are best explained by the spectrum of an atmosphere with a temperature decreasing with altitude. A fit to the spectrum assuming an isothermal blackbody atmosphere constrains the dayside temperature to be $T_{\rm{p}}$=$1545$$\pm$$90$K., Comment: Accepted for publication in MNRAS

We present a uniform analysis of transit observations from the Hubble Space Telescope and Spitzer Space Telescope of two warm gas giants orbiting K-type stars - WASP-29b and WASP-80b. The transmission spectra, which span 0.4-5.0 $\mu$m, are interpreted using a suite of chemical equilibrium PLATON atmospheric retrievals. Both planets show evidence of significant aerosol opacity along the day-night terminator. The spectrum of WASP-29b is flat throughout the visible and near-infrared, suggesting the presence of condensate clouds extending to low pressures. The lack of spectral features hinders our ability to constrain the atmospheric metallicity and C/O ratio. In contrast, WASP-80b shows a discernible, albeit muted H$_2$O absorption feature at 1.4 $\mu$m, as well as a steep optical spectral slope that is caused by fine-particle aerosols and/or contamination from unocculted spots on the variable host star. WASP-80b joins the small number of gas-giant exoplanets that show evidence for enhanced atmospheric metallicity: the transmission spectrum is consistent with metallicities ranging from $\sim$30-100 times solar in the case of cloudy limbs to a few hundred times solar in the cloud-free scenario. In addition to the detection of water, we infer the presence of CO$_2$ in the atmosphere of WASP-80b based on the enhanced transit depth in the Spitzer 4.5 $\mu$m bandpass. From a complementary analysis of Spitzer secondary eclipses, we find that the dayside emission from WASP-29b and WASP-80b is consistent with brightness temperatures of $937 \pm 48$ and $851 \pm 14$ K, respectively, indicating relatively weak day-night heat transport and low Bond albedo., Comment: Published in AJ, 26 pages, 13 figures. Updated to reflect proof changes

We present the most complete emission spectrum for inflated hot Jupiter HAT-P-41b combining new HST WFC/G141 spectrum from the Hubble Panchromatic Comparative Exoplanet Treasury (PanCET) program with archival Spitzer eclipse observations. We found a near blackbody-like emission spectrum which is best fitted with an isothermal temperature-pressure (TP) profile that agrees well with the dayside heat redistribution scenario assuming zero Bond albedo. The non-inverted TP profile is consistent with the non-detection of NUV/optical absorbers in the transit spectra. We do not find any evidence for significant H$^-$ opacity nor a metal-rich atmosphere. HAT-P-41b is an ideal target that sits in the transitioning parameter space between hot and ultra-hot Jupiters, and future JWST observations will help us to better constrain the thermal structure and chemical composition., Comment: Accepted for publication in AJ

The temperature profile of a planetary atmosphere is a key diagnostic of radiative and dynamical processes governing the absorption, redistribution, and emission of energy. Observations have revealed dayside stratospheres that either cool or warm with altitude for a small number of gas giant exoplanets, while other dayside stratospheres are consistent with constant temperatures. Here we report spectroscopic phase curve measurements for the gas giant WASP-121b, which constrain stratospheric temperatures throughout the diurnal cycle. Variations measured for a water vapour spectral feature reveal a temperature profile that transitions from warming with altitude on the dayside hemisphere to cooling with altitude on the nightside hemisphere. The data are well explained by models assuming chemical equilibrium, with water molecules thermally dissociating at low pressures on the dayside and recombining on the nightside. Nightside temperatures are low enough for perovskite (CaTiO3) to condense, which could deplete titanium from the gas phase and explain recent non-detections at the day-night terminator. Nightside temperatures are also consistent with the condensation of refractory species such as magnesium, iron, and vanadium. Detections of these metals at the day-night terminator suggest, however, that if they do form nightside clouds, cold trapping does not efficiently remove them from the upper atmosphere. Horizontal winds and vertical mixing could keep these refractory condensates aloft in the upper atmosphere of the nightside hemisphere until they are recirculated to the hotter dayside hemisphere and vaporised., Comment: Published in Nature Astronomy (publisher version is Open Access)

We report observations of the recently discovered warm Neptune TOI-674 b (5.25 \rearth{}, 23.6 \mearth{}) with the Hubble Space Telescope's Wide Field Camera 3 instrument. TOI-674 b is in the Neptune desert, an observed paucity of Neptune-size exoplanets at short orbital periods. Planets in the desert are thought to have complex evolutionary histories due to photoevaporative mass loss or orbital migration, making identifying the constituents of their atmospheres critical to understanding their origins. We obtained near-infrared transmission spectroscopy of the planet's atmosphere with the G141 grism. After extracting, detrending, and fitting the spectral lightcurves to measure the planet's transmission spectrum, we used the petitRADTRANS atmospheric spectral synthesis code to perform retrievals on the planet's atmosphere to identify which absorbers are present. These results show moderate evidence for increased absorption at 1.4 $\mu$m due to water vapor at 2.9$\sigma$ (Bayes factor = 15.8), as well as weak evidence for the presence of clouds at 2.2$\sigma$ (Bayes factor = 4.0). TOI-674 b is a strong candidate for further study to refine the water abundance, which is poorly constrained by our data. We also incorporated new TESS short-cadence optical photometry, as well as Spitzer/IRAC data, and re-fit the transit parameters for the planet. We find the planet to have the following transit parameters: $R_p/R_* = 0.1135\pm0.0006$, $T_0 = 2458544.523792\pm0.000452$ BJD, and $P = 1.977198\pm0.00007$ d. These measurements refine the planet radius estimate and improve the orbital ephemerides for future transit spectroscopy observations of this highly intriguing warm Neptune., Comment: Accepted to the Astronomical Journal. 20 pages, 17 figures

It is widely anticipated that the James Webb Space Telescope (JWST) will be transformative for exoplanet studies. It has even been suggested that JWST could provide the first opportunity to search for biosignatures in an alien atmosphere using transmission spectroscopy. This claim is investigated, specifically for the proposed anoxic biosignature pair CH4-CO2. The most favourable known target is adopted (TRAPPIST-1e), with an assumed atmospheric composition similar to the Archean Earth. Compared to previous studies, a more systematic investigation of the effect that cloud/haze-layers have on the detectability of CH4 and CO2 is performed. In addition to a clear atmosphere scenario, cloud/haze-layers are considered at eight pressure levels between 600mbar and 1mbar. These pressures cover a plausible range for H2O cloud and photochemical haze, based on observations of solar system atmospheres and physical models of tidally-locked planets such as TRAPPIST-1e, although no assumptions regarding the cloud/haze-layer composition are made in this study. For the clear atmosphere and cloud/haze-layer pressures of 600-100mbar, strong (5-sigma) detections of both CH4 and CO2 are found to be possible with approximately 5-10 co-added transits measured using the Near Infrared Spectrograph (NIRSpec) prism, assuming a dry stratosphere. However, approximately 30 co-added transits would be required to achieve the same result if a cloud/haze-layer is present at 10mbar. A cloud/haze-layer at 1mbar would prevent the detection of either molecule with the NIRSpec prism for observing programs up to 50 transits (>200 hours of JWST time), the maximum considered., Comment: 13 pages. Accepted in MNRAS

Here we present a thermal emission spectrum of WASP-79b, obtained via Hubble Space Telescope Wide Field Camera 3 G141 observations as part of the PanCET program. As we did not observe the ingress or egress of WASP-79b's secondary eclipse, we consider two scenarios: a fixed mid-eclipse time based on the expected occurrence time, and a mid-eclipse time as a free parameter. In both scenarios, we can measure thermal emission from WASP-79b from 1.1 to 1.7 $\mu$m at 2.4$\sigma$ confidence consistent with a 1900 K brightness temperature for the planet. We combine our observations with Spitzer dayside photometry (3.6 and 4.5 $\mu$m) and compare these observations to a grid of atmospheric forward models that span a range of metallicities, carbon-to-oxygen ratios, and recirculation factors. Given the strength of the planetary emission and the precision of our measurements, we found a wide range of forward models to be consistent with our data. The best-match equilibrium model suggests that WASP-79b's dayside has a solar metallicity and carbon-to-oxygen ratio, alongside a recirculation factor of 0.75. Models including significant H- opacity provide the best match to WASP-79b's emission spectrum near 1.58 $\mu$m. However, models featuring high-temperature cloud species-formed via vigorous vertical mixing and low sedimentation efficiencies-with little day-to-night energy transport also match WASP-79b's emission spectrum. Given the broad range of equilibrium chemistry, disequilibrium chemistry, and cloudy atmospheric models consistent with our observations of WASP-79b's dayside emission, further observations will be necessary to constrain WASP-79b's dayside atmospheric properties., Comment: 13 pages, 8 figures. Accepted for publication in AJ

Ultra-hot Jupiters (UHJs) present excellent targets for atmospheric characterisation. Their hot dayside temperatures (T $\gtrsim$ 2200 K) strongly suppress the formation of condensates, leading to clear and highly-inflated atmospheres extremely conducive to transmission spectroscopy. Recent studies using optical high-resolution spectra have discovered a plethora of neutral and ionised atomic species in UHJs, placing constraints on their atmospheric structure and composition. Our recent work has presented a search for molecular features and detection of Fe I in the UHJ WASP-121b using VLT/UVES transmission spectroscopy. Here, we present a systematic search for atomic species in its atmosphere using cross-correlation methods. In a single transit, we uncover potential signals of 17 atomic species which we investigate further, categorising 5 as strong detections, 3 as tentative detections, and 9 as weak signals worthy of further exploration. We confirm previous detections of Cr I, V I, Ca I, K I and exospheric H I and Ca II made with HARPS and ESPRESSO, and independently re-recover our previous detection of Fe I at 8.8 $\sigma$ using both the blue and red arms of the UVES data. We also add a novel detection of Sc II at 4.2 $\sigma$. Our results further demonstrate the richness of UHJs for optical high-resolution spectroscopy., Comment: 20 pages, 8 figures, 3 tables. Accepted for publication in MNRAS

We present ground-based optical transmission spectroscopy of the low-density hot Jupiter WASP-88b covering the wavelength range 4413-8333 {\AA} with the FORS2 spectrograph on the Very Large Telescope. The FORS2 white light curves exhibit a significant time-correlated noise which we model using a Gaussian Process and remove as a wavelength-independent component from the spectroscopic light curves. We analyse complementary photometric observations from the Transiting Exoplanet Survey Satellite and refine the system properties and ephemeris. We find a featureless transmission spectrum with increased absorption towards shorter wavelengths. We perform an atmospheric retrieval analysis with the AURA code, finding tentative evidence for haze in the upper atmospheric layers and a lower likelihood for a dense cloud deck. Whilst our retrieval analysis results point toward clouds and hazes, further evidence is needed to definitively reject a clear-sky scenario., Comment: 19 pages, 12 figures, 3 tables, Accepted for publication in MNRAS

The search for signs of life through the detection of exoplanet atmosphere biosignature gases is gaining momentum. Yet, only a handful of rocky exoplanet atmospheres are suitable for observation with planned next-generation telescopes. To broaden prospects, we describe the possibilities for an aerial, liquid water cloud-based biosphere in the atmospheres of sub Neptune-sized temperate exoplanets, those receiving Earth-like irradiation from their host stars. One such planet is known (K2-18b) and other candidates are being followed up. Sub Neptunes are common and easier to study observationally than rocky exoplanets because of their larger sizes, lower densities, and extended atmospheres or envelopes. Yet, sub Neptunes lack any solid surface as we know it, so it is worthwhile considering whether their atmospheres can support an aerial biosphere. We review, synthesize, and build upon existing research. Passive microbial-like life particles must persist aloft in a region with liquid water clouds for long enough to metabolize, reproduce, and spread before downward transport to lower altitudes that may be too hot for life of any kind to survive. Dynamical studies are needed to flesh out quantitative details of life particle residence times. A sub Neptune would need to be a part of a planetary system with an unstable asteroid belt in order for meteoritic material to provide nutrients, though life would also need to efficiently reuse and recycle metals. The origin of life may be the most severe limiting challenge. Regardless of the uncertainties, we can keep an open mind to the search for biosignature gases as a part of general observational studies of sub Neptune exoplanets., Comment: Published in Universe: https://www.mdpi.com/2218-1997/7/6/172

We present a ground-based optical transmission spectrum for the warm Saturn-mass exoplanet WASP-110b from two transit observations made with the FOcal Reducer and Spectrograph (FORS2) on the Very Large Telescope (VLT). The spectrum covers the wavelength range from 4000 to 8333\AA, which is binned in 46 transit depths measured to an averaged precision of 220 parts per million (ppm) over an averaged 80\AA~bin for a Vmag=12.8 star. The measured transit depths are unaffected by a dilution from a close A-type field dwarf, which was fully resolved. The overall main characteristic of the transmission spectrum is an increasing radius with wavelength and a lack of the theoretically predicted pressure-broadened sodium and potassium absorption features for a cloud-free atmosphere. We analyze archival high-resolution optical spectroscopy and find evidence for low to moderate activity of the host star, which we take into account in the atmospheric retrieval analysis. Using the AURA retrieval code, we find that the observed transmission spectrum can be best explained by a combination of unocculted stellar faculae and a cloud deck. Transmission spectra of cloud-free and hazy atmospheres are rejected at a high confidence. With a possible cloud deck at its terminator, WASP-110b joins the increasing population of irradiated hot-Jupiter exoplanets with cloudy atmospheres observed in transmission., Comment: Accepted for publication in The Astronomical Journal

We present 2,241 exoplanet candidates identified with data from the Transiting Exoplanet Survey Satellite (TESS) during its two-year prime mission. We list these candidates in the TESS Objects of Interest (TOI) Catalog, which includes both new planet candidates found by TESS and previously-known planets recovered by TESS observations. We describe the process used to identify TOIs and investigate the characteristics of the new planet candidates, and discuss some notable TESS planet discoveries. The TOI Catalog includes an unprecedented number of small planet candidates around nearby bright stars, which are well-suited for detailed follow-up observations. The TESS data products for the Prime Mission (Sectors 1-26), including the TOI Catalog, light curves, full-frame images, and target pixel files, are publicly available on the Mikulski Archive for Space Telescopes., Comment: 39 pages, 16 figures. The Prime Mission TOI Catalog is included in the ancillary data as a CSV. For the most up-to-date catalog, refer to https://tess.mit.edu/toi-releases/

We present ground-based, spectroscopic observations of two transits of the ultra-hot Jupiter WASP-121b covering the wavelength range $\approx$500 - 950 nm using Gemini/GMOS. We use a Gaussian process framework to model instrumental systematics in the light curves, and also demonstrate the use of the more generalised Student's-T process to verify our results. We find that our measured transmission spectrum, whilst showing overall agreement, is slightly discrepant with results obtained using HST/STIS, particularly for wavelengths shortward of $\approx$650 nm. In contrast to the STIS results, we find evidence for an increasing blueward slope and little evidence for absorption from either TiO or VO in our retrieval, in agreement with a number of recent studies performed at high-resolution. We suggest that this might point to some other absorbers, particularly some combination of recently detected atomic metals, in addition to scattering by hazes, being responsible for the excess optical absorption and observed vertical thermal inversion. Our results are also broadly consistent with previous ground-based photometry and 3D GCM predictions, however, these assumed different chemistry to our retrievals. In addition, we show that the GMOS observations are repeatable over short periods (days), similarly to the HST/STIS observations. Their difference over longer periods (months) could well be the result of temporal variability in the atmospheric properties (i.e. weather) as predicted by theoretical models of ultra-hot Jupiters; however, more mundane explanations such as instrumental systematics and stellar activity cannot be fully ruled out, and we encourage future observations to explore this possibility., Comment: 17 pages, 10 Figures. Accepted for publication in MNRAS

Exoplanets with cloud-free, haze-free atmospheres at the pressures probed by transmission spectroscopy represent a valuable opportunity for detailed atmospheric characterization and precise chemical abundance constraints. We present the first optical to infrared (0.3-5 microns) transmission spectrum of the hot Jupiter WASP-62b, measured with Hubble/STIS and Spitzer/IRAC. The spectrum is characterized by a 5.1-sigma detection of Na I absorption at 0.59 microns, in which the pressure-broadened wings of the Na D-lines are observed from space for the first time. A spectral feature at 0.4 microns is tentatively attributed to SiH at 2.1-sigma confidence. Our retrieval analyses are consistent with a cloud-free atmosphere without significant contamination from stellar heterogeneities. We simulate James Webb Space Telescope (JWST) observations, for a combination of instrument modes, to assess the atmospheric characterization potential of WASP-62b. We demonstrate that JWST can conclusively detect Na, H2O, FeH, and SiH within the scope of its Early Release Science (ERS) program. As the only transiting giant planet currently known in the JWST Continuous Viewing Zone, WASP-62b could prove a benchmark giant exoplanet for detailed atmospheric characterization in the James Webb era., Comment: 14 pages, 5 figures, accepted for publication in ApJL

We present a transmission spectrum for the warm (500-600K) sub-Neptune HD3167c obtained using the Hubble Space Telescope Wide Field Camera 3 infrared spectrograph. We combine these data, which span the 1.125-1.643 micron wavelength range, with broadband transit measurements made using Kepler/K2 (0.6-0.9 micron) and Spitzer/IRAC (4-5 micron). We find evidence for absorption by at least one of H2O, HCN, CO2, and CH4 (Bayes factor 7.4; 2.5-sigma significance), although the data precision does not allow us to unambiguously discriminate between these molecules. The transmission spectrum rules out cloud-free hydrogen-dominated atmospheres with metallicities <100x solar at >5.8-sigma confidence. In contrast, good agreement with the data is obtained for cloud-free models assuming metallicities >700x solar. However, for retrieval analyses that include the effect of clouds, a much broader range of metallicities (including subsolar) is consistent with the data, due to the degeneracy with cloud-top pressure. Self-consistent chemistry models that account for photochemistry and vertical mixing are presented for the atmosphere of HD3167c. The predictions of these models are broadly consistent with our abundance constraints, although this is primarily due to the large uncertainties on the latter. Interior structure models suggest the core mass fraction is >40%, independent of a rock or water core composition, and independent of atmospheric envelope metallicity up to 1000x solar. We also report abundance measurements for fifteen elements in the host star, showing that it has a very nearly solar composition., Comment: Accepted for publication in the Astronomical Journal

Phase curve measurements provide a global view of the composition, thermal structure, and dynamics of exoplanet atmospheres. Although most of the dozens of phase curve measurements made to date are of large, massive hot Jupiters, there is considerable interest in probing the atmospheres of the smaller planets that are the more typical end product of planet formation. One such planet is the ultra-hot Neptune LTT 9779b, a rare denizen of the Neptune desert. A companion paper presents the planet's secondary eclipses and day-side thermal emission spectrum; in this work we describe the planet's optical and infrared phase curves, characterized using Spitzer and TESS photometry. We detect LTT 9779b's thermal phase variations at 4.5um, finding a phase amplitude of 358+/-106 ppm and a longitude of peak emission -10 deg +/- 21 deg east of the substellar point. Combined with our secondary eclipse observations, these phase curve measurements imply a 4.5um day-side brightness temperature of 1800+/-120 K, a night-side brightness temperature of 700+/-430 K (<1350 K at 2 sigma confidence), and a day-night brightness temperature contrast of 1110+/-460 K. We compare our data to the predictions of 3D GCMs and to similar observations of hot Jupiters experiencing similar levels of stellar irradiation. Though not conclusive, our measurement of its small 4.5um phase offset, the relatively large amplitude of the phase variation, and the qualitative differences between our target's day-side emission spectrum and those of hot Jupiters of similar temperatures all suggest a super-Solar atmospheric metallicity for LTT 9779b, as might be expected given its size and mass. Finally, we provide a refined ephemeris (P=0.79207022+/-0.00000069 d, T0=2458783.51636+/-0.00027, BJD_TDB) to enable efficient scheduling of future observations to further characterize the atmosphere of this intriguing planet. (abstract abridged), Comment: 27 pages, 14 pages, 1 data table. ApJL in press. Companion paper to Dragomir et al. 2020

Non-rocky sub-jovian exoplanets in high irradiation environments are rare. LTT 9979b, also known as TESS Object of Interest (TOI) 193.01, is one of the few such planets discovered to date, and the first example of an ultra-hot Neptune. The planet's bulk density indicates that it has a substantial atmosphere, so to investigate its atmospheric composition and shed further light on its origin, we obtained {\it Spitzer} IRAC secondary eclipse observations of LTT 9979b at 3.6 and 4.5 $\mu$m. We combined the {\it Spitzer} observations with a measurement of the secondary eclipse in the {\it TESS} bandpass. The resulting secondary eclipse spectrum strongly prefers a model that includes CO absorption over a blackbody spectrum, incidentally making LTT 9979b the first {\it TESS} exoplanet (and the first ultra-hot Neptune) with evidence of a spectral feature in its atmosphere. We did not find evidence of a thermal inversion, at odds with expectations based on the atmospheres of similarly-irradiated hot Jupiters. We also report a nominal dayside brightness temperature of 2305 $\pm$ 141 K (based on the 3.6 $\mu$m secondary eclipse measurement), and we constrained the planet's orbital eccentricity to $e < 0.01$ at the 99.7 \% confidence level. Together with our analysis of LTT 9979b's thermal phase curves reported in a companion paper, our results set the stage for similar investigations of a larger sample of exoplanets discovered in the hot Neptune desert, investigations which are key to uncovering the origin of this population., Comment: 12 pages, 5 figures; accepted to ApJ Letters

For solar-system objects, ultraviolet spectroscopy has been critical in identifying sources for stratospheric heating and measuring the abundances of a variety of hydrocarbon and sulfur-bearing species, produced via photochemical mechanisms, as well as oxygen and ozone. To date, less than 20 exoplanets have been probed in this critical wavelength range (0.2-0.4 um). Here we use data from Hubble's newly implemented WFC3 UVIS G280 grism to probe the atmosphere of the hot Jupiter HAT-P-41b in the ultraviolet through optical in combination with observations at infrared wavelengths. We analyze and interpret HAT-P-41b's 0.2-5.0 um transmission spectrum using a broad range of methodologies including multiple treatments of data systematics as well as comparisons with atmospheric forward, cloud microphysical, and multiple atmospheric retrieval models. Although some analysis and interpretation methods favor the presence of clouds or potentially a combination of Na, VO, AlO, and CrH to explain the ultraviolet through optical portions of HAT-P-41b's transmission spectrum, we find that the presence of a significant H- opacity provides the most robust explanation. We obtain a constraint for the abundance of H-, log(H-) = -8.65 +/- 0.62 in HAT-P-41b's atmosphere, which is several orders of magnitude larger than predictions from equilibrium chemistry for a 1700 - 1950 K hot Jupiter. We show that a combination of photochemical and collisional processes on hot hydrogen-dominated exoplanets can readily supply the necessary amount of H- and suggest that such processes are at work in HAT-P-41b and many other hot Jupiter atmospheres., Comment: 17 pages, 7 figures. Published in ApJL (October 8th 2020)

We present a publicly available library of model atmospheres with radiative-convective equilibrium Pressure-Temperature ($P$-$T$) profiles fully consistent with equilibrium chemical abundances, and the corresponding emission and transmission spectrum with R$\sim$5000 at 0.2 $\mu$m decreasing to R$\sim$35 at 30 $\mu$m, for 89 hot Jupiter exoplanets, for four re-circulation factors, six metallicities and six C/O ratios. We find the choice of condensation process (local/rainout) alters the $P$-$T$ profile and thereby the spectrum substantially, potentially detectable by JWST. We find H$^-$ opacity can contribute to form a strong temperature inversion in ultra-hot Jupiters for C/O ratios $\geq$ 1 and can make transmission spectra features flat in the optical, alongside altering the entire emission spectra. We highlight how adopting different model choices such as thermal ionisation, opacities, line-wing profiles and the methodology of varying the C/O ratio, effects the $P$-$T$ structure and the spectrum. We show the role of Fe opacity to form primary/secondary inversion in the atmosphere. We use WASP-17b and WASP-121b as test cases to demonstrate the effect of grid parameters across their full range, while highlighting some important findings, concerning the overall atmospheric structure, chemical transition regimes and their observables. Finally, we apply this library to the current transmission and emission spectra observations of WASP-121b, which shows H$_2$O and tentative evidence for VO at the limb, and H$_2$O emission feature indicative of inversion on the dayside, with very low energy redistribution, thereby demonstrating the applicability of library for planning and interpreting observations of transmission and emission spectrum., Comment: 26 pages, 19 figures in the main paper. 13 pages, 6 figures, 3 tables in the supplementary material attached with the main paper here. Accepted for Publication in MNRAS. Full grid of model P-T profiles, chemical abundances, transmission and emission spectra, contribution functions are available here, https://drive.google.com/drive/folders/1zCCe6HICuK2nLgnYJFal7W4lyunjU4JE

We present a transmission spectrum for the Neptune-size exoplanet HD 106315 c from optical to infrared wavelengths based on transit observations from the Hubble Space Telescope/Wide Field Camera 3, K2, and Spitzer. The spectrum shows tentative evidence for a water absorption feature in the $1.1 - 1.7\mu$m wavelength range with a small amplitude of 30 ppm (corresponding to just $0.8 \pm 0.04$ atmospheric scale heights). Based on an atmospheric retrieval analysis, the presence of water vapor is tentatively favored with a Bayes factor of 1.7 - 2.6 (depending on prior assumptions). The spectrum is most consistent with either enhanced metallicity, high altitude condensates, or both. Cloud-free solar composition atmospheres are ruled out at $>5\sigma$ confidence. We compare the spectrum to grids of cloudy and hazy forward models and find that the spectrum is fit well by models with moderate cloud lofting or haze formation efficiency, over a wide range of metallicities ($1 - 100\times$ solar). We combine the constraints on the envelope composition with an interior structure model and estimate that the core mass fraction is $\gtrsim0.3$. With a bulk composition reminiscent of that of Neptune and an orbital distance of 0.15 AU, HD 106315 c hints that planets may form out of broadly similar material and arrive at vastly different orbits later in their evolution., Comment: Submitted to AAS journals; 19 pages, 12 figures

We present a 0.3-5 micron transmission spectrum of the hot Jupiter HAT-P-32Ab observed with the Space Telescope Imaging Spectrograph (STIS) and Wide Field Camera 3 (WFC3) instruments mounted on the Hubble Space Telescope, combined with Spitzer Infrared Array Camera (IRAC) photometry. The spectrum is composed of 51 spectrophotometric bins with widths ranging between 150 and 400 \AA, measured to a median precision of 215 ppm. Comparisons of the observed transmission spectrum to a grid of 1D radiative-convective equilibrium models indicate the presence of clouds/hazes, consistent with previous transit observations and secondary eclipse measurements. To provide more robust constraints on the planet's atmospheric properties, we perform the first full optical to infrared retrieval analysis for this planet. The retrieved spectrum is consistent with a limb temperature of 1248$\pm$92 K, a thick cloud deck, enhanced Rayleigh scattering, and $\sim$10x solar H2O abundance. We find log($Z/Z_{\odot}$) = 2.41$_{-0.07}^{+0.06}$, in agreement with the mass-metallicity relation derived for the Solar System., Comment: 30 pages, 13 figures, accepted for publication in AJ

We present four new secondary eclipse observations for the ultrahot Jupiter WASP-121b acquired using the Hubble Space Telescope Wide Field Camera 3. The eclipse depth is measured to a median precision of 60ppm across 28 spectroscopic channels spanning the 1.12-1.64 micron wavelength range. This is a considerable improvement to the 90ppm precision we achieved previously for a single eclipse observation using the same observing setup. Combining these data with those reported at other wavelengths, a blackbody spectrum for WASP-121b is ruled out at >6-sigma confidence and we confirm the interpretation of previous retrieval analyses that found the data is best explained by a dayside thermal inversion. The updated spectrum clearly resolves the water emission band at 1.3-1.6 micron, with higher signal-to-noise than before. It also fails to reproduce a bump in the spectrum at 1.25 micron derived from the first eclipse observation, which had tentatively been attributed to VO emission. We conclude the latter was either a statistical fluctuation or a systematic artefact specific to the first eclipse dataset., Comment: Accepted in MNRAS

Recent years have seen increasing interest in the characterization of sub-Neptune sized planets because of their prevalence in the Galaxy, contrasted with their absence in our solar system. HD 97658 is one of the brightest stars hosting a planet of this kind, and we present the transmission spectrum of this planet by combining four HST transits, twelve Spitzer/IRAC transits, and eight MOST transits of this system. Our transmission spectrum has higher signal to noise ratio than that from previous works, and the result suggests that the slight increase in transit depth from wavelength 1.1 to 1.7 microns reported in previous works on the transmission spectrum of this planet is likely systematic. Nonetheless, our atmospheric modeling results are not conclusive as no model provides an excellent match to our data. Nonetheless we find that atmospheres with high C/O ratios (C/O >~ 0.8) and metallicities of >~ 100x solar metallicity are favored. We combine the mid-transit times from all the new Spitzer and MOST observations and obtain an updated orbital period of P=9.489295 +/- 0.000005 d, with a best-fit transit time center at T_0 = 2456361.80690 +/- 0.00038 (BJD). No transit timing variations are found in this system. We also present new measurements of the stellar rotation period (34 +/- 2 d) and stellar activity cycle (9.6 yr) of the host star HD 97658. Finally, we calculate and rank the Transmission Spectroscopy Metric of all confirmed planets cooler than 1000 K and with sizes between 1 and 4 R_Earth. We find that at least a third of small planets cooler than 1000 K can be well characterized using JWST, and of those, HD 97658b is ranked fifth, meaning it remains a high-priority target for atmospheric characterization., Comment: Accepted to AJ. 29 pages, 21 figures, 11 tables, 2 machine-readable tables (system RVs and TSM values). v2: updated typos

We present the discovery of three sub-Neptune-sized planets transiting the nearby and bright Sun-like star HD 191939 (TIC 269701147, TOI 1339), a $K_{s}=7.18$ magnitude G8 V dwarf at a distance of only 54 parsecs. We validate the planetary nature of the transit signals by combining five months of data from the Transiting Exoplanet Survey Satellite with follow-up ground-based photometry, archival optical images, radial velocities, and high angular resolution observations. The three sub-Neptunes have similar radii ($R_{b} = 3.42^{+0.11}_{-0.11}\,R_{\oplus}$, $R_{c}=3.23_{-0.11}^{+0.11}\,R_{\oplus}$, and $R_{d}=3.16_{-0.11}^{+0.11}\,R_{\oplus}$) and their orbits are consistent with a stable, circular, and co-planar architecture near mean motion resonances of 1:3 and 3:4 ($P_{b}=8.88$ days, $P_{c}=28.58$ days, and $P_{d}=38.35$ days). The HD~191939 system is an excellent candidate for precise mass determinations of the planets with high-resolution spectroscopy due to the host star's brightness and low chromospheric activity. Moreover, the system's compact and near-resonant nature can provide an independent way to measure planetary masses via transit timing variations while also enabling dynamical and evolutionary studies. Finally, as a promising target for multi-wavelength transmission spectroscopy of all three planets' atmospheres, HD 191939 can offer valuable insight into multiple sub-Neptunes born from a proto-planetary disk that may have resembled that of the early Sun., Comment: 24 pages, 14 figures, 6 tables

Thermal inversions have long been predicted to exist in the atmospheres of ultra-hot Jupiters. However, detection of two species thought to be responsible -- TiO and VO -- remain elusive. We present a search for TiO and VO in the atmosphere of the ultra-hot Jupiter WASP-121b ($T_\textrm{eq} \gtrsim 2400$ K), an exoplanet already known to show water features in its dayside spectrum characteristic of a temperature inversion as well as tentative evidence for VO at low-resolution. We observed its transmission spectrum with UVES/VLT and used the cross-correlation method -- a powerful tool for the unambiguous identification of the presence of atomic and molecular species -- in an effort to detect whether TiO or VO were responsible for the observed temperature inversion. No evidence for the presence of TiO or VO was found at the terminator of WASP-121b. By injecting signals into our data at varying abundance levels, we set rough detection limits of $[\text{VO}] \lesssim -7.9$ and $[\text{TiO}] \lesssim -9.3$. However, these detection limits are largely degenerate with scattering properties and the position of the cloud deck. Our results may suggest that neither TiO or VO are the main drivers of the thermal inversion in WASP-121b, but until a more accurate line list is developed for VO, we cannot conclusively rule out its presence. Future work will search for finding other strong optically-absorbing species that may be responsible for the excess absorption in the red-optical., Comment: 12 pages, 7 figures, accepted for publication in A&A

High-resolution Doppler-resolved spectroscopy has opened up a new window into the atmospheres of both transiting and non-transiting exoplanets. Here, we present VLT/UVES observations of a transit of WASP-121b, an 'ultra-hot' Jupiter previously found to exhibit a temperature inversion and detections of multiple species at optical wavelengths. We present initial results using the blue arm of UVES ($\approx$3700-5000A), recovering a clear signal of neutral Fe in the planet's atmosphere at >8$\sigma$, which could contribute to (or even fully explain) the temperature inversion in the stratosphere. However, using standard cross-correlation methods, it is difficult to extract physical parameters such as temperature and abundances. Recent pioneering efforts have sought to develop likelihood `mappings' that can be used to directly fit models to high-resolution datasets. We introduce a new framework that directly computes the likelihood of the model fit to the data, and can be used to explore the posterior distribution of parameterised model atmospheres via MCMC techniques. Our method also recovers the physical extent of the atmosphere, as well as account for time- and wavelength-dependent uncertainties. We measure a temperature of $3710^{+490}_{-510}$K, indicating a higher temperature in the upper atmosphere when compared to low-resolution observations. We also show that the Fe I signal is physically separated from the exospheric Fe II. However, the temperature measurements are highly degenerate with aerosol properties; detection of additional species, using more sophisticated atmospheric models, or combining these methods with low-resolution spectra should help break these degeneracies., Comment: Accepted for publication in MNRAS. 14 pages, 7 figures

We present new observations of the transmission spectrum of the hot Jupiter WASP-6b both from the ground with the Very Large Telescope (VLT) FOcal Reducer and Spectrograph (FORS2) from 0.45-0.83 $\mu$m, and space with the Transiting Exoplanet Survey Satellite (TESS) from 0.6-1.0 $\mu$m and the Hubble Space Telescope (HST) Wide Field Camera 3 from 1.12-1.65 $\mu$m. Archival data from the HST Space Telescope Imaging Spectrograph (STIS) and Spitzer is also reanalysed on a common Gaussian process framework, of which the STIS data show a good overall agreement with the overlapping FORS2 data. We also explore the effects of stellar heterogeneity on our observations and its resulting implications towards determining the atmospheric characteristics of WASP-6b. Independent of our assumptions for the level of stellar heterogeneity we detect Na I, K I and H$_2$O absorption features and constrain the elemental oxygen abundance to a value of [O/H] $\simeq -0.9\pm0.3$ relative to solar. In contrast, we find that the stellar heterogeneity correction can have significant effects on the retrieved distributions of the [Na/H] and [K/H] abundances, primarily through its degeneracy with the sloping optical opacity of scattering haze species within the atmosphere. Our results also show that despite this presence of haze, WASP-6b remains a favourable object for future atmospheric characterisation with upcoming missions such as the James Webb Space Telescope., Comment: Accepted to MNRAS