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Exposure to ceramic powders, which is frequent during handling operations, is known to cause adverse health effects. Finding proxy parameters to quantify exposure is useful for efficient and timely exposure assessments. Worker exposure during handling of five materials [a silica sand (SI1), three quartzes (Q1, Q2, and Q3), and a kaolin (K1)] with different particle shape (prismatic and platy) and sizes (3.4–120 µm) was assessed. Materials handling was simulated using a dry pendular mill under two different energy settings (low and high). Three repetitions of two kilos of material were carried out per material and energy conditions with a flow rate of 8–11 kg h−1. The performance of the dustiness index as a predictor of worker exposure was evaluated correlating material's dustiness indexes (with rotating drum and continuous drop) with exposure concentrations. Significant impacts on worker exposure in terms of inhalable and respirable mass fractions were detected for all materials. Mean inhalable mass concentrations during background were always lower than 40 µg m−3 whereas during material handling under high energy settings mean concentrations were 187, 373, 243, 156, and 430 µg m−3 for SI1, Q1, Q2, Q3, and K1, respectively. Impacts were not significant with regard to particle number concentration: background particle number concentrations ranged between 10 620 and 46 421 cm−3 while during handling under high energy settings they were 20 880 – 40 498 cm−3. Mean lung deposited surface area during background ranged between 27 and 101 μm2 cm−3 whereas it ranged between 22 and 42 μm2 cm−3 during materials handling. TEM images evidenced the presence of nanoparticles (≤100 nm) in the form of aggregates (300 nm–1 µm) in the worker area, and a slight reduction on mean particle size during handling was detected. Dustiness and exposure concentrations showed a high degree of correlation (R 2 = 0.77–0.97) for the materials and operating conditions assessed, suggesting that dustiness could be considered a relevant predictor for workplace exposure. Nevertheless, the relationship between dustiness and exposure is complex and should be assessed for each process, taking into account not only material behaviour but also energy settings and workplace characteristics. [ABSTRACT FROM AUTHOR]

Ground-level and vertical measurements (performed using tethered and non-tethered balloons), coupled with modelling, of ozone (O3), other gaseous pollutants (NO, NO2, CO, SO2) and aerosols were carried out in the plains (Vic Plain) and valleys of the northern region of the Barcelona metropolitan area (BMA) in July 2015, an area typically recording the highest O3 episodes in Spain. Our results suggest that these very high O3 episodes were originated by three main contributions: (i) the surface fumigation from high O3 reservoir layers located at 1500-3000ma.g.l. (according to modelling and non-tethered balloon measurements), and originated during the previous day(s) injections of polluted air masses at high altitude; (ii) local/regional photochemical production and transport (at lower heights) from the BMA and the surrounding coastal settlements, into the inland valleys; and (iii) external (to the study area) contributions of both O3 and precursors. These processes gave rise to maximal O3 levels in the inland plains and valleys northwards from the BMA when compared to the higher mountain sites. Thus, a maximum O3 concentration was observed within the lower tropospheric layer, characterised by an upward increase of O3 and black carbon (BC) up to around 100-200ma.g.l. (reaching up to 300 μgm-3 of O3 as a 10 s average), followed by a decrease of both pollutants at higher altitudes, where BC and O3 concentrations alternate in layers with parallel variations, probably as a consequence of the atmospheric transport from the BMA and the return flows (to the sea) of strata injected at certain heights the previous day(s). At the highest altitudes reached in this study with the tethered balloons (900-1000ma.g.l.) during the campaign, BC and O3 were often anti-correlated or unrelated, possibly due to a prevailing regional or even hemispheric contribution of O3 at those altitudes. In the central hours of the days a homogeneous O3 distribution was evidenced for the lowest 1 km of the atmosphere, although probably important variations could be expected at higher levels, where the high O3 return strata are injected according to the modelling results and non-tethered balloon data. Relatively low concentrations of ultrafine particles (UFPs) were found during the study, and nucleation episodes were only detected in the boundary layer. Two types of O3 episodes were identified: type A with major exceedances of the O3 information threshold (180 μgm-3 on an hourly basis) caused by a clear daily concatenation of local/regional production with accumulation (at upper levels), fumigation and direct transport from the BMA (closed circulation); and type B with regional O3 production without major recirculation (or fumigation) of the polluted BMA/regional air masses (open circulation), and relatively lower O3 levels, but still exceeding the 8 h averaged health target. To implement potential O3 control and abatement strategies two major key tasks are proposed: (i) meteorological forecasting, from June to August, to predict recirculation episodes so that NOx and VOC abatement measures can be applied before these episodes start; (ii) sensitivity analysis with high-resolution modelling to evaluate the effectiveness of these potential abatement measures of precursors for O3 reduction. [ABSTRACT FROM AUTHOR]

We investigated the seasonal trends of OA sources affecting the air quality of Marseille (France) which is the largest harbor of the Mediterranean Sea. This was achieved by measurements of nebulized filter extracts using an aerosol mass spectrometer (offline-AMS). PM2.5 (particulate matter with an aerodynamic diameter < 2.5 micrometers) filter samples were collected over 1 year from August 2011 to July 2012. The same samples were also analyzed for major water-soluble ions, metals, elemental and organic carbon (EC/OC), and organic markers, including n-alkanes, hopanes, polyaromatic hydrocarbons (PAHs), lignin and cellulose pyrolysis products and nitrocatechols. The application of positive matrix factorization (PMF) to the water-soluble AMS spectra enabled the extraction of five factors, related to hydrocarbon-like OA (HOA), cooking OA (COA), biomass burning OA (BBOA), oxygenated OA (OOA), and an industry-related OA (INDOA). Seasonal trends and relative contributions of OA sources were compared with the source apportionment of OA spectra collected from the AMS field deployment at the same station but in different years and for shorter monitoring periods (February 2011 and July 2008). Online- and offline-AMS source apportionment revealed comparable seasonal contribution of the different OA sources. Results revealed that BBOA was the dominant source during winter representing on average 48 % of the OA, while during summer the main OA component was OOA (63 % of OA mass on average). HOA related to traffic emissions contributed on a yearly average 17 % to the OA mass, while COA was a minor source contributing 4 %. The contribution of INDOA was enhanced during winter (17 % during winter and 11 % during summer), consistent with an increased contribution from light alkanes, light PAHs (fluoranthene, pyrene, phenantrene) and selenium, which is commonly considered as an unique coal combustion and coke production marker. Online- and offline-AMS source apportionments revealed evolving levoglucosan:BBOA ratios, being higher during late autumn and March. A similar seasonality was observed in the ratios of cellulose combustion markers to lignin combustion markers, highlighting the contribution from cellulose rich biomass combustion, possibly related to agricultural activities. [ABSTRACT FROM AUTHOR]

Ground level and vertical measurements (coupled with modelling) of ozone (O3), other gaseous pollutants (NO, NO2, CO, SO2) and aerosols were carried out in the plains (Vic Plain) and valleys of the northern region of the Barcelona Metropolitan Area (BMA) in July 2015; an area typically recording the highest O3 episodes in Spain. Our results suggest that these very high O3 episodes were originated by three main contributions: (i) the surface fumigation from high O3 reservoir layers located at 1500-3000 m a.g.l., and originated during the previous day(s) injections of polluted air masses at high altitude; (ii) local/regional photochemical production and transport (at lower heights) from the BMA and the surrounding coastal settlements, into the inland valleys; and (iii) external (to the study area) contributions of both O3 and precursors. These processes gave rise to maximal O3 levels in the inland plains and valleys northwards from the BMA when compared to the higher mountain sites. Thus, a maximum O3 concentration was observed within the lower tropospheric layer, characterised by an upward increase of O3 and black carbon (BC) up to around 100-200 m a.g.l. (reaching up to 300 µg/m³ of O3 as a 10-s average), followed by a decrease of both pollutants at higher altitudes, where BC and O3 concentrations alternate in layers with parallel variations, probably as a consequence of the atmospheric transport from the BMA and the return flows (to the sea) of strata injected at certain heights the previous day(s). At the highest altitudes reached in this study (900-1000 m a.g.l.) during the campaign, BC and O3 were often anti-correlated or unrelated, possibly due to a prevailing regional/hemispheric contribution of O3 at those altitudes. In the central hours of the days a homogeneous O3 distribution was evidenced for the lowest 1 km of the atmosphere, although probably important variations could be expected at higher levels, where the high O3 return strata are injected according to the modelling results and free sounding data. Relatively low concentrations of ultrafine particles (UFP) were recorded in the 100-200 m a.g.l. atmospheric layer where concentrations of O3 were high; and nucleation episodes were only detected into the boundary layer. Two types of O3 episodes were identified: Type A) with major exceedances of the O3 information threshold (180 µg/m3 on an hourly basis) caused by a clear daily concatenation of local/regional production with accumulation (at upper levels), fumigation and direct transport from the BMA (closed circulation); and Type B) with regional O3 production without major recirculation (neither fumigation) of the polluted BMA/regional air masses (open circulation), and relatively lower O3 levels. The interpretation of OX (O3 + NO2) experimental data from strategically selected monitoring sites on the coast and inland, together with the photochemical modelling results have allowed to study the O3 phenomenology associated with the onset and development of severe episodes in the region of Catalonia in NE Spain. To implement potential O3 control and abatement strategies two major key tasks are proposed: (i) meteorological forecasting, from June to August, to predict recirculation episodes so that NOX and VOCs abatement measures can be applied before these episodes start; (ii) sensitivity analysis with high resolution modelling to evaluate the effectiveness of these potential abatement measures of precursors for O3 reduction. [ABSTRACT FROM AUTHOR]

Ground level and vertical measurements (coupled with modelling) of ozone (O3), other gaseous pollutants (NO, NO2, CO, SO2) and aerosols were carried out in the plains (Vic Plain) and valleys of the northern region of the Barcelona Metropolitan Area (BMA) in July 2015; an area typically recording the highest O3 episodes in Spain. Our results suggest that these very high O3 episodes were originated by three main contributions: (i) the surface fumigation from high O3 reservoir layers located at 1500-3000 m a.g.l., and originated during the previous day(s) injections of polluted air masses at high altitude; (ii) local/regional photochemical production and transport (at lower heights) from the BMA and the surrounding coastal settlements, into the inland valleys; and (iii) external (to the study area) contributions of both O3 and precursors. These processes gave rise to maximal O3 levels in the inland plains and valleys northwards from the BMA when compared to the higher mountain sites. Thus, a maximum O3 concentration was observed within the lower tropospheric layer, characterised by an upward increase of O3 and black carbon (BC) up to around 100-200 m a.g.l. (reaching up to 300 µg/m³ of O3 as a 10-s average), followed by a decrease of both pollutants at higher altitudes, where BC and O3 concentrations alternate in layers with parallel variations, probably as a consequence of the atmospheric transport from the BMA and the return flows (to the sea) of strata injected at certain heights the previous day(s). At the highest altitudes reached in this study (900-1000 m a.g.l.) during the campaign, BC and O3 were often anti-correlated or unrelated, possibly due to a prevailing regional/hemispheric contribution of O3 at those altitudes. In the central hours of the days a homogeneous O3 distribution was evidenced for the lowest 1 km of the atmosphere, although probably important variations could be expected at higher levels, where the high O3 return strata are injected according to the modelling results and free sounding data. Relatively low concentrations of ultrafine particles (UFP) were recorded in the 100-200 m a.g.l. atmospheric layer where concentrations of O3 were high; and nucleation episodes were only detected into the boundary layer. Two types of O3 episodes were identified: Type A) with major exceedances of the O3 information threshold (180 µg/m³ on an hourly basis) caused by a clear daily concatenation of local/regional production with accumulation (at upper levels), fumigation and direct transport from the BMA (closed circulation); and Type B) with regional O3 production without major recirculation (neither fumigation) of the polluted BMA/regional air masses (open circulation), and relatively lower O3 levels. The interpretation of OX (O3 + NO2) experimental data from strategically selected monitoring sites on the coast and inland, together with the photochemical modelling results have allowed to study the O3 phenomenology associated with the onset and development of severe episodes in the region of Catalonia in NE Spain. To implement potential O3 control and abatement strategies two major key tasks are proposed: (i) meteorological forecasting, from June to August, to predict recirculation episodes so that NOX and VOCs abatement measures can be applied before these episodes start; (ii) sensitivity analysis with high resolution modelling to evaluate the effectiveness of these potential abatement measures of precursors for O3 reduction. [ABSTRACT FROM AUTHOR]