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Sources, historical trends and inventories of polychlorinated biphenyls (PCBs) were investigated in sediments collected in five transects along the north-south axis of the western Adriatic Sea. The concentration of total PCBs (∑ 28 PCBs) ranged from < LOD (limit of detection) to 9.0 ng g − 1 in the sediment cores and between 0.1 and 2.2 ng g − 1 in recent sediments. Chronological records of PCB concentrations displayed a common pattern with historical PCB production and use, with the maximum peak values detected between the 1960s and the 1980s. Sediments deposited within the last two decades presented a ~ 40% to ~ 80% PCB reduction in comparison to the peak levels, reflecting the ban on PCB production and use since the late 1970s. PCB levels along with the presence of high-chlorinated congeners decreased southwards, indicating the Po River as the major source of PCBs in the western Adriatic Sea. This is further corroborated by the estimated inventories of PCBs, which were ~ 4–7 times higher in the Po River prodelta (256 ng cm − 2 ) in comparison to the middle and southern Adriatic, respectively, and about 100 times higher than the in the deep Adriatic Sea. [ABSTRACT FROM AUTHOR]

Abstract: As part of the EuroSTRATAFORM project, a multi-proxy study was conducted in order to investigate origin, transport and deposition of riverine organic matter in the Gulf of Lions. Surface sediments (0–1 cm) from the Rhône prodelta area and along the sediment dispersal system were collected in September 2004 and in April 2005. Lignin, elemental and stable carbon isotopic analyses were carried out to characterize the source of sedimentary organic material and to facilitate evaluation of temporal and spatial variability. Large contrasts in the organic matter composition of prodelta sediments were observed as a result of the preferential transport of the finest material. In our hypothesis, woody debris, rich in organic matter, hydraulically behaves like very fine sand and is retained within the prodelta area. In contrast, the organic matter adsorbed onto finer particles is selectively transported away from the prodelta along the sediment dispersal system, explaining the distinct organic matter composition observed in the offshore regions. [Copyright &y& Elsevier]

Abstract: Thirty-three surface sediment samples from cross-shelf transects on the northern Adriatic shelf were collected in December 2000, soon after a 100-yr flood of the Po River, in order to determine the distribution of organic carbon (OC) along the main sediment dispersal system. To evaluate the temporal variability, stations were re-occupied eight times at seasonal intervals until June 2003. Downcore sediment profiles from two sites characterized by high flood deposit thicknesses were also examined to assess the OC variability within the flood layer. In December 2000, the highest contents of OC (up to 1.24wt%) were measured in front of the main distributary mouths (Pila, Tolle and Gnocca-Goro) where the greatest thicknesses of the flood deposit were recorded. However, the influence of the Po di Gnocca-Goro sediment supply on the OC surface distribution declined after ∼1.5 years from the fall-2000 river flood, probably because these mouths are less active when the water discharge is lower. The δ13C of organic matter was used to trace the dispersal of fluvial OC on the continental shelf. The δ13C values ranged from −25.9‰ to −23.1‰. The fraction of fluvially derived organic particles decreased with increasing water depth according to a radial dispersal pattern around the Po River delta. This pattern persisted in all cruises. δ13C values increased progressively until April 2002, suggesting an increasing marine contribution to the OC content but decreased again following a second minor flood event in November 2002. The molar C/N ratio was on average 10.0±1.6, with slightly lower values in southern and central areas. Assuming contributions from three OC end-members (terrestrial, riverine and marine), a mixing model based on δ13C and the ratio of N to C (statistically more robust than C/N; Goñi, M.A., Teixeir, M.J., Perkley, D.W., 2003. Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA). Estuarine, Coastal and Shelf Science 57, 1023–1048) was applied in order to quantitatively assess the OC sources for Po shelf sediments. δ13C is significantly and positively correlated with the marine OC fraction. The terrestrial fraction is inversely correlated with N/C, while the riverine fraction is positively correlated with N/C. The terrestrial OC source was the most abundant end-member (>70%) showing only little temporal variability regardless of the Po River water discharge. Temporal and spatial changes in OC composition suggest that: (a) the Po River prodelta is always dominated from terrestrial OC input; (b) the Po della Pila supplies most terrestrial OC, whilst other tributaries (e.g., Po di Gnocca-Goro) are secondary sources. However, these mouths are as important as the Po della Pila in affecting the riverine OC signature; (c) offshore, biological primary production raises the marine OC contribution. At two sites on the Po River prodelta, the 2000-flood deposit shows slight but consistent compositional changes of organic matter (N/C and δ13C) which can help to recognize other flood events in the sedimentary record. The OC budget for the 2000-flood deposit accounts for a terrestrial+riverine OC supply of 68–162Gg (109 g) against an OC deposition of 106–162Gg (excluding the marine fraction), which implies a rapid and efficient sedimentation of the flood material, and scarce or negligible export out the study area. Flood events may thus enhance terrestrial carbon burial, whereas marine carbon arrives more slowly and may be largely mineralized at the sediment–water interface. [Copyright &y& Elsevier]

We conducted this study to investigate the relationship between environmental stressors and mesozooplankton fluxes in inner Kongsfjorden, Svalbard. The ongoing Arctic amplification, characterized by phenomena such as increased temperatures, glacial and watershed runoff, and diminishing ice cover, poses significant challenges to marine ecosystems. Our multi-year time-series analysis (2010–2018) of mesozooplankton, collected from a moored automatic sediment trap at approximately 87 m depth, aims to elucidate seasonal and interannual variations in fluxes within this Arctic fjord. We integrate meteorological, hydrological, and chemical datasets to assess their influence on zooplankton populations. Principal component analysis reveals the impact of seawater characteristics on mesozooplankton fluxes and composition, while two-way ANOVA highlights the role of seasonality in driving variations in our dataset. We observe a decrease in swimmer fluxes following the maxima mass flux event (from 2013 onwards), coupled with an increase in community diversity, possibly attributed to copepod decline and functional diversity. Notably, sub-Arctic boreal species such as Limacina retroversa have been detected in the sediment trap since 2016. Our continuous multi-year dataset captures the physical, chemical, and biological dynamics in this extreme environment. With Arctic amplification in Kongsfjorden and increasing submarine and watershed runoff, we anticipate significant shifts in mesozooplankton communities in the medium to long-term. This underscores the urgency for further research on their adaptation to changing environmental conditions and the potential introduction of alien species. [ABSTRACT FROM AUTHOR]

The near-bottom nepheloid layer in the western margin of the Southern Adriatic Sea was monitored for 8-years by measurements acquired at two mooring sites. The two moorings, equipped with CTD probes and ADCPs, are located in the Bari Canyon and in an open slope sector along the Southern Adriatic Margin. These regions are of interest because affected by episodic dense shelf water cascading events whose dynamic has direct implications on deepwater morpho-dynamic, biogeochemical cycles and trophic networks. In this work, the sedimentation flux and its interdecadal dynamic is analysed examining in detail the sedimentary processes triggered by dense water flow through the analysis of the echo records of ADCPs. The integration of hydrodynamic, turbidity and particle grain-size data provided estimates of the sediment flux, separating phases when the flow actively erodes the seabed from phases when particles are transported to the mooring location through density flows. The frequency and velocity of dense-water cascading currents vary in time and space reflecting the capacity of sediment transport. Data analysis demonstrated that the hydrodynamic event that mostly accounts for sediment transfer to the deep basin is represented by current pulses induced by the passage of dense waters. The average annual sediment flux has been quantified and the Bari canyon shows transport more than five time larger than in the open slope sector, confirming that the canyon is the dominant pathway of sediment transfer to the deep basin. In contrast, in the open slope, albeit a minor lateral sediment advection, is impacted by currents that are able to trigger intense resuspension of seabed sediments, which can contribute over 80% of the total solid load. This study allows unravelling the role of cascading in the sediment resuspension and transport processes and is essential to support deciphering the sedimentary records in the study area. The long temporal extent of the dataset used for quantification provides a reliable contribution to the Quaternary sediment budget determination. • The integrated approach proposed in the study made it possible to determine sediment flux during dense water cascade events. • This study allows unravelling the role of cascading in the sediment resuspension and transport processes • The characterization of short-lived events can improve the high-resolution interpretation of the stratigraphic records. • The large temporal extension of the dataset used provides a reliable contribution to the Quaternary sediment budget [ABSTRACT FROM AUTHOR]

Spatial patterns of major (Al, Fe and Ti) and trace metals (Cu, Cr, Mn, Ni, Pb and Zn) measured in surficial sediments collected within the Late-Holocene mud-wedge in the western Adriatic Sea were analyzed to elucidate their sources, transport and mass budgets. Distributions of sedimentary trace metals, their fluvial inputs and accumulation loads reveal along-shore transport towards the southern Adriatic. Pb and to a lower extent Zn accumulation loads over time decreased significantly since 1988 in the North Adriatic, consistently with the implementation of regulations in the Western Europe, whereas Zn accumulation in the Po River prodelta remained unchanged since 1995. The Po River fluvial inputs accounted for half of Cr, Ni, Pb and Zn of the fluvial inputs into the western Adriatic Sea, contributing for the delivery of important amounts of Cr and Ni into the sediments, probably related to the natural occurrence of ultramafic rocks in the North sector. Collectively, ~ 30% of trace metal fluvial inputs discharged into the North sector are exported to the Central and South sectors. The Po River acts as both a bypass and an accumulation zone. In contrast, trace metal accumulation in the Central sector far exceed trace metal fluvial inputs, which suggested that this area is a preferential sink for particle-reactive river-borne material from the North Adriatic. The North sector shows moderate enrichment of Zn and Pb mainly related to the Po River influence. The anthropogenic fraction of Pb shows a large drop of ~ 30% from the North sector southwards, whereas Zn proportions remain fairly the same up to the Central sector only decreasing in the South sector. [ABSTRACT FROM AUTHOR]

This work presents an 8-years-long dataset of monitoring activities conducted on the western margin of the southern Adriatic Sea where two moorings have been placed since 2012 in sites that are representative of different morpho-dynamic conditions of the continental slope (open slope vs. submarine canyon). The dataset includes measurements conducted with both current meters and conductivity, temperature and depth (CTD) probes, and it provides information about the hydrodynamics and thermohaline properties of the last 100 m of the water column. The hydrodynamics in both sites are dominated by weak currents (< 0.1 ms-1) which undergo yearly to episodic pulsation able to exceed intensity greater than 0.5 ms-1 , which are linked to the passage of dense waters. The 8-years records presented here represent a starting point for the continuous observation activity set up on occasion of the "Operation Dense Water" in 2012 focussed on the southern Adriatic deep-water dynamics. Since then, the observatory has been ongoing since 2012 and the database is regularly updated. All the data described here are made publicly available from 10.5281/zenodo.6770201 (Paladini de Mendoza et al., 2022) and are compliant with the FAIR principles (findable, accessible, interoperable and reusable). [ABSTRACT FROM AUTHOR]

Shallow seabed depressions attributed to focused fluid seepage, known as pockmarks, have been documented in all continental margins. In this study, we demonstrate how pockmark formation can be the result of a combination of multiple factors—fluid type, overpressures, seafloor sediment type, stratigraphy and bottom currents. We integrate multibeam echosounder and seismic reflection data, sediment cores and pore water samples, with numerical models of groundwater and gas hydrates, from the Canterbury Margin (off New Zealand). More than 6800 surface pockmarks, reaching densities of 100 per km2, and an undefined number of buried pockmarks, are identified in the middle to outer shelf and lower continental slope. Fluid conduits across the shelf and slope include shallow to deep chimneys/pipes. Methane with a biogenic and/or thermogenic origin is the main fluid forming flow and escape features, although saline and freshened groundwaters may also be seeping across the slope. The main drivers of fluid flow and seepage are overpressure across the slope generated by sediment loading and thin sediment overburden above the overpressured interval in the outer shelf. Other processes (e.g. methane generation and flow, a reduction in hydrostatic pressure due to sea‐level lowering) may also account for fluid flow and seepage features, particularly across the shelf. Pockmark occurrence coincides with muddy sediments at the seafloor, whereas their planform is elongated by bottom currents. [ABSTRACT FROM AUTHOR]

The Southern Adriatic is an area of dense shelf water (DSW) cascading and open-ocean convection. The impact of DSW cascading events in transferring organic matter to the deep benthic community and in producing a wide range of bedforms along the continental margin has been highlighted in recent years. In order to improve our knowledge on the interannual variability of the DSW cascading with the ultimate goal to understand timing of DSW formation and transport as well as the cascading process, its variability in intensity and duration, and the ultimate impact of the dense water on the deep sea, in March 2009 we deployed an instrumented mooring in a field of sediment waves (860 m depth) located down current to the Bari canyon. In March 2010, a second mooring was installed in the northern channel of the canyon. Winters 2009, 2010 and 2011 were mild and particularly wet and the Po river discharge remained relatively high throughout the whole winter. Hence, we expected weak dense shelf water formation associated with a shallow shelf water overflowing off the Adriatic shelf. By contrast, in winter 2012, the North Adriatic experienced a severe cold wave with NE Bora winds and reduced fresh water input. These weather conditions allowed the formation of extremely dense shelf water. Three additional moorings were quickly deployed during this cold event in the Southern Adriatic Sea to investigate the spatial variability of particle and organic matter fluxes exiting from the Adriatic continental shelf under the influence of a strong DSW cascading event. Slow near-bottom currents, never exceeding 40 cm s − 1 , were recorded between March 2009 and February 2012. Water temperatures depicted minor negative shifts. Total mass fluxes (TMFs) were low (annual avg., 1.7–2.8 g m − 2 d − 1 and 0.3–0.6 g m − 2 d − 1 in the canyon and in the sediment wave field, respectively; and peak values ≤ 6.8 g m − 2 d − 1 ), but showed significant seasonal and interannual variability. Fluxes in the canyon were higher than those measured in the sediment wave field at deeper water depth. Mass flux peaks during the 2112-DSW cascading were up to 5 times higher than the peaks of previous years (up to 18.70 g m − 2 d − 1 ), with a spatial variability mainly driven by the localized pathways of DSW cascading. In the canyon, near-bottom currents exceeded 70 cm s − 1 and temperature dropped to 12.2 °C while current speeds were high also at 1200 m depth (~ 60 cm s − 1 ) in the moat surrounding the Dauno seamount. Surprisingly, mass flux peaks occurred from the 16th February to the 1st of March, 3–4 weeks ahead of the usual DSW occurrence, suggesting an early arrival of the DSW. The deep DSW cascading was the main process driving the particle transfer across the southern Adriatic margin during late winter–spring 2012. Mooring data showed a NW–SE gradient of temperature and kinetic energy from upslope to basin floor, indicating slope transverse flow modulated by local obstruction caused by the rugged seafloor topography. Bari canyon is one of the sites of DSW flow and in this area we have the possibility to extend observations back in time using continuous mooring data since 2009 and previous published materials; this approach allowed evaluation of additional mechanisms of particle transport (e.g., open-ocean convection, storm-driven downward transport, shallow dense water cascading) that are particularly relevant in years when the DSW formation is less vigorous and cascading processes are sluggish. The small amplitude of total mass flux peaks, the weak currents and the relatively high and constant temperatures recorded during 2009, 2010 and 2011 springs are consistent with an enhanced vertical particle rain from a mid-water nepheloid layer, triggered in turn by a shallow cascading of not-particularly dense shelf water detaching from the seafloor when reaches its neutral buoyancy. Thus, the intensity of DSW cascading (shallow vs. deep) plays a first order control on the particulate fluxes through the western margin of the Southern Adriatic, while storm-induced sediment transport can occasionally be relevant too. [ABSTRACT FROM AUTHOR]

Antarctic fjords and coastal bays are excellent traps for sediment and represent key areas for high-resolution investigation of past environmental conditions. Robertson Bay is an understudied coastal area located at the confluence of the Ross Sea and the Southern Ocean. Recently obtained seafloor morphology data indicate the presence of a cross-shelf elongated valley, composed of three minor basins separated by sills and seabed ridges with an arcuate shape. Several cores were collected within the basins, and investigated using a multiproxy approach including sedimentological, chemical, geochemical, and micropaleontological characterization to reconstruct the paleoenvironmental evolution from the last glacial period to present. The ages of two of these cores are constrained using ramped pyrolysis oxidation radiocarbon dating. Four sedimentary facies were recognised from which we developed a sedimentary model covering the last 21,000 years (21 ka BP). Our record provide evidence for a covering ice shelf cover from 21 to 16.5 ka BP, which gradually receded between 16,5 and 11 ka BP due to the progressive intrusion of modified Circumpolar Deep Water, thereby promoting the formation of Ice Shelf Water and High Salinity Shelf Water. From 11 to 5,8 ka BP, the ice shelf continued shrinking and nutrient-rich of modified Circumpolar Deep Water penetration onto the continental shelf progressively favoured diatom blooms and a general increase in primary productivity until 5.8 ka BP. The Late Holocene is characterised by an alternation of prolonged sea ice cover with stratified water column and strong bottom current with prolonged sea-ice free season with the intrusion of modified Circumpolar Deep Water and very slow energy bottom current. • First paleoenvironmental study from the LGM to the present in Robertson Bay. • Strong impact of regional ice sheet recession on environmental conditions and productivity. • Multiproxy approach constrained by Ramped Pyrolysis based age model. • The coastal bay area was studied by sediment cores and geophysical data. [ABSTRACT FROM AUTHOR]

This work presents an 8-years long dataset of monitoring activities conducted on the western margin of the Southern Adriatic Sea, where two moorings have been placed since 2012 in sites that are representative of different morpho-dynamic conditions of the continental slope (open slope vs. submarine canyon). The dataset includes measurements conducted with both current meters and CTD probes, and provides information about the hydrodynamics and thermohaline properties of the last 100 m of the water column. The hydrodynamics in both sites is dominated by weak currents (<0.1 ms-1), which undergo yearly to episodic pulsation able to exceed intensity greater than 0.5 ms-1 which are linked to the passage of dense waters. The 8-years records presented here, represents a starting point for the continuous observation activity set up on occasion of the "Operation Dense Water" in 2012, focused on the Southern Adriatic deep-water dynamic. Since then the observatory has been on-going since 2012 and the database is regularly updated. [ABSTRACT FROM AUTHOR]

The article presents a study that explores the rapid atlantification along the Fram Strait at the beginning of the 20th century. It mentions that expansion of Atlantic waters into the Arctic Ocean represents undisputable evidence of the rapid changes occurring in this region. It discusses that history of Atlantification.

The Ross Sea is one of the major areas for Antarctic Bottom Water formation (the Ross Sea Bottom Water, RSBW), representing the densest ocean water mass, filling the deepest ocean basins connected to the southern ocean. Periodic refill of the RSBW occurs through formation of dense, cold and saline water masses (brine) forming on the shelf at the Ross Sea permanent polynya by freezing and salt rejection (high-salinity shelf water, HSSW). The HSSW periodically overspills the shelf area and descends along the slope. This mechanism represents the engine of the global ocean circulation regulating the climate.The Hillary Canyon, crossing the Ross Sea continental slope, represents one of the main conducts through which the HSSW descends the slope to reach the deeper ocean. On its western levee, there is a mounded depocentre that was mapped and ground-sampled during the Italian ITRS17-ODYSSEA expedition on board the RV OGS-Explora (January-February 2017). Geophysical data allowed interpreting such feature as a sediment drift (ODYSSEA Drift), generated by along-slope, contour currents sediment transport and accumulation through several hundred-thousands years. It was inferred that contour currents transported and deposited the sediments that descent the Hillary Canyon by means of the HSSW. Therefore, the depositional sequence of the ODYSSEA Drift potentially contains the record of the variability of HSSW formation, the along slope current intensity in association to climate change, and the interplay between the two bottom currents.A multidisciplinary investigation was applied to six gravity cores collected in the proximal and distal area of the ODYSSEA Drift. The cores were analysed to reconstruct the age model combining AMS radiocarbon dating on foraminifera tests, biostratigraphy, and the sediment palaeomagnetic record; the sediment physical properties (wet bulk density, water content and grain size); and compositional characteristics (XRF core scan and geochemistry). Three main lithofacies were distinguished and associated to depositional processes and climatic conditions: 1) finely laminated and bioturbated sediments characterized by a relatively high Ca content with common presence of biogenic component. Such facies was associated to contour current deposition during relatively warm conditions. 2) Bioturbated sediments with abundant, sparse and/or layered Ice Rafted Debris, and high Ca content. The onset of this facies is characterized by a prominent Mn peak that was associated to bottom ocean oxygenation through ice sheet melting/decay. 3) Laminated, barren sediments associated to steady strong bottom currents under harsh climate conditions. Further preliminary data interpretations are discussed. [ABSTRACT FROM AUTHOR]

Kongsfjorden (Spitsbergen, Svalbard) is an inlet treated as a model site for studies on the impact of climate change in the Arctic due to its hydrological features. In this research, seven-days monitoring was carried out to evaluate the effects of hydrological variability on phytoplankton biomass and diversity in the late summer period. Temperature, salinity, nutrients, total suspended matter, phytoplankton abundance and biomass were determined for each sample. The thermo-haline properties of the column water seemed to affect phytoplankton communities. Their abundances and biomass were correlated with the amount of the total suspended matter. Moreover, species composition and biomass dramatically changed throughout the study period. Cold-water and Atlantic species were replaced by temperatewarm water dinoflagellates, including harmful species. An increase in phytoplankton biomass as well as the presence of dinoflagellate aggregations, mainly composed of Prorocentrum cf. gracile, were detected. This kind of algal accumulation is a new phenomenon in the Arctic and was probably related to the mobilization of sediment-rich glacial meltwaters. These findings, even if preliminary, suggest the need to study how additional biomass pulses and the increase of harmful species may alter the food web structure and the biogeochemical cycles, leading to major ecosystem changes. [ABSTRACT FROM AUTHOR]

In February 2012, a severe cold spell in the European region triggered a massive production of very dense water on the northern Mediterranean Sea shelves. The spreading phase of the newly formed dense water was extensively studied in the Adriatic Sea by means of 2 ship surveys and 5 moorings fully equipped to monitor the flow of the bottom layer. For the Adriatic Sea, opposite to the Gulf of Lions, the area of cascading is far from the source area and this implies substantial modifications, adjustments and dilution of the source water mass along its path, with a spreading phase lasting several months. Indeed all the moorings detected events, although weaker than in the preceding months, until June 2012. The surveys detected 2 branches of NAdDW on the shelf, the first branch not denser than 29.7 kg/m 3 and the second branch not denser than 29.5 kg/m 3 . Despite the extremely dense water generated in the Northern Adriatic, during events of dense-water flow, moorings recorded temperatures generally between 12.5 and 13 °C, seldom less. Temperatures along the shelf break also did not fall below 13 °C at depths greater than 400 m. Turbulent mixing, therefore, heavily modified the cascading plumes, which left the shelf with thicknesses between 10 and 30 m. Mooring data in the lowermost 100 mab suggest that the thickness of the cascading layer increased by several tens of meters downslope, as a consequence of entrainment. Detraining frictional layers as well as locations of active cascading were identified mostly by isolated casts, highlighting the submesoscale domain of the downsloping plumes. The use of LADCP data allowed identification of very energetic bottom flow (40–50 cm/s in many locations), with otherwise little signature in tracers, not previously observed. The Bari Canyon System (BCS) was so far recognized as a hot spot for cascading in the Southern Adriatic. However, during the 2012 event, this is not the only preferred site for cascading. Significant dense flow was detected in other locations. The northernmost mooring site, closer to the inception of the cascading process, in particular showed active cascading and several dynamical differences from the BCS: denser water with thinner boundary layer, events organized in multiple pulses with sub-inertial periodicity and with very short duration (12 h to 1 day) that is generally not seen in other locations. [ABSTRACT FROM AUTHOR]

Abstract: Using the results of a numerical model for the description of bottom-arrested currents and statistical analyses, we elucidate different characteristics of the dynamics of a southward propagating vein of North Adriatic Dense Water (NAdDW) observed to evolve within a complex canyon system of the southern Adriatic basin. The vein, monitored from March 2004 to March 2005 by three distinct mooring lines, exhibits a complex, highly time-dependent dynamics characterized by large velocity and density fluctuations. In particular, lag correlation analyses performed on the observed velocity and temperature data show that a temporal lag ranging between 7 and 10h governs the NAdDW signal propagation along the different canyons, its magnitude inversely depending on vein downslope velocities and density anomalies. The performed model simulations reveal that, weakly depending on its initial layer thickness, exact position, and density contrast with the upper ocean, a coherent flow of dense water located upstream of the canyon system on the Italian shelf will always bifurcate at the entrance of that system; while its shallower part will disintegrate into several branches, its deeper part will continue to flow more coherently, injecting part of the bottom water downward. Regions dominated by supercritical flow regimes are simulated, which contributes to explain part of the observed flow variability. Simulated lag times between signals propagating in the canyons are consistent with observations. They are found to depend crucially on initial, upstream vein location, layer thickness, and density contrast with the upper ocean. We finally use this information, retrieved by our numerical simulations on the basis of the available observations, to infer, in a kind of inverse problem solving, possible shape, location, and density contrast possessed by the observed vein of NAdDW on the Italian continental shelf, prior to its sinking toward the Bari canyon system. [Copyright &y& Elsevier]

Abstract: To investigate the role of coastal canyons in the transfer of organic matter from the shelf to the slope and basin, we deployed sediment trap/current meter pairs at the head of five canyons in the Gulf of Lions (GoL) between November 2003 and May 2004. Analysis of organic carbon, biogenic silica, Corg isotopic composition, Corg/total nitrogen, chloropigments, and amino acids clearly shows the seasonal influence and effect of extreme meteorological events on the composition of collected particles. The sampling period was divided into three “scenarios”. The first corresponded to a large easterly storm and flood of the Rhone river during stratified water column conditions; the composition of material collected during this event was influenced by increased transfer of riverine and coastal particulate matter, with a lower Corg content. During the second “fall-winter” scenario, northern and northwestern winds blowing over the shelf caused cooling and homogenization of the shelf water column; particles collected at this time reflected the homogeneous source of particulate matter transported through canyons; particles sitting in the vicinity of canyon heads are most likely swept downslope by the general south-westward circulation. Organic tracers indicate a degraded origin for organic matter transported during this period. A third “spring” scenario corresponded to northern winds alternating with eastward windstorms that triggered and/or enhanced the cascading of dense waters accumulated on the bottom of the shelf due to previous cooling. These conditions occurred in conjunction with increased phytoplankton productivity in shelf surface waters. Organic matter advected mainly by dense shelf water cascading was fresher due to the transport of newly produced particles and a variable terrestrial fraction; this fraction depended on the proportion of resuspended material accumulated during previous high discharge periods that was involved in each transport pulse. The tight link shown between meteorological conditions and organic matter transport is important for continental margin geochemical studies as future changes in climatic conditions may lead to dramatic changes in carbon sequestration capability and in the ecosystems of deep margin environments. [Copyright &y& Elsevier]

Abstract: We really appreciate the interest and comments regarding our manuscript. We hope we address all the lingering issues in this reply. This also gives us the opportunity of publishing an update on our dataset that will complete the original manuscript (see ). We have followed the author pattern in our answers: 1-Gas sampling procedure, 2-Reported gas concentrations results, 3-General remarks, 4-Conclusions. [Copyright &y& Elsevier]

Abstract: With the aim of improving the knowledge of the open ocean carbon cycle, we present a budget of particulate organic carbon (POC) fluxes carried out in the deep central part of the Algero-Balearic Basin (ABB) at 2850m water depth based on a single mooring equipped with five automated sediment traps deployed from April 2001 to May 2002 at depths of 250, 845, 1440, 2145 and 2820m. Suspended particulate matter (SPM) and superficial sediments were also used as indicators of hydrodynamics and carbon burial, respectively. The data reveal that the fraction of primary production buried in the sediment, which finally leads to the sequestration of carbon dioxide from the atmosphere, is 0.16%, lower than the values found in the nearby continental margin regions such as the Alboran Sea (0.48–0.89%) but of the same order as recorded at other Mediterranean sites at similar depths, such as the Ionian Sea (0.11%). As they sink through the water column, the particles exhibit decreases in flux that are similar to those observed elsewhere, but also show variations that appear to correlate with hydrological features of the water masses present in the basin, as revealed by SPM concentrations and compositions. The input of the tyrrhenian deep water (TDW) into the ABB at 800–1500m of water depth exhibits low suspended POC concentrations and low sinking POC fluxes were also observed in this depth range. Gulf of Lions water mass formation appears to also contribute to elevated suspended POC concentrations and perhaps POC accumulation in the traps and sediments by spreading of dense cold water along the whole ABB that supplied POC at depths higher than 2000m. [Copyright &y& Elsevier]

From 2000 to 2002, sediment contamination by Cd, Cu, Hg, Pb and Zn was analysed in the Pialassa Baiona salt marsh, which receives petrochemical wastewaters from the industrial district of Ravenna (Italy). The recent contamination levels were compared with data of previous studies carried out in 1982, in order to assess whether environmental policies and remedial measures reduced sediment pollution. Sedimentary profiles of Cu and Pb were homogeneous along the uppermost 0–10 cm horizon, which corresponded to the sedimentation in the last 30 years. Concentrations of Zn attained a peak (up to 800 mg kg−1 dry weight) in the 0–4 cm sediment horizon, which was assumed to correspond to the last 10–15 years. A wide-spread contamination by Hg was detected in the salt marsh as well as in the main channel with peaks up to 20–40 mg kg−1 dry weight. Nonetheless, recent sediments resulted less contaminated, since Hg discharge from industrial plants ceased about 20 years ago. Contamination levels by Hg values were two orders of magnitude higher than the international sediment quality standards. Cadmium, which was analysed for the first time in 2000–2002, attained a peak in the surface layers (1–2.5 mg kg−1 d.w.), with a progressive decline along the sediment column. Through comparison with pre-industrial values detected in the deeper sediment horizons (before 1920), Hg showed the highest enrichment factor, up to 300 times. Cd and Zn concentrations in recent sediments were from 2 to 10 times higher than background values. In terms of possible adverse effects, Hg posed the highest risk, and Cd and Zn were frequently above the recommended thresholds. [ABSTRACT FROM AUTHOR]

The results of a comprehensive study of submerged paleoenvironments developed along the karstified eastern Adriatic coast during the Late Quaternary are presented in this study. The Lošinj Channel is a drowned karst basin filled with sediments. A multi-proxy analysis of two sediment cores (LK-12 and LK-15) recovered from water depths of 62 and 64 m was conducted. We used magnetic susceptibility, grain size, mineralogy, XRF core scanning, organic and inorganic carbon, total nitrogen, and paleontological data, supplemented with AMS 14C dating results and high-resolution seismic data, to reconstruct the infill history of the Lošinj basin during the Late Pleistocene and Holocene. Our findings include the first detailed description of the presumed Marine Isotope Stage (MIS) 5a marine sediment succession along the eastern Adriatic coast. Deposition in the brackish-to-freshwater lacustrine body (Lošinj paleolake) occurred during MIS 3. Sea level lowstand that followed caused the formation of environmental conditions typical of a karst polje. The post-Last Glacial Maximum (LGM) sea level rise led to the establishment of a brackish marine lake with seawater seepage through the karstified sill at 13.7 cal kyr B.P. The transition to the present-day marine conditions commenced at 10.5 cal kyr B.P. Paleoenvironmental changes in the investigated area can be linked to the presence of a sill at −50 m depth that separates the Lošinj basin from the Kvarnerić Bay. The sill depth determines the isolation or inundation of the investigated basin in response to the changes in sea level. Paleoenvironments reacted sensitively to these changes, and therefore, the study area represents an ideal setting to track regional sea level and climate variabilty. • A paleoenvironmental sedimentary record has been preserved in a silled karst basin in the eastern Adriatic. • Sedimentary successions alternated in the karst basin due to the Late Quaternary sea level fluctuations and sill depth. • The karst basin was occupied by marine and lake environments and karst poljes probably since MIS 5a. • The first sedimentary evidence of an isolated lacustrine MIS 3 environment in the Adriatic Sea is reported. [ABSTRACT FROM AUTHOR]

The sources and depositional history of polycyclic aromatic hydrocarbons (PAHs) and organochlorine compounds (OCs) over the last century were investigated in sediment cores from the North Adriatic Sea (Po River prodelta) and the South-Western Adriatic Margin (SWAM). Contaminant concentrations were higher in the Po River prodelta. ∑ 16 PAHs ranged from 193 to 533 ng g−1, ∑ 5 PCBs ranged from 0.9 to 5.2 ng g−1 and ∑DDTs (p,p′- DDD + p,p′- DDE) ranged from 0.1 to 2.5 ng g−1. In the SWAM, ∑PAHs ranged from 11 to 74 ng g−1 while ∑PCB and ∑DDT concentrations were close to the MQL. Accordingly, contaminant fluxes were much higher in the northern (mean values of 152 ± 31 ng cm2 y−1 and 0.70 ± 0.35 ng cm2 y−1 for PAHs and OCs, respectively) than in the southern Adriatic (2.62 ± 0.9 ng cm2 y−1 and 0.03 ± 0.02 ng cm2 y−1 for PAHs and OCs, respectively). The historical deposition of PAHs seemed to be influenced by the historical socioeconomic development and by changes in the composition of fossil fuel consumption (from petroleum derivatives to natural gas) in Italy from the end of the 19th century to the present. Similarly, vertical variations in DDT concentrations matched its historical use and consumption in Italy, which started around in the mid-late 1940s to fight typhus during the II World War. Contaminant concentrations detected in sediments does not seem to pose ecotoxicological risk for marine organisms in the Adriatic Sea. • Unprecedented data of historical deposition of contaminants in the SWAM were assessed. • The first use of DDT in Italy followed the typhus epidemics during the II World War. • Concentrations of PCB and DDT decreased after 1980 due to international restrictions. • Historical variation of PAHs seem to follow shifts in energy production in Italy. • The deep Adriatic basin represents as an important repository for contaminants. [ABSTRACT FROM AUTHOR]