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We report the detection of radio recombination line (RRL) H40α towards 75 sources, with data obtained from ACA (Atacama Compact 7 m Array) observations in the ATOMS (ALMA Three-millimeter Observations of Massive Star-forming regions) survey of 146 active Galactic star-forming regions. We calculated ionized gas mass and star formation rate (SFR) with H40α line emission. The mass of ionized gas is significantly smaller than molecular gas mass, indicating that ionized gas is negligible in the star-forming clumps of the ATOMS sample. The SFR estimated with RRL H40α agrees well with that calculated with the total bolometric luminosity (Lbol) when SFR ≥ 5 M⊙ Myr−1, suggesting that millimetre RRLs could well sample the upper part of the initial mass function and thus be good tracers of SFR. We also study the relationships between Lbol and the molecular line luminosities (L$^{^{\prime }}_{\rm mol}$) of CS J = 2–1 and HC3N J = 11–10 for all the 146 ATOMS sources. The $L_{\rm bol} \!-\! L^{\prime }_{\rm mol}$ correlations of both the CS J = 2–1 and HC3N J = 11–10 lines appear approximately linear and these transitions have success in predicting Lbol similar to that of more commonly used transitions. The Lbol-to-$L^{\prime }_{\rm mol}$ ratios or SFR-to-mass ratios (star formation efficiency) do not change with galactocentric distances (RGC). Sources with H40α emission (or H ii regions) show higher Lbol-to-$L^{\prime }_{\rm mol}$ ratios than those without H40α emission, which may be an evolutionary effect.

The nature of the gas in CO-rich debris discs remains poorly understood, as it could either be a remnant from the earlier Class II phase or of secondary origin, driven by the destruction of icy planetesimals. The aim of this paper was to elucidate the origin of the gas content in the debris discs via various simple molecules that are often detected in the less-evolved Class II discs. We present millimetre molecular line observations of nine circumstellar discs around A-type stars: four CO-rich debris discs (HD 21997, HD 121617, HD 131488, HD 131835) and five old Herbig Ae protoplanetary discs (HD 139614, HD 141569, HD 142666, HD 145718, HD 100453). The sources were observed with the Atacama Large Millimeter/submillimeter Array (ALMA) in Bands 5 and 6 with 1-2'' resolution. The Herbig Ae discs are detected in the CO isotopologues, CN, HCN, HCO$^+$, C2H, and CS lines. In contrast, only CO isotopologues are detected in the debris discs, showing a similar amount of CO to that found in the Herbig Ae protoplanetary discs. Using chemical and radiative transfer modelling, we show that the abundances of molecules other than CO in debris discs are expected to be very low. We consider multiple sets of initial elemental abundances with various degrees of H2 depletion. We find that the HCO+ lines should be the second brightest after the CO lines and that their intensities strongly depend on the overall CO/H$_2$ ratio of the gas. However, even in the ISM-like scenario, the simulated HCO+ emission remains weak as required by our non-detections., 15 pages, 9 figures, 7 tables Accepted for publication in MNRAS

We have performed a molecular line search towards the flaring 6.7-GHz masers G 24.33+0.13, and G 359.6−0.24 using the Australia Telescope Compact Array. We present spectra of the 6.7-GHz class II methanol and 22.2-GHz water masers towards these sources and provide a comparison with other recent flaring events these sources have experienced. We also detect the fourth example of a 23.4-GHz class I methanol maser and the 11th example of a 4.8-GHz formaldehyde maser towards G 24.33+0.13. Alongside these results, we also observe the previously detected ammonia (3,3) emission and report upper limits on the presence of various other cm-wavelength methanol, ammonia, and OH transitions. Our results are consistent with the flaring of G 24.33+0.13 being driven by a variable accretion rate in the host high mass young stellar object.

We present ALMA 3 mm molecular line and continuum observations with a resolution of ~3.5" towards five first hydrostatic core (FHSC) candidates (L1451-mm, Per-bolo 58, Per-bolo 45, L1448-IRS2E and Cha-MMS1). Our goal is to characterize their envelopes and identify the most promising sources that could be bona fide FHSCs. We identify two candidates which are consistent with an extremely young evolutionary state (L1451-mm and Cha-MMS1), with L1451-mm being the most promising FHSC candidate. Although our envelope observations cannot rule out Cha-MMS1 as a FHSC yet, the properties of its CO outflow and SED published in recent studies are in better agreement with the predictions for a young protostar. For the remaining three sources, our observations favor a prestellar nature for Per-bolo 45 and rule out the rest as FHSC candidates. Per-bolo 58 is fully consistent with being a Class 0, while L1448 IRS2E shows no emission of high-density tracers (NH2D and N2H+) at the location of the previously identified compact continuum source, which is also undetected in our observations. Thus we argue that there is no embedded source at the presumptive location of the FHSC candidate L1448 IRS2E. We propose instead, that what was thought to be emission from the presumed L1448 IRS2E outflow corresponds to outflow emission from a nearby Class 0 system, deflected by the dense ambient material. We compare the properties of the FHSC candidates studied in this work and the literature, which shows that L1451-mm appears as possibly the youngest source with a confirmed outflow., 26 pages, 14 figures. Accepted for publication in MNRAS

A new line list for hydronium (H316O+) is computed. The line list is based on a new ab initio dipole moment surface (CCSD(T)/aug-cc-pVQZ) and a new empirical potential energy surface (PES). The empirical PES of H3O+ was obtained by refining an ab initio surface through a global fit to the experimentally determined rovibrational energies collected from the literature covering the ground, $\nu _1^{\pm }$, $\nu _2^{\pm }$, $2\nu _2^{\pm }$, $\nu _3^{\pm }$, and $\nu _4^{\pm }$ vibrational states. The line list covers the wavenumber range up to 10 000 cm−1 (wavelengths $\gt 1 \, \mu$m) and should be complete for temperatures up to T = 1500 K. This is the first comprehensive line list for H3O+ with extensive wavenumber coverage and accurate transitional probabilities. Prospects of detection of hydronium in spectra of Solar system giant planets as well as exoplanets are discussed. The eXeL line list is publicly available from the ExoMol and CDS data bases.

We report observations of molecular line emission toward dense clumps of the WB 673 interstellar filament: WB 668, WB 673, S233–IR, and G173.57+2.43. The observations were done with the 20-m telescope at the Onsala Space Observatory (Sweden). Maps of emission, column densities, and relative abundances of CO, N2H $$^{ + }$$ , CS, HCN, and HNC molecules are presented. It was found that the molecular abundances decrease toward the peaks of molecular hydrogen column densities in the clumps.

6.7 GHz methanol masers are the brightest of class II methanol masers that are regarded as excellent signposts in the formation of young massive stars. We present here a molecular line study of 68 6.7 GHz methanol maser hosts chosen from the MMB catalogue, that have MALT90 data available. We performed (1) pixel-by-pixel study of 9 methanol maser sources that have high signal-to-noise ratio and (2) statistical study taking into account the entire 68 sources. We estimated the molecular column densities and abundances of N$_2$H$^+$(1-0), HCO$^+$(1-0), HCN(1-0) and HNC(1-0) lines. The derived abundances are found to be in congruence with the typical values found towards high mass star forming regions. We derived the column density and abundance ratios between these molecular species as an attempt to unveil the evolutionary stage of methanol maser sources. We found the column density and abundance ratio of HCN to HNC to increase and that of N$_2$H$^+$ to HCO$^+$ to decline with source evolution, as suggested by the chemical models. The HCN/HNC, N$_2$H$^+$/HCO$^+$, HNC/HCO$^+$ and N$_2$H$^+$/HNC ratios of the methanol maser sources are consistent with them being at a later evolutionary state than quiescent phase and possibly protostellar phase, but at an earlier stage than HII regions and PDRs., 17 pages, 53 figures, accepted for publication in MNRAS

Collisions between interstellar gas clouds are potentially an important mechanism for triggering star formation. This is because they are able to rapidly generate large masses of dense gas. Observationally, cloud collisions are often identified in position-velocity (PV) space through bridging features between intensity peaks, usually of CO emission. Using a combination of hydrodynamical simulations, time-dependent chemistry, and radiative transfer, we produce synthetic molecular line observations of overlapping clouds that are genuinely colliding, and overlapping clouds that are just chance superpositions. Molecules tracing denser material than CO, such as NH$_3$ and HCN, reach peak intensity ratios of $0.5$ and $0.2$ with respect to CO in the `bridging feature' region of PV space for genuinely colliding clouds. For overlapping clouds that are just chance superpositions, the peak NH$_3$ and HCN intensities are co-located with the CO intensity peaks. This represents a way of confirming cloud collisions observationally, and distinguishing them from chance alignments of unrelated material., 7 pages, 4 figures, MNRAS accepted

An accurate line list, called XABC, is computed for nitric oxide which covers its pure rotational, vibrational and rovibronic spectra. A mixture of empirical and theoretical electronic transition dipole moments are used for the final calculation of $^{14}\mathrm{N}^{16}\mathrm{O}$ rovibronic $\mathrm{A}\,^2\Sigma^+$ -- $\mathrm{X}\,^2\Pi$, $\mathrm{B}\,^2\Pi$ -- $\mathrm{X}^2\Pi$ and $\mathrm{C}\,^2\Pi$ -- $\mathrm{X}\,^2\Pi$ which correspond to the $\gamma$, $\beta$ and $\delta$ band systems, respectively, as well as minor improvements to transitions within the $\mathrm{X}\,^2\Pi$ ground state. The work is a major update of the ExoMol NOname line list. It provides a high-accuracy NO ultraviolet line list covering the complicated regions where the $\mathrm{B}\,^2\Pi$-$\mathrm{C}\,^2\Pi$ states interact. XABC provides comprehensive data for the lowest four doublet states of NO in the region of $\lambda > 160 ~ \mathrm{nm}$ ($\tilde{\nu} < 63~000~\mathrm{cm}^{-1}$) for the analysis of atmospheric NO on Earth, Venus or Mars, other astronomical observations and applications. The data is available via www.exomol.com., Comment: 13 pages, 14 figures, 2 tables

The GYT line list covering rotational, rovibrational and rovibronic transitions of the mercapto radical SH is presented. This work extends and replaces the SNaSH line list [Yurchenko et al., 2018, MNRAS, 478, 270] which covers the ground (electronic) $X$ $^{2}\Pi$ state only. This extension is prompted by the tentative identification of the ultra-violet features of SH as being of importance in the transmission spectrum of the ultra-hot Jupiter exoplanet WASP-121b [Evans et al., 2018, AJ., 156, 283]. This GYT line list model is generated by fitting empirical potential energy, spin-orbit and electronic angular momenta functions to experimentally measured wavelengths within the $X$ $^{2}\Pi$ and $A$ $^{2}\Sigma^{+}$ states and to the $A$ $^{2}\Sigma^{+}$ - $X$ $^{2}\Pi$ band system using ab initio curves as a starting reference point. The fits are compatible with the quoted uncertainty of the experimental data used of $\sim$ 0.03 - 0.3 cm$^{-1}$. The GYT line list covers wavelengths longer than 0.256 $\mu$m and includes 7686 rovibronic states and 572 145 transitions for $^{32}$SH. Line lists for the $^{33}$SH, $^{34}$SH, $^{36}$SH and $^{32}$SD isotopologues are generated including a consideration of non-Born-Oppenheimer effects for SD. The line lists are available from the CDS (http://cdsarc.u-strasbg.fr) and ExoMol (www.exomol.com) data bases.

The goal of this study is to measure and calculate for the first time the O2-broadening coefficients of ethylene (C2H4) in the 5 µm region. High-resolution Fourier transform spectra were recorded at various pressures for the whole 1750–3000 cm-1 spectral range. Using these spectra, a large set of 590 O2-broadening coefficients was measured for the ν7 + ν8, ν4 + ν8, ν6 + ν10, ν6 + ν7, ν3 + ν10 and ν4 + ν6 bands. The broadening coefficients were measured using a mono-spectrum non-linear least squares fitting procedure of Voigt profiles which appeared to properly model the observed molecular line shapes within the noise level. These coefficients are compared to theoretical results calculated with the semi-classical Robert and Bonamy formalism in which the intermolecular potential includes electrostatic and dispersion energy contributions. These results are generally in satisfactory agreement with experimental data. The average discrepancy 〈 ( ( γ m e a − γ c a l ) / γ m e a ) × 100 〉 and the absolute difference 〈 ( | γ m e a − γ c a l | / γ m e a ) × 100 〉 between the measured and calculated values for 590 lines are (−2.3 ± 8.9)% and (7.3 ± 5.5)%, respectively. The rotational and vibrational dependences of O2-broadening coefficients are examined. The present results of C2H4 O2 and those of C2H4 N2 are used to determine the corresponding C2H4-air system. Comparison between obtained results leads to an average value of the absolute difference of (7.2 ± 5.5)%.

We present a polarimetric investigation of the protoplanetary nebula Frosty Leo performed with the Submillimeter Array. We were able to detect, in the low continuum level (peak at 14.4 mJy beam$^{-1}$), a marginal polarization at $\sim2.6\sigma$. The molecular line investigation based on the CO $J=3\rightarrow2$ emission shows a peak emission of 68.1 Jy beam$^{-1}$ km s$^{-1}$ and the polarization detection in this CO line is also marginal, with a peak at $\sim3.8\sigma$. In both cases, it was therefore not possible to use the electric vector maps (B-field) to accurately trace the magnetic field (B-field) within the PPN. The spatio-kinematic modelling realised with the different velocity channel maps indicates three main structures: a distorted torus accompanied by a bipolar outflow or jet aligned with its axis and a flattened spherical "cap". The comparison of the CO polarization segments with our model suggests that the polarized emission probably arises in the first two components., Comment: 8 pages, Accepted for publication in Monthly Notices of the Royal Astronomical Society