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1. Sign control of circularly polarized luminescence of chiral Schiff-base Zn(<scp>ii</scp>) complexes through coordination geometry changes

Author

Masahiro Ikeshita, Momo Mizugaki, Takahiro Ishikawa, Kana Matsudaira, Maho Kitahara, Yoshitane Imai, and Takashi Tsuno

Subjects
Materials Chemistry, Metals and Alloys, Ceramics and Composites, General Chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials
Abstract

The handedness of circularly polarized luminescence (CPL) of Zn(II) complexes with a chiral Schiff-base ligand can be controlled by coordination geometry changes in solution and in the solid state. The relationships between molecular structure and chiroptical properties were discussed with the results of X-ray diffraction analysis and DFT calculations.

Published
2022
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