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A dicationic diradical has been synthesized from the N,N′- trans-1,4-cyclohexylene bridged bis-NHC–CAAC dimer.

Herein we report the development of a new methodology for the synthesis of various quinodimethane derivatives under two-electron oxidation of bis-Nheterocyclic olefins linked by different pi-conjugated aromatic spacers. In case of paraand ortho-phenylene bridge, we obtained air and moisture stable diimidazolium paraand ortho-quinodimethane derivatives. Analogues of the para-phenylene spacer such as tetrafluoro-p-phenylene and p-anthracene also led to the corresponding air and moisture stable quinodimethane derivatives. This emphasizes the influence of imidazolium substituents which facilitate the air and moisture stability of the quinodimethane derivatives. Differences were observed for the electron transfer processes: two one-electron vs one two-electron redox transitions between bis-N-heterocyclic olefins and diimidazolium-quinodimethanes depending on the employed pi-conjugated aromatic spacer. The formation of the pi-conjugated radical-cations, transient redox intermediates between bis-N-heterocyclic olefins and diimidazolium-quinodimethanes, was addressed by an EPR investigation.

Herein, a new type of carbodicarbene (CDC) comprising two different classes of carbenes is reported; NHC and CAAC as donor substituents and compare the molecular structure and coordination to Au(I)Cl to those of NHC-only and CAAC-only analogues. The conjugate acids of these three CDCs exhibit notable redox properties. Their reactions with [NO][SbF6] were investigated. The reduction of the conjugate acid of CAAC-only based CDC with KC8 results in the formation of hydrogen abstracted/eliminated products, which proceed through a neutral radical intermediate, detected by EPR spectroscopy. In contrast, the reduction of conjugate acids of NHC-only and NHC/CAAC based CDCs led to intermolecular reductive (reversible) carbon–carbon sigma bond formation. The resulting relatively elongated carbon–carbon sigma bonds were found to be readily oxidized. They were, thus, demonstrated to be potent reducing agents, underlining their potential utility as organic electron donors and n-dopants in organic semiconductor molecules.

Herein, we report tethered cyclic(alkyl)(amino)carbene (CAAC) dimers in which two CAAC-motifs are connected by an ethylene-, trans-1,2-cyclohexylene- and propylene-spacer through their N-centres. The 1-electron oxidized radical cations are isolable, whereas a significant influence of the bridging unit on the chemical reactivity becomes apparent in and with the 2-electron oxidized products.

Herein we report secondary pyrrolidin-2-ols as a source of cyclic (alkyl)(amino)carbenes (CAAC) for the synthesis of CAAC-Cu-I-complexes and cyclic thiones when reacted with Cu-I-salts and elemental sulfur, respectively, under reductive elimination of water from the carbon(IV)-center. This result demonstrates a convenient and facile access to CAAC-based Cu-I-salts, which are well known catalysts for different organic transformations. It further establishes secondary alcohols to be a viable source of carbenes-realizing after 185 years Dumas' dream who tried to prepare the parent carbene (CH2) by 1,1-dehydration of methanol. Addressed is also the reactivity of water towards CAACs, which proceeds through an oxidative addition of the O-H bond to the carbon(II)-center. This emphasizes the ability of carbon-compounds to mimic the reactivity of transition-metal complexes: reversible oxidative addition and reductive elimination of the O-H bond to/from the C(II)/C(IV)-centre.

Correction for ‘Tethered CAAC–CAAC dimers: oxidation to persistent radical cations and bridging-unit dependent reactivity/stability of the dications’ by Mithilesh Kumar Nayak et al., Chem. Commun., 2021, 57, 1210–1213, DOI: 10.1039/D0CC07385G.

This work presents a stepwise reversible two‐electron transfer induced hydrogen shift leading to the conversion of a bis‐pyrrolinium cation to an E‐diaminoalkene and vice versa. Remarkably, the forward and the reverse reaction, which are both reversible, follow two completely different reaction pathways. Establishing such unprecedented property in this type of processes was possible by developing a novel synthetic route towards the starting dication. All intermediates involved in both the forward and the backward reactions were comprehensively characterized by a combination of spectroscopic, crystallographic, electrochemical, spectroelectrochemical, and theoretical methods. The presented synthetic route opens up new possibilities for the generation of multi‐pyrrolinium cation scaffold‐based organic redox systems, which constitute decidedly sought‐after molecules in contemporary chemistry., N,N′ ‐Ethylene bridged bis‐2‐aryl pyrrolinium cations are reported in this work, which (a) undergo stepwise reversible two‐electron reduction coupled two hydrogen transfer to form E‐diaminoalkenes; and (b) have non identical pathways for reduction and oxidation.

PubMed ID: 30256354, Herein we report two different reactivity modes of lithium(aryl)(boryl)amide, 4, when it is reacted with chlorosilanes such as SiCl4 and MeSiHCl2, and chlorophosphine, Ph2PCl. Thus, the reaction of lithium(aryl)(boryl)amide, 4, with MeSiHCl2 leads exclusively to an N-substitution product, 6. On the other hand, the reaction of 4 with SiCl4 and Ph2PCl proceeds completely differently affording exclusively p-aryl-C-substitution products, 5 and 7, respectively. © 2018 The Royal Society of Chemistry., Department of Science and Technology, Ministry of Science and Technology Tata Institute of Fundamental Research, This work was supported by the TIFR Centre for Interdisciplinary Science Hyderabad, India and SERB-DST (EMR/2014/001237), India. V. C. is thankful to the Department of Science and Technology, New Delhi, India, for a National J. C. Bose fellowship. We are thankful to Professor Dr David Scheschkewitz, Saarland University, Saarbrücken, Germany, for facilitating the measurement of elemental analysis for compounds 4 and 7 and for the 7Li{1H} NMR of compound 4. We are also thankful to Professor Dr Biprajit Sarkar, Freie Universität Berlin, Berlin Germany for the elemental analysis for compounds 3, 5, and 6.