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The fate of legacy and emerging flame retardants are poorly reported in developing countries, including India. Also, the positive matrix factorization (PMF) application-based source apportionment of these pollutants is less comprehensive. This study analyzed the contamination level and sources of 25 flame retardants in dust from India's central Indo-Gangetic Plain (Patna city) using the PCA and PMF model. Dust samples were collected from various functional areas of indoor (n = 22) and outdoor (n = 16) environments. The sum of four groups of FRs in indoor dust (median 8080 ng/g) was 3-4 times greater than the outdoor dust (median 2410 ng/g). The novel-brominated flame retardants (NBFRs) and organophosphate esters (OPFRs) were more dominant than polybrominated diphenyl ethers (PBDEs), indicating the influence of worldwide elimination of PBDEs. The median concentration of ∑NBFRs in indoor and outdoor dust was 1210 ng/g and 6820 ng/g, while the median concentration of ∑OPFRs was measured to be 383 ng/g and 1210 ng/g, respectively. Likewise, ∑

The application of agrochemicals into the environmental matrix has sluggishly degraded the quality of their original form. Pesticide consumption in the agricultural sector has been used for the quantity production of crops however, now considered as a culprit for the quality crops. Lands that once provided ample crops of good quality are now facing a case of severe damage impacting their crop quality. The prime need is to reclaim these contaminated matrices. For the same, an eco-friendly approach should be adopted. One such approach is the application of biochar for pesticide sorption. Biochar is a carbon-rich, stabilized product acquired when biomass undergoes pyrolysis at 200-650˚C. It is known for sequestration ability and mitigation of environmental contaminants. Its properties (surface area, pore size, ash contents, and functional groups) determine the potential for sorption. Biochar when modified is most effective for the sorption mechanism. For instance, rice straw biochar when treated with phosphoric acid (T-RSBC) showed stronger adsorption capacity for sorption in waste water effluent. Corn straw when doped with phosphorus functional groups was highly effective for adsorption of triazine pesticide from water. Other biochar that could remove pesticides are corn cob and corn starch. Activated coconut shell biochar showed the highest adsorption capacity for diazinon removal from water than other modified coconut shell biochar. Plant biochar (pine needle, oak wood, corn stover) having a high content of lignin have better properties such as large surface areas (112-642 m g ) and macropores (0.06- 1.90 cm g ) that increase the sorption capacity of pesticides in soils than animal and cellulose-based biochar. This review paper aims to evaluate the role of biochar in the sorption of pesticides from soil and water.

Raising population, deteriorating environmental conditions and limiting natural resources to handle the key environmental health problems have critically affected human health and the environment. Policy makers and planners in Nepal are more concerned today than at any other time in the past about the deterioration of the environmental condition. Therefore, understanding the connection between pollution and human wellbeing is fundamental endeavors to control pollution exposures and secure human wellbeing. This ability is especially critical for countries like Nepal where the issues of environmental pollution have customarily taken a second place to request for economic development. In this study, spatial distribution and sources of 12 heavy metals (HMs) were investigated in surface soils (n = 24) and house dust (n = 24) from four major urban areas of Nepal in order to mark the pollution level. Additionally, a health risk was estimated to establish the link between HMs pollution and human health. Results showed that the median concentration of Ag, Cd, Co, Cr, Cu, Ni, Pb, Sb, Mn and Zn in soil and dust were 2–13 times greater than the background value. The As, Zn, Cu, Cd, and Pb showed a relatively higher spatial variability in soil and dust. Zn was the most abundant metal measured in dust and soil and accounted for 59% and 55% of ∑7HMs, respectively. The HMs in soil and dust were poorly correlated with total organic carbon (TOC) and black carbon (BC), suggesting little or no influence on HMs contamination. Source analysis study indicated the distribution of Cr, Ni, Sb, Ag, Pb, Cu, and Zn in soil and dust are mainly affected by anthropogenic sources, particularly traffic emissions, industrial source, and domestic households materials, while Co, Fe, As, Mn and Cd were from natural sources. The estimated carcinogenic risk (CR) of HMs in soil and dust exceeded the acceptable level of human exposure, recommending significant CR to the local population.

Although the fate and behavior of parent polycyclic aromatic hydrocarbon (PAHs) have been documented worldwide, the information about PAH-derivatives (NPAHs and OPAHs) is limited, especially in developing countries, including Nepal. Moreover, the greater parts of the investigations concentrating on NPAHs/OPAHs are on the air (borne) particulate phase only; and are primarily based on a limited number of compounds analyzed. Little is known about the environmental concentration, fate, and behavior of NPAHs and OPAHs in air gas phase and dust. In this study, the concentration, fate, spatial distributions of 26 NPAHs and 3 OPAHs in the air (n = 34) and dust (n = 24) were investigated in suspected source area/more densely populated areas of Nepal. Four critical source areas in Nepal were considered as it was conjectured that the urban areas are more prone to NPAH/OPAH contamination due to the high density of automobiles and industrial activities. Overall, the measured ∑19NPAHs in air and dust were 5 and 2 times lower than their parent-PAHs, respectively. Highest levels of NPAHs/OPAHs were measured in Birgunj, followed by Kathmandu, Biratnagar, and Pokhara, respectively, while Biratnagar showed the highest level of ∑OPAHs. 3-Nitrodibenzofuran (3-NDBF) was the most abundant NPAHs measured both in air and dust, whereas 9-Fluorenone (9-FLUONE) prevailing OPAHs. The molecular diagnostic ratio (MDR) of 2-Nitrofluoranthene/1-Nitropyrene indicated the contribution from secondary emission via photochemical reaction as the primary source of NPAHs, while solid fuel combustion and crop residue burning were identified as the essential sources of OPAHs. The human exposure to NPAH/OPAH through the different route of intake suggested dermal contact via dust as the primary pathway of NPAH/OPAH exposure for both adult and children. However, other routes of exposure, for instance, dietary intake or dermal absorption via soil may still be prominent in case of Nepal.

Although several global/regional studies have detailed the high level of polycyclic aromatic hydrocarbons in urban areas worldwide, unfortunately, Nepal has never been part of any global/regional regular monitoring plan. Despite few sporadic studies exist, the systematic monitoring and integrated concentration of PAHs in urban region of Nepal are lacking. In this study, the concentrations, sources, and health risk assessment of 16 PAHs in air (n = 34) were investigated in suspected source areas/more densely populated regions of Nepal. Four potential source areas in Nepal were focused as it was conjectured that urban centers in plain areas (Birgunj and Biratnagar) would possibly be more influenced by PAHs as a result of intense biomass/crop residue burning than those in hilly areas (Kathmandu and Pokhara). The overall concentrations of ∑16PAHs ranged from 4.3 to 131 ng/m3 (median 33.3 ng/m3). ∑16PAH concentrations in plain areas were two folds higher than those in hilly areas. PHE was the most abundant followed by FLUA, PYR, and NAP, which accounted for 36%, 15%, 12%, and 9% of ∑16PAHs, respectively. Principal component analysis confirmed that PAHs in highly urbanized areas (Kathmandu and Pokhara) were related to diesel exhausts and coal combustion, while PAHs in less urbanized regions (Birgunj and Biratnagar) originated from biomass and domestic wood combustions. Furthermore, in the urban areas of Nepal, vehicular emission could also influence atmospheric PAHs. The lifetime cancer risk per million populations due to PAH exposures was estimated to be higher for plain areas than that for hilly areas, suggesting a relatively greater risk of cancer in people living in plain areas.

Urban centers have turned to be the provincial store for resource consumptions and source releases of different types of semi-volatile organic compounds (SVOCs) including polycyclic aromatic hydrocarbons (PAHs), bringing about boundless environmental pollutions, among different issues. Human prosperity inside urban communities is unambiguously dependent on the status of urban soils and house dusts. However, environmental occurrence and sources of release of these SVOCs are challenging in Nepalese cities, as exceptionally very limited data are accessible. This motivated us to explore the environmental fate, their source/sink susceptibilities and health risk associated with PAHs. In this study, we investigated the contamination level, environmental fate and sources/sink of 16 EPA's priority pollutants in surface soil and house dusts from four major cities of Nepal. Additionally, the toxicological effect of individual PAH was studied to assess the health risk of PAHs. Generally, the concentrations of ∑16PAHs in surface soil were 1.5 times higher than house dust, and ranged 767–6770 ng/g dry weight (dw) (median 1810 ng/g dw), and 747–4910 dw (median 1320 ng/g dw), respectively. High molecular weight-PAHs both in soil and dust were more abundant than low molecular weight-PAHs, suggesting the dominance of pyrogenic source. Moderate to weak correlation of TOC and BC with PAHs in soil and dust suggested little or no role of soil organic carbon in sorption of PAHs. Source diagnostic ratio and principal component analysis indicated fossil fuel combustion, traffic/vehicular emissions and combustion of biomass are the principal sources of PAHs contamination in Nepalese urban environment. The high average TEQ value of PAHs in soil than dust suggested high risk of soil carcinogenicity compared to dust.

While various investigations have been driven on polybrominated diphenyl ethers (PBDEs) and other flame retardants (FRs) in different framework around the world, information about contamination and fate of PBDEs and other FRs in developing countries especially in the Indian subcontinent is uncommon. Nepal being located in the Indian subcontinent, very little is known about contamination level of semi-volatile organic pollutants discharged into the environment. This motivated us to investigate the environmental fate of halogenated flame retardant (HFRs) in Nepalese condition. In this study, we investigated the concentration, fate, and sources of 9 PBDEs, 2 dechlorane plus isomers (DPs), and 6 novel brominated flame retardants (NBFRs). Moreover, air-soil exchange and soil-air partitioning were also evaluated to characterize the pattern of air-soil exchange and environmental fate. In general, the concentrations of NBFRs in soil were more prevalent than PBDEs and DPs, and accounted 95% of ∑HFRs. By and large, the concentrations of NBFRs and DPs were measured high in Kathmandu, while PBDEs level exceeded in Pokhara. Principal component analysis (PCA) study suggested contributions from commercial penta-, octa-, and deca-BDEs products and de-bromination of highly brominated PBDEs as the significant source of PBDEs. Likewise, low fanti ratio suggested DPs in soil might have originated from long-range atmospheric transport from remote areas, while high levels of decabromodiphenyl ethane (DBDPE) in soil were linked with the use of wide varieties of consumer products. The estimated fugacity fraction (ff) for individual HFR was quite lower (

Despite soil being the major terrestrial environmental reservoir and one of the significant sinks for many hydrophobic organic compounds including organophosphate ester flame retardants (OPFRs), limited information is available about concentration and fate of OPFRs contamination in urban soil in general and especially in case of Nepal. This study investigates the environmental concentration, spatial distribution and source apportionment of eight OPFRs in surface soil (n = 28) from four major cities of Nepal with special interest on air-soil exchange. Overall, significantly high concentrations of ∑ 8 OPFR were measured in soil ranging from 25–27,900 ng/g dw (median 248 ng/g dw). In terms of compositional pattern, tris(methyl phenyl) phosphate (TMPP) was the most abundant phosphorus chemical in soil, followed by tris(2-chloroisopropyl) phosphate (TCIPP), and accounted for 35–49% and 8–25% of ∑ 8 OPFRs, respectively. The high level of these OPFRs was attributed to local sources as opposed to transboundary influence from remote areas. A Spearman's rank correlation analysis exhibited weak correlation of ∑ 8 OPFRs with TOC ( Rho = 0.117, p Rho = 0.007, p 8 OPFRs. The fugacity fraction ( ff ) results indicated a strong influence of soil contamination on atmospheric level of OPFRs via volatilization.

Although, many biomass burning (BB) emissions products (particulate matter and trace gases) are believed to be trans-boundary pollutants that originates from India and China (the two most populous countries in Asia), the information about BB emission and related contents is limited for Indo-China Peninsula (ICP) region. This motivated us to review this region pertaining to BB emission. The main objective of the review is to document the current status of BB emission in ICP region. In order to highlight the impact of BB on regional air quality and global climate change, the role of BB emission in ICP region is also discussed. Based on the available literature and modeling simulations studies, it is evidenced that ICP is one of the hotspot regional source for aerosols in terms of BB emissions. In addition, regional emissions through BB have significant implications for regional air quality especially in the neighboring countries such as China, Taiwan and India. Our assessment highlight that there is still a general lack of reliable data and research studies addressing BB related issues in context of environmental and human health. There is therefore a critical need to improve the current knowledge base, which should build upon the research experience and further research into these issues is considered vital to help inform future policies/control strategies.

Nepal is a landlocked country located between world's two most populous countries-India and China where high level of organochlorines pesticides has been reported from multi-environmental matrices. In this study, we investigated the occurrence, distributions and profile of selected OCP chemicals in surface soil samples (N = 72) from four major cities of Nepal. Overall, the sum of total OCPs in soil ranged from 20 to 250 ng/g with Biratnagar being the most polluted site in Nepal. DDTs and endosulfans were the most abundant OCP chemicals in soil samples. The concentration of DDTs ranged from 8 to 230 ng/g, 8-56 ng/g, 8-63 ng/g, and 8-27 ng/g in surface soil, while endosulfans were in the range of 2.9–3.3 ng/g, 2.8–8.7 ng/g, 2.8–3.4 ng/g, 2.8–3.2 ng/g in Biratnagar, Kathmandu, Pokhara and Birgunj, respectively. The isomeric ratio of DDT and their metabolites suggested the ongoing usages of technical DDT as well as dicofol in this region. Lower ratio of α/β-endosulfan indicated past application of endosulfans in Nepal. HCHs were less detected OCPs in soil sample accounting only 4–9% of ∑ OCPs. The isomeric ratio of α-/γ-HCH indicated that the HCHs may be originated from mixed source of technical HCH as well as lindane use. Scattered plot of TOC and BC showed they were weakly and positively related with concentration of OCPs in soil. Health risk assessment modeling study of OCPs in soil suggested moderate cancer risk with ingestion being the most potential pathway of OCPs exposure.

River Brahmaputra (RB) from the outer Himalayan Range and River Hooghly (RH), a distributary of River Ganga, are the two largest transboundary perennial rivers supplying freshwater to the northeastern and eastern states of India. Given the history of extensive usage of organochlorine pesticides and increasing industrialization along the banks of these rivers we investigated selected organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in the surface water of River Brahmaputra and River Hooghly. Geomean of ΣOCPs (53 ng L −1 ) and Σ 19 PCBs (108 ng L −1 ) was higher in RH compared with geomean of ΣOCPs (24 ng L −1 ) and Σ 19 PCBs (77 ng L −1 ) in RB. Among OCPs, γ -HCH showed maximum detection frequency in both the rivers reflecting ongoing lindane usage. DDT and endosulfan residues were observed at specific locations where past or ongoing sources exist. Elevated concentrations of heavier congeners (penta-hepta) were observed in those sites along RH where port and industrial activities were prevalent including informal electronic waste scrap processing units. Furthermore along River Hooghly PCB-126 was high in the suburban industrial belt of Howrah district. PCBs were found to be ubiquitously distributed in RB. Atmospheric transport of tri- and tetra-PCB congeners from the primary source regions might be a major contributor for PCBs in RB. Heavier congeners (penta-nona) in the urban centers of RB were likely due to industrial wastewater runoff from the oil refineries in the Brahmaputra valley. Σ 19 PCBs concentrations in this study exceeded the USEPA recommended limit for freshwater. Ecotoxicological risk assessment showed the possibility of adverse impact on the organisms in the lower trophic level due to DDT and lindane contamination. Impact of endosulfan on fishes might be of considerable concern for aquatic environment.