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1. Dimethylammonium trichlorocuprate(II): Structural transition, low-temperature crystal structure, and unusual two-magnetic chain structure dictated by nonbonding chloride-chloride contacts

Author

Willett, Roger D., Twamley, Brendan, Montfroolj, Wouter, Granroth, Garrett E., Nagler, Stephen E., Hall, Donavan W., Ju-Hyun Park, Watson, Brian C., Meisel, Mark W., and Talham, Daniel R.

Subjects
Copper compounds -- Chemical properties, Copper compounds -- Magnetic properties, Halides -- Chemical properties, Halides -- Magnetic properties, Chlorides -- Chemical properties, Dichloropropane -- Chemical properties, Chemistry
Abstract

The room-temperature crystal structure of Dimethylammonium trichlorocuprate consisting of a linear chain of [Cu.sup.2+] dimers with unusual magnetic properties is presented. The reported structure has solved the confusion regarding the origins of the magnetic behavior of the compound and gives a convincing example of the importance of two-halide magnetic exchange.

Published
2006

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