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The interplay between substrates and superconducting thin films has attracted increasing attention. Here, we report an in-depth investigation on superconducting properties of the epitaxial TiN thin films grown on three different substrates by dc reactive magnetron sputtering. The TiN films grown on (0001) sapphire exhibit (111) crystal orientation, while that grown on (100) Si and MgO substrates exhibit (100) orientation. Moreover, the samples grown on Si reveal a relatively lower level of disorder, accompanied by the higher critical transition temperature $T_c$ and smaller magnitude of upper critical field slope near $T_c$. Remarkably, we uncovered a rather high value of superconducting gap (with $\Delta_0/k_BT_c$ = 3.05) in TiN film on Si indicating a very strong coupling superconductivity, in sharp contrast to the case using sapphires and MgO as the substrate which reveals a weak-coupling feature. The comprehensive analysis considering the scenarios of the three substrate shows that the grain size of the thin films may be an important factor influencing the superconductivity., Comment: 8 pages, 6 figures

Exploring new unconventional superconductors is of great value for both fundamental research and practical applications. It is a long-term challenge to develop and study more hole-doped superconductors in 1111 system of iron-based superconductors. Here we report the discovery of superconductivity with a critical transition temperature up to 30.7 K in the compound CaFeAsF by a post-annealing treatment in air atmosphere. The superconducting behaviors are verified in both the single-crystalline and polycrystalline samples by the resistance and magnetization measurements. The analysis by combining the depth-resolved time-of-flight secondary ion mass spectrometry (TOF-SIMS) and X-ray photoelectron spectroscopy (XPS) measurements shows that the introduction of oxygen elements and the consequent changing in Fe valence by the annealing treatment may lead to the hole-type doping, which is the origin for the occurrence of superconductivity. Our results pave the way for further in-depth investigations on the hole-doped 1111 system in iron-based superconductors., Comment: 26 pages, 6 figures and 1 table

The coexistence of superconductivity and ferromagnetism is a long-standing issue in superconductivity due to the antagonistic nature of these two ordered states. Experimentally identifying and characterizing novel heterointerface superconductors that coexist with magnetism presents significant challenges. Here, we report the experimental observation of two-dimensional long-range ferromagnetic order in the KTaO$_3$ heterointerface superconductor, showing the coexistence of superconductivity and ferromagnetism. Remarkably, our direct current superconducting quantum interference device measurements reveal an in-plane magnetization hysteresis loop persisting above room temperature. Moreover, the first-principles calculations and X-ray magnetic circular dichroism measurements provide decisive insights into the origin of the observed robust ferromagnetism, attributing it to oxygen vacancies that localize electrons in nearby Ta 5$d$ states. Our findings not only suggest KTaO$_3$ heterointerfaces as time-reversal symmetry breaking superconductors, but also inject fresh momentum into the exploration of the intricate interplay between superconductivity and magnetism, enhanced by the strong spin-orbit coupling inherent to the heavy Ta in 5$d$ orbitals of KTaO$_3$ heterointerfaces., Comment: 9 pages, 5 figures

The quantum spin Hall (QSH) effect has attracted extensive research interest because of the potential applications in spintronics and quantum computing, which is attributable to two conducting edge channels with opposite spin polarization and the quantized electronic conductance of 2e2/h. Recently, 2M-WS2, a new stable phase of transition metal dichalcogenides with a 2M structure showing an identical layer configuration to that of the monolayer 1T' TMDs, was suggested to be a QSH insulator as well as a superconductor with critical transition temperature around 8 K. Here, high-resolution angle-resolved photoemission spectroscopy (ARPES) and spin-resolved ARPES are applied to investigate the electronic and spin structure of the topological surface states (TSS) in the superconducting 2M-WS2. The TSS exhibits characteristic spin-momentum-locking behavior, suggesting the existence of long-sought nontrivial Z2 topological states therein. We expect that 2M-WS2 with co-existing superconductivity and TSS might host the promising Majorana bound states.

Quantum Griffiths singularity (QGS), which is closely correlated with the quenched disorder, is characterized by the divergence of the dynamical critical exponent and the presence of activated scaling behavior. Typically such a quantum phenomenon is rather rare and only observed in extremely low temperatures. Here we report the experimental observation of a robust QGS in nitride thin films, NbN, which survives in a rather high temperature range. The electrical transport propertied were measured under the magnetic field up to 12 T. The field induced superconductor-metal transitions were observed with the continuously changed transition points with the decrease of temperature. The dynamical critical exponent based on the conventional power-law scaling reveals a divergent trend when approaching the the low temperature limit. Moreover, the temperature and field dependence of sheet resistance can be described by the activated scaling analysis in the temperature region up to 1.6 K $\leq T \leq$ 4.0 K. We argue that the robustness of QGS in the present system originates from the Pauli paramagnetic effect due to the strong coupling between the magnetic field and the spin degree of freedom., Comment: 6 pages, 4 figures

Superconductivity and the normal-state properties of NbN films can be tuned in a wide range, supplying a suitable platform to investigate the systematical evolution of the superconducting performances. Herein, we report the upper critical field of NbN films in both the vertical ($B\perp$ film) and parallel ($B\parallel$ film) orientations over a wide temperature range. Eight samples with the superconducting critical temperature $T_c$ ranging from 2.5 K to 9.8 K are studied. Meanwhile, the normal-state resistivity is tuned by more than six times by changing the conditions of the film growth. It is found that the magnitudes of the upper critical field in both field directions ($B_{c2}^{\perp}$ and $B_{c2}^{\parallel}$) exceed the paramagnetic limiting field $B_p$. The temperature dependent $B_{c2}^{\perp}$ can be described by the extended Werthamer--Helfand--Hohenberg (WHH) model considering the Pauli spin paramagnetism. Meanwhile, the $B_{c2}^{\parallel}$-$T$ data shows the feature of two-dimensional superconductivity in the temperature range near $T_c$. The evolution of the obtained Maki parameter with other parameters, such as the slope of the upper critical field near $T_c$ and the normal-state resistivity, are discussed to reveal the characteristics of the Pauli paramagnetic effect in this system., Comment: 7 pages, 6 figures

The emergence of quantum metallic state marked by a saturating finite electrical resistance in the zero-temperature limit in a variety of two-dimensional superconductors injects an exciting momentum to the realm of heterostructure superconductivity. Despite much research efforts over last few decades, there is not yet a general consensus on the nature of this unexpected quantum metal. Here, we report the observation of a unique quantum metallic state within the hallmark of Bose-metal in the titanium sesquioxide heterointerface superconductor Ti$_2$O$_3$/GaN. Remarkably, the quantum bosonic metallic state continuously tuned by a magnetic field in the vicinity of the two-dimensional superconductivity-metal transition persists in the normal phase, indicating the existence of composite bosons formed by electron Cooper pairs even in the normal phase. Our findings provide a distinct evidence for electron pairing in the normal phase of heterointerface superconductors, and shed fresh light on the pairing nature underlying heterointerface superconductivity., Comment: 12 pages, 4 figures

Both cuprates and iron-based superconductors demonstrate nematicity, defined as the spontaneous breaking of rotational symmetry in electron systems. The nematic state can play a role in the high-transition-temperature superconductivity of these compounds. However, the microscopic mechanism responsible for the transport anisotropy in iron-based compounds remains debatable. Here, we investigate the electronic anisotropy of CaFeAsF by measuring its interlayer resistivity under magnetic fields with varying field directions. Counterintuitively, the interlayer resistivity was larger in the longitudinal configuration ($B \parallel I \parallel c$) than in the transverse one ($B \perp I \parallel c$). The interlayer resistivity exhibited a so-called coherence peak under in-plane fields and was highly anisotropic with respect to the in-plane field direction. At $T$ = 4 K and $B$ = 14 T, the magnetoresistance $\Delta\rho/\rho_0$ was seven times larger in the $B \parallel b_o$ than in the $B \parallel a_o$ configuration. Our theoretical calculations of the conductivity based on the first-principles electronic band structure qualitatively reproduced the above observations but underestimated the magnitudes of the observed features. The proposed methodology can be a powerful tool for probing the nematic electronic state in various materials., Comment: 25 pages, 5 figures

CaFeAsF is an iron-based superconductor parent compound whose Fermi surface is quasi-two dimensional, composed of Dirac-electron and Schr\"odinger-hole cylinders elongated along the $c$ axis. We measured the longitudinal and Hall resistivities in CaFeAsF with the electrical current in the $ab$ plane in magnetic fields up to 45 T applied along the $c$ axis and obtained the corresponding conductivities via tensor inversion. We found that both the longitudinal and Hall conductivities approached zero above $\sim$40 T as the temperature was lowered to 0.4 K. Our analysis indicates that the Landau-level filling factor is $\nu$ = 2 for both electrons and holes at these high field strengths, resulting in a total filling factor $\nu$ = $\nu_{hole} - \nu_{electron}$ = 0. We therefore argue that the $\nu$ = 0 quantum Hall state emerges under these conditions., Comment: 18 pages, 1 table, 4 figures

The study of exotic superconductivity in two dimensions has been a central theme in solid state and materials research communities. Experimentally exploring and identifying new fascinating interface superconductors with a high transition temperature ($T_c$) is challenging. Here, we report an experimental observation of intriguing two-dimensional superconductivity with a $T_c$ up to 3.8 K at the interface between Mott insulator Ti$_2$O$_3$ and polar semiconductor GaN. At the verge of superconductivity, we also observe a striking quantum metallic-like state, demonstrating that it is a precursor to the two-dimensional superconductivity as the temperature is decreased. Our work is the first time finding this intriguing superconducting state at the heterointerface, which not only brings a new broad of perspective on the emergent quantum phenomena at the heterointerfaces but also sheds new light on exploiting the novel heterointerface superconductivity with high-$T_c$ via heterostructure engineering., Comment: 8 pages, 4 figures

Guo, Alexandradinata, \textit{et al.} have recently proposed that quantum-oscillation frequencies from Dirac/Weyl fermions exhibit a negative shift proportional to $T^2$ because of the energy dependence of the effective mass peculiar to a linear band-dispersion. We have measured Shubnikov--de Haas oscillation in CaFeAsF up to $T$ = 9 K. The frequency of the $\alpha$ Dirac electron exhibits a negative shift with increasing $T$, while that of the $\beta$ Schr\"odinger hole does not. For $T \geqslant 5$ K where $\beta$ is negligible, the $\alpha$-frequency shift is proportional to $T^2$ and its rate agrees with the theoretical prediction within experimental accuracy. At lower temperatures, the shifts of $\alpha$ and $\beta$ deviate from theoretical expectations, which we ascribe to the inaccuracy in the frequency determination due to unfavorable interference between frequencies. Our results confirm that the topological frequency shift can be utilized to identify Dirac/Weyl fermions when quantum-oscillation frequencies can be determined accurately., Comment: Minor revision after publication, ref. 16 updated (found already published), 16 pages, 4 figures, 1 table

Recently V-based Kagome metal attracted intense attention due to the emergence of superconductivity in the low temperature. Here we report the fabrication and physical investigations of the high quality single-crystalline thin films of the Kagome metal KV$_3$Sb$_5$. For the sample with the thickness of about 15 nm, the temperature dependent resistance reveals a Berezinskii-Kosterlitz-Thouless (BKT) type behavior, indicating the presence of two-dimensional superconductivity. Compared with the bulk sample, the onset transition temperature $T^{onset}_{c}$ and the out-of-plane upper critical field $H_{c2}$ are enhanced by 15\% and more than 10 times respectively. Moreover, the zero-resistance state is destroyed by a magnetic field as low as 50 Oe. Meanwhile, the temperature-independent resistance is observed in a wide field region, which is the hallmark of quantum metallic state. Our results provide evidences for the existence of unconventional superconductivity in this material., Comment: 5 pages, 4 figures

A magnetic field is generally considered to be incompatible with superconductivity as it tends to spin-polarize electrons and breaks apart the opposite-spin singlet superconducting Cooper pairs. Here, an experimental phenomenon is observed that an intriguing reemergent superconductivity evolves from a conventional superconductivity undergoing a hump-like intermediate phase with a finite electric resistance in the van der Waals heterointerface of layered NbSe2 and CrCl3 flakes. This phenomenon merely occurred when the applied magnetic field is parallel to the sample plane and perpendicular to the electric current direction as compared to the reference sample of a NbSe2 thin flake. The strong anisotropy of the reemergent superconducting phase is pointed to the nature of the Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) state driven by the strong interfacial spin-orbit coupling between NbSe2 and CrCl3 layers. The theoretical picture of FFLO state nodes induced by Josephson vortices collectively pinning is presented for well understanding the experimental observation of the reemergent superconductivity. This finding sheds light on an opportunity to search for the exotic FFLO state in the van der Waals heterostructures with strong interfacial spin-orbit coupling., Comment: 24

We present a systematic study of electrical resistivity, Hall coefficient, magneto-optical imaging, magnetization, and STEM analyses of KCa${_2}$Fe${_4}$As${_4}$F${_2}$ single crystals. Sharp diamagnetic transition and magneto-optical imaging reveal homogeneity of single crystal and prominent Bean-like penetrations of vortices. Large anisotropy of electrical resistivity, with ${\rho _c / \rho _{ab}}$ > 100, and semiconductor-like ${\rho _c}$ suggest that the electronic state is quasi two-dimensional. Hall effect measurements indicate that KCa${_2}$Fe${_4}$As${_4}$F${_2}$ is a multiband system with holes as main carriers. Magnetization measurements reveal significantly larger J$_c$ compared with that in other iron-based superconductors with different values of J$_c$ depending on the direction of magnetic field. Origin of these J$_c$ characteristics is discussed based on microstructural observations using STEM. In addition, further enhancement of J$_c$ in KCa${_2}$Fe${_4}$As${_4}$F${_2}$ for future application is demonstrated in terms of heavy-ion irradiation., Comment: 23 pages, 10 figures

Two-dimensional (2D) superconductors supply important platforms for exploring new quantum physics and high-$T_c$ superconductivity. The intrinsic superconducting properties in the 2D iron-arsenic superconductors are still unknown owing to the difficulties in the preparation of ultrathin samples. Here we report the fabrication and physical investigations of the high quality single-crystalline ultrathin films of the iron-arsenic superconductor KCa$_2$Fe$_4$As$_4$F$_2$. For the sample with the thickness of 2.6$\sim$5 nm (1$\sim$2 unit cells), a sharp superconducting transition at around 30 K (onset point) is observed. Compare with the bulk material, the ultrathin sample reveals a relatively lower $T_c$, wider transition width, and broader flux liquid region under the in-plane field. Moreover, the angle dependent upper critical field follows the Tinkham model, demonstrating the two-dimensional superconductivity in ultrathin KCa$_2$Fe$_4$As$_4$F$_2$., Comment: 5 pages, 4 figures

We report resistance and elastoresistance measurements on (Ba$_{0.5}$K$_{0.5}$)Fe$_2$As$_2$, CaKFe$_4$As$_4$, and KCa$_2$Fe$_4$As$_4$F$_2$. The Fe-site symmetry is $D_{2d}$ in the first compound but $C_{2v}$ in the latter two, which lifts the degeneracy of the Fe $d_{xz}$ and $d_{yz}$ orbitals. The temperature dependence of the resistance and elastoresistance is similar between the three compounds. Especially, the [110] elastoresistance is enhanced with decreasing temperature irrespective of the Fe-site symmetry. This appears to be in conflict with recent Raman scattering studies on CaKFe$_4$As$_4$, which suggest the absence of nematic fluctuations. We consider possible ways of reconciliation and suggest that the present result is important in elucidating the origin of in-plane resistivity anisotropy in iron-based superconductors., Comment: 8 pages, 5 figures, 1 table

The temperature dependence of the upper critical field ($H_{c2}$) in RbCr$% _{3}$As$_{3}$ single crystals ($T_{c}\approx $ 7.3 K) has been determined by means of magnetoresistance measurements with temperature down to 0.35 K in static magnetic fields up to 38 T. The magnetic field was applied both for directions parallel ($H\parallel c $, $H_{c2}^{\parallel c}$) and perpendicular ($H\perp c$, $H_{c2}^{\perp c}$) to the Cr chains. The curves $H_{c2}^{\parallel c}(T)$ and $H_{c2}^{\perp c}(T)$ cross at $\sim $ 5.5 K. As a result, the anisotropy parameter $\gamma (T)=H_{c2}^{\perp c}/H_{c2}^{\parallel c}(T)$ increases from 0.5 near $T_{c}$ to 1.6 at low temperature. Fitting with the Werthamer-Helfand-Hohenberg (WHH) model yields zero-temperature critical fields of $\mu_0H_{c2}^{\parallel c}(0)\approx $ 27.2 T and $\mu_0H_{c2}^{\perp c}(0)\approx $ 43.4 T, both exceeding the BCS weak-coupling Pauli limit $\mu_0H_{p}=1.84T_{c}=13.4$ T. The results indicate that the paramagnetic pair breaking effect is strong for $H \parallel c$ but absent for $H \perp c$, which was further confirmed by the angle dependent magnetoresistance and $H_{c2}$ measurements., Comment: 6 pages, 5 figures

The emergence of unconventional superconductivity is generally considered to be related to spin fluctuations. Unveiling the intriguing behaviors of spin fluctuations in parent compounds with layered transition-metal ions may shed light on the search for exotic unconventional superconductors. Here, based on the framework of the first-principles calculations, we theoretically propose that LaCoSb$_2$ is a weak antiferromagnetic layered metal with an in-plane ferromagnetic moment of 0.88 $\mu_B$ at the Co sites, as a candidate parent compound of the cobalt-based superconductors. Importantly, this theoretical finding is experimentally supported by our magnetization measurements on polycrystalline samples of LaCo$_{0.78}$Sb$_2$. Following the symmetry analysis, we suggest a possible $p$-wave superconductivity hosted in doped LaCoSb$_2$ emerging at the verge of ferromagnetic spin fluctuations, which implies potential applications in topological quantum computing in future., Comment: 10 pages, 7 figures, 3 table

Recently, 12442 system of Fe-based superconductors has attracted considerable attention owing to its unique double-FeAs-layer structure. A steep increase in the in-plane upper critical field with cooling has been observed near the superconducting transition temperature, $T_c$, in KCa$_2$Fe$_4$As$_4$F$_2$ single crystals. Herein, we report a high-field investigation on upper critical field of this material over a wide temperature range, and both out-of-plane ($H\|c$, $H_{c2}^{c}$) and in-plane ($H\|ab$, $H_{c2}^{ab}$) directions have been measured. A sublinear temperature-dependent behavior is observed for the out-of-plane $H_{c2}^{c}$, whereas strong convex curvature with cooling is observed for the in-plane $H_{c2}^{ab}$. Such behaviors could not be described by the conventional Werthamer--Helfand--Hohenberg (WHH) model. The data analysis based on the WHH model by considering the spin aspects reveals a large Maki parameter $\alpha=9$, indicating that the in-plane upper critical field is affected by a very strong Pauli paramagnetic effect., Comment: 6 pages, 4 figures, accepted by SCIENCE CHINA Physics, Mechanics & Astronomy

Recently, Bi2O2Se is discovered as a promising two-dimensional (2D) semiconductor for next generation electronics, due to its moderate bandgap size, high electron mobility and pronounced ambient stability. Meanwhile, it has been predicted that high quality Bi2O2Se-related heterostructures may possess exotic physical phenomena, such as piezoelectricity and topological superconductivity. Herein, we report the first successful heteroepitaxial growth of Bi2O2Se films on SrTiO3 substrates via pulsed laser deposition (PLD) method. Films obtained under optimal conditions show an epitaxial growth with the c axis perpendicular to the film surface and the a and b axes parallel to the substrate. The growth mode transition to three dimensional (3D) island from quasi-2D layer of the heteroepitaxial Bi2O2Se films on SrTiO3 (001) substrates is observed as prolonging deposition time of films. The maximum value of electron mobility reaches 160 cm2/V-1s-1 at room temperature in a 70nm-thick film. The thickness dependent mobility provides evidence that interface-scattering is likely to be the limiting factor for the relatively low electron mobility at low temperature, implying that the interface engineering as an effective method to tune the low temperature electron mobility. Our work suggests the epitaxial Bi2O2Se films grown by PLD are promising for both fundamental study and practical applications., Comment: 18 pages, 5 figures, 1 table, supplementary information

Gap symmetry and structure are crucial issues in understanding the superconducting mechanism of unconventional superconductors. Here we report an in-depth investigation on the out-of-plane lower critical field $H_{c1}^{c}$ of fluorine-based 1111 system superconductor CaFe$_{0.88}$Co$_{0.12}$AsF with $T_c$ = 21 K. A pronounced two-gap feature is revealed by the kink in the temperature dependent $H_{c1}^c(T)$ curve. The magnitudes of the two gaps are determined to be $\Delta_1$ = 0.86 meV and $\Delta_2$ = 4.48 meV, which account for 74% and 26% of the total superfluid density respectively. Our results suggest that the local antiferromagnetic exchange pairing picture is favored compared to the Fermi surface nesting scenario., Comment: 19 pages, 4 figures

Low-temperature specific heat (SH) is measured on the 1111-type CaFe_{0.88}Co_{0.12}AsF single crystals under different magnetic fields. A clear SH jump with the height \Delta C/T|_Tc = 10.4 mJ/mol K^2 was observed at the superconducting transition temperature T_c. The electronic SH coefficient \Delta\gamma (B) increases linearly with the field below 5 T and a kink is observed around 5 T, indicating a multi-gap feature in the present system. Such a sign is also reflected in the Tc-B data. A detailed analysis shows that this behavior can be interpreted in terms of a two-gap scenario with the ratio \Delta_L=\Delta_S = 2:8-4:5., Comment: 5 pages, 4 figures

Low-temperature specific heat (SH) is measured for the 12442-type KCa$_2$Fe$_4$As$_4$F$_2$ single crystal under different magnetic fields. A clear SH jump with the height of $\Delta C/T|_{T_c}$ = 130 mJ/mol K$^2$ is observed at the superconducting transition temperature $T_c$. It is found that the electronic SH coefficient $\Delta\gamma (H)$ quickly increases when the field is in the low-field region below 3 T and then considerably slows down the increase with a further increase in the field, which indicates a rather strong anisotropy or multi-gap feature with a small minimum in the superconducting gap(s). The temperature-dependent SH data indicates the presence of the $T^2$ term, which supplies further information and supports the picture with a line-nodal gap structure. Moreover, the onset point of the SH transition remains almost unchanged under the field as high as 9 T, which is similar to that observed in cuprates, and placed this system in the middle between the BCS limit and the Bose-Einstein condensation., Comment: 6 pages, 4 figures, accepted by SCIENCE CHINA Physics, Mechanics & Astronomy

Millimeter sized single crystals of KCa_2Fe_4As_4F_2 were grown using a self-flux method. The chemical compositions and crystal structure were characterized carefully. Superconductivity with the critical transition T_c = 33.5 K was confirmed by both the resistivity and magnetic susceptibility measurements. Moreover, the upper critical field H_c2 was studied by the resistivity measurements under different magnetic fields. A rather steep increase for the in-plane H_c2^ab with cooling, d\mu_0H_c2^a/dT|T_c = -50.9 T/K, was observed, indicating an extremely high upper critical field. Possible origins for this behavior were discussed. The findings in our work is a great promotion both for understanding the physical properties and applications of 12442-type Fe-based superconductors., Comment: 5 pages, 4 figures

Recently, intriguing phenomena of superconductivity, type-II Weyl semimetal or quantum spin Hall states were discovered in metastable 1T'-type VIB-group transition metal dichalcogenides (TMDs). Here, we report that monoclinic phase WS2 was discovered and synthesized in our experiments. The intrinsic superconducting transition was observed in monoclinic WS2 with a transition temperature Tc of 8.8 K which is the highest among previously reported TMDs without any fine-tuning process. Intersteing, topological insulator state, defined by topological invariant Z2, was also discovered with a single Dirac cone on the surface, which is different from all topological states reported in TMDs. Further, the electronic structure was found to have a strong anisotropy by Shubnikov-de Haas oscillations and first-principles calculations. Our findings reveal that monoclinic WS2 might be a new topological superconductivity candidate with a strong anisotropy., Comment: 20 pages, 5 figures, 1 table

2H MoS2 has been intensively studied because of layer-dependent electronic structures and novel physical properties. Though the metastable 1T MoS2 with the [MoS6] octahedron was observed from the microscopic area, the true crystal structure of 1T phase has not been determined strictly. Moreover, the true physical properties have not been demonstrated from experiments due to the challenge for the preparation of pure 1T MoS2 crystals. Here, we successfully synthesized the 1T MoS2 single crystals and re-determined the crystal structure of 1T MoS2 from single-crystal X-ray diffraction. 1T MoS2 crystalizes in space group P-3m1 with a cell of a = b = 3.190(3) {\AA} and c = 5.945(6) {\AA}. The individual MoS2 layer consists of MoS6 octahedron sharing edge with each other. More surprisingly, the bulk 1T MoS2 crystals undergo a superconducting transition of Tc = 4 K, which is the first observation of superconductivity in pure 1T MoS2 phase.

Recently we reported an enhanced superconductivity in restacked monolayer TaS_2 nanosheets compared with the bulk TaS_2, pointing to the exotic physical properties of low dimensional systems. Here we tune the superconducting properties of this system with magnetic field along different directions, where a strong Pauli paramagnetic spin-splitting effect is found in this system. Importantly, an unusual enhancement as high as 3.8 times of the upper critical field B_{c2}, as compered with the Ginzburg-Landau (GL) model and Tinkham model, is observed under the inclined external magnetic field. Moreover, with the out-of-plane field fixed, we find that the superconducting transition temperature T_c can be enhanced by increasing the in-plane field and forms a dome-shaped phase diagram. An extended GL model considering the special microstructure with wrinkles was proposed to describe the results. The restacked crystal structure without inversion center along with the strong spin-orbit coupling may also play an important role for our observations., Comment: 21 pages, 4 figures, 1 table, Supplementary Information available upon request

We have grown single crystals of the iron-based ladder material BaFe_2S_3, which is superconductive under high pressure, adopting different conditions. By comparing the behaviors of these samples, it is found that the in situ annealing process can affect the crystal structure and the electrical transport, enhance the antiferromagnetic transition temperature, and reduce the extrinsic ferromagnetic component of the system. An in-depth analysis indicates that the crystal quality is improved by the in situ annealing in terms of reducing both the Fe deficiency and the Fe impurity in the samples. The improvement of the sample quality will facilitate the investigations on the intrinsic properties of this material., Comment: 6 pages, 3 figures, 1 table