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Molasses of foredeeps are important indicators of the newest orogenic uplifts, as well as the source of data on climate and landscape changes. One of the fullest sections of Neogene–Quaternary deposits is studied in valleys of the Belaya, Pshekha, and Psekups rivers at the junction of the Western and Northwestern Caucasus with the Eastern Kuban and Western Kuban foredeeps. The formation of the deposits corresponds to the main evolution stages of the Great Caucasus orogen, as well as the foredeeps. A summary of extensive published and original tectonostratigraphic materials has shown that the lowland and then hilly relief in an axial zone of Western Caucasus existed at least from the Middle Miocene. At the same time, the northern flank of the present-day orogen and the foredeeps were located at sea level and were repeatedly flooded by the seas up to the Kuyalnikian (Piacenzian–Gelasian) time, and the Western Kuban Foredeep was flooded even later. The main data on stratigraphy of the upper molasses and Pliocene–Quaternary tectonic movements of the region are based on facies analysis and bio- and magnetostratigraphic studies of the Upper Pliocene–Lower Pleistocene Belorechensk Formation. Its sedimentation started at the beginning of the Kuyalnikian as a result of an increase in the energy of mountain rivers due to the uplift of the riverheads. It is stated that the minimum average rate of uplift of the Western Caucasus in the basin of the Belaya River is 0.8 mm/year over last 4 mln years with acceleration up to 1.7 mm/year from the beginning of the Calabrian. The Belorechensk Formation includes three subformations, which successively become coarser clastic and correspond to the main stages of the accumulation of upper molasses in the Late Pliocene and Early Pleistocene during the intensification of uplifts and landscape-climate changes of Western Caucasus and Ciscaucasia. [ABSTRACT FROM AUTHOR]

The current crustal stress field is of key importance to understand geodynamic processes and to assess stability aspects during subsurface usage. To provide a 3-D continuous description of the stress state, linear elastic forward geomechanical-numerical models are used. These models solve the equilibrium of forces between gravitational volume forces and surfaces forces imposed mainly by plate tectonics. The latter are responsible for the horizontal stress anisotropy and impose the inverse problem to estimate horizontal displacement boundary conditions that provide a fit best to horizontal stress magnitude data within the model volume. However, horizontal stress magnitude data have high uncertainties and they are sparse, clustered and not necessarily representative for a larger rock volume. Even when Bayesian statistics are incorporated and additional stress information such as borehole failure observations or formation integrity test are used to further constrain the solution space, this approach may result in a low accuracy of the model results, that is the result is not correct. Here, we present an alternative approach that removes the dependence of the solution space based on stress magnitude data to avoid potential low accuracy. Initially, a solution space that contains all stress states that are physically reasonable is defined. Stress magnitude data and the additional stress information are then used in a Bayesian framework to evaluate which solutions are more likely than others. We first show and validate our approach with a generic truth model and then apply it to a case study of the Molasse foreland basin of the Alps in Southern Germany. The results show that the model's ability to predict a reliable stress state is increasing while the number of likely solutions may also increase, and that outlier of stress magnitude data can be identified. This alternative approach results in a substantial increase in computational speed as we perform most of the calculations analytically. [ABSTRACT FROM AUTHOR]

Copyright of Hydrogeology Journal is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Highly saline lithium-rich hydrothermal fluids (measured chloride concentration up to 44 g kg−1, lithium concentration up to 162 mg kg−1) occur in the deep calcareous Muschelkalk aquifer beneath the northern Alpine foreland (Molasse) basin. We have combined geologic, hydraulic, hydrochemical, and stress field data of the Triassic Muschelkalk aquifer beneath younger sediments of Triassic–Jurassic successions and the Cenozoic Molasse basin of SW-Germany for a synthesis to constrain the origin and development of these brines. In contrast to the regional southeast plunge of Jurassic and Cenozoic strata, low-gradient groundwater flow in the Upper Muschelkalk aquifer is to the north, induced by regional recharge from west, south, and east. The investigated area is seismically active and north trending maximum horizontal stress likely fosters development of necessary fracture permeability for northward flow in the competent carbonates of the Upper Muschelkalk aquifer. The highest lithium concentrations and total dissolved solids (TDS) can be found in the southern parts of the Muschelkalk aquifer. Here, the Muschelkalk Group overlays directly a crystalline basement swell separating two ENE-trending Permocarboniferous troughs. We argue that the highly saline lithium-rich fluids originate from fluid–rock interaction of meteoric water with Variscan crystalline basement rocks and entered the Muschelkalk aquifer on top of the basement swell by permeable faults and fractures. The marginal calcareous sand-rich facies of the Muschelkalk enables the inflow of brines from crystalline basement faults and fractures into the aquifer. We thus argue for an external origin of these brines into the aquifer and further intra-reservoir development by dilution with meteoric water. [ABSTRACT FROM AUTHOR]

The biomethane accumulation of several combinations of whey and sugarcane molasses, inoculated with sludge from a treatment facility of one of the dairy enterprises of the Imbabura province in Ecuador, was assessed in the current experiment at a constant COD0/VSin ratio of 0.5. The whey/molasses (W:M) ratios for each treatment were (in % (m/m)) 0:100, 25:75, 50:50, 75:25, and 100:0, with a constant temperature of 37 °C and an initial pH adjustment of 7.5. Half a litre of total mixes was used for each treatment in duplicate. Six kinetic models were evaluated to account biomethane accumulation in anaerobic co-digestion processes in batch of whey and sugarcane molasses. Five of these have been tested by other researchers, and one was developed by modifying a first-order model to consider changes in the biomethane accumulation profile. This proposed model, along with the modified two-phase Gompertz model, resulted in the ones that were best able to adjust the experimental data, obtaining in all cases an R2 ≥ 0.949, indicating the accuracy of both models. In addition, the proposed here model has five parameters, one less than the modified two-phase Gompertz model, making it more straightforward and robust. [ABSTRACT FROM AUTHOR]

The quality of geothermal carbonate reservoirs is controlled by, for instance, depositional environment, lithology, diagenesis, karstification, fracture networks, and tectonic deformation. Carbonatic rock formations are thus often extremely heterogeneous, and reservoir parameters and their spatial distribution difficult to predict. Using a 3D seismic dataset combined with well data from Munich, Germany, we demonstrate how a comprehensive seismic attribute analysis can significantly improve the understanding of a complex carbonate reservoir. We deliver an improved reservoir model concept and identify possible exploitation targets within the Upper Jurassic carbonates. We use seismic attributes and different carbonate lithologies from well logs to identify parameter correlations. From this, we obtain a supervised neural-network-based 3D lithology model of the geothermal reservoir. Furthermore, we compare fracture orientations measured in seismic (ant-tracking analysis) and well scale (image log analysis) to address scalability. Our results show that, for example, acoustic impedance is suitable to identify reefs and karst-related dolines, and sweetness proves useful to analyse the internal reef architecture, whereas frequency- and phase-related attributes allow the detection of karst. In addition, reef edges, dolines, and fractures, associated with high permeabilities, are characterized by strong phase changes. Fractures are also identified using variance and ant tracking. Morphological characteristics, like dolines, are captured using the shape index. Regarding the diagenetic evolution of the reservoir and the corresponding lithology distribution, we show that the Upper Jurassic carbonate reservoir experienced a complex evolution, consisting of at least three dolomitization phases, two karstification phases, and a phase of tectonic deformation. We observe spatial trends in the degree of dolomitization and show that it is mainly facies-controlled and that karstification is facies- and fault-controlled. Karstification improves porosity and permeability, whereas dolomitization can either increase or decrease porosity. Therefore, reservoir zones should be exploited that experienced only weak diagenetic alteration, i.e. the dolomitic limestone in the upper part of the Upper Jurassic carbonates. Regarding the fracture scalability across seismic and well scales, we note that a general scalability is, due to a combination of methodological limitations and geological reasons, not possible. Nevertheless, both methods provide an improved understanding of the fracture system and possible fluid pathways. By integrating all the results, we are able to improve and adapt recent reservoir concepts, to outline the different phases of the reservoir's structural and diagenetic evolution, and to identify high-quality reservoir zones in the Munich area. These are located southeast at the Ottobrunn Fault and north of the Munich Fault close to the Nymphenburg Fault. [ABSTRACT FROM AUTHOR]

The Tramelan-2 borehole (Canton Bern, Switzerland) continuously cored a 275.60 m sequence of Palaeogene to Neogene sediments, providing a rare opportunity for sedimentological analysis of the Jura Molasse. Lithostratigraphy, sedimentary facies and heavy minerals allow correlation with the classical Swiss Molasse. Evidence for clastic input from Alpine and non-Alpine sources is consistent with deposition at the northern feather edge of the Molasse Basin. Grey sandstones at the base of the succession are tentatively interpreted as fluvial facies of the Lower Freshwater Molasse (USM). These are overlain by erosively-based conglomerates, interpreted as winnowed storm lags of locally-derived clasts and distantly-sourced Alpine material at the transgressive base of the Upper Marine Molasse (OMM). Above this, a range of plane-laminated and cross-bedded bioclastic sandstones are interpreted as the deposits of a meso- or macrotidal flat or estuarine complex. Facies evolution in the upper OMM records a series of stacked regressive cycles within an overall upward trend of reducing current energy, reflecting a transition from offshore to nearshore shallow marine environments. The unconformably overlying Upper Freshwater Molasse (OSM) passes upwards from micaceous siltstones and marls into a series of freshwater carbonates, dominated by lacustrine limestones which are arranged in repeated regressive cycles, each capped by organic-rich horizons. The middle part of the carbonate interval comprises palustrine limestones with pedogenetic fabrics recording periodic subaerial exposure. Stable isotope signatures from the palustrine facies reflect subaerial pedogenetic overprint, while the lacustrine carbonates record cyclical variations in δ13C which may reflect increases in organic material during progressive lake fill and/or an increased influence of aquifer waters during flooding events. The Jura Molasse onlapped a Mesozoic carbonate pediment hosting a regional karst system which remained active at least until the Burdigalian transgression on footwall highs bounding the Delémont Basin, and locally into the Langhian near Tramelan. This configuration controlled subsequent deposition of OSM carbonates which onlapped erosional and potentially early tectonic relief, and were deposited in groundwater-fed seasonal lacustrine/palustrine environments, where the karstic aquifer controls on seasonal hydrology appear to have been comparable to Caribbean freshwater carbonate wetland systems today. [ABSTRACT FROM AUTHOR]

The Amer Belt, hosting eleven informal formations of the Amer supergroup, is proposed as type area for four regional Paleoproterozoic sequences (Ps1–Ps4) in central Rae Craton, western Churchill Province. The ca. 1.9–1.865 Ga Snowbird orogeny (DP1) affected only Ps1–Ps3, whereas the ca. 1.87–1.81 Ga Hudsonian orogeny (DP2) affected all four. Sequence Ps1 Ayagaq Lake formation (<2.3 Ga quartzite) initiates as schistose basal polymict orthoconglomerate unconformably overlying paleoweathered Neoarchean rocks. It transitions upward to lower Ps2 Resort Lake formation: gossanous, recessive, graphitic, pyritic-metalliferous phyllite (Re–Os age: 2126 ± 24 Ma). Ps2 conductors beneath the <1.74 Ga Thelon formation have been drilled for unconformity-related uranium. Gradationally overlying siliceous dolomitic marble (Aluminium River formation) completes Ps2. The gradationally overlying lower Ps3 is either foliated calcareous tholeiitic basalt (Five Mile Lake formation) or grey phyllite (Three Lakes formation). These lateral equivalents host strong linear aeromagnetic markers. The Oora Lake formation foliated feldspathic calcareous sandstone gradationally overlies only the Three Lakes formation and underlies the upper Ps3 Showing Lake formation (interbedded phyllite and foliated calcareous arkose) whose two arkose members host laterally continuous disseminated uraninite + magnetite forming linear aeromagnetic markers. Pristine sequence Ps4 molasse, deposited and weakly deformed during DP2, comprises four formations of rhythmically interbedded, deep maroon to pink and green, feldspathic-lithic arenite, conglomerate, and mudstone that unconformably overlie and include clasts of DP1-deformed Ps1–Ps3 + Neoarchean basement. Ps4 detrital zircon (3.05–1.90 Ga) suggests local + distal provenance from south Rae and Slave Cratons, and Taltson–Thelon magmatic zone. [ABSTRACT FROM AUTHOR]

The characterization of swelling clays is important for diverse fields, including the field of conservation of built cultural heritage. Villarlod molasse, a building stone utilized frequently across Switzerland, is known to be damaged by swelling clays embedded in its matrix. In this study, the mechanism of how the clays lead to swelling in the stone itself is examined, and similar to previous studies, crystalline swelling is noted as the most likely source. A scaling factor linking X-ray diffraction (XRD) and dilatometric swelling experiments is calculated, and evidence for the existence of an initial monolayer of moisture in the embedded clays at ambient relative humidities is presented. A qualitative micromechanical model describing how the nonswelling stone matrix exerts a pressure on the clay layers, affecting their swelling behavior, is presented. [ABSTRACT FROM AUTHOR]

Collision between Australia and SE Asia began in Sulawesi, the world's eleventh‐largest island, in the Early Miocene and subsequently Neogene sediments were deposited largely in coastal to shelf environments throughout the island. These sediments have been assigned to the Celebes Molasse, previously considered as a single post‐orogenic unit deposited unconformably on pre‐Neogene sedimentary, metamorphic and ophiolitic rocks. The most complete and extensive sequences of Neogene sediments are in the Kendari Basin, situated at the southern end of the SE Arm of Sulawesi, where an outcrop‐based sedimentological study was undertaken to interpret depositional environments, palaeogeography and stratigraphy. The oldest Neogene sediments are shallow marine carbonates and deltaic siliciclastics of the Bungku Formation. They are unconformably overlain by the Upper Miocene Pandua Formation which consists of sediments deposited in a variety of environments including braided river channels, fluvio‐tidal channels, tidal flats, mouth bar complex and shoreface deposits. A Mio‐Pliocene subaerial unconformity separates the marginal marine serpentinite‐rich sediments of the Pandua Formation from the overlying fluviatile quartz‐rich Langkowala Formation. The sediments of the lower part of the Langkowala Formation include conglomeratic channel fill, while the sediments of the upper part are transgressive deposits decreasing in maximum grain‐size, marked by a reduction in channel/overbank ratio and increasing tidal influence. The transgressive Pliocene Eemoiko Formation is characterised by transgressive lags or onlap shell beds and deposits of a landwards‐backstepping carbonate platform. The improved understanding of the Kendari Basin will aid the interpretation of the sedimentation history of frontier basins surrounding SE Sulawesi, many of which have not yet been drilled. [ABSTRACT FROM AUTHOR]

The quality of geothermal carbonate reservoirs is controlled by numerous factors and processes, such as the depositional environment, lithology, diagenesis, karstification, fracture networks, and tectonic deformation. Carbonatic rock formations are thus often extremely heterogeneous, and reservoir parameters and their spatial distribution are therefore difficult to predict. For the example of a 3D seismic dataset combined with well data from Munich, Germany, we demonstrate, how an advanced analysis can deliver an improved reservoir model concept and help to identify possible exploitation targets within the Upper Jurassic carbonates. To identify possible reservoir sections and to understand their above-mentioned controlling factors, we analyse different seismic single- and multi-attributes. Some of the seismic attributes, together with lithology logs from wells, are then used to identify parameter correlations between the seismic attributes and the different carbonate lithologies to obtain a supervised neural network based 3D lithology model of the geothermal reservoir. Furthermore, we compare the fracture orientations measured in seismic (ant-tracking analysis) and well scale (image log analysis), to address scalability. Our results show that, for example, acoustic impedance is well suited to identify reefs and karst-related dolines. Areas with strong karstification or fault- and fracture-related deformation, which are both associated with high permeabilities, are also indicated by e.g. strong frequency attenuation, variance anomalies, and/or morphological features like bowl-shaped structures derived from the shape index. Furthermore, by using sweetness we can reconstruct the reef development of two exemplary reefs, and regarding the lithology distribution, we show that the upper part of the reservoir is dominated by limestone and dolomitic limestone rather than dolomite. In addition, we observe spatial trends in the degree of dolomitization. With respect to the fracture orientations on seismic- and well scales, we point out that a general scalability is not possible due to a combination of methodological limitations and geological reasons. Nonetheless, we argue that the combination of both methods provides an improved overall impression of the fracture systems, and therefore possible fluid pathways. By taking all the results into account, we are able to improve and adapt recent reservoir concepts to outline the different phases of its structural and diagenetic evolution. Furthermore, our results help to identify high quality reservoir zones in the Munich area. [ABSTRACT FROM AUTHOR]

The Bohemian Massif is the relic of a major Paleozoic mountain range that is known to have exhumed and its surface levelled in the Permian, but its Neogene landscape evolution is largely unconstrained. The landscape is characterized by rolling hills and extended planation surfaces above an elevation of about 500 m. However, at lower elevations deeply incised gorges confined by steep hillslopes are abundant and contrast impressively with the low relief landscapes above. Rivers with a bimodal morphology (i.e. steep at lower elevations and gentle at higher elevations) drain either to the north into the Vltava (Moldau) River or to the south into the Danube River. Hence, a continental drainage divide runs through the Bohemian Massif. Here, we quantify spatial characteristics of the Bohemian Massif landforms by computing landscape metrics like steepness index or geophysical relief derived from digital elevation models. From this we infer temporal change of the landscape in the past and predict them for the future evolution of the region. We show that the landscape is characterized by out-of-equilibrium river profiles with knickpoints abundantly at elevations between 450 m and 550 m separating steep channel segments at lower elevations from less steep channels at higher elevations. Hypsometric maxima at or close above knickpoint elevations, along with high and low values in geophysical relief as indicator for the degree of fluvial landscape dissection downstream and upstream of major knickpoints, support the idea of landscape bimodality. Furthermore, we find a distinct drainage divide asymmetry, which causes the reorganization of the drainage network of the region. Across-divide gradients in channel steepness predict the northward migration of the Danube-Vltava drainage divide including growth and shrinkage of tributary catchments, thus controlling changes in the Central European drainage pattern. All aspects suggest that the region experienced relief rejuvenation during the last few million years. We suggest that this relief rejuvenation is related to the inversion of the Molasse basin with a long wavelength rock uplift pattern and low uplift rates. Vertical motion of crustal blocks at discrete faults may locally affect the uplift pattern. However, the contrasting bedrock properties between the sedimentary cover (Molasse sediments) and the crystalline basement (Bohemian Massif) cause substantial differences in erosion rate and are thus the superior control on the topographic variations of the entire region. [ABSTRACT FROM AUTHOR]

Multiple strategies have been used in anaerobic digestion of effluents aiming to enhance the efficiency of the methane (CH 4) recovery process, where co-digestion and the two-stage process emerge as prominent methods. In this context, this study aimed at evaluating the co-digestion of sugarcane vinasse and molasse in a two-stage process using anaerobic fluidized bed reactors (AFBR), verifying the effect of increasing the organic loading rate (OLR) (5–22.5 kg COD.m−3.d−1) and temperature in the second stage methanogenic reactor. Regarding the two-stage process, sugarcane vinasse and molasses fermentation demonstrated the maximum energy potential (E.P) of 57.08 kJ.d−1 (7.5 g COD.L−1). Regarding the methanogenic sequential reactors, organic matter removal reached high values (up to 84.5 % in a thermophilic sequential reactor (TSR); up to 84.5 % in a mesophilic sequential reactor (MSR)). The highest CH 4 yield (MY) of 306.77 ± 38.84 mL CH 4.g−1 COD rem was observed in MSR (9 kg COD.m−3.d−1). Meanwhile, the maximum value of MPR (3.8 ± 0.5 L CH 4.L−1.d−1) was observed in TSR (21 kg COD.m−3.d−1). Regarding the Archaea domain, a predominance of hydrogenotrophic microorganisms could be identified, in which the genera Methanobacterium and Methanothermobacter were the most abundant in MSR and TSR, respectively. This study demonstrates that anaerobic digestion of sugarcane vinasse and molasses enhances anaerobic treatment using two-stage AFBRs. It not only produces CH 4 but also generates hydrogen and high-value products through an acidogenic reactor. This research marks a significant advancement in managing sugarcane processing by-products, offering promising approaches to maximize biogas production and improve pollutant removal efficiency. [Display omitted] • Sugarcane vinasse and molasse co-digestion was evaluated in two-stage reactors. • Mesophilic process increased the energy potential by 21.62 % at < 15 g COD.L−1. • The highest methane (CH 4) yield was 306.8 mL CH 4.g−1COD in process at 30 °C. • Increasing substrate concentration decreased CH 4 yield by up to 112 %. • Methanobacterium and Methanothermobacter were the most abundant in co-digestion. [ABSTRACT FROM AUTHOR]

Reconstructing the evolution of foreland basins that experienced late exhumation is challenging due to an incomplete sedimentary record. Thermochronometry has been applied successfully to reconstruct basin evolution, but the method is subject to uncertainties. For the Swiss Molasse Basin, a wide range of exhumation magnitude and timing has been proposed based on thermochronometry. We aim to reduce uncertainty by dating larger numbers of grains and samples, to obtain statistically more robust data. New apatite (U-Th-Sm)/He (AHe) data from a single borehole shows ages of 4 to 30 Ma in the upper 500 meters and ages of 3 to 80 Ma below 1300 meters. This is counterintuitive as a total reset is expected at depths exceeding approximately 600 m. To arrive at a single consistent thermal history including our and previously published data, we conduct thermal modeling with different software. In particular we test the influence of different provenance histories and distinguish between cooling associated with changes in heat flow vs changes in exhumation. We determine 1050 m +/- 100 m of exhumation, starting slowly at 13 Ma and accelerating at 9 Ma. Coinciding with exhumation, heat flow begins to rise sharply, causing heating until 5 Ma, despite ongoing exhumation. We show that this discrepancy between start of exhumation and start of cooling is the main reason for differing estimates for the burial and exhumation history of the basin. We suggest that the remaining misfit between modeled and measured Molasse AHe ages can be explained by post-Miocene hydrothermal flux in the Neogene sediment fill above a sealing layer, potentially the Middle Jurassic claystones or Triassic evaporites. In summary, we show that a single consistent model for basin exhumation relies on large sets of grains and samples, as well as inclusion of provenance ages in the models. With timing of the main exhumation phase constrained to start at 9 Ma, we can rule out a 5 Ma climatic event as exhumation driver. As the region is not affected by extensive faulting, deep seated processes related to mantle dynamics remain as exhumation driving process. [ABSTRACT FROM AUTHOR]

Copyright of BHM Berg- und Hüttenmännische Monatshefte is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The Upper Jurassic carbonates are the prime target for deep geothermal exploration in the Molasse basin, South Germany. The carbonates have a thickness of over 500m (1640 ft) and consist of two major facies: (1) bedded marly limestone and (2) massive limestone and dolostone. The massive limestone facies is composed of sponge-microbial biohermal buildups It is considered the main geothermal reservoir facies. Only this facies type may be (1) karstified, (2) dolomitized, and/or (3) faulted and fractured, and therefore can yield very high flow rates of >100 l/sec = 26 gps. The main data source used in this study is the 3D seismic survey of the Freiham geothermal field in the western part of Munich/Germany. Blended in were cutting logs to describe the lithology from 2 wells and borehole image logs from the two geothermal wells. Lithologies derived from these wells were upscaled in support of the seismic interpretation. The study presents an integrated workflow of 3D seismic attribute analysis to analyze the distribution and quantification of reservoir facies (massive limestone) versus non-reservoir facies (bedded marly limestone) per time slice. The attribute "sum of magnitude" is mapped for 9-time slices based on the vertical resolution of the Freiham 3D cube. The seismic facies interpretation is compared with upscaled borehole image facies associations of two geothermal wells. BHI log data is calibrated with an interpretation of the depositional environment based on cutting analysis Reservoir geometries were derived from an outcrop analog study to better understand the 3D seismic facies interpretation and to construct the conceptual depositional model of the Upper Jurassic carbonates. This technique is commonly used in hydrocarbon exploration but is not yet adapted to geothermal projects, which are often based on little data, smaller company sizes, tight budgets, and limited access to specialized geomodelling software and experience. The approach of using 3D seismic attribute analysis presented in this study provides a quantitative subsurface model of geothermal reservoir facies in the Freiham geothermal field. It is quick and straightforward and can easily be applied in the exploration workflow for similar fields and reservoirs. [ABSTRACT FROM AUTHOR]

CERN (Conseil Européen pour la Recherche Nucléaire) is the world's largest research centre for high‐energy and particle physics. The research infrastructure contributed to the greatest successes in the field of experimental physics. A new, approximatively 91 km long subsurface infrastructure connected to the existing particle accelerator complex is being conceived in the frame of the Future Circular Collider. It would serve a global community of researchers with two subsequently operated particle colliders until the end of the 21st century. Even at an early stage of such a project, comprehensive investigations have to be carried out into the nature of the subsoil in order to find an optimal utilisation strategy for the excavated material in accordance with the national and international regulations in order to promote the recycling of excavated tunnel material in terms of resource conservation and the improvement of the sustainability of underground construction projects. [ABSTRACT FROM AUTHOR]

Late brittle extension is a common feature in orogenic belts, and its role in mountain building processes is still the subject of debate. Its timing relationship with crustal thickening, the building of topography, basin infill, and rock exhumation are of key importance in determining whether it is a major factor in orogenic development or merely causes near-surface secondary effects. We examined this question in relation to the active arc-continent collision of Taiwan, studying its structural evolution by integrating new and critical geochronological results for tensile vein filling of hinterland metamorphic terrane with syn-collision deposition records. Acceleration of rock exhumation and molasse deposition was found to be coeval with the initiation of brittle tensile structures at ca. 1.6 Ma, which was long overdue as continental subduction started well before 6.5 Ma in central to northern Taiwan. The topographic mountain of Taiwan was thus constructed when the upper crust of the thickened orogenic prism turned extensional, as orographic elevation and relief are prerequisites for molasses production. Syn-collisional brittle extension is therefore proposed as a possible facilitator of both augmented extrusive exhumation and the formation of orography. [ABSTRACT FROM AUTHOR]

The Late Cretaceous orogeny followed by the Eocene collision of the Adriatic with the European plate dissected the Northern Calcareous Alps (NCA) by a number of well-studied strike-slip fault systems accommodating N-S shortening and E-W stretching. However, the post-Miocene fault activity is poorly constrained due to lack of Neogene faulted sediments, and glacial erosion of geomorphic indicators. Using the protected environment of caves, we fill the knowledge gap in the post-Miocene evolution of the NCA by paleostress analysis of 172 reactivated faults that offset passages in 28 caves near major faults. Constrained maximum age of caves, our results indicate that the NCA have been subjected to N to NE trending compression since Pliocene. Faulted speleothems dated with 230Th/U method, indicate that the recorded present-day stress state did not significantly change during the last 0.5 Ma. In contrast to the previously proposed post-Miocene N-S extension of NCA, but in agreement with what was observed in Vienna and Pannonian basins, we conclude that the eastward extrusion resulting from N-S convergence has continued despite a distinct slowdown of plate tectonic velocities in the late Miocene. The N-S extension affected only the Alpine front during Pliocene Molasse basin inversion, while at the scale of the Alpine orogen the NCA underwent successive N-S shortening and E-W stretching. [ABSTRACT FROM AUTHOR]

More than 30% of Germany's final energy consumption currently results from thermal energy for heating and cooling in the building sector. One possibility to achieve significant greenhouse gas emission savings in space heating and cooling is the application of aquifer thermal energy storage (ATES) systems. Hence, this study maps the spatial technical potential of shallow low-temperature ATES systems in Germany. Important criteria for efficient ATES operation considered in this assessment encompass suitable hydrogeological conditions, such as aquifer productivity and groundwater flow velocity, and balanced space heating and cooling demands. The latter is approximated by the ratio of heating and cooling degree days, which is incorporated as a time-dependent criterion to also evaluate the impact of climate change on the ATES potential. The hydrogeological and climatic criteria are combined within a spatial analysis revealing that, regarding the upcoming decades, about 54% of the investigated German area are very well or well suitable for ATES applications, largely concentrating on three regions: the North German Basin, the Upper Rhine Graben and the South German Molasse Basin. Considering time-dependent climatic conditions, the very well or well suitable areas will increase by 13% for the time period 2071–2100. This is mostly caused by a large relative area increase of the very well suitable regions due to an increasing cooling demand in the future. The sensitivity of the very well and well suitable regions to the criteria weightings is relatively low. Accounting for existing water protection zones shows a reduction of the country-wide share of very well or well suitable areas by around 11%. Nevertheless, the newly created potential map reveals a huge potential for shallow low-temperature ATES systems in Germany. [ABSTRACT FROM AUTHOR]

We investigated fault gases (helium, radon, CO2) in two seismically active Cenozoic sedimentary basins: (a) Meinweg (in 2015), at a tectonically quiescent horst structure in the Lower Rhine Embayment; and (b) Bodanrück (in 2012; Lake of Constance), in the Molasse Basin and part of the seismically active Freiburg–Bonndorf–Bodensee Fault Zone (FBBFZ). Both study areas were selected because recent "GeoBio-Interactions" findings showed that red wood ants (RWA) are biological indicators of otherwise undetected degassing systems. We combined presence/absence data of RWA nests, their spatial pattern analysis (prototype lines), seismicity and known tectonic settings with soil gas analyses (a total of 817 samples) to unveil geochemical anomalies related to tectonic developments unknown so far. Currently, Meinweg can be considered "no ants land" due to the very low background-level of geogas concentrations. Thus, anomalies (Rn-CO2) weakly trending in NE-SW extension direction emerged. This could probably indicate the onset of (re)activation of the NE-SW-trending (Variscan) structures or the development of new fractures as an aftershock process of the 1992 Roermond earthquake that occurred about 15 km to the west. Results at Bodanrück (three RWA clusters and two RWA-free corridors) revealed degassing patterns in NW-SE and NNE-SSW directions in the clusters corresponding to re-activated and recent strike-slip fault systems. No gas anomalies were found in RWA-free corridors. The RWA nest distribution was shown to be a valuable tool for identifying areas of even actively degassing spotty anomalies caused by macro- and microscale brittle deformation masked by sediment cover. [ABSTRACT FROM AUTHOR]

Most temperature predictions for deep geothermal applications rely on correcting bottom-hole temperatures (BHTs) to undisturbed or static formation temperatures (SFTs). The data used for BHT correction are usually of low quality due to a lack of information and poor documentation, and the uncertainty of the corrected SFT is therefore unknown. It is supposed that the error within the input data exceeds the error due to the uncertainty of the different correction schemes. To verify this, we combined a global sensitivity study with Sobol indices of six easy-to-use conventional correction schemes of the BHT data set of the Bavarian Molasse Basin with an uncertainty study and developed a workflow that aims at presenting a valid error range of the corrected SFTs depending on the quality of their input data. The results give an indication of which of the investigated correction methods should be used depending on the input data, as well as show that the unknown error in the input parameters exceeds the error of the individual BHT correction methods as such. The developed a priori uncertainty-based BHT correction helps to provide a real estimate of the subsurface temperatures needed for geothermal prospecting and probabilistic risk assessment. [ABSTRACT FROM AUTHOR]

The Molasse Basin is one of the most promising areas for deep geothermal exploitation in Germany and the target horizon is the aquifer in the Upper Jurassic carbonates. Carbonate deposits can be very heterogeneous even over a small area due to diagenetic processes and varying depositional environments. The preferential targets for geothermal exploitation in carbonate deposits are fault zones, reef facies and karstified areas, since they are expected to act as hydraulically permeable zones due to high porosity and high permeability. Therefore, identifying these structures and characterizing, e.g., their internal porosity distribution are of high importance. This can be accomplished using 3D reflection seismic data. Besides structural information, 3D seismic surveys provide important reservoir properties, such as acoustic impedance, from which a porosity model can be derived. In our study area in Munich we carried out a seismic amplitude inversion to get an acoustic impedance model of the Upper Jurassic carbonate reservoir using a 3D seismic data set, a corresponding structural geological model, and logging data from six wells at the 'Schäftlarnstraße' geothermal site. The impedance model and porosity logs were than used to calculate a porosity model. The model shows a wide porosity range from 0 to 20% for the entire reservoir zone and the lithology along the wells reveals that dolomitic limestone has the highest porosities and calcareous dolomite has the lowest porosities. The study area is cut by a large W–E striking fault, the Munich Fault, and the footwall north of it shows higher porosities and more intense karstification than the hanging wall to the south. Considering the entire study area, an increase in porosity from east to west is observed. Furthermore, we identified a complex porosity distribution in reef buildups and pinnacle reefs. The reef cores have mostly low porosities of, e.g., < 3% and the highest porosities of up to 7 to 14% are observed at the reef caps and on the reef slopes. The reef slopes show a characteristic interfingering of the reef facies with the surrounding bedded facies, which indicates a syn-sedimentary reef development with slightly varying build up growth rates. We also assessed the reservoir quality with regard to porosity distribution and determined areas with moderate to good quality for geothermal exploitation by defining porosity evaluation levels. The porosity evaluation maps show that the carbonate rocks of Berriasian to Malm ζ 1 are preferential targets for exploitation, especially in the footwall of the Munich Fault and to the west of the hanging wall, because these areas are characterized by high porosities due to intense karstification of bedded and massive facies, although the latter is mainly restricted to reef caps and reef slopes. [ABSTRACT FROM AUTHOR]

The paper provides detailed information on the natural radioactivity of sedimentary rocks in the northeastern part of the Moravo-Silesian Palaeozoic Basin in the Bohemian Massif. The studied area is dominated by the Lower Carboniferous flysch sediments belonging to the Horní Benešov, Moravice, and Hradec-Kyjovice formations (from botttom to the top). These three flysch formations consist of siliciclastic sediments, mainly graywackes, siltstones, silty shales, and clay shales, while conglomerates are less abundant. The overlying sediments of the Ostrava Formation (Namurian) occur on the eastern margin of the studied area. The Ostrava Formation has a character of a paralic coal-bearing molasse with alternating beds of sandstone (or arkose), siltstone and claystone. The sediments often have an elevated content of organic matter, concentrating into coal seams. The rocks of the Ponikev Formation (Devonian) occur in a narrow belt in the western part of the studied area. The Ponikev Formation consists mainly of silicites. Potassium, uranium and thorium contents were measured using a laboratory gammaray spectrometer in 1612 rock samples from 672 localities on five map sheets (1: 50 000 scale). The calculated values of mass activity of 226Ra equivalent (am) demonstrate that the natural radioactivity of sedimentary rocks of all three flysch formations is lower or similar to that of the average Earth crust (about 180 Bq.kg-1). The radioactivity of flysch sediments increases with decreasing grain size from psephites (average am is 122 Bq.kg-1) to psammites (144 Bq.kg-1) and to aleurites + pelites (188 Bq.kg-1). Siltstones and claystones with a low organic matter content (226 Bq.kg-1), coaly siltstones and coaly claystones (240 Bq.kg-1), coaly sandstones and arkose sandstones (232 Bq.kg-1), and coal (202 Bq.kg-1) of the Ostrava Formation show slightly higher average am values. The relatively high radioactivity of these sediments is related to the elevated content of uranium (7.9 ppm on average). [ABSTRACT FROM AUTHOR]

Deep geothermal energy has tremendous potential for decarbonizing the heating sector. However, one common obstacle can be the mismatch between geologically attractive regions in the countryside and urban areas with a high heat demand density, which are therefore attractive for district heating systems. In the last years, an increasing number of regions consider the transport of geothermal heat into urban clusters. One example of such a region is the South German Molasse Basin in Upper Bavaria. However, such heat transport pipelines come along with massive upfront investment costs due to the required large pipe diameter and insulation thickness. While the classic concept foresees the use of water as a heat carrier in such long-distance heat transportation pipelines, CO 2 can be an attractive alternative. This study investigates the thermo-economic performance of CO 2 as a heat transport carrier for a potential long-distance heat transmission pipeline with a length of 20 km, which could connect a planned geothermal project in the South of Munich with the existing district heating network of Munich. The results of the base case scenario demonstrate that for both heat carrier options water and CO 2 rather low LCOH for the transport of the heat can be achieved. • A Bavarian case study for long-distance heat transport has been analysed. • CO 2 and water-based systems LCOH are compared to identify the most attractive one. • The cost of the system appears to be dominated by the heat exchangers cost. • The LCOHs of the solutions are comparable but CO 2 -based system is more flexible. [ABSTRACT FROM AUTHOR]

Information about the absolute stress state in the upper crust plays a crucial role in the planning and execution of, e.g., directional drilling, stimulation and exploitation of geothermal and hydrocarbon reservoirs. Since many of these applications are related to sediments, we present a refined geomechanical–numerical model for Germany with focus on sedimentary basins, able to predict the complete 3D stress tensor. The lateral resolution of the model is 2.5 km, the vertical resolution about 250 m. Our model contains 22 units with focus on the sedimentary layers parameterized with individual rock properties. The model results show an overall good fit with magnitude data of the minimum (Shmin) and maximum horizontal stress (SHmax) that are used for the model calibration. The mean of the absolute stress differences between these calibration data and the model results is 4.6 MPa for Shmin and 6.4 MPa for SHmax. In addition, our predicted stress field shows good agreement to several supplementary in-situ data from the North German Basin, the Upper Rhine Graben and the Molasse Basin. [ABSTRACT FROM AUTHOR]

The Jiaojia giant gold deposit is the largest gold deposit in China, with a total gold reserve of approximately 1200 t. Until now, the knowledge of the exhumation history of post-mineralization period is limited, in particular for the low-temperature thermochronology studies of samples below −1000 m. In this work, we combined zircon fission-track (ZFT) and apatite fission-track (AFT) dating of samples between −1100 and −2000 m to determine the post-mineralization cooling and exhumation history of the Jiaojia giant gold deposit. The ZFT ages ranged from 144.2±6.3 to 124.4±5.5 Ma, representing the cooling period and the disturbance of ore-forming fluid. The AFT ages ranged from 28.1±2.6 to 16.2±1.0 Ma, recording the exhumation and cooling processes. With reference to previous low-temperature thermochronology studies in the Jiaojia goldfield, we estimated the exhumation rate and amount of the Jiaojia giant gold deposit and reconstructed its exhumation and preservation history. The exhumation history was divided into four stages, rapid exhumation (~120–95 Ma), relatively slow exhumation (~95–50 Ma), slow exhumation (~50–30 Ma) and relatively rapid exhumation (since 30 Ma). Each stage corresponds to geological events related to the basin-mountain coupling that have occurred since the Cretaceous in the Jiaodong area, namely, a strong tectonic extension and volcanic eruption in the Jiaolai Basin, subsidence of the Jiaolai Basin and Wangshi Group molasse sedimentary, tectonic quiescence, and the Linqu Group basalt eruption of the Jiaobei uplift. Our results show that the exhumation of the Jiaojia giant gold deposit is ~5.2±1.2 km and the orebody erosion degree is relatively low, indicating huge prospecting potential deep in the Jiaojia giant gold deposit. These findings have significance and practical value for deep prospecting in the Jiaodong area. [ABSTRACT FROM AUTHOR]

We present a data set of calcite twinning strain results (n = 209 samples; 9919 measured calcite twins) from the internal Alpine nappes northwestward across the Alps and Alpine foreland to the older extensional margin along the Atlantic coast in Ireland. Along the coast of Northern Ireland, Cretaceous chalks and Tertiary basalts are cross-cut by calcite veins and offset by calcite-filled normal and strike-slip faults. Both Irish sample suites (n = 16 with four U-Pb vein calcite ages between 70–42 Ma) record a sub-horizontal SW-NE shortening strain with vertical extension and no strain overprint. This sub-horizontal shortening is parallel to the margin of the opening of the Atlantic Ocean (~58 Ma), and this penetrative fabric is only observed ~100 km inboard of the margin to the southeast. The younger, collisional Alpine orogen (~40 Ma) imparted a stress–strain regime dominated by SE-NW sub-horizontal shortening ~1200 km northwest from the Alps preserved in Mesozoic limestones and calcite veins (n = 32) in France, Germany and Britain. This layer-parallel shortening strain (−3.4%, 5% negative expected values) is preserved across the foreland in the plane of Alpine thrust shortening (SE-NW) along with numerous outcrop-scale contractional structures (i.e., folds, thrust faults). Calcite veins were observed in the Alpine foreland in numerous orientations and include both a SE-NW layer-parallel shortening fabric (n = 11) and a sub-vertical NE-SW vein-parallel shortening fabric (n = 4). Alpine foreland strains are compared with twinning strains from the frontal Jura Mountains (n = 9; layer-parallel shortening), the Molasse basin (n = 26; layer-parallel and layer-normal shortening), Pre-Alp nappes (n = 39; layer-parallel and layer-normal shortening), Helvetic and Penninic nappes (Penninic klippe; n = 46; layer-parallel and layer-normal shortening plus four striated U-Pb calcite vein ages ~24 Ma) and calcsilicates from the internal Tauern window (n = 4; layer-normal shortening). We provide a chronology of the stress–strain history of the European plate from 58 Ma through the Alpine orogen. [ABSTRACT FROM AUTHOR]

The stratigraphic development of foreland basins has mainly been related to surface loading in the adjacent orogens, whereas the control of slab loads on these basins has received much less attention. This has also been the case for interpreting the relationships between the Oligocene to Micoene evolution of the European Alps and the North Alpine foreland basin or Molasse basin. In this trough, periods of rapid subsidence have generally been considered as a response to the growth of the Alpine topography, and thus to the construction of larger surface loads. However, such views conflict with observations where the surface growth in the Alps has been partly decoupled from the subsidence history in the basin. In addition, surface loads alone are not capable of explaining the contrasts in the stratigraphic development particularly between its central and eastern portions. Here, we present an alternative view on the evolution of the Molasse basin. We focus on the time interval between c. 30 and 15 Ma and relate the basin-scale development of this trough to the subduction processes, and thus to the development of slab loads beneath the European Alps. At 30 Ma, the western and central portions of this basin experienced a change from deep marine underfilled (Flysch stage) to overfilled terrestrial conditions (Molasse stage). During this time, however, a deep marine Flysch-type environment prevailed in the eastern part of the basin. This was also the final sedimentary sink as sediment was routed along the topographic axis from the western/central to the eastern part of this trough. We interpret the change from basin underfill to overfill in the western and central basin as a response to oceanic lithosphere slab-breakoff beneath the Central and Western Alps. This is considered to have resulted in a growth of the Alpine topography in these portions of the Alps, an increase in surface erosion and an augmentation in sediment supply to the basin, and thus in the observed change from basin underfill to overfill. In the eastern part of the basin, however, underfilled Flysch-type conditions prevailed until 20 Ma, and subsidence rates were higher than in the western and central parts. We interpret that high subsidence rates in the eastern Molasse occurred in response to slab loads beneath the Eastern Alps, where the subducted oceanic slab remained attached to the European plate and downwarped the plate in the East. Accordingly, in the central and western parts, the growth of the Alpine topography, the increase in sediment flux and the change from basin underfill to overfill most likely reflect the response to slab delamination beneath the Central Alps. In contrast, in the eastern part, the possibly subdued topography in the Eastern Alps, the low sediment flux and the maintenance of a deep marine Flysch-type basin records a situation where the oceanic slab was still attached to the European plate. The situation changed at 20 Ma, when the eastern part of the basin chronicled a change from deep marine (underfilled) to shallow marine and then terrestrial (overfilled conditions). During the same time, subsidence rates in the eastern basin decreased, deformation at the Alpine front came to a halt and sediment supply to the basin increased possibly in response to a growth of the topography in the Eastern Alps. This was also the time when the sediment routing in the basin axis changed from an east-directed sediment dispersal prior to 20 Ma, to a west-oriented sediment transport thereafter and thus to the opposite direction. We relate these changes to the occurrence of oceanic slab breakoff beneath the Eastern Alps, which most likely resulted in a rebound of the plate, a growth of the topography in the Eastern Alps and a larger sediment flux to the eastern portion of the basin. Beneath the Central and Western Alps, however, the continental lithosphere slab remained attached to the European plate, thereby resulting in a continued downwarping of the plate in its central and western portions. This plate downwarping beneath the central and western Molasse together with the rebound of the foreland plate in the East possibly explains the inversion of the drainage direction. We thus propose that slab loads beneath the Alps were presumably the most important drivers for the development of the Molasse basin at the basin scale. [ABSTRACT FROM AUTHOR]

The Swiss Upper Marine Molasse (OMM) documents a transgression event dated to around 21 to 17 million years in which dolphin and other vertebrate remains have been reported. We revised the whole cetacean (whales and dolphins)OMMassemblage available in main collections, focusing on the identification and interpretation of periotics (bone that contains the inner ear). Periotics are rare, but they provide the richest taxonomic information in the sample and hint to environmental associations. Micro-computerized tomography allowed the reconstruction of bony labyrinths for comparisons and environmental interpretations. Three families are represented by periotics: Kentriodontidae, Squalodelphinidae and Physeteridae. The cetacean taxonomic composition of the Swiss OMM reinforces biogeographical patterns reported for the Mediterranean and Paratethys during the Burdigalian at a regional scale and the Calvert cetacean fauna of the northwest Atlantic at oceanic scale. [ABSTRACT FROM AUTHOR]

We describe here the results of the characterization of subsurface structures in an area of the south-eastern edge of the Bohemian Massif, in Austria by high-resolution geophysical survey techniques and advanced analysis methods of potential fields. The employed methods included potential field multiscale techniques for source-edge location and characterization of sources at depth. Our results confirmed the presence of already known structures: the location of the Diendorf Fault and the Moldanubian Shearzone are clearly recognized in the data at the same location as on the geological maps, even where the Diendorf fault is covered with sediments of the Molasse Basin. In addition, we detected several geological contacts between different rock types in the Bohemian Massif west of the Diendorf Fault. From our results, we were also able to quickly identify and image, without a priori information, previously unknown structures, such as faults with-depth-to-the top of about 500 m and magmatic intrusions about 400 m deep. [ABSTRACT FROM AUTHOR]

The large amount of molasses that are generated in sugar-processing companies are not always redistributed for commercialization in by-products. Because of this, the present research uses these wastes as fuel in low-cost, lab-scale, single-chamber microbial fuel cells. Zinc and copper electrodes were used as electrodes and 100 mL of molasse in the chamber as fuel, managing to generate current and voltage peaks of 1.73 ± 0.13 mA and 0.953 ± 0.142 V. In monitoring the conductivity of the substrate, a maximum peak of 111.156 ± 8.45 mS/cm was observed, and a slightly acidic pH was observed throughout the monitoring. It was possible to obtain a power density of 5.45 ± 0.31 W/cm² for a current density of 308.06 mA/cm², while the yeast count showed a logarithmic curve throughout the monitoring. Finally, the molecular technique identified 100% of the special C. boidinii present in the anodic electrode. This research will give great benefits to sugar companies because they will be able to generate electricity using the molasses that cannot generate by-products. [ABSTRACT FROM AUTHOR]

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The vernacular architecture in many regions in Eastern Austria was characterized by the use of unfired clay, at least until the 19th century, and in some areas until the 20th century. Farmhouses and associated farm buildings, such as storage buildings or press houses for the production of wine and cider, were erected using different earth construction techniques. The study area stretches from the Weinviertel, a region located in the province of Lower Austria in the north-east of Austria, to the Burgenland, a region located in the south-east of Austria, which belonged to Western Hungary until 1921. From a geological point of view, in the east of Austria—in the Vienna Basin and the Molasse Zone—huge areas of Tertiary clay are covered with loess deposits, which is the best-known basic material used in local earth-building traditions. A core question in the research on vernacular earthen heritage focuses on the impact of the geological conditions in Eastern Austria on the local earth-building techniques. The mineralogical composition of the different clays had an impact on the local building techniques. From a material-culture point of view, research on the relationship between the mineralogical properties of clay resources and local building techniques sheds light on the factors which influenced the evolution of certain vernacular building features. Tertiary clays and loess from the Pleistocene favoured the making of earth lumps, cob walls and adobe bricks over the whole Eastern Austrian region. Contrarily, regions in Burgenland with a high amount of gravel preferred, by tradition, to make walls by ramming. The clay mineral smectite acts as a binding agent in earth-building techniques over the whole investigated region—Weinviertel, Burgenland and Western Hungary. [ABSTRACT FROM AUTHOR]

We drilled a 210 m-thick succession of Quaternary sediments and extended it 30 m upsection with information that we collected from an adjacent outcrop. In the 240 m-thick succession we identified 12 different lithofacies, grouped them into five facies assemblages, and distinguished two major sedimentary sequences. A sharp contact at 103 m depth cuts off cross-beds in sequence A and separates them from the overlying horizontal beds in sequence B. Although the lowermost facies assemblage of each sequence includes a till deposited during a period of ice cover, the two tills differ from each other. In particular, the till at the base of sequence A is dominated by large clasts derived from the underlying Molasse bedrock, whereas the till at the base of sequence B has no such Molasse components. Furthermore, the till in sequence A bears evidence of glaciotectonic deformation. Both tills are overlain by thick assemblages of subaqueous, most likely glaciolacustrine and lacustrine facies elements. The cross-bedded and steeply inclined sand, gravel, and diamictic beds of sequence A are interpreted as deposits of density currents in a subaqueous ice-contact fan system within a proglacial lake. In contrast, the lacustrine sediments in sequence B are considered to record a less energetic environment where the material was most likely deposited in a prodelta setting that gradually developed into a delta plain. Towards the top, sequence B evolves into a fluvial system recorded in sequence C, when large sediment fluxes of a possibly advancing glacier resulted in a widespread cover of the region by a thick gravel unit. Feldspar luminescence dating on two samples from a sand layer at the top of sequence B provided uncorrected ages of 250.3 ± 80.2 and 251.3 ± 59.8 ka. The combination of these ages with lithostratigraphic correlations of sedimentary sequences encountered in neighboring scientific drillings suggests that sequence B was deposited between Marine Isotope Stage 8 (MIS 8; 300–243 ka) and MIS 7 (243–191 ka). This depositional age marks the end of one stage of overdeepening–fill in the perialpine Aare Valley near Bern. [ABSTRACT FROM AUTHOR]

Geothermal energy applications are seen as one key element for a successful heat transition in Bavaria. But there are still some barriers for a further development. To minimize these barriers the joint research project Geothermal Alliance Bavaria (GAB) is established. One important issue to foster the implementations of geothermal projects is the assessment of geothermal load prediction in the South German Molasse Basin (SGMB). This includes, aside from a reservoir temperature prognosis, an accurate description of the hydraulic properties of the Upper Jurassic Malm reservoir. Hydraulic test analyses are conducted in the framework of the GAB to obtain specific information about the hydraulic productivity of the reservoir. Results from these analyses show a decrease of rock permeability in southern direction within the reservoir. Because the spatial distribution of hydraulic test data is limited, the porosity of the reservoir is assessed by borehole core tests and logs interpretation. A trend of matrix porosity decrease with depth is recognised and correlates with the hydraulic test results. Based on these findings and combined with further information the Upper Jurassic reservoir could be classified in separated zones of similar production rates, which can now be used for a thermal output prognosis for the Bavarian part of the SGMB. To spatially expand these prognoses more data must be investigated in the next research phase of the GAB. [ABSTRACT FROM AUTHOR]

Based on multi‐scale and multi‐disciplinary measured data, gathered at the Geretsried geothermal site, a 3D reservoir model of the deep and fracture‐controlled Upper Jurassic carbonates in the North Alpine Foreland Basin is generated in this work. An efficient methodology is developed to numerically simulate the coupled reservoir processes of fluid flow, heat transport and thermoporoelastic stresses resulting from possible geothermal doublet operating schemes with cold fluid injection and production profiles in an enhanced naturally fractured reservoir. A variety of numerical experiments is conducted to study the reactivation potential and dilation tendency of the fracture and fault system. Simulation results show the spatiotemporal evolution of the thermoporoelastic stresses and the zone affected after 50 years of geothermal doublet operation. From these simulations, the thermoelastic response of a geothermal doublet operating with 60 °C fluid injection temperature and 20 l/s flow rate translates into a maximum induced thermal stress of around 49.4 MPa near the injection well. In terms of a long‐term reservoir performance and fault and fracture reactivation potential, the findings reveal a negligible risk to a sustainable geothermal doublet operation. [ABSTRACT FROM AUTHOR]

The newly collected shark and ray tooth fossils from the marine sediments of the Upper Marine Molasse close to Allerding (4.8 km SE of Schärding, Austria) allow for a review of the hitherto known diversity comprising a taxonomic update and the documentation of additional taxa. Besides ten taxa already known from the area, the following taxa were collected for the first time from the site: Galeocerdo aduncus Agassiz, 1835, Rhizoprionodon sp., Hemipristis serra Agassiz, 1835, Apristurus sp., Pseudoapristurus nonstriatus Pollerspöck & Straube, 2017, Scyliorhinus sp., Keasius sp., Mitsukurina lineata (Probst, 1879), Odontaspis molassica Probst, 1879, Otodus (Megaselachus) chubutensis (Ameghino, 1901), Chlamydoselachus bracheri Pfeil, 1983, Hexanchidae indet., Paraheptranchias repens (Probst, 1879), Notorynchus primigenius (Agassiz, 1843), Deania sp., Isistius triangulus (Probst, 1879), Euprotomicrus sp., Etmopterus sp., Pristiophorus sp., Nanocetorhinus tuberculatus Underwood & Schlögl, 2013, Raja gen-tili Joleaud, 1912, Rajidae sp. indet., Rhinobatos sp., Aetobatus arcuatus (Agassiz, 1843), and Dasyatis rugosa (Probst, 1877). Fossil teeth of Euprotomicrus represent the first fossil evidence of this taxon ever. Our results indicate a typical Miocene coastal shallow and continental shelf associated diversity. In addition, we reviewed the palaeogeographic distribution ranges of the squaliform genera listed herein to test, if we can identify the origin of specific squaliform genera. [ABSTRACT FROM AUTHOR]

The paper refers to the paleo-ichnology of the Miocene Molasse deposits in the Romanian Carpathians. The principles of systematics and nomenclature of the vertebrate traces from these deposits are briefly presented. Follows a review of the ichno-fossiliferous points in the Carpathians, with a complete inventory of the traces discovered in each ichno-fossiliferous region. In the next chapter, the vertebrate tracks are described and each ichnospecies is illustrated. In the end, the article presents a hypothesis regarding the formation of the flish-like Miocene Molasse deposits having footprints of vertebrates coexisting with mechanical traces generated by strong currents (scour - and tool-marks) but also with wave ripple-marks and traces of rain drops. The present article is actually a synthesis of the papers published in 1961, 1962, 1964, 1965, 1966 and 1968 by N. Panin and N. Panin in collaboration with other researchers. [ABSTRACT FROM AUTHOR]

After more than a century of research, the chronology of the deformation of the external part of the western Alpine belt (France) is still controversial for the Miocene epoch. In particular, the poor dating of the foreland basin sedimentary succession hampers a comprehensive understanding of the deformation kinematics. Here we focus on the Miocene molasse deposits of the northern subalpine massifs, southern Jura, Royans, Bas-Dauphiné, Crest, and La Bresse sedimentary basins through a multidisciplinary approach to build a basin-wide tectono-stratigraphic framework. Based on sequence stratigraphy constrained by biostratigraphical, chemostratigraphical (Sr isotopes), and magnetostratigraphical data between the late Aquitanian (∼ 21 Ma) and the Tortonian (∼ 8.2 Ma), the Miocene molasse chronostratigraphy is revised with a precision of ∼ 0.5 Ma. The Miocene molasse sediments encompass four different paleogeographical domains: (i) the oriental domain outlined by depositional sequences S1a to S3 (∼ 21 to ∼ 15 Ma), (ii) the median domain characterized by sequences S2 to S5 (∼ 17.8 to ∼ 12 Ma), (iii) the occidental domain in which sequences S2a to S8 (∼ 17.8 to ∼ 8.2 Ma) were deposited, and (iv) the Bressan domain where sedimentation is restricted to sequences S6 to S8 (∼ 12 to ∼ 8.2 Ma). A structural and tectono-sedimentary study is conducted based on new field observations and the reappraisal of regional seismic profiles, thereby allowing the identification of five major faults zones (FZs). The oriental, median, and occidental paleogeographical domains are clearly separated by FZ1, FZ2, and FZ3, suggesting strong interactions between tectonics and sedimentation during the Miocene. The evolution in time and space of the paleogeographical domains within a well-constrained structural framework reveals syntectonic deposits and a westward migration of the depocenters, allowing for proposing the succession of three deformation phases at the western Alpine front. (i) The first is a compressive phase (P1) corresponding to thrusting above the Chartreuse oriental thrust (FZ1), which was likely initiated during the Oligocene and rooted east of Belledonne. This tectonic phase generated reliefs that limited the Miocene transgression to the east. (ii) The second is a ∼ WNW–ESE-directed compressive phase (P2) lasting between 18.05 ± 0.25 Ma and ∼ 12 Ma, with thrusts rooted in the Belledonne basal thrust. Thrusts were activated from east to west: the Salève (SAL) and Gros Foug (GF) thrusts and then successively FZ2, FZ3, FZ4, and FZ5. Along two WNW–ESE balanced cross sections the amount of horizontal shortening is of ∼ 6.3 to 6.7 km, corresponding to average shortening rates of ∼ 1.2 km Myr -1 and migration of the deformation toward the west at a rate of ∼ 2.9 km Myr -1. During ∼ 6 Myr, the Miocene Sea was forced to regress rapidly westwards in response to westward migration of the active thrusts and exhumation of piggyback basins atop the fault zones. Phase P2 thus deeply shaped the Miocene paleogeographical evolution of the area and appears as a prominent compressive phase at the scale of the western Alps from the Swiss molasse basin to the Rhodano–Provencal one. (iii) The third is a ∼ 300 m phase of uplift in the Bas-Dauphiné (P3) of probable Tortonian age (∼ 10 Ma), which would have induced southward sea retreat and been coeval with the folding of the Jura in the north and possibly with back-thrusting east of the Chartreuse massif. [ABSTRACT FROM AUTHOR]

Following recent work on the Miocene terrestrial vertebrate fauna of Kutch, we focused on bulk wet screening for microfossils from beds exposed near Tapar (=Tappar) and Pasuda villages in central Kutch (Gujarat), western India. Processing >1500 kg of bulk samples, led to the recovery of diverse rodent remains (nine species, mostly sciurids, rhizomyids, cricetids, and murids) as well as a vespertillionid bat and a possible lorisid for the first time from the Miocene succession of Kutch. This complements the previously described large and megamammal fossils of rhinos, anthracotheres, proboscideans, and ruminants from the same sections. Isolated rodent teeth represent taxa of generally short time ranges and wide distribution that assume considerable biostratigraphic significance. The rodents are similar to contemporaneous species to the north in India and to the west in Pakistan, including the Potwar Plateau. Based on the rodent assemblage, early Late Miocene (>10 Ma) age is assigned to the Tapar and Pasuda localities. The Kutch sample provides a new reference point for detailed comparisons with the better studied Manchar and Siwalik faunas of South Asia but also with broadly contemporaneous faunas from the Murree, Dagshai/Kasauli, and Dharamsala beds of the Outer Himalaya, and the Kargil molasse of Ladakh. [ABSTRACT FROM AUTHOR]

The molasse deposits in the Indus Basin of India-Asia collision zone (Indus Suture Zone) of Ladakh, NW Himalaya, preserve a record of orogenic sedimentation associated with uplift and erosion of the southern margin of Asia in the course of ongoing India–Eurasia collision. Fossils from these continental deposits are scarce but hold important clues to the early history of India-Asia collision. Here we describe a small collection of dental remains of cyprinids, a family of freshwater fishes, from the Late Eocene Liyan Formation exposed in a high altitude (>5000 m) locality in the Indus Suture Zone of Eastern Ladakh. The find assumes significance since, unlike the Liyan Formation, most other molassic deposits of Ladakh rest unconformably over the Ladakh Batholith and are much younger (Late Oligocene/Early Miocene). The Liyan cyprinids, which represent the oldest record of Cyprinidae in India, suggest fluvial connections with contemporary Eocene ecosystems in Mainland Asia where this family originated in the middle Eocene or earlier. Dispersal of cyprinids from the Mainland Asia into the Indus Suture Zone of Ladakh took place from Tibet via alluvial drainage of the paleo-Indus river during floods or high runoff following the India-Asia collision. [ABSTRACT FROM AUTHOR]

The Hauterivian–Barremian series of the Jura Mountains were measured over more than 60 sections along a 200 km long transect between Aix-les-Bains (Savoie Department, France) and Bienne (Bern Canton, Switzerland), which prompted the need for a revision and improvement of the current lithostratigraphic scheme for this stratigraphic interval. A new formation, the Rocher des Hirondelles Formation, is proposed in replacement of the unsuitable Vallorbe Formation, while the Gorges de l'Orbe Formation is formally described. The Gorges de l'Orbe Formation, equivalent to the well-known "Urgonien jaune" facies, consists of two members, namely Montcherand Member and Bôle Member. The Rocher des Hirondelles Formation, equivalent to the "Urgonien blanc" facies, consists of three members, i.e. Fort de l'Écluse Member, Rivière Member and Vallorbe Member. The marly Rivière and Bôle members appear to present time-equivalent lithostratigraphic units, recording a major sedimentological event affecting contemporarily both formations. This study proposes a new sedimentary model opening a new point of view on the long-living controversies about the age of the Urgonian series from the Jura Mountains. The data point to strong diachronic ages of lithostratigraphic units with a late Hauterivian to early Barremian occurrence of the "Urgonian blanc" facies in the Meridional Jura area versus a latest Barremian age in the Central Jura area, reflecting a general progradation of the Urgonian shallow-water carbonate platform from the present-day Meridional Jura area toward external deeper-water shelf environments of the present-day Central Jura area and Molasse basin. [ABSTRACT FROM AUTHOR]

Sand spikes, pin-shaped, carbonate-cemented sandstone bodies of variable size widely interpreted as sedimentary concretions, have been enigmatic for nearly two centuries. We here present a high-energy mechanism for their formation. Two classic sand spike occurrences are found in the North Alpine Foreland Basin of Central Europe and at Mount Signal in southern California, USA. A distinct seismite horizon in Mid-Miocene Molasse sediments of southern Germany, genetically linked with the Ries impact event, exhibits dewatering structures and contains numerous sand spikes with tails systematically orientated away from the Ries crater. Sand spikes at Mount Signal, strikingly similar in shape to those found in Germany, have tails that point away from the nearby San Andreas Fault. Based on their structural and stratigraphic context, we interpret sand spikes as a new type of seismite and a promising tool to identify strong impact-induced or tectonic palaeo-earthquakes and their source regions in the geologic record. Sand spikes, sandstone bodies that have been enigmatic for nearly two centuries, represent a new type of seismite and a promising tool to identify strong impact-induced or tectonic paleo-earthquakes and their source regions in the geologic record. [ABSTRACT FROM AUTHOR]

The Molasse Basin in Southern Germany is part of the North Alpine Foreland Basin and hosts the largest accumulation of deep geothermal production fields in Central Europe. Despite the vast development of geothermal energy utilization projects especially in the Munich metropolitan region, the evolution of and control factors on the natural geothermal field, more specifically the time-varying recharge and discharge governing groundwater and heat flow, are still debated. Within the Upper Jurassic (Malm) carbonate aquifer as the main geothermal reservoir in the Molasse Basin, temperature anomalies such as the Wasserburg Trough anomaly to the east of Munich and their underlying fluid and heat transport processes are yet poorly understood. We delineate the two end members of thermal–hydraulic regimes in the Molasse Basin by calculating two contrasting permeability scenarios of the heterogeneously karstified Malm carbonate aquifer along a model section through the Wasserburg Trough anomaly by means of two-dimensional numerical thermal-hydraulic modelling. We test the sensitivity of the thermal-hydraulic regime with regard to paleoclimate by computing the two Malm permeability scenarios both with a constant surface temperature of 9 °C and with the impact of paleo-temperature changes during the last 130 ka including the Würm Glaciation. Accordingly, we consider the hydraulic and thermal effects of periglacial conditions like permafrost formation and the impact of the numerous glacial advances onto the Molasse Basin. Thermal-hydraulic modelling reveals the effect of recurrent glacial periods on the subsurface targets of geothermal interest, which is minor compared to the effect of permeability-related, continuous gravity-driven groundwater flow as a major heat transport mechanism. [ABSTRACT FROM AUTHOR]

In East Greenland, sedimentation during the Middle Devonian‐earliest Carboniferous interval was characterized by the Old Red Sandstone Molasse Basin deposits. The continental succession recorded folding and intrabasinal unconformities associated with the activation of extensional detachments and core complex formation which post‐dated high‐P granulite facies metamorphism at c. 403 Ma. The extensional collapse responsible for the initiation of the Devonian basin and associated bimodal magmatism must be understood in the context of continued continental convergence during the Early Carboniferous, required by ultrahigh‐pressure metamorphism in North‐East Greenland at c. 355 Ma. Along a small nunatak within the Wordie Gletscher in Payer Land, NE Greenland (lat. 74°N), Precambrian gneisses recording Devonian granulite‐facies metamorphism are in tectonic contact with the molasse deposits along an ESE‐ward dipping thrust fault: the Scotstounhill Thrust. This paper will discuss the role of Devonian contractional structures and contemporaneous extensional faulting and present a new tectonic model that accounts for the exhumation of deep crustal rocks by these coupled mechanisms. [ABSTRACT FROM AUTHOR]