1. Self-healing, adhesive, photothermal responsive, stretchable, and strain-sensitive supramolecular nanocomposite hydrogels based on host-guest interactions
- Author
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Chen, Shiying, Nie, Yixuan, Huang, Yingying, Yang, Yuxuan, Chen, Hongyi, and Zhang, Xiongzhi
- Subjects
Engineering and manufacturing industries ,Science and technology - Abstract
The development of multifunctional supramolecular nanocomposite hydrogels remains challenging. Here, the dynamic host-guest interactions involving the host molecule CB[8] and guest units were utilized to prepare [Fe.sub.3][O.sub.4] hybrid supramolecular nanocomposite hydrogels. The results showed that the hydrogels obtained possessed a porous structure. The CB[8]-modified [Fe.sub.3][O.sub.4] ([Fe.sub.3][O.sub.4]@CB[8]) nanoparticles served as cross-linkers in forming the network of hydrogels. By adjusting the [Fe.sub.3][O.sub.4]@CB[8] content, the mechanical properties of the hydrogels could be controlled. The tensile stress was measured at 160 kPa with a fracture strain of 1380%, while the compression stress was 230 kPa at 70% compression strain. The self-healing efficiency of the hydrogels at room temperature reached 95% after 24 h. The as-obtained hydrogels show strain sensitivity and have the potential for applications in detecting elbow and finger movements. Our supramolecular nanocomposite hydrogels exhibit multiple functions, including self-healing, injectability, photothermal responsiveness, and conductivity, making them suitable for integration into flexible electronics. Highlights * [Fe.sub.3][O.sub.4]@CB[8] nanoparticles serve as cross-linkers for the nanocomposite hydrogels. * CB[8] based host-guest interactions enable hydrogels to self-heal. * [Fe.sub.3][O.sub.4]@CB[8] endow hydrogels with stretchability and photothermal responsiveness. * Hydrogels exhibit injectability, NIR responsiveness, and conductive ability. KEYWORDS host-guest interactions, nanocomposite, self-healing, supramolecular hydrogels, 1 | INTRODUCTION Hydrogels are 3D crosslinked polymer networks formed by either chemical or physical crosslinking, which can hold a large amount of water. (1) Hydrogels have been extensively studied [...]
- Published
- 2024
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