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Abstract The South Eastern Desert (SED) of Egypt is one of the most promising areas in Egypt; it is widely explored for exploring the rare earth elements (REEs) and uranium-bearing ores. It is a main part of the Arabian-Nubian Shield (ANS). Therefore, the present study concerns with Sikait-Nugrus area as one of the most prolific sites in this region. The study provides a detailed geological, structural, and mineralogical investigation of the monzogranites to describe and characterize the various alteration types and sequence. For this purpose, remote sensing, geochemical and petrographical techniques were applied. The remote sensing technique helped in constructing a detailed geologic map of the study area to follow up strictly the alteration zone of the Sikait-Nugrus area. Petrographically, the granites predominates in the study area, they are described as slightly and highly altered monzogranites. The slightly altered one is composed mainly of quartz (~ 20–35%), alkali feldspar (~ 25–30%), plagioclase (~ 25–30%), and mica (~ 5–15%), while accessory minerals are represented by zircon and monazite. On the other hand, the portion of this granite close to the shearing zone is intensively altered and characterized by sericitization as the main alteration processes. This sheared portion is characterized by accessory minerals as, uranothorite, allanite, fluorite and Nb-minerals (ishikawaite). Minerlogically, the altered monzogranites are predominated by the following mineral groups: (1) radioactive minerals as uranyl silicates (soddyite, uranophane and kasolite), and thorium minerals (thorite and uranothorite), (2) Nb–Ta minerals (betafite, plumbobetafite, columbite, fergusonite, and aeschynite), (3) REE minerals (monazite, cheralite and xenotime), and (4) zircon and fluorite as accessory minerals. Geochemically, the recorded pattern of the REEs tetrad effect (M-type) for the highly altered samples indicate that these granites are highly evolved and affected by late stage of hydrothermal alteration and the effective water-rich alteration processes that connected to intensive physico-chemical changes. The total REE concentrations equal 241.8 and 249.75 ppm for the highly and slightly altered samples. A significant mass change (MC) was analyzed by the isocon technique (22.95 & 11.11) and volume change (VC) (1.8 &-7.99) for the highly and slightly altered samples, respectively. The mass balance calculations and the isocon diagrams revealed that some major oxides were removed from the slightly altered monzogranites and transformed later into highly altered monzogranites with increasing the alteration intensity due to the impacts of hydrothermal alteration processes. The studied area is virgin, where no detailed studies have been applied to this region. It is extendable to other parts of the Arabian-Nubian Shield in around the Red Sea in Egypt, Sudan, Saudi Arabia and Yemen. The applied technical workflow is also extendible to other surface analogues everywhere.

The South Eastern Desert (SED) of Egypt is one of the most promising areas in Egypt; it is widely explored for exploring the rare earth elements (REEs) and uranium-bearing ores. It is a main part of the Arabian-Nubian Shield (ANS). Therefore, the present study concerns with Sikait-Nugrus area as one of the most prolific sites in this region. The study provides a detailed geological, structural, and mineralogical investigation of the monzogranites to describe and characterize the various alteration types and sequence. For this purpose, remote sensing, geochemical and petrographical techniques were applied. The remote sensing technique helped in constructing a detailed geologic map of the study area to follow up strictly the alteration zone of the Sikait-Nugrus area. Petrographically, the granites predominates in the study area, they are described as slightly and highly altered monzogranites. The slightly altered one is composed mainly of quartz (~ 20–35%), alkali feldspar (~ 25–30%), plagioclase (~ 25–30%), and mica (~ 5–15%), while accessory minerals are represented by zircon and monazite. On the other hand, the portion of this granite close to the shearing zone is intensively altered and characterized by sericitization as the main alteration processes. This sheared portion is characterized by accessory minerals as, uranothorite, allanite, fluorite and Nb-minerals (ishikawaite). Minerlogically, the altered monzogranites are predominated by the following mineral groups: (1) radioactive minerals as uranyl silicates (soddyite, uranophane and kasolite), and thorium minerals (thorite and uranothorite), (2) Nb–Ta minerals (betafite, plumbobetafite, columbite, fergusonite, and aeschynite), (3) REE minerals (monazite, cheralite and xenotime), and (4) zircon and fluorite as accessory minerals. Geochemically, the recorded pattern of the REEs tetrad effect (M-type) for the highly altered samples indicate that these granites are highly evolved and affected by late stage of hydrothermal alteration and the effective water-rich alteration processes that connected to intensive physico-chemical changes. The total REE concentrations equal 241.8 and 249.75 ppm for the highly and slightly altered samples. A significant mass change (MC) was analyzed by the isocon technique (22.95 & 11.11) and volume change (VC) (1.8 &-7.99) for the highly and slightly altered samples, respectively. The mass balance calculations and the isocon diagrams revealed that some major oxides were removed from the slightly altered monzogranites and transformed later into highly altered monzogranites with increasing the alteration intensity due to the impacts of hydrothermal alteration processes. The studied area is virgin, where no detailed studies have been applied to this region. It is extendable to other parts of the Arabian-Nubian Shield in around the Red Sea in Egypt, Sudan, Saudi Arabia and Yemen. The applied technical workflow is also extendible to other surface analogues everywhere. [ABSTRACT FROM AUTHOR]

The Molo‐Sarychat multiphase pluton is situated along the fault systems of the 'Main Structural Line of Tien Shan' (known also as the 'Nikolaev Line'). It comprises mafic to intermediate (monzodiorite, monzonite) and silicic (quartz monzonite, monzogranite and leucogranite‐alaskite) rocks, followed by the late mafic (monzodiorite‐porphyry to lamprophyre) dikes. Isotopic U‐Pb zircon dating of quartz monzonite and monzogranite indicates their Early Permian age (ca. 293 to 286 Ma). The rocks appear to have been produced by remelting of a partially crystallized (mush) magma batch at deeper levels, which is evident by the presence of zircon antecrysts dated at some 306 to 320 Ma. These geochronological data are consistent with a post‐collisional setting of the pluton that occurred after the cessation of subduction, which affected the Middle Tien Shan in the Late Palaeozoic. Geochemical signatures of the igneous rocks from the Molo‐Sarychat pluton correspond to high‐K calc‐alkaline to shoshonitic series intrusions emplaced in a post‐collisional setting. An initial shoshonitic magma was produced by a low‐degree partial melting of the metasomatically enriched upper mantle, with amphibole fractionation in a deep (lower crustal) magma chamber. In this evolution, a generation, under the influence of mantle‐supplied fluids and heat, granitic magmas in the crustal protolith can be suggested, with further mixing/mingling of the mantle‐derived mafic (shoshonitic) magma and mantle‐induced crustal granitic magma, followed by the magma fractionation and emplacement at shallower crustal levels. The skarn‐porphyry Mo‐Cu‐W(‐Au) mineralization associated with the Molo‐Sarychat pluton complements the group of similar deposits associated with high‐K calc‐alkaline to shoshonitic series intrusions in the Middle Tien Shan and globally. The characteristic Mo‐W‐Cu‐Au metal assemblage and the high endowment in W and particularly Mo can be related to the fertilization of subduction‐modified subcontinental mantle in these metals, and its subsequent involvement in the magma generation in post‐collisional setting. A certain role of crustal magma sources in the strong Mo endowment can be considered that would be consistent with some A‐type granitoid affinity of the igneous rocks. The Early Permian age of these high‐potassic intrusions supporting their post‐collisional emplacement is remarkably similar to the age of hydrothermal alteration assemblages, previously reported for the super‐large Kumtor Au deposit situated in a similar post‐collisional setting nearby. [ABSTRACT FROM AUTHOR]

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A reconnaissance study of the Ash-Sharqi area displays that this area is covered by Tertiary rift-related volcanic rocks and their associated plutonic rocks with some exposures of Mesozoic sandstones. These volcanic rocks belong to the Yemen Trap Series (YTS) that form the lower part of the Yemen Volcanic Group (YVG), which consists of a part of the Afro-Arabian continental flood basalt province. The plutonic rocks are represented by intrusion composed of granitoid rocks located in the center of the study area, which is the subject of this paper. These granitoid rocks range in composition from granite (G) to quartz-monzonite - quartz-monzodiorite - quartz diorite (QM-QMD-QD) and are composed of plagioclase (An32-46: Andesine), K-feldspars, quartz, hornblende with minor, biotite, opaques, allanite and zircon. Secondary minerals are represented by chlorite, sericite calcite sphene, hematite epidote, and kaolinite. These rocks show variations in their colors (color index 6 to 47 vol. %) and grain sizes, which reflect changes in mineral composition and textures. They have equigranular, porphyritic, rapakivi, and anti-rapakivi textures and contain enclaves of various sizes of basalt and diorite blocks. Xenocrysts of pyroxene and plagioclase are found and detonated during the magma-mingling processes. Finally, these granitoid rocks are subjected to various degrees of hydrothermal alterations, including silicification, argillization, hematitization, chloritization, epidotization, sericitization, carbonation and spheronization. [ABSTRACT FROM AUTHOR]

Abstract The volume evolution behavior of rock fissures and the characteristics of acoustic emission under cyclic loading are critical for rock stability analysis. To study the volume change behavior of monzogranite fissures and the characteristics of acoustic emission signals under cyclic loading, we selected samples of monzogranite at − 1600 m from a gold mine located in the Jiaodong Peninsula at a depth of − 1600 m and investigated the samples using triaxial cyclic loading—unloading tests and acoustic emission monitoring. As the volume change behavior of the monzogranite fissures and acoustic emission signals were monitored and recorded, the calculated fracture volume strain ratio coefficient and acoustic emission entropy value were proposed to describe the evolution process of fissures inside the rock. The research results showed that the volume strain ratio curve of the rock fractures exhibited a logarithmic variation characteristic during the cyclic loading and unloading, and the fracture volume strain ratio better reflected the relative scale of the internal fracture strain in the rock to the total volume strain. The acoustic emission entropy value reflected the crack evolution behavior during the loading and failure processes, which was a rapid decline in the initial stage of loading and a rapid upward trend in the failure stage. The observed “V”-shaped change in the acoustic emission entropy can be used as an early warning for rock failure. The research results can provide theoretical guidance for rock stability analysis.

Field, petrochemical, and stable isotope data from peraluminous microgranite dikes and their molybdenite-bearing vugs in the Archean Preissac-Lacorne batholith, Québec, provide evidence for the transport and deposition of molybdenum by an aqueous fluid that exsolved from a felsic magma. A model is proposed in which the microgranite-forming liquid fractionated from a magma that was parental to and intruded less-evolved muscovite monzogranite. Fluid saturation is interpreted to have occurred immediately prior to emplacement, allowing sufficient time for small spherical pockets of fluid to form and rise through the liquid but insufficient time for them to leave the system. These fluid pockets scavenged molybdenum and other components during their migration but were frozen in situ to form molybdenite-bearing vugs as a result of the quenching of the magma. We therefore conclude that the vugs are relicts of the exsolved fluid pockets and that the molybdenite in them reflects the concentration of molybdenum in the fluid, estimated from volumetric relationships to have reached ~7800 ppm. [ABSTRACT FROM AUTHOR]

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The East Kunlun Orogenic Belt (E-KOB) documents successive subduction and accretion processes of the Paleo-Tethyan Ocean. However, the tectonic regime of the E-KOB at the late orogenic stage remains ambiguous. This study presents new results of whole-rock geochemistry and zircon U-Pb-Hf isotopes of the Xidatan pluton in the southern E-KOB. Detailed investigation reveals that the pluton is composed of quartz monzodiorite, host monzogranite, and igneous microgranular enclaves (IMEs). Zircon U-Pb dating results suggest that they are coeval magmatic rocks emplaced at ca. 206–203 Ma. Geochemical studies reveal that the quartz monzodiorite and IMEs share a common magma source, evidenced by consistent compositions of major elements, congruently enriched LREEs and LILEs, and consistently moderately depleted HFSEs and HREEs. Enriched to slightly juvenile zircon Hf isotopes (εHf(t) = −4.24 to +0.49) indicate that the primitive magmas of the quartz monzodiorite and IMEs involve the addition of mantle-derived magmas. The quartz monzodiorite and IMEs have identical ages, and consistent isotope features with the host monzogranite, together with the observation of ingestion of xenocrysts from host felsic rocks into the IMEs indicating that they were produced through the mixing of the mantle-derived mafic magmas and host felsic magmas. In contrast, The host monzogranite has moderately high SiO2 and Na2O+K2O, but low Fe2O3T and MgO contents. It shows crust-like trace element patterns such as strong enrichments in LREEs and LILEs, but remarkable depletions in HREEs. Along with enriched zircon Hf isotopes (εHf(t) = −3.51 to −0.25), the host monzogranite was most likely to have originated from partial melting of lower crustal mafic rocks induced by underplated mantle-derived magmas. Considering abundant Late Triassic igneous rocks across the E-KOB, these new data provide further evidence that the Late Triassic magmatism in the E-KOB may be related to the delamination of thickened orogenic root under an extensional setting. [ABSTRACT FROM AUTHOR]

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• I-type monzogranites in the East Kunlun Orogen Belt were emplaced at 251–221 Ma. • The studied monzogranites were generated by partial melting of ancient lower crust. • The Early Triassic monzogranites were formed in a localized extensional environment during a subduction-dominated stage. • The Late Triassic (ca. 232–221 Ma) monzogranites were formed in a post-collisional environment. The Triassic granitoids in the East Kunlun Orogenic Belt (EKOB) are crucial for understanding the tectonic evolution of the Paleo-Tethys Ocean. This study presents zircon U–Pb ages, Lu–Hf isotopes, whole-rock major and trace elements, and Sr–Nd isotope compositions from monzogranite plutons in the central segment of EKOB to constrain their petrogenesis and tectonic evolution. These monzogranites are dominant composed of mineral assemblages of K-feldspars, plagioclase, minor biotite and accessory minerals. U–Pb dating of zircons from the Xinle South (XLS), Nanshankou (NSK) and Changgou South (CGS) plutons yield ages of 251 Ma, 232 Ma and 221 Ma, respectively. The studied monzogranites have relatively high SiO 2 and Al 2 O 3 , but have low contents of TiO 2 , Fe 2 O 3 T, MgO relative to the coeval granodiorites. These monzogranites are classified as fractionated I-type granites, ranging from calc-alkaline to high-K calc-alkaline compositions. Their negative εNd(t) values (−4.2 to −6.3) and zircon εHf(t) values (−6.1 to −9.3) suggest that magma generation occurred through partial melting of ancient lower crust, followed by extensive fractional crystallization. Integrating our new data with regional geological evidence, we propose that the Early Triassic XLS monzogranite emplaced in a localized extensional environment linked to the northward subduction of the Paleo-Tethys oceanic plate. In contrast, during the post-collisional extensional phase of the Late Triassic, the formation of the NSK and CGS monzogranite plutons was directly influenced by asthenospheric upwelling, lower crust delamination, and subsequent continental rifting. [ABSTRACT FROM AUTHOR]

Introduction Granitoids are the main rock units in the continental crust. Study of granitoids reveals significant information on tectonic mantle and upper crust. Many researchers have investigated petrogenesis and origin of granitoids (e.g., Chappell and White, 2001; Barbarin, 1999; Frost et al., 2001). For example, Chappell and White (1992), Pitcher (1993) and Chappell et al., (1998) have divided granites into two major groups of: (1) I-type granites (high-temperature or Cordellerian granitoids, including low-K granitoid to high-Ca tonalite, without inherited zircons) formed by partial melting of mafic rocks at >1000 ℃ in mantle or subduction zones of continental margins, and (2) S-type (low-temperature or Caledonian granitoids with inherited zircons) granites formed by partial melting of felsic crust at ~700-800 ℃. Northeast of Iran is a key location for studying the Cimmerian Orogeny, which is related to the Late Triassic collision between it and Eurasia, and the closure of the Paleo-Tethys (Samadi et al., 2014). Mesozoic Mashhad granitoids have cropped out along with the Paleo-Tethys suture zone. Distinct granitoid suites, i.e., monzogranite, granodiorite, tonalite, and diorite occur in Mount Khalaj located in the south of Mashhad. It comprises of monzogranite and granodiorite. However, monzogranite is the most abundant. To study the plutonic events during the Turan and Central Iran collision, the origin and tectonic setting of monzogranite of Mount Khalaj are investigated in this study based on whole rock geochemical data. Materials and methods This research study is based on field studies and petrography. Fresh thin sections samples were selected for geochemical analysis. Whole rock composition was measured on pressed powder tablets by X-ray fluorescence (XRF) using a Philips PW 1480 wavelength dispersive spectrometer with a Rh-anode X-ray tube and a 3 MeV electron beam Van de Graaff Accelerator, at the center for Geological Survey of Iran. The trace element data of a sample was measured at the Activation Laboratories, Ontario, Canada (ActLabs). Samples were digested by lithium metaborate/tetraborate fusion and analyzed with a Perkin Elmer Sciex ELAN 6000, 6100 or 9000 ICP/MS. GCDkit 4.1 and CorelDraw software packages were used for plotting diagrams and calculation of saturation temperatures. Results The Khalaj granitoid is mineralogically composed of quartz, potassic feldspar, plagioclase, mica, and accessory minerals of zircon and apatite. Geochemically, it is an unaltered acidic intrusion with ~72-73 wt.% SiO2. It is a granitoid (monzogranite) based on various classification diagrams (e.g., Cox et al., 1979; etc.). It shows the peraluminous nature (A/CNK~ 1.08-1.24) with negative Eu anomaly of ~0.62-0.73 (Eu/Eu*

New integrated geochemical studies are reported for Jurassic granites of the Xingcheng area in the northeastern North China Craton. U–Pb zircon data indicate that the Huashan and Taili monzogranites were emplaced during the Early (189 ± 2 Ma) and Late (155 ± 1 Ma) Jurassic, respectively. They are typical of high‐K calc‐alkaline series rocks and I‐type granites, according to our whole‐rock geochemical researches. Both Early and Late Jurassic monzogranites show adakitic rock characteristics because of their high Sr contents (221–347 ppm) and Sr/Y ratios (28.7–37.5), and low Y contents (7.83 –14.7 ppm). The Early Jurassic monzogranite samples have an (87Sr/86Sr)i ratio of 0.7046, ∊Nd(t) values of –11.62 to –11.51, and ∊Hf(t) values of –13.6 to –6.4, whereas the Late Jurassic monzogranites have higher (87Sr/86Sr)i ratios of 0.7069–0.7071 and lower ∊Nd(t) (–20.65 to –20.46) and ∊Hf(t) (–27.6 to –20.0) values. We suggest that the Early Jurassic adakitic rocks were derived from partial melting of thickened lower crust contaminated with mantle‐derived materials, related to subduction of the Paleo‐Pacific Plate. The Late Jurassic adakitic rocks were derived from partial melting of thickened lower crust in an extensional tectonic setting associated with an active continental margin. [ABSTRACT FROM AUTHOR]

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The present study aims to examine the usability of the Gümüşhane Granitoid as a building stone taking into consideration the short-term freeze-thaw cycles and mean block volume. A total of 180 specimens were used in the study prepared from the block samples compiled from 10 different areas in the Gümüşhane (NE Turkey) provincial borders. Mean block volume was calculated about 8 dm3 during the discontinuity studies carried out on the Gümüşhane Granitoid; as a result of which, it was determined that the granitoids are suited for obtaining blocks. The annual freeze-thaw cycle map of Turkey was used for determining the number of freeze-thaw cycles to be applied on the rocks in addition to taking into account the weathering of monzogranites. A total of 25 freeze-thaw cycle tests were applied on the rocks with experimental studies repeated at every 5 cycles. It was determined following the freeze-thaw tests that significant changes have occurred especially in the strength and water absorption parameters of the monzogranites and that they have been affected negatively. This indicates that the monzogranites are not suited for outdoor use as building stone in regions such as the Gümüşhane province and regions with similar climate characteristics, but that they can be used in a lot of regions with more moderate climates. As a building stone, monzogranites can be used either as cobblestone, curbstone, or paving stone subject to their mean block volume. It is considered that the widespread of the Gümüşhane Granitoid may provide a substantial economical income to the country. [ABSTRACT FROM AUTHOR]

The Shimian Neoproterozoic plutons are located on the western margin of the Yangtze Block and are important for reconstructing the tectonic environment of this region. We present in situ zircon LA–ICP–MS U–Pb geochronological and Hf isotopic analyses for the plutons, as well as whole‐rock major‐ and trace‐element compositions. The monzogranite and syenogranite yield concordant ages of 773.6 ± 5.6 Ma and 812.2 ± 1.8 Ma, respectively, which indicates that they formed during the Tonian of the Neoproterozoic. The samples have very similar geochemistry, with high SiO2 (71.45–75.46 wt%) and Al2O3 (12.38–14.36 wt%) contents. The samples have a geochemical characteristics typical of peraluminous A‐type granites, including high Ga/Al and Rb/Sr ratios and elevated contents of high‐field‐strength elements. The samples also display high Rb/Sr (13.9–23.0) and Rb/Nb (12.5–19.2) ratios. The monzogranite and syenogranite yield positive εHf(t) values (+1.6 to +9.4 and + 5.2 to +9.8, respectively) and T2DM ages of 1.54–1.22 Ga and 1.51–1.21 Ga, respectively, which indicates that they were derived from partial melting of Mesoproterozoic crust or contamination with upper mantle. We propose that the syenogranite and monzogranite formed in a syn‐orogenic extensional setting during the Tonian period and that continuous subduction was responsible for the Neoproterozoic magmatic activities. [ABSTRACT FROM AUTHOR]

Bu çalışmada, Gümüşhane il merkezinde yüzeylenen andezit ve monzogranit bileşimindeki magmatik kökenli kayaların jeomekanik özellikleri belirlenmiş ve aralarındaki görgül ilişkiler araştırılmıştır. Deneysel çalışmalar sonucunda, andezit ve monzogranitlerin özgül ağırlık, birim hacim ağırlık, ağırlıkça su emme, hacimce su emme ve gözeneklilik değerleri belirlenmiştir. Her iki kaya türü için kuru ve doygun koşullarda P ve S dalga hızı ölçümleri gerçekleştirilmiştir. Bu değerlere bağlı olarak dinamik elastik parametreler saptanmıştır. Mekanik özelliklerden tek eksenli basınç dayanımı, nokta yükü dayanım indeksi ve dolaylı çekilme dayanımı ile statik elastik parametrelerden elastisite modülü ve poisson oranı değerleri belirlenmiştir. Yapılan istatistiksel değerlendirmeler sonucunda, en yüksek korelasyon katsayısı andezitlerde r: 0.90 ve monzogranitlerde r: 0.94 değeri ile P ve S dalga hızı ölçümlerine ait verilerden elde edilmiştir. En düşük korelasyon katsayısı değeri ise monzogranitlerde Kuvars/Alkali Feldispat oranı ile gözeneklilik arasında tespit edilmiştir. Yapılan analizler neticesinde istatistiksel olarak anlamlı bulunan ve yüksek korelasyon katsayısına sahip ilişkilerin çalışma açısından önemli olduğu ve ilgili parametrelerin dolaylı tahminlerinde kullanılabilir nitelikte olduğu öngörülmüştür.

The Tengchong Block within the Sanjiang Tethys belt in the southeastern part of the Tibetan plateau experienced a widespread intrusion of a felsic magmatic suite of granites in its central domain during Late Cretaceous times. Here, we investigate the Guyong and Xiaolonghe plutons from this suite in terms of their petrological, geochemical, and Sr–Nd, zircon U–Pb and Lu–Hf–O isotopic features to gain insights into the evolution of the Neo-Tethys. The Guyong pluton (76 Ma) is composed of metaluminous monzogranites, and the Xiaolonghe pluton (76 Ma) is composed of metaluminous to peraluminous medium- and fine-grained syenogranite. A systematic decrease in Eu, Ba, Sr, P and Ti concentrations; a decrease in Zr/Hf and LREE/HREE ratios; and an increase in the Rb/Ba and Ta/Nb ratios from the Guyong to Xiaolonghe plutons suggest fractional crystallization of biotite, plagioclase, K-feldspar, apatite, ilmenite and titanite. They also show the characteristics of I-type granites. The negative zircon εHf(t) isotopic values (−10.04 to −5.22) and high δ18O values (6.69 to 8.58 ‰) and the negative whole-rock εNd(t) isotopic values (−9.7 to −10.1) and high initial 87Sr/86Sr ratios (0.7098–0.7099) of the Guyong monzogranite suggest that these rocks were generated by partial melting of the Precambrian basement without mantle input. The zircon εHf(t) isotopic values (−10.63 to −3.04) and δ18O values (6.54 to 8.69 ‰) of the Xiaolonghe syenogranite are similar to the features of the Guyong monzogranite, and this similarity suggests a cogenetic nature and magma derivation from the lower crust that is composed of both metasedimentary and meta-igneous rocks. The Xiaolonghe fine-grained syenogranite shows an obvious rare earth element tetrad effect and lower Nb/Ta ratios, which indicate its productive nature with respect to ore formation. In fact, we discuss that the Sn mineralization in the region was possible due to Sn being scavenged from these rocks by exsolved hydrothermal fluids. We correlate the Late Cretaceous magmatism in the central Tengchong Block with the northward subduction of the Neo-Tethys beneath the Burma–Tengchong Block. [ABSTRACT FROM AUTHOR]

The morphology, trace-element composition and geochronology of 43 zircon grains from two monzogranite samples from the Northeast Xing'an Block, northeastern China, were determined using cathodoluminescence imaging and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Three morphological subtypes (S3, S8 and S9) are recognized in the zircon grain samples, and subtype S8 is dominant, reflecting a calc-alkaline, moderately aluminous, high-pressure crystallization medium and a crystallization temperature of 700 ± 50 °C. The zircon grains are characterized by oscillatory zoning, relatively high Th/U ratios (0.3–1.0), steep chondrite-normalized rare-earth element patterns, high Hf contents (>9000 ppm), positive Ce (Ce/Ce* = 4.84 to 2914) and negative Eu (Eu/Eu* = 0.24 to 0.90) anomalies, indicating a magmatic source. The 206Pb/238U ages of the two monzogranite samples are 180 ± 1 and 181 ± 1 Ma, respectively, implying an Early Jurassic emplacement age for the intrusion. The disparate geochemical behaviors of Hf, Th, and Nb within the zircons, as well as the U/Yb, Nb/Yb, Th/U, Nb/Hf, Th/Nb, and Hf/Th ratios, suggest a continental-crust source in a compressional-magmatic-arc or orogenic-tectonic setting, and a calc-alkaline parent magma. All of the grains show relatively high Ce4+/Ce3+ ratios, suggesting that they were derived from an oxidized magma, which favors enrichment of Cu-Mo elements in the granite porphyry. [ABSTRACT FROM AUTHOR]

The Xujiawan monzogranitic intrusion is located at the junction of the Tongbai-Tongcheng fault and the Tancheng-Lujiang fault in North Huaiyang tectonic belt. The rocks intruded into the Neoproterozoic metamorphic rocks as stocks. In this study, major and trace element contents of the rocks are determined by Atomic Absorption Spectrometer and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Results show that these rocks have high contents of SiO2 and Al2O3 and are alkali-rich and peraluminous with low Mg# values. They are rich in large ion lithophile elements such as Rb and Ba, but are poor in Sr. They are rich in high field strength elements such as Y, Th, Nb, Hf, U, but are poor in Ta, P, Ti. In general, these rocks are deplete in HFSE but enriched in LILE. They have high LaN/YbN and LREE/HREE ratios and have weak Ce anomalies. Major and trace elements indicate that these rocks belong to peraluminous A-type granite. LA-ICP-MS Zircon U-Pb dating of Xujiawan monzogranite yield ages of 128.0 0.9 Ma to 129.6 1.4 Ma, indicating that these intrusions were produced by the early Cretaceous magmatism. Xujiawan monzogranite may have formed in a post-collisional extensional setting. The magma may be derived from the mantle and contaminated by the continental crust.

A comparative study of the zircon composition and texture in granites of a three-stage Late Cretaceous magmatism in the Chaun area, Chukotka, Russia, was conducted in biotite granites (BG), quartz monzonites-monzogranites (MG), and zinnwaldite granites (ZG). The significance of the study entails determining the mineralogical indicators of similar granitoids in areas of multi-stage petrogenesis. It is shown that in the rock series of Northern Chukotka, BG → MG → ZG, a morphological evolution of zircon takes place: a reduction in size, elongation, a growing complexity of the crystallography, and an individual texture. In later generations of zircon, as a result of the recrystallization and metasomatism, rare-metal overgrowths, defects in the crystal structure, pores and fissures, and mineral inclusions appear, whereas the crystal-face indices and patterns become more complicated. We can observe the geochemical evolution of zircon: a gradual change in the concentration of trace elements (Hf, U, Y, Th, Nb, and Ti), rare earth elements (Yb, Er, and Dy, as well as Ce and Nd), and uncommon elements (Ca and Al). Rare elements (REE, Y, Hf, Nb, U, and Th) at the post-magmatic stage of the regional history acquired economic abundances. Zircon is therefore indicative of productive ore-magmatic systems.

The Guojialing and Aishan plutons in the northern Jiaobei Terrane represent the magmatic products of the lithospheric thinning of the North China Craton in the Early Cretaceous. The exhumation history of the terrane in response to the thinning process and its effect on the formation and preservation of coeval gold deposits remain poorly constrained. Granodiorites from the Guojialing pluton and monzogranites from the Aishan pluton contain zircon grains with U-Pb ages of ca. 130 Ma and ca. 116 Ma, respectively. Using the Al-in-hornblende barometry, the Guojialing and Aishan plutons had crystallization pressures of 3.2–5.4 kbar (∼12 km) and 1.5–2.6 kbar (∼5 km), respectively. Using the hornblende-plagioclase thermometry, the Guojialing and Aishan plutons had crystallization temperatures of 628–697 °C and 702–745 °C, respectively. Fluid inclusion microthermometric data show that auriferous quartz veins in the Daliuhang deposit formed at temperatures between 243 and 322 °C at a depth of 7–11 km which was similar to the emplacement depth of the Aishan pluton. These thermobarometric and geochronological data reveal ∼7 km uplift between 130 Ma and 116 Ma, but negligible exhumation for the gold deposits after its formation until 116 Ma. Combining previous results, we envisage that the exhumation magnitude of the Guojialing intrusions were nearly the same in the wide area with slight differences between the core and margin of a single pluton. Numerous gold deposits in the Jiaobei Terrane formed during or after the late stage of rapid exhumation of granitoids, and were uplifted with similar depths to the Aishan pluton since ca. 116 Ma. The rapid exhumation of the Guojialing pluton was with the regional extension, and might be genetically associated with the intensive delamination of destabilized lithospheric root and dense residues. [ABSTRACT FROM AUTHOR]

The Valdepeñas pluton is the easternmost outcrop of the Cáceres-Valdepeñas magmatic alignment (southern Central Iberian Zone). This massif is constituted by a cordierite-bearing porphyritic monzogranite and may be grouped within the so-called “Serie Mixta” granitoids. The Valdepeñas monzogranite is of magnesian [FeOt/(FeOt+MgO)~0.76], alkali-calcic [(Na2O+K2O)–CaO=7.8–8.5] and peraluminous (A/CNK=1.14–1.20). Multielemental- and REE-normalized patterns are comparable to those of similar rocks in the Nisa- Alburquerque-Los Pedroches magmatic alignment, and slightly differ from those of the Montes de Toledo batholith, both in the southern Central Iberian Zone. The U-Pb zircon age of 303±3Ma is consistent with the late-orogenic character of the intrusion and is in accordance with most of the granitic peraluminous intrusions in the southern Central Iberian Zone. 86Sr/87Sr300Ma ratios (0.707424–0.711253), εNd300Mavalues (-5.53 to -6.68) and whole-rock major and trace element compositions of the studied rocks, suggest that the parental magma of the Valdepeñas monzogranite could derive from a crustal metaigneous source. The U-Pb ages (552–650Ma) of inherited zircon cores found in Valdepeñas monzogranite samples match those often found in Lower Paleozoic metavolcanics and granitic orthogneisses of Central Iberia and, furthermore, point to Upper Neoproterozoic metaigneous basement rocks as possible protoliths at the magma source. Based on the solubility of monazite in peraluminous melts, the estimated emplacement temperature of the studied monzogranite is 742–762ºC. The results obtained in this work would contribute to a better understanding of the origin of the “Serie Mixta” granitoids.

The Valdepeñas pluton is the easternmost outcrop of the Cáceres-Valdepeñas magmatic alignment (southern Central Iberian Zone). This massif is constituted by a cordierite-bearing porphyritic monzogranite and may be grouped within the so-called "Serie Mixta" granitoids. The Valdepeñas monzogranite is of magnesian [FeOt/(FeOt+MgO)~0.76], alkali-calcic [(Na2O+K2O)-CaO=7.8-8.5] and peraluminous (A/CNK=1.14-1.20) composition. Multielemental- and REE-normalized patterns are comparable to those of similar rocks in the Nisa- Alburquerque-Los Pedroches magmatic alignment, and slightly differ from those of the Montes de Toledo batholith, bOth in the southern Central Iberian Zone. The U-Pb zircon age of 303±3Ma is consistent with the late-orogenic character of the intrusion and is in accordance with most of the granitic peraluminous intrusions in the southern Central Iberian Zone. 86Sr/87Sr300Ma ratios (0.707424-0.711253), εNd300Ma values (-5.53 to -6.68) and whole-rock major and trace element compositions of the studied rocks, suggest that the parental magma of the Valdepeñas monzogranite could derive from a crustal metaigneous source. The U-Pb ages (552-650Ma) of inherited zircon cores found in Valdepeñas monzogranite samples match those often found in Lower Paleozoic metavolcanics and granitic orthogneisses of Central Iberia and, furthermore, point to Upper NeoprOterozoic metaigneous basement rocks as possible prOtoliths at the magma source. Based on the solubility of monazite in peraluminous melts, the estimated emplacement temperature of the studied monzogranite is 742-762°.C. The results obtained in this work would contribute to a better understanding of the origin of the "Serie Mixta" granitoids. [ABSTRACT FROM AUTHOR]

The problematic nature of Etruscan funerary architecture conservation due to the peculiar environmental conditions consisting of underground positions with flows of visitors represents a typical aim of the archaeological restoration The study case should be considered as emblematic for the iconographic relevance of the gentilitial etruscan tomb, of late orientalizing or archaic age, and for the particular physical nature of the hypogeum which is entirely excavated in a granodiorite rockmass in the center of Marciana village (Isola d 'Elba). The documental uniqueness of the hypogeum, currently under final determination, and the exceptional nature of the environment of the ancient site as well as the necessary radical measures to safeguard and specific intervention of consolidation and restoration are described from multiple viewpoints. In addition to the aspects relating to the conservation problems, the cruciform plan chronology of this extraordinary hypogeum was taken in account.

[Display omitted] • Tourmalines of the Lianyunshan Complex record host-rock chemistry. • Lianyunshan tourmalines are schorlitic alkali type with dominant hydroxyl species. • MgFe -1 alkali-deficiency vectors are the dominant elemental exchange vectors. • Lianyunshan tourmaline boron isotopes indicate a crustal boron source. • Key geochemical differences fingerprint rare-metal-productive vs barren deposits. Although tourmaline is common in pegmatite-related Nb-Ta deposits and metasedimentary cover rocks in the Lianyunshan Complex of northeastern Hunan Province, South China, its fluid sources and genetic relationship to the host pegmatite remain unresolved. In this contribution, we chose the less-studied tourmaline minerals and analyzed their chemical (major, trace, and rare earth elements) and boron isotopic compositions to shed light on the process of pegmatite-related Nb-Ta mineralization. Lianyunshan tourmalines are both metasedimentary-hosted (Tourmalines I and II) and pegmatite-hosted (Tourmaline III), belong to the alkali group, have mainly schorlitic compositions, and contain dominantly hydroxyl anionic species. Element substitution is controlled by the activities MgFe -1 , alkali-deficiency vector R1Al[ Na (FeMg)] -1 , AlO[ R (OH)] -1 , and □Al(NaR) -1. Lianyunshan tourmalines define a trend consistent with foitite to magnesio-foitite compositions. Lianyunshan tourmalines are poor in Fe3+, with a Fe3+/Fe2+ ratio of zero in all samples. This feature, as well as their non-alignment with the FeAl -1 vector, suggests precipitation from a reduced fluid. Fluid salinity may have been moderate to low given the low Na contents of all samples (0.60–0.66 apfu). Tourmaline I is rich in Mg and Ti, but the contents of these elements decrease in Tourmalines II and III. Fluid fractionation may have played a role in the decreasing Mg and Ti contents with corresponding enrichment in the contents of Fe, Na and X□ as Tourmalines II and III precipitated. Unusual enrichment of Li is found in the pegmatite-hosted Tourmaline III (mean 97 ppm) relative to Tourmalines I and II (means ∼ 31–33 ppm), and of Sn in Tourmaline II (mean 291 ppm) relative to Tourmalines I and III (means ∼ 3–10 ppm). δ11B values are similar for Tourmalines I (–14.21 to –12.09 ‰), II (–15.07 to –13.71 ‰), and III (–14.48 to –13.55 ‰), being consistent with the δ11B of typical S-type granites (∼−16 to −8 ‰) such as the S-type muscovite monzogranite host of the Lianyunshan tourmalines. We conclude that the Lianyunshan tourmalines precipitated from an evolved melt that formed muscovite monzogranite. [ABSTRACT FROM AUTHOR]

The Xujiawan monzogranitic intrusion is located at the junction of the Tongbai-Tongcheng fault and the Tancheng-Lujiang fault in North Huaiyang tectonic belt. The rocks intruded into the Neoproterozoic metamorphic rocks as stocks. In this study, major and trace element contents of the rocks are determined by Atomic Absorption Spectrometer and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Results show that these rocks have high contents of SiO2 and Al2O3 and are alkali-rich and peraluminous with low Mg# values. They are rich in large ion lithophile elements such as Rb and Ba, but are poor in Sr. They are rich in high field strength elements such as Y, Th, Nb, Hf, U, but are poor in Ta, P, Ti. In general, these rocks are deplete in HFSE but enriched in LILE. They have high LaN/YbN and LREE/HREE ratios and have weak Ce anomalies. Major and trace elements indicate that these rocks belong to peraluminous A-type granite. LA-ICP-MS Zircon U-Pb dating of Xujiawan monzogranite yield ages of 128.0 0.9 Ma to 129.6 1.4 Ma, indicating that these intrusions were produced by the early Cretaceous magmatism. Xujiawan monzogranite may have formed in a post-collisional extensional setting. The magma may be derived from the mantle and contaminated by the continental crust. [ABSTRACT FROM AUTHOR]

The Ordovician rocks of Sierra Las Planchadas are an exceptionally preserved natural example of a plutonic-volcanic connection. Located in northwestern Argentina, the Las Planchadas Formation consists of a monzogranitic batholith that displays a window into the source of large subvolcanic rhyolitic rocks, cryptodomes and volcanic feeder-dykes. Mafic intrusions and felsic dykes occur cutting the plutonic rocks. Grain-scale relationships, whole-rock compositions and mineral chemistry indicate that monzogranites and rhyolites are two comagmatic members which differentiated within upper crust magma reservoirs. Monzogranites accumulated some plagioclase and trapped a large volume of melt, denoted by a high modal percentage (~64–71%) of near-solidus minerals, comprised of alkali feldspar, albite-rich plagioclase (An <30), and late crystallized quartz. The formation of felsic dykes and rhyolitic cryptodomes is the result of a late melt extraction stage facilitated by the injection of hot mafic magmas from deeper in the system. The mafic-induced thermal reactivation increased the amount of melt-filled pore stored within a highly-crystallized monzogranite reservoir. The breakdown of the low-temperature phases overpressurized the mush and opened a network of microfractures into which residual melts, depleted in feldspar-compatible trace elements (Ba, Sr, and Eu), infiltrated. The draining system involved thin interconnected vein-like channels that merged into wider sheet-like conduits. Our results suggest that channelized segregation of late-stage melts in the subvolcanic environment is a mechanism for triggering rhyolitic eruptions. • Las Planchadas Formation exposes a monzogranitic-rhyolitic stratified magma chamber of the Famatinian magmatic arc. • The plutonic-volcanic construction involved low-pressure crystal fractionation within a single upper-crustal magmatic system. • Thermal reactivation drove late remobilization of residual melts depleted in feldspar-controlled trace elements. • Channelling of felsic melt through a highly crystallized reservoir acted as a potential volcanic feeding mechanism. [ABSTRACT FROM AUTHOR]

Mafic microgranular enclaves (MMEs) are common in the monzogranites from the Yangba pluton in the Bikou Terrane of central China. Zircon LA-ICP-MS U–Pb dating yields ages of 208.7 ± 0.7 Ma and 209.3 ± 0.9 Ma for the host monzogranites, and 211.9 ± 0.8 Ma for the MMEs, indicating formation from coeval magmas. The field occurrence and textures including spheroidal shapes, transitional contacts, igneous mineral assemblages, acicular apatites, and oscillatory zoning with repeated resorption surfaces in plagioclase, indicate that the MMEs crystallized from mafic magma that was injected into and mingled with the host felsic magma. The host monzogranites are intermediate-felsic, metaluminous, and lack typical peraluminous minerals or alkaline mafic minerals, suggesting their I-type affinity. The monzogranites display depletion in high field strength elements, with Nb and Ta anomalies, and enrichment in large ion lithophile elements and light rare earth elements (LREE), with slightly negative Eu anomalies (Eu/Eu ∗ = 0.72–0.93). The MMEs from the Yangba pluton are intermediate, metaluminous, and have higher K 2 O, Al 2 O 3 , Fe 2 O 3 T , MgO, Ni, and Cr contents than the pluton. The MMEs also display much higher total rare earth element (REE) concentrations and REE patterns that are sub-parallel to those of the host rocks, enrichments in Rb, Th, U, K, and LREE, and depletions in Ba, Nb, Ta, and Ti. These features are similar to those of the host rocks, indicating crust–mantle interaction during their petrogenesis. Zircons from the MMEs have highly variable ε Hf ( t ) values (−5.5 to +8.7) with corresponding two-stage Hf model ages ( T DM2 ) of 1.14 to 1.42 Ga, indicating they were derived from depleted mantle with crustal contamination. In contrast, zircons from host monzogranite show ε Hf ( t ) values ranging from −1.7 to +2.7, with T DM2 of 1.13 to 1.21 Ga, corresponding to that of the basement rocks in the Bikou Terrane, which indicates that these granitic magmas were probably derived from the Neoproterozoic juvenile lower crust with minor contribution of Mesoproterozoic ancient lower crust. The integrated petrology and elemental and isotopic geochemistry suggest that the MMEs and host monzogranites were generated by the interaction of a granitic magma and a mafic magma in the lower crust. We envisage that Neoproterozoic subcontinental lithosphere mantle-derived mafic magma intruded the lower continental crust during Late Triassic, following the Late Permian to Early Triassic collision between the South China and North China Blocks. [ABSTRACT FROM AUTHOR]

The Ghaidou monzogranite in the southeast of Khomein constitute a part of rock complex from the northern part of the Sanandaj-Sirjan zone. This body intruded into the Jurassic micaschists and created a metamorphic aureole. Also, aplitic veins, tourmaline bearing pegmatitic dikes, felsic microgranular enclaves and surmicaeous enclaves are observed in this area. The predominant minerals of these rocks are K-feldspar (orthoclase and microcline), Na-plagioclase (Albite-oligoclase in the monzogranite and oligoclase in the felsic microgranular enclaves), quartz and black mica (Annite) -as the main mineralswith minor amount of tourmaline (schorle), garnet, white mica (phengite), sillimanite, kyanite, zircon, apatite and ilmenite. On the basis of biotites mineral chemistry, these phases are enriched in FeO and Al2O3 and relatively low in TiO2. These minerals are magmatic and primary and thermometry results yielded 660-690 °C. According to the chemical composition of primary igneous biotites in the enclaves and monzogranites, these rocks have calc-alkaline, peraluminous and an orogenic continental collision affinity characteristics of S-type granites. Also, the biotite composition and the presence of ilmenite point to low oxygen fugacity and redox conditions during magma crystallization. Based on the available data, the generation of these rocks can be related to Arabian-Eurasia collision zone. [ABSTRACT FROM AUTHOR]

The study area is part of the Basement Complex of North Central Nigeria. The study aims at identifying the rock types and interpretation of the structural elements. The major rock units in the area comprises of porphyritic granite, gneiss and schist. Structural evidence shows that the rocks are deformed and where intruded by the granite. Petrographic analysis reveals the existence of feldspar phenocrysts in a groundmass of quartz and biotite. The granite is composed of quartz (25-35%), plagioclase (15-20%), orthoclase (10-20%), microcline (5-25%), biotite (15-20%) and other accessory minerals. The granites displayed a porphyritic texture while the schist and gneisses exhibit planar and linear structures. Variation in structural trend and mineralogical composition is due to the series of deformational activities which has affected the rocks during geologic time. [ABSTRACT FROM AUTHOR]

The Alvand batholith is one of the largest plutonic bodies in the west of Iran. In this research, several physico-mechanical tests have been performed on granodiorite and porphiroid monzogranite consisting of five degrees of weathering in Hamedan area, west of Iran. Furthermore, weathering process of Alvand granitoid is studied by chemical analysis and petrographical studies. The results indicated that engineering properties of weathered granodiorite and monzogranite vary over the wide range depending on the degree of weathering. On the other hand, this research is focused on the assessment of relationship between weathering indices and uniaxial compressive strength. For this reason, some of the most important weathering indices are reviewed. It should be noted that, application of these chemical, engineering and petrographical indices are good quantitative indicators for describing the degree of weathering. Using these indices for the assessment of uniaxial compressive strength of granodiorite and monzogranite rocks, yields suitable and meaningful results. [ABSTRACT FROM AUTHOR]

Abstract: Geochemical and Nd isotope data on granitoids of the NW part of the late Archaean eastern Dharwar craton are presented to elucidate their petrogenesis and role in crust formation. The granitoids are divided into three suites viz. trondhjemite–granodiorite gneisses, biotite monzogranites and porphyritic biotite granodiorites. The gneisses are pre- to syn-kinematic (with respect to deformation in the adjacent Hungund–Kushtagi schist belt), which show variable SiO2 and Al2O3, enriched LREE and depleted HREE with slightly negative to no Eu anomalies. They display unusual chemistry in having higher FeO(T), K2O, Ba, Cr and Ni compared to the typical Archaean tonalite–trondhjemite–granodiorite (TTG). The biotite monzogranites are mostly syn- to late-kinematic and exhibit evolved calc-alkaline compositions with high SiO2, K2O, LILE and LREE, depleted to undepleted HREE and strongly negative to no Eu anomalies. The porphyritic granodiorites show syn- to late-kinematic calc-alkaline, sanukitoid-like character with a wide range of SiO2, higher TiO2, P2O5, Sr, Ba, Cr and Ni, and lower Rb. They, however, uniquely display higher K2O, ΣREE and Th than typical sanukitoids. The trondhjemite–granodiorite gneisses are interpreted as product of melting of a subducted basaltic slab followed by slight contamination from the overlying metasomatized mantle wedge. Subsequent melting of the extremely metasomatized mantle wedge resulted in formation of the parental magma of the porphyritic granodiorites. Intrusion of the latter triggered melting of the TTG crust accreted earlier and generated the evolved monzogranites. The monzogranites occurring east of the Hungund–Kushtagi schist belt show higher εNd but lower T DM ages than those occurring to the west, indicating that terranes with different histories were juxtaposed by lateral accretion. [Copyright &y& Elsevier]

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The Monte Capanne pluton (Tuscan Magmatic Province, Elba Island, Italy) displays a great variety of magmatic products. Mafic microgranular enclaves (MME) are widespread and display variable size, texture and composition. Petrographic and mineralogical features highlight the importance of magma mixing in their genesis. In particular, patchy-zoned phenocrysts and corroded An-rich plagioclase are common in the MME, which, together with their abundance in the monzogranitic host, suggest that mixing between mantle and crustal-derived magmas occurred relatively early in the crystallisation history of the pluton. A gabbroic enclave is characterised by the abundance of An-rich plagioclase and amphibole, the latter possibly replacing former clinopyroxene. Differences in biotite composition between MME reflect the heterogeneous nature of the mafic magmas prior to the enclave formation. The importance of magma mixing is also evident in K-feldspar megacrysts, which commonly exhibit resorption surfaces followed rimward by a high-Ba zone. Hybrid Orano dykes, which are the latest magmas injected into the Monte Capanne pluton, display specific disequilibrium textures (i.e. sieve-textured plagioclase phenocrysts) and mineral content (i.e. abundance of amphibole) compared to the MME.The genesis of most MME, which display a wide spectrum of major and trace element compositions compared to the host monzogranite, involves a complex interplay between mixing and crystallisation following the input of mantle-derived magma into a silicic magma chamber. Possible loss of the liquid phase from the evolving basic magma may have produced MME distinctively depleted in LREE and enriched in MgO. Fingerprinting the chemical and isotopic signature of the basic magma involved in the genesis of the MME is further complicated by subsequent (but limited) exchange between MME and host. The basic magma is inferred to be similar to coeval high-K calc-alkaline volcanic rocks occurring on Capraia Island.Isotopically, the monzogranite and its MME display distinctive trends pointing towards a low-ɛNd end-member, represented by a garnet mica schist xenolith. We propose that these trends, together with the abundance of variably digested metasedimentary xenoliths dispersed throughout the pluton, reflect assimilation of metapelitic crust early in the evolution of the pluton during storage of the magma within the Tuscan basement, i.e. prior to the final emplacement of the pluton at upper crustal levels.The hybrid Orano dykes, which were injected at the end of the Monte Capanne crystallisation history, display distinctive trace element compositions, similar to REE-Sr-Ba-rich andesites on Capraia. The Orano dykes originated from a deeper level of magma storage and interacted with a crystal-rich enclave-bearing monzogranitic mixture.The proposed scenario involving periodic recharge by mantle-derived magmas and crustal assimilation is also in agreement with isotopic variations observed within a zoned K-feldspar megacryst, which exhibits a core with high 87Sr/86Sr and a rimward decrease of 87Sr/86Sr, arguing for a high 87Sr/86Sr silicic system replenished by lower 87Sr/86Sr mantle-derived magmas. [Copyright &y& Elsevier]

The Chalice gold deposit (∼20 t Au produced), in the southwestern portion of the Late-Archean Norseman–Wiluna greenstone belt of the Yilgarn Craton, Western Australia, is hosted both in a sequence of intercalated mafic and ultramafic amphibolites and a post-peak metamorphism monzogranite dike. The deposit is flanked on the western side by calc-alkaline plutonic rocks, and to the east by a predominantly monzogranitic pluton, with at least four generations of monzogranitic dikes that intrude the local mine stratigraphy. Locally, four deformation events (D1–D4) have affected this sequence of amphibolites, and two stages of gold mineralisation are recognised, controlled by the progressive D2 event.Main Stage gold mineralisation (95% of the resource), which is demonstrably later than all granitic bodies except second generation and subsequent monzogranite dikes, is controlled by localised D2 asymmetric folds developed in the mafic amphibolite. It is expressed as veins and wall-rock replacement, characterised by a prograde assemblage of quartz–diopside–plagioclase–K-feldspar–titanite–pyrrhotite–pyrite–magnetite±garnet, hornblende, scheelite and biotite. Second Stage gold mineralisation (5% of the resource) is associated with the intrusion of a monzogranite dike and is expressed as disseminated gold in the dike, as well as foliation-discordant veins of quartz–gold, quartz–diopside–gold, actinolite–gold and molybdenite–tellurobismuthite–gold.Detailed field mapping and petrography suggest that Main Stage gold mineralisation at Chalice is equivalent to hypozonal orogenic lode–gold mineralisation in other Archean greenstone belts of the Yilgarn Craton, whereas monzogranite-associated Second Stage gold mineralisation is atypical of such deposits. The Main Stage mineralisation cannot be correlated to any particular granitoid in the local environment, although temporally, it is bracketed by granitic magmatism. A deep magmatic or metamorphic source cannot be resolved from the field data. It is also uncertain as to whether Second Stage mineralisation represents a true magmatic-gold event, or is a product of the assimilation and remobilisation of Main Stage gold, during the intrusion of the monzogranite dike. However, its distinctive metal association of Au–Bi–Mo–Te–W suggests the former. Irrespective of this uncertainty, Chalice remains as a deposit which is more intimately related both spatially and temporally to granitic magmatism than other Yilgarn deposits. [Copyright &y& Elsevier]

A comparative study of the zircon composition and texture in granites of a three-stage Late Cretaceous magmatism in the Chaun area, Chukotka, Russia, was conducted in biotite granites (BG), quartz monzonites-monzogranites (MG), and zinnwaldite granites (ZG). The significance of the study entails determining the mineralogical indicators of similar granitoids in areas of multi-stage petrogenesis. It is shown that in the rock series of Northern Chukotka, BG → MG → ZG, a morphological evolution of zircon takes place: a reduction in size, elongation, a growing complexity of the crystallography, and an individual texture. In later generations of zircon, as a result of the recrystallization and metasomatism, rare-metal overgrowths, defects in the crystal structure, pores and fissures, and mineral inclusions appear, whereas the crystal-face indices and patterns become more complicated. We can observe the geochemical evolution of zircon: a gradual change in the concentration of trace elements (Hf, U, Y, Th, Nb, and Ti), rare earth elements (Yb, Er, and Dy, as well as Ce and Nd), and uncommon elements (Ca and Al). Rare elements (REE, Y, Hf, Nb, U, and Th) at the post-magmatic stage of the regional history acquired economic abundances. Zircon is therefore indicative of productive ore-magmatic systems. [ABSTRACT FROM AUTHOR]